• Title/Summary/Keyword: subsequent rate

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Effect of Pre-Cycling Rate on the Passivating Ability of Surface Films on Li4Ti5O12 Electrodes

  • Jung, Jiwon;Hah, Hoe Jin;Lee, Tae jin;Lee, Jae Gil;Lee, Jeong Beom;Kim, Jongjung;Soon, Jiyong;Ryu, Ji Heon;Kim, Jae Jeong;Oh, Seung M.
    • Journal of Electrochemical Science and Technology
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    • v.8 no.1
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    • pp.15-24
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    • 2017
  • A comparative study was performed on the passivating abilities of surface films generated on lithium titanate (LTO; $Li_4Ti_5O_{12}$) electrodes during pre-cycling at two different rates. The surface film deposited at a faster pre-cycling rate (i.e., 0.5 C) is irregularly shaped and unevenly covers the LTO electrode. Owing to the incomplete coverage of the protective film, this LTO electrode exhibits poor passivating ability. Additional electrolyte decomposition and concomitant film deposition occur during subsequent charge/discharge cycles. As a result of the thick surface film, severe cell polarization occurs and eventually causes cell failure. However, pre-cycling the Li/LTO cell at a slower rate (0.1 C) improves cell polarization and capacity retention; this occurs because the surface film uniformly covers the LTO electrode and provides strong passivation. Accordingly, there is no significant film deposition during subsequent charge/discharge cycling. Additionally, self-discharge is reduced during high-temperature storage.

Kinetic Study of Synthesis of Aluminum Nitride Using Carbon Reduction and Subsequent Nitridation Method (탄소환원질화법에 의한 AlN 합성의 속도론적 연구)

  • Park, Hyungkyu;Choi, Youngyoon;Nam, Chulwoo
    • Resources Recycling
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    • v.26 no.3
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    • pp.39-46
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    • 2017
  • AlN powder was prepared by carbon reduction and subsequent nitridation method through lab- scale experiments. AlN powder was synthesized using the mixture of high purity $Al_2O_3$ powder and carbon black at $1,600{\sim}1,700^{\circ}C$ for 0.5~6 hours under nitrogen atmosphere (flow rate of nitrogen gas: $4.7{\times}10^{-6}{\sim}20{\times}10^{-6}m^3/sec$) with variation of charged height of the mixture powder. Experimental results showed that size of the synthesized particles grows with increasing of temperature. The reaction activation energy was calculated as 382 kJ/mol at the temperature range, and it was considered that chemical reaction is the rate determining step. Content of oxygen and nitrogen of the prpared samples were 0.71~0.96 wt% and 30.7~35.1 wt%. The results was similar with those of the commercial AlN product.

Effects of a Recreation Therapy Program on Mental Health and Heart Rate Variability in Burn Rehabilitation Patients (치료레크리에이션 프로그램이 화상재활환자의 정신건강 상태와 심박동 변이에 미치는 효과)

  • Kil, Myung-Sook;Lee, Mi-Hwa;Lee, Yong-Mi
    • Journal of Korean Biological Nursing Science
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    • v.17 no.2
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    • pp.179-187
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    • 2015
  • Purpose: This study was done to evaluate the effects of a recreation therapy program on burn rehabilitation patients to determine if the program is an effective nursing intervention which can affect mental health problems and heart rate variability. Methods: Subjects were 54 hospitalized burn rehabilitation patients (25 in the control group, 29 in the experimental group). The experimental group participated 6 times in a recreation therapy program led by a qualified instructor. Brief symptoms inventory-18 (somatization, anxiety, depression) questionnaire, and heart rate variability were checked before and after the recreation therapy program. Results: The mental health scale showed significant differences in somatization (p<.001), anxiety (p<.001) and depression (p<.001). There was no significant difference in heart rate variability (autonomic activity, autonomic balance, stress resistance, stress parameter and fatigue, mean heart rate, electro-cardiac stability). Conclusion: The findings from this study suggest that a recreation therapy program is an effective nursing intervention to decrease the level of mental health problems of burn rehabilitation patients. However, a subsequent study is needed to develop an intervention program that will induce the effect of physiological parameters like heart rate variability (HRV).

Characteristics of waterflood at low rate in low permeability sandstones based on the CT scanning

  • Mo, S.Y.;Lei, Q.;Lei, G.;Gai, S.H.;Liu, Z.K.
    • Geosystem Engineering
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    • v.21 no.6
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    • pp.344-351
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    • 2018
  • It is reported that the flooding rate in low permeability sandstones is low and the oil recovery is hard to increase after water breakthrough. Understanding characteristics of waterflood is hence important for the recovery improvement. In this work, flooding tests on low permeability sandstones were conducted. The corresponding flooding characteristics were investigated by means of CT scanning and Nuclear Magnetic Resonance. Effects of irreducible water and different rates were also discussed in detail. Experimental results reveal a piston-like displacement at a low rate in low permeability samples. The saturation profile is steep and almost vertical to the forward direction. The results at a low rate confirm that once water broke through, increasing the flooding rate or flooding time can hardly reduce the remaining oil inside the sample. It is probably due to the high pore-throat ratio proven by rate-controlled mercury. Results also confirm that the presence of initial water enhanced sweep efficiency substantially. On one hand, because water had previously occupied the small pores, the subsequent oil can only invade relatively large pores and became more movable. On the other hand, stable collars can not form due to the steep front, which may suppress the snap-off.

Tidal Disruption Flares from Stars on Bound Orbits

  • Hayasaki, Kimitake;Stone, Nicholas;Loeb, Abraham
    • The Bulletin of The Korean Astronomical Society
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    • v.38 no.2
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    • pp.60.1-60.1
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    • 2013
  • We study tidal disruption and subsequent mass fallback process for stars approaching supermassive black holes on bound orbits, by performing three dimensional Smoothed Particle Hydrodynamics simulations with a pseudo-Newtonian potential. We find that the mass fallback rate decays with the expected -5/3 power of time for parabolic orbits, albeit with a slight deviation due to the self-gravity of the stellar debris. For eccentric orbits, however, there is a critical value of the orbital eccentricity, significantly below which all of the stellar debris is bound to the supermassive black hole. All the mass therefore falls back to the supermassive black hole in a much shorter time than in the standard, parabolic case. The resultant mass fallback rate considerably exceeds the Eddington accretion rate and substantially differs from the -5/3 power of time. We also show that general relativistic precession is crucial for accretion disk formation via circularization of stellar debris from stars on moderately eccentric orbits.

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The Factors. affecting Longevity and its Changing Trend in Korea (한국의 장수동향과 그의 상관요인에 관한 분석)

  • 조유향
    • Korean Journal of Health Education and Promotion
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    • v.6 no.1
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    • pp.34-47
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    • 1989
  • The changing trend of longevity from 1955 through 1985 and its interprovincal variation were studied with longevity rate as indicator. In order to detect the affecting factors of longevity rate, eleven urbanalizational, geographic-environmental, demographic and social-economic variables were employed to carry out multiple stepwise regression analysis. The data used for this study were from Population Census Reports 1955-1985 published by EPB and Year book of Public Health and Social Statistics 1986 published by Ministry of Health and Social Affairs and other reference. Subsequent to that longevity rate decreased during 1950's it has increased continuously by the yeat of 1980's. This trend was especially remarkable in the south area and the GIRI mountain area in Korea. The stepwise regression analysis shows that the longevity rates were significantly associated with the independent variables, and the dependent variables explained at the level of 93.7percent-99.9 percent. Longevity is a reflection of the demographic and socio-economic, environmental and health resourses factor etc., longevity problems cannot be dealt with in isolation. The possible research and services which could be provided by government will be discuss.

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The Effect of Coal Particle Arrangement and Size Difference on Combustion Characteristics (미분탄 입자의 크기 차이와 배열이 연소특성에 미치는 영향)

  • Kim, Ki-Duck;Kim, Ho-Young;Cho, Chong-Pyo;Yoon, Suk-Goo
    • 한국연소학회:학술대회논문집
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    • 2007.05a
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    • pp.47-53
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    • 2007
  • The laminar combustion characteristics of interacting coal particles in a convective flow are numerically investigated at particle arrangement and size difference. The numerical simulations, which use the two-step global reaction model to account for the surrounding gas effect, show the detailed interaction among the inter-space particles, undergoing devolatilization and subsequent char burning. Several parametric studies, which include the effect of the gas temperature (1700 K), high pressure(10 atm) and variation in geometrical arrangement of the particle diameter on the volatile release rate and the char combustion rate, have been carried out. The comparison indicates that the shift to the multiple particle arrangement resulted in the substantial change of the combustion characteristics and that the volatile release rate of the interacting coal particles exhibits a strong dependency on the particle spacing and size difference.

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Physical Properties and Dyeing Behaviors of Cotton Fabric Treated with Low Temperature Plasma and/or Cellulase (저온플라즈마 및 효소처리한 면의 물성 및 염색성)

  • Yoon, Nam Sik;Lim, Yong Jin
    • Textile Coloration and Finishing
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    • v.8 no.3
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    • pp.59-65
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    • 1996
  • Cotton fabrics were treated by low temperature plasma and/or cellulase, and its physical and dyeing properties were investigated. All the pretreatments of the cotton with low temperature plasma of oxygen, nitrogen and argon slowed down the rate of weight loss of cotton in cellulase solution. Plasma pretreatment did not show any strength retention effect on cotton fiber in the subsequent cellulase treatment. Pretreatment of cotton with low temperature oxygen plasma decreased the rate of dyeing in direct dye bath, while cellulase or plasma/cellulase pretreatment increased the rate. Equilibrium dye uptake of cotton was not changed greatly by the pretreatments except the normal untreated cotton showed more or less high uptake. The pretreatment of cellulase with a water-soluble carbodiimide reduced the enzymatic activity, and did not show any strength retention of cotton in enzymatic weight loss.

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The Use of a Decanter for Harvesting Biomass rom plant Cell Cultures (데칸터를 이용한 텍서스속 식물세포 회수)

  • 김진현
    • KSBB Journal
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    • v.15 no.4
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    • pp.337-341
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    • 2000
  • The decanter is very useful to harvest biomass from plant cell cultures in large-scale process. It is very important to obtain high yield and low moisture content in recovered biomass so as to minimize solvent usage in subsequent extraction steps. Effluent clarity was also affected by the differential speed although this affect was more dramatic at higher flow rates than at lower flow rates. Moisure content was largely unaffected by flow rate. A decrease in moisture content was evident as differential speed decreased.

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Busy Period Analysis for the GI/M/1 Queue with Working Vacations (워킹 휴가형 GI/M/1 대기행렬의 바쁜기간 분석)

  • Chae, Kyung-Chul;Lim, Dae-Eun
    • Journal of the Korean Operations Research and Management Science Society
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    • v.32 no.2
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    • pp.141-147
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    • 2007
  • We consider a GI/M/1 queue with vacations such that the server works with different rate rather than completely stops working during a vacation period. We derive the transform of the joint distribution of the length of a busy period, the number of customers served during the busy period, and the length of the subsequent idle period.