• Progress in Superconductivity
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• 제12권2호
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• pp.88-92
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• 2011

특수합금 등 금속분말을 이용하는 분말압연 공정을 적용하여 $MgB_2$ 판재를 제조하고 공정변수에 대한 특성을 조사하였다. 압연롤 간격 0.7 mm와 회전속도 0.7 rpm(~120 cm/min) 조건에서 두께 ~1 mm, 폭 ~100 mm, 그리고 길이 수 cm 크기의 $MgB_2$ 판재를 성공적으로 제조하였으며, 측정된 최고 밀도는 2.05 g/$cm^3$이고 이론 값 대비 약 78 %로 계산되었다. 분말압연 공정을 통해 최종 선재의 크기(특히 두께 측면에서)에 가깝게 공정을 시작할 수 있고 높은 충진 밀도를 유지할 수 있으므로 초전도 선재의 특성 향상과 더불어 생산 비용, 생산속도 측면에서도 매우 유리한 방법이 될 것이다. 또한 자기장하 $MgB_2$ 초전도 특성 향상을 위해 자속 고정점 역할을 할 다양한 도핑 물질(분말 형태 또는 액체 형태 등)을 첨가하는 공정에 있어서 도 본 분말압연 공정을 쉽게 적용될 수 있다.

• 한국초전도ㆍ저온공학회논문지
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• 제21권2호
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• pp.40-44
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• 2019

In this study, the effects of the compaction method for (Mg+2B) powders on the apparent density and superconducting properties of $MgB_2$ bulk superconductor were investigated. The raw powders used in this study were nano-sized boron (B) and spherical magnesium (Mg). A batch of a powder mixture of (Mg+2B) was put in a steel mold and uniaxially pressed at 1 ton or 3 tons into pellets. Another batch of the powder mixture was uniaxially pressed at 1 ton and then pressed isostatically at $1800kg/cm^2$ in the water chamber. All pellets were heat-treated at $650^{\circ}C$ for 1 h in flowing argon gas for the formation of $MgB_2$. The apparent density of powder compacts pressed at 3 ton was higher than that at 1 ton. The cold isostatic pressing (CIP) in a water chamber allowed further increase of the apparent density of powder compacts, which influenced the pellet density of the final products ($MgB_2$). The compaction methods (uniaxial pressing and CIP) did not affect the formation of $MgB_2$ and superconducting critical temperature ($T_c$) of $MgB_2$, but affected the critical current density ($J_c$) of $MgB_2$ significantly. The sample with the high apparent density showed high $J_c$ at 5 K and 20 K at applied magnetic fields (0-5 T).

• 대한전기학회:학술대회논문집
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• 대한전기학회 1991년도 하계학술대회 논문집
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• pp.201-203
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• 1991

T. Kanal et al, were studied the superconducting properties in Bi system by mechanical grinding, in which the authors found that the samples ground degraded from the superconducting phases to nonsuperconducting phases. To obtain more information of the practical application in Bi system with high-Tc phase in this paper, these samples mechanically ground and the high-Tc phase properties of grinding powder samples were investigated.

• 대한전기학회논문지
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• 제43권6호
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• pp.958-964
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• 1994

To study on the superconducting properties with cooling conditions, silver-sheathed Bi-Pb-Sr-Ca-Cu-O wires fabricated by the powder-in-tube method. The wires cooled down in the furnace, air and liquid NS12T after sintering at 840$^{\circ}C$ Critical current density of sample cooled in the furnace is 5.1${\times}$10S03TA/cmS02T and sample cooled in the air is 40A/cmS02T at 77K, zero magnetic field. The latter is very low critical current density of Bi system. 2223 high-Tc superconducting phase of sample cooled in the air was distroyed. Properties of sample cooled down in the liquid nitrogen is the same as cooled in the furnace.

• E2M - 전기 전자와 첨단 소재
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• 제9권6호
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• pp.600-604
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• 1996

High-T$_{c}$, superconducting wire is very important element for the application of electrical power systems. But it is very difficult to develope the long high T, wire with excellent properties. BiSrCaCuO multi-layer tapes are fabricated by a rolling method and pressing method sintered for several step at 840.deg. C. The critical current densities of 637 filament multi-layer tapes sintering 100 hours fabricated by the rolling method and pressing method are 1.3*10$^{4}$ A/cm$^{2}$ and 5.5*10$^{3}$ A/cm$^{2}$. The critical cur-rent densites of multi-layer tapes made by rolling method are found to be better than those fabricated by the powder-in-tube method and pressing process. As result, the rolling method is the best way to fabricated the multi-layer filament.t.

• 한국초전도저온공학회:학술대회논문집
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• 한국초전도저온공학회 2000년도 KIASC Conference 2000 / 2000년도 학술대회 논문집
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• pp.85-88
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• 2000

Cu-free Bi-Sr-Ca-O powder mixtures were screen-printed on Cu tapes and heat-treated at 850-$870^{\circ}C$ for several minutes in air, oxygen, nitrogen and low oxygen pressure. Cu-free precursors were composed of Bi_{x}$SrCaO_{y}$ (x=1.2-2). In order to obtain the optimum heat-treatment condition, we studied on an effect of the precursor composition, the printing thickness and the heat-treatment atmosphere on the superconducting properties of Bi2212 films and the reaction mechanism of their rapid formation. Microstructures and phases of thick films were analyzed by optical microscope and XRD. The electric properties of superconducting films were examined by the four probe method. At heat-treatment temperature, the thick films were in a partially molten state by liquid reaction between CuO in the oxidized copper tape and the precursors which were printed on Cu tapes.

• Progress in Superconductivity
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• 제10권1호
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• pp.17-22
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• 2008

We have examined the effect of ball-milling on the superconducting properties of $MgB_2$ doped with C. The ball-milling of pre-reacted $MgB_2$ powder was carried out in dry or wet state using C or diethylenetriamine ($C_{4}H_{13}N_3$) as additives. The diethylenetriamine, whose chemical formula contains no oxygen, was chosen to avoid an excess oxidation during doping. The superconducting transition temperature (Tc) of the ball-milled or doped $MgB_2$ powders was only slightly smaller than that of undoped $MgB_2$. The critical current density (Jc) of the highly ball-milled $MgB_2$ was higher than that of C-doped $MgB_2$. The addition of diethylenetriamine was detrimental to Jc, although Tc was almost unchanged.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2003년도 춘계학술대회 논문집 센서 박막재료 반도체 세라믹
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• pp.53-56
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• 2003

The properties of YBCO thick film coated on Ag wire with YBCO powder is deeply affected by cracking on its surface which was deposited in organic solution by electrophoretic method. YBCO superconducting thick films were prepared on Ag wire$({\Psi}0.8mm)$ by electrophoresis in acetone with added PEG (Poly-Ethylene Glycol, 3% in Acetone), 1ml for being crack-free. The surface properties of YBCO superconducting wire was evidently improved with adding PEG. Added PEG which molecular weight is 600, 1000, 3400 was affected with variation of deposition voltages to the surface properties of samples. As a result, with adding PEG (its molecular weight is 3400), YBCO superconducting wire was better on its surface properties.

• 한국전기전자재료학회논문지
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• 제34권6호
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• pp.461-465
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• 2021

A diffusion heat treatment process for YBa₂Cu₃O_7-y bulk superconductor in a Gd₂O₃ powder was attempted. As a result of measuring the critical temperature of the superconducting bulk, there was no change in the superconducting transition temperature as the Gd particles diffused into the YBa₂Cu₃O_7-y lattice, resulting in dense microstructure. As a result of measuring the critical current, the critical current density (J_c) of the superconducting bulk having treated by the Gd thermal diffusion treatment at 0 T increased to 3×10⁴ A/cm² at 0 T, which was higher than that of the superconducting bulk without thermal diffusion treatment. The surface magnetic force of the superconducting bulk with Gd thermal diffusion treatment was observed at the center of the superconducting bulk with the maximum trapped magnetic force (Hmax) of 1.51 kG. This result means that the Gd thermal diffusion treatment contributes to improving the critical current density Jc of YBa₂Cu₃O_7-y, and it is believed that Gd particles migrating into the superconducting bulk through thermal diffusion either fill the surface pores of YBa₂Cu₃O_7-y superconductors or act as a flux pinning center.

• 한국초전도ㆍ저온공학회논문지
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• 제19권1호
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• pp.22-25
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• 2017

Steel slag has been considered as an industrial waste. A huge amount of slag is produced as a byproduct and the steel slag usually has been dumped in a landfill site. However the steel slag contains valuable resources such as iron, copper, manganese, and magnesium. Superconducting magnetic separation has been applied on recovery of the valuable resources from the steel slag and this process also has intended to reduce the waste to be dumped. Cryo-cooled Nb-Ti superconducting magnet with 100 mm bore and 600 mm of height was used as the magnetic separator. The separating efficiency was evaluated in the function of magnetic field. A steel slag was ground and analyzed for the composition. Iron containing minerals were successfully concentrated from less iron containing portion. The separation efficiency was highly dependent on the particle size giving higher separating efficiency with finer particle. The magnetic field also effects on the separation ratio. Current study showed that an appropriate grinding of slag and magnetic separation lead to the recovery of metal resources from steel slag waste rather than dumping all of the volume.