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Local structural study of commercial grade MBa2Cu3O7-x (M = Y and/or Gd) coated conductors by polarized Raman spectroscopy

  • Moon, Hankyoul;Shin, Hae-Young;Jin, Hye-Jin;Jo, William;Yoon, Seokhyun
    • Progress in Superconductivity and Cryogenics
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    • v.17 no.4
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    • pp.25-29
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    • 2015
  • In 1987, M. K. Wu and Paul Chu discovered $Y_{1.2}Ba_{0.8}CuO_4$ (YBCO) with critical temperature ($T_c$) of 93 K. It has significantly lowered the cost of cooling of a material up to the point where superconductivity set in. Utilizing the cost reduction of attaining superconductivity and the vast amount of research to understand characteristics of high temperature oxide superconducting materials, there has been effort to use a high temperature superconductor as a coated conductor. It is important to characterize the materials precisely for stable performance before commercializing. We used polarized Raman scattering spectroscopy to study structural and stoichiometric information regarding $YBa_2Cu_3O_{7-x}$, $GdYBa_2Cu_3O_{7-x}$, and $GdBa_2Cu_3O_{7-x}$ produced by three leading groups of producing commercial grade high temperature superconductor coated conductors American Superconductor Corporation, Superpower, and SuNAM.

X-ray / gamma ray radiation shielding properties of α-Bi2O3 synthesized by low temperature solution combustion method

  • Reddy, B. Chinnappa;Manjunatha, H.C.;Vidya, Y.S.;Sridhar, K.N.;Pasha, U. Mahaboob;Seenappa, L.;Sadashivamurthy, B.;Dhananjaya, N.;Sathish, K.V.;Gupta, P.S. Damodara
    • Nuclear Engineering and Technology
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    • v.54 no.3
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    • pp.1062-1070
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    • 2022
  • In the present communication, pure and stable α-Bismuth Oxide (Bi2O3) nanoparticles (NPs) were synthesized by low temperature solution combustion method using urea as a fuel and calcined at 500℃. The synthesized sample was characterized by using powder X-ray Diffraction (PXRD), Scanning Electron Microscopy (SEM), Energy dispersive X-ray analysis (EDAX), Transmission Electron Microscopy (TEM), Fourier Transform Infrared Spectroscopy (FTIR) and UV-Visible absorption spectroscopy. The PXRD pattern confirms the formation of mono-clinic, stable and low temperature phase α-Bi2O3. The direct optical energy band gap was estimated by using Wood and Tauc's relation which was found to be 2.81 eV. The characterized sample was studied for X-ray/gamma ray shielding properties in the energy range 0.081-1.332 MeV using NaI (Tl) detector and multi channel analyzer (MCA). The measured shielding parameters agrees well with the theory, whereas, slight deviation up to 20% is observed below 356 keV. This deviation is mainly due to the influence of atomic size of the target medium. Furthermore an accurate theory is necessary to explain the interaction of X-ray/gamma ray with the NPs.The present work opens new window to use this facile, economical, efficient, low temperature method to synthesize nanomaterials for X-ray/gamma ray shielding purpose.

A comparison of the absolute error of estimated speaking fundamental frequency (AEF0) among etiological groups of voice disorders (음성장애의 병인 집단 간 추정 발화 기본주파수 절대 오차 비교)

  • Seung Jin Lee;Jae-Yol Lim;Jaeock Kim
    • Phonetics and Speech Sciences
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    • v.15 no.4
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    • pp.53-60
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    • 2023
  • This study compared the absolute error of estimated fundamental frequency (AEF0) using voice - (VRP) and speech range profile (SRP) tasks across various etiological groups with voice disorders. Additionally, we explored the association between AEF0 and related voice parameters within each specific etiological group. The participants included 120 individuals, comprising 30 each from the functional (FUNC), organic (ORGAN), and eurological (NEUR) voice disorder groups, and a normal control group (NC). Each participant performed voice and SRP tasks, and the fundamental frequency of connected speech was measured using electroglottography (EGG). When comparing the AEF0 measures across the etiological groups, there were no differences in Grade and Severity among the patients. However, variations were observed in AEF0VRP and AEF0SUM. Specifically, AEF0VRP was higher in the ORGAN group than in the FUNC and NC groups, whereas AEF0SUM was higher in the ORGAN group than in the NC group. Furthermore, within FUNC and NEUR, AEF0 showed a positive correlation with Grade, while in ORGAN, it exhibited a positive correlation with the mean closed quotient (CQ). Attention should be paid to the application of AEF0 measures and related voice variables based on the etiological group. This study provides foundational information for the clinical application of AEF0 measures.

X-ray/gamma radiation shielding properties of Aluminium-Bariume-Zinc Oxide nanoparticles synthesized via low temperature solution combustion method

  • K.V. Sathish;K.N. Sridhar;L. Seenappa;H.C. Manjunatha;Y.S. Vidya;B. Chinnappa Reddy;S. Manjunatha;A.N. Santhosh;R. Munirathnam;Alfred Cecil Raj;P.S. Damodara Gupta;B.M. Sankarshan
    • Nuclear Engineering and Technology
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    • v.55 no.5
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    • pp.1519-1526
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    • 2023
  • For the first time Aluminium-BariumeZinc oxide nanocomposite (ZABONC) was synthesized by solution combustion method where calcination was carried out at low temperatures (600℃) to study the electromagnetic (EM) (X/γ) radiation shielding properties. Further for characterization purpose standard techniques like PXRD, SEM, UV-VISIBLE, FTIR were used to find phase purity, functional groups, surface morphology, and to do structural analysis and energy band gap determination. The PXRD pattern shows (hkl) planes corresponding to spinel cubic phase of ZnAl2O4, cubic Ba(NO3)2, α and γ phase of Al2O3 which clearly confirms the formation of complex nano composite. From SEM histogram mean size of nano particles was calculated and is in the order of 17 nm. Wood and Tauc's relation direct energy band gap calculation gives energy gap of 2.9 eV. In addition, EM (X/γ) shielding properties were measured and compared with the theoretical ones using standard procedures (NaI (Tl) detector and multi channel analyzer MCA). For energy above 356 keV the measured shielding parameters agree well with the theory, while below this value slight deviation is observed, due to the influence of atomic/crystallite size of the ZABONC. Hence synthesized ZABONC can be used as a shielding material in EM (X/γ) radiation shielding.

Influence of Electrolyte on the Shape and Characteristics of TiO2 during Anodic Oxidation of Titanium (Titanium 양극산화시 TiO2 의 형상 및 특성에 미치는 전해질의 영향)

  • Yeji Choi;Chanyoung Jeong
    • Corrosion Science and Technology
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    • v.22 no.3
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    • pp.193-200
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    • 2023
  • Titanium alloy (grade-4) is commonly used in industrial and medical applications. To improve its corrosion resistance and biocompatibility for medical use, it is necessary to form a titanium oxide film. In this study, the morphology of the oxide film formed by anodizing Ti-grade 4 using different electrolytes was analyzed. Wetting properties before and after surface modification with SAM coating were also observed. Electrolytes used were categorized as A, B, and C. Electrolyte A consisted of 0.3 M oxalic acid and ethylene glycol. Electrolyte B consisted of 0.1 M NH4F and 0.1 M H2O in ethylene glycol. Electrolyte C consisted of 0.07 M NH4F and 1 M H2O in ethylene glycol. Samples B and C exhibited a porous structure, while sample A formed a thickest oxide film with a droplet-like structure. AFM analysis and contact angle measurements showed that sample A with the highest roughness exhibited the best hydrophilicity. After surface modification with SAM coating, it displayed superior hydrophobicity. Despite having the thickest oxide film, sample A showed the lowest insulation resistance due to its irregular structure. On the other hand, sample C with a thick and regular porous oxide film demonstrated the highest insulation resistance.

The Characteristics of Flora and Distribution in Uiseong Traditional Irrigation System Reservoirs as National Important Agricultural Heritage System (국가중요농어업유산 의성 전통수리농업시스템 소류지의 식물상 및 분포 특성)

  • Cha, Doo-Won;Wei, Si-Yang;Lee, Jun-Young;Oh, Choong-Hyeon
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.24 no.3
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    • pp.69-84
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    • 2021
  • This study was conducted as a basic data for the management of the Uiseong Traditional Irrigation Agricultural System by identifying plant diversity and distribution characteristics. The total number of plant taxa was identified as 88 families, 250 genera, 368 species, 7 subspecies, 9 varieties and 384 taxa. In the case of life form, the domancy form was in the therophytes(th), the radicoid form was a R5(monophyte), the disseminule form was the gravity D4(having no special modification for dissemination), and the growth form was the erect form was high. The number of plant taxa by land use type was higher in mountainoustype reservoirs and plain type reservoirs than other land use types. The distribution of plants by land use type according to the hemeroby grade was plantation in the case of 3 grade(meso-hemeroby) forests, and the understory were mainly photophilic plants. With 4 grade(β-euhemeroby), traditional cemetery, plain type reservoirs, mountainoustype reservoirs, stream, and rice terraces are areas with relatively low intensive management and have a wide variety of flora, whereas 5 grade(α-euhemeroby) orchard were mainly distributed with ruderal plant due to high intensive management. As for the number of plant taxa by reservoirs, the Wisgol pond in the case of plain type reservoirs, Ungok pond was high in mountainous type reservoirs. The protected species were rare plants 2 classification groups of Vulnerable(VU) species, 4 classification groups of Least Concrned(LC) species, 1 classification group of Data Deficient(DD) species, 5 classification groups of Korean endemic plants, and 49 classification groups of invasive alien plants, and the total naturalization index was 12.2%.

Experimental research on flow regime and transitional criterion of slug to churn-turbulent and churn-turbulent to annular flow in rectangular channels

  • Qingche He;Liang-ming Pan;Luteng Zhang;Wangtao Xu;Meiyue Yan
    • Nuclear Engineering and Technology
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    • v.55 no.11
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    • pp.3973-3982
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    • 2023
  • As for two-phase flow in rectangular channels, the flow regimes especially like churn-turbulent and annular flow are significant for the physical problem like Countercurrent Flow Limitation (CCFL). In this study, the rectangular channels with cross-sections of 4 × 66 mm, 6 × 66 mm, 8 × 66 mm are adopted to investigate the flow regimes of air-water vertical upward two phase flow under adiabatic condition. The gas and liquid superficial velocities are 0 ≤ jg ≤ 20m/s and 0.25 ≤ jf ≤ 3m/s respectively which covering bubbly to annular flow. The flow regimes are identified by random forest algorithm and the flow regime maps are obtained. As the results, the transitional void fraction from slug to churn turbulent flow fluctuate from 0.47 to 0.58 which is significantly affected by the dimensional size of channel and flow rate. Besides, the void fraction at transitional points from churn-turbulent (slug) to annular flow are 0.66-0.67, which are independent with the gap size. Furthermore, a new criteria of slug to churn-turbulent flow is established in this study. In addition, by introducing the interfacial force model, the criteria of churn-turbulent (slug) flow to annular flow is verified.

The Content of Primary Science in the National Curricula of Korea, China, and Japan

  • Kim, Chan-Jong
    • Journal of The Korean Association For Science Education
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    • v.21 no.5
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    • pp.924-943
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    • 2001
  • The purpose of the study is to analyze and compare the primary science curricula of Korea, China, and Japan. Science textbooks for Korea and China and national science curriculum guides for Korea and Japan were analyzed in terms of the scope and sequence of the topics. The number of primary science topics dealt with is greatest in China, followed by Korea, then Japan. In addition to the wide range of topics, the Chinese curriculum also shows more in-depth coverage of topics. On the contrary, the Japanese curriculum has the least number of topics and shallowest depth of coverage. Korea seems to be in the middle between China and Japan. The similarities of the curricula in these East Asian countries is greatest between Korea and China. and the least between China and Japan. The similarities between Korea and Japan is somewhere in the middle. Korean primary science curriculum shows a comparatively even distribution of topics across grades. A relatively smaller number of sub-topics are introduced at each grade level, especially in the area of earth science and physics. On the contrary, in the Chinese curriculum, sub-topics tend to be concentrated at a certain grade level, thus major topics are dealt with in a grade or two. The Japanese science curriculum has fewer topics than those of the other countries, and generally one or two sub-topics appeared in a grade or two.

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High-temperature electrochemical corrosion behavior of SA106 Grade B carbon steel with corrosion inhibitors in HyBRID solution

  • Sung-Wook Kim;Sang-Yoon Park;Chang-Hyun Roh;Sun-Byeong Kim
    • Nuclear Engineering and Technology
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    • v.55 no.6
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    • pp.2256-2262
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    • 2023
  • The electrochemical corrosion behaviors of SA106 Grade B (SA106B) carbon steel in H2SO44-N2H4 and H2SO4-N2H4-CuSO4 solutions at 95 ℃ have been investigated with the addition of commercial corrosion inhibitors (CI#30 and No. 570S), to determine the stability of SA106B in the hydrazine-based reductive metal ion decontamination (HyBRID) process. The potentiodynamic polarization experiment revealed that the corrosion inhibitors were capable of lowering the corrosion rate of SA106B in H2SO4-N2H4 solution. It was found that the corrosion inhibitors induced formation of fixed surface layer on the carbon steel upon the corrosion. This corrosion inhibition performance was reduced in the presence of CuSO4 in the solution owing to the chemical reactions between organic compounds in the corrosion inhibitors and CuSO4. CI#30 showed a better corrosion inhibition effect in the H2SO4-N2H4-CuSO4 solution. Although the corrosion inhibitors can provide better stability to SA106B in the HyBRID solution, their application should be carefully considered because it may result in reduced decontamination performance and increased secondary waste generation.

Study on multi-objective optimization method for radiation shield design of nuclear reactors

  • Yao Wu;Bin Liu;Xiaowei Su;Songqian Tang;Mingfei Yan;Liangming Pan
    • Nuclear Engineering and Technology
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    • v.56 no.2
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    • pp.520-525
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    • 2024
  • The optimization design problem of nuclear reactor radiation shield is a typical multi-objective optimization problem with almost 10 sub-objectives and the sub-objectives are always demanded to be under tolerable limits. In this paper, a design method combining multi-objective optimization algorithms with paralleling discrete ordinate transportation code is developed and applied to shield design of the Savannah nuclear reactor. Three approaches are studied for light-weighted and compact design of radiation shield. Comparing with directly optimization with 10 objectives and the single-objective optimization, the approach by setting sub-objectives representing weight and volume as optimization objectives while treating other sub-objectives as constraints has the best performance, which is more suitable to reactor shield design.