• Title/Summary/Keyword: superconducting transition temperature

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New MOD solution for the preparation of high $J_c$ REBCO superconducting films (고특성 REBCO 초전도 박막 제조를 위한 새로운 MOD 전구 용액 제조)

  • Kim, Byeong-Joo;Hong, Gye-Won;Lee, Hee-Gyoun
    • Proceedings of the KIEE Conference
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    • 2005.07c
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    • pp.2001-2003
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    • 2005
  • Various organic acid were used in order to prepare new metalorganic deposition solution for high quality $REBa_2Cu_3O_{7-{\delta}}$ (RE=Y, Eu, Gd) films. Prepared fluorine free MO precursor solution was coated on single crystal (001) $LaAlO_3$ (LAO) by dip coating method. Processing parameters such as oxygen partial pressure, water vapor, ramping rate and pyrolysis temperature etc havebeen controlled in order to make high $J_c$ films with a good epitaxial relationship with substrate. 0.5 micron-thick film was obtained by single coating and no crack appeared after calcination. Oxygen partial pressure was varied in the range of $100{\sim}1,000 ppm$ and conversion heat treatment was carried out at the temperature of $725{\sim}765^{\circ}C$. A critical transition temperature $(T_{c0})$ of 90K and a critical transport current density $(J_c)$ of $>0.5MA/cm^2$ (77K and self-field) were demonstrated for the YBCO film on (001) oriented LAO substrates with a thickness of 0.5 micron. $I_c$ was determined by utilizing a transport measurement. SEM and XRD investigations confirmed that films were grown epitaxially onto the LAO single crystal substrate. It is thought that fluorine free new MOD solutionis promising for high quality REBCO films.

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The Analysis of Quench Protection System through Thermo-Electrodynamics of Resistive Transition in SC Magnet (초전도자석내의 국부적 상변이에 대한 열적.전기역학적 해석 및 퀜치보호시스템의 설계 및 특성해석)

  • Chu, Y.;Bae, J.H.;Kim, H.M.;Jang, M.H.;Joo, M.S.;Ko, T.K.;Kim, K.M.;Jeong, S.K.
    • Proceedings of the KIEE Conference
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    • 1997.07a
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    • pp.86-88
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    • 1997
  • The detection of the normal zones in the coil winding and the initiation of the proper dump sequence have been one of the most important areas in the superconducting magnet technology. In this paper, the process to derive optimal dump sequence has been investigated through quench simulation and analysis of magnetically coupled superconducting magnet system. The magnet terminal voltage and maximum temperature rise in the quench initiated point are calculated with respect to various input variables such as operation current, dump resistance, etc. The experimental system is comprised of sc solenoidal coil, data aquisition device, external circuit breakers and dump resistor. The quench behavior of the magnet(e.g., temperature profile and the voltage signal) was measured. From this results, theoretical predictions were found to coincide with the experimental observations.

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Transport properties of polycrystalline TaNx thin films prepared by DC reactive magnetron sputtering method

  • Hwang, Tae Jong;Jung, Soon-Gil
    • Progress in Superconductivity and Cryogenics
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    • v.23 no.2
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    • pp.1-5
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    • 2021
  • We have investigated the electrical transport properties of polycrystalline tantalum nitride (TaNx) films. Various compositions of tantalum (nitride) thin films have been deposited on SiO2 substrates by reactive DC magnetron sputtering while changing the ratio of nitrogen partial pressure. The substrate temperature was maintained at 283 K during deposition. X-ray diffraction analyses indicated the presence of α-Ta and β-Ta phases in the Ta film deposited in pure argon atmosphere, while fcc-TaNx phases appeared in the sputtering gas mixture of argon and nitrogen. The N/Ta atomic ratio in the film increased ranging from 0.36 to 1.07 for nitrogen partial pressure from 7 to 20.7%. The superconducting transition temperatures of the TaNx thin films were measured to be greater than 3.86 K with a maximum of 5.34 K. The electrical resistivity of TaNx thin film was in the range of 177-577 𝜇Ωcm and increased with an increase in nitrogen content. The upper critical filed at zero temperature for a TaN0.87 thin film was estimated to exceed 11.3 T, while it showed the lowest Tc = 3.86 K among the measured superconducting TaNx thin films. We try to explain the behavior of the increase of the residual resistivity and the upper critical field for TaNx thin films with the nitrogen content by using the combined role of the intergrain Coulomb effect and disorder effect by grain boundaries.

Effect of Cu substitution on Superconductivity in $(Ru_{1-x}Cu_x)Sr_2(Eu_{1.34}Ce_{0.66})Cu_2O_z$ System (Cu 치환에 따른 $(Ru_{1-x}Cu_x)Sr_2(Eu_{1.34}Ce_{0.66})Cu_2O_z$ 계의 초전도 특성)

  • Lee, H.K.
    • Progress in Superconductivity
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    • v.11 no.1
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    • pp.67-71
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    • 2009
  • The effect of Cu substitution on the structural and superconducting properties of the $(Ru_{1-x}Cu_x)Sr_2(Eu_{1.34{\cdot}}Ce_{0.66})Cu_2O_z$ system with x = 0, 0.25 and 0.5 prepared under ambient pressure have been investigated. The X-ray diffraction patterns indicated that the Ru ions are replaced by the Cu ions. It is found that the Cu substitution for Ru significantly reduces the ferromagnetic component of field-cooled magnetic susceptibility, but results in a small change in diamagnetic onset transition temperature of zero-field-cooled magnetic susceptibility. In contrast to the Ru $Sr_2(Eu_{1.34{\cdot}}Ce_{0.66})Cu_2O_z$, bulk Meissner effect is observed in the field-cooled magnetization measurements of the Cu doped samples. The experimental results are discussed in connection with the spontaneous vortex phase interpretation.

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Preparation and Characterization of Bi-Sr-Ca-Cu-O Superconductor Thin Film by Metal Organic Chemical Vapor Deposition (MOCVD법을 이용한 Bi-2212계 초전도박막 제조 및 특성에 관한 연구)

  • 장건익;김호인;박인길;김호기
    • Journal of the Korean Ceramic Society
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    • v.31 no.10
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    • pp.1123-1132
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    • 1994
  • Bi-Sr-Ca-Cu-O superconductor thin films were prepared on MgO and LaAlO3 substrates by MOCVD technique. The films deposited on MgO and LaAlO3 substrates became superconducting at 64 K and 70 K respectively. The measured critical current density of thin film deposited on LaAlO3 substrate was around 104 A/$\textrm{cm}^2$. After annealing at $700^{\circ}C$ for 3 hours, the critical transition temperature(Tc) of films deposited on LaAlO3 was changed from 70 K to 74 K.

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A Simple a.c. Magnetic Susceptometer Using self-inductance Measurement of a Single Coil Mounted on a Cryostat Cold Head

  • Dho, Joong-Hoe
    • Journal of Magnetics
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    • v.13 no.4
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    • pp.177-181
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    • 2008
  • A very simple a.c. magnetic susceptometer for use in a helium closed cycle cryostat is reported in this paper. This simple setup has only a single bobbin-less copper coil, instead of the primary coil and two secondary coils typically used in mutual-inductance types. The single bobbin-less copper coil is directly mounted on the cryostat cold head. A sample is attached on the inside wall of the copper coil using a thermal contact material and its a.c. magnetic susceptibility is obtained from the measurement of the self-inductance of the sample coil using an LCR meter or an impedance analyzer. Experimental details are described and illustrative measurements on magnetic and superconducting materials as a function of temperature are included. The performances and limitations of this simple a.c. magnetic suceptometer are also discussed.

High Tc Superconductor, YBa2 Cu3 O7-$\delta$; (I) Its Preparation and Physicochemical Characterization (고온 초전도체 YBa2 Cu3 O7-$\delta$;(1) 합성 및 물리화학적 특성 연구)

  • 최진호;변송호;홍승태;정덕영;최석용;김배환;김진태;노동윤;유한일
    • Journal of the Korean Ceramic Society
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    • v.25 no.2
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    • pp.154-160
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    • 1988
  • Almost single phase of Y1Ba2Cu3Ox, which exhibits the onset of superconducting transition at 90K, has been prepared via a conventional ceramic processing route followed by an anneal for a period of 10 hours at 45$0^{\circ}C$ in an atmosphere of 100% O2. The mean value for the oxygen content has been determined as x=6.85$\pm$0.02 by an iodometric titration technique. X-ray photoemission spectra are found to be consistent with a mixture of the d8(Cu3+) and d9(Cu2+) as the ground state and reveals that the local concentration of Cu3+ decreases with depth from the surface where x corresponds to 7.0. This is explained as being associated with the intercalation of oxygen during cooling from the annealing temperature.

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YBCO coated conductors fabricated by a MOCVD (metal organic chemical vapor deposition) method (MOCVD (metal organic chemical vapor deposition)법으로 제조한 YBCO 초전도 coated conductors)

  • 김찬중;전병혁;최준규;선종원;김호진
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2003.10a
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    • pp.21-23
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    • 2003
  • MOCVD method is one of promising techniques which can fabricate YBCO coated conductors in a low Price A continuous reel-to-reel MOCVD device using a dispersed solid source was designed and manufactured. YBCO films were deposited on various substrates of metallic silver, (100) MgO and SrTiO3 single crystals. The chemical composition of the metal organic sources was changed to optimize the processing condition associate to the deposition of the stoichiometric Y3a2Cu3O7-y. We report the superconducting transition temperature, surface morphology and chemical composition of the YBCO film surfaces.

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Effects of the size of Mg powder on the formation of MgB2 and the superconducting properties

  • Kim, D.N.;Jun, B.H.;Park, S.D.;Kim, C.J.;Park, H.W.
    • Progress in Superconductivity and Cryogenics
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    • v.18 no.4
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    • pp.9-14
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    • 2016
  • The effect of the size and shape of magnesium(Mg) powder on the formation of $MgB_2$ and the critical current density($J_{c,}$) of $MgB_2$ bulk was studied. As a precursor for the formation of $MgB_2$, Mg and $MgB_4$ powder, which was synthesized through the reaction of boron (B) with Mg powders, was used. $MgB_4$ was mixed with Mg powders of various sizes, pressed into pellets and heat-treated at $650^{\circ}C-750^{\circ}C$ in flowing argon gas. The XRD analysis of the heat-treated $MgB_2$ samples showed that the volume fraction of $MgB_2$ was the highest as 92.74 % when spherical Mg powder with an average size of $25.7{\mu}m$ was used, whereas the volume fraction was the lowest as 79.64 % when plate-like Mg powder with a size of $34.1{\mu}m$ was used. The superconducting transition temperature ($T_c$) of $MgB_2$ was not sensitive to the characteristics of the Mg powders used. All of the prepared $MgB_2$ samples showed a high $T_c$ of 38.3 K and a small superconducting transition width of 0.2 K-0.5 K. $J_c$ (5 K and 1 T) of $MgB_2$ was the highest as $3.93{\times}10^4A/cm^2$ when spherical Mg powder with a size of $25.7{\mu}m$ was used, whereas $J_c$ was the lowest as $2.18{\times}10^4A/cm^2$when plate-like Mg powder with a size of $34.1{\mu}m$ was used. The relationship between the $J_c$ of $MgB_2$ and the characteristics of the Mg powders used was explained in terms of the volume fraction of $MgB_2$ and the apparent density of the $MgB_2$ pellets.

Development of Optical Signal Transmission for the KSTAR Project Pertaining to Instrumentation and Control of the Neutral Beam Test Stand at KAERI

  • Jung, Ki-Sok;Oh, Byung-Hoon
    • KIEE International Transaction on Electrical Machinery and Energy Conversion Systems
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    • v.5B no.3
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    • pp.289-295
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    • 2005
  • Instrumentation and Control (I&C) of the Neutral Beam Test Stand (NB- TS) Facility at the Korea Atomic Energy Research Institute (KAERI) for the Korea Superconducting Tokamak Advanced Research (KSTAR) project has been underway since the start of the project to answer the diverse requests arising from the various facets of the development and construction phases of the project. Optical signal transmission constitutes a significant portion of I&C works and has been performed for the entirety of the project. During the NB- TS construction and related experiments, significant achievements to a more accurate as well as more refined optical signal transmissions have been made. Examples of those I&C works that utilized the optical signal transmission are the Langmuir probe signal transmission, gradient grid current signal transmission, gas flow control and signal transmission, ion source temperature measurement, beam line component temperature monitoring, and coolant flow signal transmission, etc. These optical signal transition provisions are now performing part of the indispensable functions for the proper operation of the NB- TS facility. Attained experience and expertise are expected to be well applied to the upcoming main neutral beam injection (NBI) system construction for the KSTAR project.