• 제목/요약/키워드: styrene-butadiene-styrene

검색결과 330건 처리시간 0.031초

가스사출성형에서 성형조건에 따른 ABS 성형품의 가스채널의 변화

  • 박태원;한성렬;정영득
    • 한국정밀공학회:학술대회논문집
    • /
    • 한국정밀공학회 2004년도 춘계학술대회 논문요약집
    • /
    • pp.221-221
    • /
    • 2004
  • 플라스틱의 사출성형중 용용 수지에 가스를 주입하는 가스사출성형(Gas Assisted Injection Molding GAIM)에 의해 성형품을 만드는 생산방법은 약 30년 전부터 유럽지역을 중심으로 시작되었다 GAIN의 개발 배경은 발포성형을 대체하기 위한 공법으로 개발되었다. 발포성형은 싱크마크(sink mark) 제거, 치수안정성, 강도보강의 목적으로 사용하는 공법이지만, 가스기포가 표면으로 빠져나오고 표면에 가스 기포가 발생하여 외관부품에 부적당하며, 두께가 5-6mm이하의 성형품에는 적용할 수 없고, 성형시간이 긴 문제점을 가지고 있어 이러한 문제를 보강한 공법을 연구할 결과로 GAIM이 탄생하게 되었다.(중략)

  • PDF

高分子物質의 熱分解에 關한 硏究 (第3報) 合成고무類의 熱分解生成物의 Gas Chromatography에 의한 檢索과 合成고무 確認에의 利用 (On the Pyrolysis of Polymers III. Identification of Gases from Rubber Pyrolysis by Gas Chromatography)

  • 성좌경
    • 대한화학회지
    • /
    • 제7권2호
    • /
    • pp.115-121
    • /
    • 1963
  • Aliphatic hydrocarbon gases from rubber pyrolysis have been identified by gas chromatography with tetraethyleneglycol dimethylether column. Rubbers used in this work are polyisoprene, SBR, NBR, polybutadiene, buthyl rubber, polychloroprene and polyurethane rubber. The chromatogram is characteristic for each polymer. Author proposes a method of identification of synthetic rubbers by gas chromatograph of pyrolyzed gas. Sample is pyrolyzed at $450^{\circ}C$ under nitrogen or more effectively helium and gaseous portion, which eliminated liquid condensate, is passed to the column. The appearance of exclusively large peak of isoprene, isobutylene and carbon dioxide shows the presence of polyisoprene, polyisobutylene and polyurethane, respectively. Large peak of butadiene will appear in case of polybutadiene, SBR and NBR, but SBR can be identified through the styrene peak in gas chromatogram of liquid pyrolyzate and NBR can be identified by the evolution of hydrogen cyanide during pyrolysis. Polychloroprene is identified by the evolution of hydrogen chloride. This method could be applied to the identification of copolymer or polymer blend.

  • PDF

필러재료의 변화에 따른 NR-SBR 타입 엘라스토머 기반 고무재료의 기계적물성 (Effect of Changing of Filling Materials in NR-SBR Type Elastomer Based Rubber Materials on Mechanical Properties)

  • Bulbul, Saban;Yasar, Mustafa;Akcakale, Nuretttin
    • 폴리머
    • /
    • 제38권5호
    • /
    • pp.664-670
    • /
    • 2014
  • The effects of different filling materials and stabilizers in polymer based materials that are used as shoe soles in the shoemaking industry on the mechanical properties (strength, failure, tensile, tearing, bending etc.) of the final products have been examined in this study. Natural rubber (NR RSS3) and styrene-butadiene rubber (SBR 1502) were used as the main matrix material. New compounds were formed by replacing the fillings in the general compound of the existing factory ($SiO_2$, $CaCO_3$) with 40% (1200 g) blast furnace flue dust, rice husk, reclaimed rubber (recycled) and wood ash. Comparison of the new compounds with the existing compounds revealed a decrease in hardness, density, dimension stability, bending, tearing, % elongation and failure strength and an increase in wearing.

Synthesis of a Novel Nitrogen-Phosphorus Flame Retardant Based on Phosphoramidate and Its Application to PC, PBT, EVA, and ABS

  • Nguyen, Congtranh;Kim, Jin-Hwan
    • Macromolecular Research
    • /
    • 제16권7호
    • /
    • pp.620-625
    • /
    • 2008
  • A novel nitrogen-phosphorus compound, diphenyl piperazine-1,4-diylbis(methylphosphinate)(DPPMP) was synthesized via a two step reaction and its flame retarding efficiency as a single component additive was investigated. The success of synthesis was confirmed by FTIR and $^1H$ and $^{31}P$ NMR analysis. The product was mixed with polycarbonate (PC), poly(butylene terephtalate) (PBT), ethylene-vinyl-acetate copolymer (EVA), and acrylonitrile-butadiene-styrene copolymer (ABS). The flame-retarding efficiency was evaluated using the limiting oxygen index (LOI) and the UL-94 vertical test methods. The addition of DPPMP enhanced the flame retardancy of the polymers and the V-0 ratings were obtained for the polymers examined in this study at a loading of 7-30 wt%. The gas-phase flame retardancy mode of action was suggested for this material from the thermogrametry experiment results.

Preparation of Cross-linked Asymmetric Membrane and Control of Its Morphology and Mechanical Property

  • Hong, Byung-Pyo;Ko, Moon-Young;Kwon, Byeong-Min;Byun, Hong-Sik
    • Korean Membrane Journal
    • /
    • 제10권1호
    • /
    • pp.1-7
    • /
    • 2008
  • Polystyrene-co-divinylbenzene (PS-co-DVB) asymmetric membranes were prepared. In order to control their structure and mechanical properties the degree of cross-linking and the composition of casting solution were varied. The rubber added PS-DVB membranes was also prepared to overcome the mechanical limitation of cross-linked membrane, and their mechanical properties were investigated. It was revealed that the concentration of polymer in the casting solution affected the determination of skin formation. When the PS-co-DVB membrane consists of styrene-butadiene (SB) rubber or liquid polybutadiene (PBD), the structures formed showed that the PS content in the PS/DVB system played an important role in determining the porous sublayer structure.

폴리머 코팅 폐타이어 분말을 혼입한 시멘트 모르터의 특성 (Properties of Cement Mortar Using Polymer Coated Powdered Rubber)

  • 송훈;조영국;박홍신;소양섭
    • 한국콘크리트학회:학술대회논문집
    • /
    • 한국콘크리트학회 1996년도 가을 학술발표회 논문집
    • /
    • pp.51-57
    • /
    • 1996
  • The purpose of this study is to improve the properties by increasing of the adhesion strength of styrene-butadiene rubber(SBR) latex coated powdered rubber in cement mortar. SBR-modified mortar using powdered rubber is also tested as the same method. From the test results, the cement mortar using SBR latex coated powdered rubber have a good mechanical properties compared with that using uncoated powdered rubber. The mechanical properties of SBR-modified mortar using powdered rubber with polymer-cement ratios of 10% are also improved.

  • PDF

MBS 공중합물의 자연발화 특성에 관한 연구 (A Study on Autoignition Characteristics of Methylmethacrylate-butadiene-styrene Copolymer)

  • 목연수;최재욱
    • 한국안전학회지
    • /
    • 제16권3호
    • /
    • pp.83-88
    • /
    • 2001
  • This study was preformed by measuring the minimum ignition temperature of MBS according to the change of sample vessel size and the minimum ignition temperature of MBS dust cloud The minimum ignition temperature of MBS product decreased as the vessel size was large, and it was obtained in the range from $120.5^{\circ}C$ to $94.5^{\circ}C$ and the apparent activation energy was obtained with 32.94Kcal/mol. The minimum ignition temperature of MBS dust cloud was measured by using Godbert-Greenwald furnace and it was obtained at $407^{\circ}C$ with the sample of 0.4g in the air and the ignition of dust cloud was not occurred below 13% oxygen concentration.

  • PDF

박막(薄膜) Rubber Coated Fabrics에 관(關)한 연구(硏究) (제1보(第1報)) 천연(天然) 및 합성(合成)고무를 각종(各種) 원반(原反)에 도포(塗布)했을 때의 물리적성능(物理的性能)에 대(對)하여 (Studies on the Thin Rubber Coated Fabrics. (Part. 1) Physical Properties of the Coated Fabrics of Natural Rubber and of Butadiene-Styrene Rubber)

  • 김준수;이명환;염홍찬;이숙자;임광규
    • Elastomers and Composites
    • /
    • 제1권1호
    • /
    • pp.41-48
    • /
    • 1966
  • The physical properties of rubber coated fabrics, treated by means of spreading and topping process were studied. 1. The tearing strength of the rubber coated fabrics has shown decreasing tendency in comparison with fabric itself 2. Generally, the tearing strength is inversely proportional to the adhesion. 3. The value of hydrostatic pressure is in proportion to the density and tensile strength of the fabrics. 4. The topping process shows greater difference in adhesion initial and after water immersion than spreading process.

  • PDF

EPDM과 각종(各種) Polymer의 Blend에 의(依)한 성능변화(性能變化) 및 그 응용(應用)에 관(關)한 연구(硏究)(제6보(第6報)) EPDM과 Natural Rubber 및 Butadiene-Styrene Rubber의 Blend에 대(對)하여 (Studies on the Physical Properties and Application of EPDM-Polymer Blends. Part 6. Physical Properties for EPDM-NR-SBR Blends)

  • 김준수
    • Elastomers and Composites
    • /
    • 제7권2호
    • /
    • pp.183-192
    • /
    • 1972
  • As a series of tile studies of EPDM-Polymer blends, tile experiment are concentrated to the investigation of the physical properties of tile EPDM-NR-SBR blends. The results are shown as follows: 1. In blending, tensile strength decreased with increase in EPDM contents, especially the ratio of EPDM/NR-SBR is 75/25. 2. Elongation and tear strength were much influenced by blending, especially the ratio of EPDM/NR-SBR is 50/50. 3. Ozone resistance is much improved after blending. It was effective more than tile ratio of EPDM/NR-SBR is 25/75. 4. Aging resistance is much improved after blending. It was effective more than the ratio of EPDM/NR-SBR is 50/50. 5. Hardness increased with increase in EPDM contents and on the other hand, abrasion resistance decreased.

  • PDF

Properties of Silica-SBR Compounds Using Cellulose Dispersant Applicable to Tire Tread Rubber

  • Kim, Jung Soo;Kim, Dong Hyun
    • Elastomers and Composites
    • /
    • 제55권3호
    • /
    • pp.176-183
    • /
    • 2020
  • Silica-styrene butadiene rubber (Silica-SBR) compounds have been used in the preparation of tire treads. The silica dispersibility of silica-SBR compounds is related to the processability, mechanical properties, and wear resistance of tires. Recently, in order to improve the silica dispersibility of the silica-SBR compounds, the wet masterbatch (WMB) process was introduced, which is a method of mixing rubber in the water phase. We aimed to improve the silica dispersibility of the silica-SBR compounds by preparing a silica dispersant applicable to the WMB process. For this purpose, cellulose, 2-hydroxyethyl cellulose, and cellulose acetate were employed as a silica dispersant. The silica dispersibility of the compounds was measured by a moving die rheometer. Improvement in the processability of silica-SBR compounds was evaluated by the Mooney viscometer. The wear resistance of silica-SBR compounds using a cellulose dispersant was improved by up to 29%.