• Corrosion Science and Technology
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• v.5 no.3
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• pp.99-105
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• 2006

This paper is to investigate feasibility on quantitative aging state of epoxy coating on concrete wall in containment structure under operation of nuclear power plants. For evaluating the physical characteristics of the epoxy coating, adhesion strengths of two kinds of degraded epoxy coating systems on both steel surfaces and concrete surfaces were measured via accelerated aging. Comparatively impedance data taken by ultrasonic test were also taken to relate with adhesion data. After aging, in case of concrete, from half of specimens, aging of epoxy coating was developed. As for steel, on $4^{th}$ inspection day, adhesion force was failed. To improve reliability on quality degradation of epoxy, relationship between adhesion and impedance was analyzed. By tracing to co-respond to these data, it was possible to Fig. out physical state of as-built epoxy coating. The possibility to develop new methodology of time - dependent aging state on epoxy coating was found and discussed.

• Analytical Science and Technology
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• v.37 no.2
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• pp.98-113
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• 2024

The current investigation entails the characterization of five degradation products (DPs) formed under different stress conditions of loteprednol using liquid chromatography-tandem mass spectrometry (LC-MS/MS). In addition, this study developed a stable high-performance liquid chromatography (HPLC) method for evaluating loteprednol along with impurities. The method conditions were meticulously fine-tuned which involved the exploration of the appropriate solvent, pH, flow of the mobile phase, columns, and wavelength. The method conditions were carefully chosen to successfully resolve the impurities of loteprednol and were employed in subsequent validation procedures. The stability profile of loteprednol was exposed to stress degradation experiments conducted under five conditions, and DPs were structurally characterized by employing LC-MS/MS. The chromatographic resolution of loteprednol and its impurities along with DPs was effectively achieved using a Phenomenex Luna 250 mm C18 column using 0.1 % phosphoric acid, methanol, and acetonitrile in 45:25:30 (v/v) pumped isocratically at 0.8 mL/min with 243 nm wavelength. The method produces an accurate fit calibration curve in 50-300 ㎍/mL for loteprednol and LOQ (0.05 ㎍/mL) - 0.30 ㎍/mL for its impurities with acceptable precision, accuracy, and recovery. The stress-induced degradation study revealed the degradation of loteprednol under basic, acidic, and photolytic conditions, resulting in the formation of seven distinct DPs. The efficacy of this method was validated through LC-MS/MS, which allowed for the verification of the chemical structures of the newly generated DPs of loteprednol. This method was appropriate for assessing the impurities of loteprednol and can also be appropriate for structural and quantitative assessment of its degradation products.

• Aerospace Engineering and Technology
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• v.9 no.1
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• pp.72-77
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• 2010

A hydraulic test on a filament wound case of Kick-Motor was conducted to evaluate the structural stiffness degradation and to confirm the burst performance. Failure criteria have been defined with bursting above 150% of MEOP(Maximum Expected Operation Pressure) and failure in the cylinder. The analysis result showed that filament fiber in the cylinder should be broken at about 2088psig. From a hydraulic test it has been verified that composite case meets the failure requirements, and that the stiffness does not decrease even after a year since the manufacturing.

• Geomechanics and Engineering
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• v.18 no.2
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• pp.133-140
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• 2019

Strain-rate and temperature have significant effects on the one-dimensional (1D) compression behavior of soils. This paper focuses on the bonding degradation effect of soil structure on the time and temperature dependent behavior of soft structured clay. The strain-rate and temperature dependency of preconsolidation pressure are investigated in double logarithm plane and a thermal viscoplastic model considering the combined effect of strain-rate and temperature is developed to describe the mechanical behavior of unstructured clay. By incorporating the bonding degradation, the model is extended that can be suitable for structured clay. The extended model is used to simulate CRS (Constant Rate of Strain) tests conducted on structural Berthierville clay with different strain-rates and temperatures. The comparisons between predicted and experimental results show that the extended model can reasonably describe the effect of bonding degradation on the stain-rate and temperature dependent behavior of soft structural clay under 1D condition. Although the model is proposed for 1D analysis, it can be a good base for developing a more general 3D model.

• Mass Spectrometry Letters
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• v.5 no.3
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• pp.89-93
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• 2014

Lincomycin is one of the major species among the Pharmaceuticals and Personal Care Products (PPCPs) detected from the four major rivers in Korea. The structure characterization was performed of six degradation products of lincomycin formed under the irradiation of electron beam, and the degradation efficiency as a function of the various irradiation dose and sample concentration was investigated. Electron beam (10 MeV, 0.5 mA and 5 kW) experiments for the structural characterization of degradation products that are fortified with lincomycin, were performed at the dose of 10 kGy. The separation of degradation products and lincomycin was carried out using a C18 column ($2.1{\times}100$ mm, $3.5{\mu}m$), using gradient elution with 20 mM ammonium acetate and acetonitrile. The structures of six degradation products of lincomycin were proposed by interpretation of mass spectra and chromatograms by LC-MS/MS. The mass fragmentation pathways of mass spectra in tandem mass spectrometry were also proposed. Experiments were performed of the degradation efficiency as a function of the irradiation dose intensity and the initial concentration of lincomycin in an aqueous environment. In addition, increased degradation efficiency was observed with a higher dose of electron beam and lower concentration.

• Journal of the Korean Society for Railway
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• v.8 no.4
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• pp.299-307
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• 2005

In general, structural integrity of rolling stock structures should last more than 25 years. During the lifetime corrosive degradation occurs. For structural design and diagnosis, quantitative relationship between corrosive degradation and variation of mechanical properties such as tensile strength and fatigue strength is needed. In this study, first of all we established the atmospheric corrosion test procedure. At regular intervals using specimens of SM490A and SS400 on the atmospheric corrosion test bed, we carried out tensile and fatigue tests. The fatigue strength decreases as the atmospheric corrosion period increases. In addition we studied the effect of post-weld heat treatment on the tensile and fatigue behaviour and performed electrochemical corrosion tests.

• Proceedings of the Computational Structural Engineering Institute Conference
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• 2003.04a
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• pp.161-166
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• 2003

The purpose Performance degradation of concrete structures is generally caused by the deteriorations, such as surface collapse, pop-out, crack, and so on. It may result in serious defects of the concrete structures. Thus it is very important to detect and repair the defects of concrete structures within a proper time to assure the structural safety. However, the defects due to the deteriorations are usually difficult to find by visual inspection. A sensor is developed in this study, which may give early indications for degradation of concrete structures and show the locations of the demage. Cracks can be defected by the liquid in a small glass capsules which are embedded in the concrete structures. This paper discusses the applicability of that was developed smart concrete.

• Computers and Concrete
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• v.17 no.4
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• pp.499-521
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• 2016

In this paper, a probabilistic- and finite element-based approach to evaluate and predict the lifetime performance of reinforced concrete (RC) bridges undergoing various maintenance actions is proposed with the time-variant system reliability being utilized as a performance indicator. Depending on their structural state during the degradation process, the classical maintenance actions for RC bridges are firstly categorized into four types: Preventive type I, Preventive type II, Strengthening and Replacement. Preventive type I is used to delay the onset of steel corrosion, Preventive type II can suppress the corrosion process of reinforcing steel, Strengthening is the application of various maintenance materials to improve the structural performance and Replacement is performed to restore the individual components or overall structure to their original conditions. The quantitative influence of these maintenance types on structural performance is investigated and the respective analysis modules are written and inputted into the computer program. Accordingly, the time-variant system reliability can be calculated by the use of Monte Carlo simulations and the updated the program. Finally, an existing RC continuous bridge located in Shanghai, China, is used as an illustrative example and the lifetime structural performance with and without each of the maintenance types are discussed. It is felt that the proposed approach can be applied to various RC bridges with different structural configurations, construction methods and environmental conditions.

• Structural Engineering and Mechanics
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• v.76 no.4
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• pp.479-489
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• 2020

This paper proposed a novel form of reinforced concrete (RC) shear wall confined with boundary columns. The structural effect of applying steel fiber reinforced concrete (SFRC) in the wall-column systems was studied. Three full-scale wall samples were constructed including two RC wall-RC column samples with different stirrup ratios and one RC wall-SFRC column sample. Low frequency cyclic testing was carried out to investigate the failure modes, hysteretic behavior, load-bearing capacity, ductility, stiffness degradation and energy dissipation. ABAQUS models were set up to simulate the structural behavior of tested samples, and good agreement was achieved between numerical simulation and experimental results. A further supplementary parametric study was conducted based on ABAQUS models. Both experimental and numerical results showed that increasing stirrup ratio in boundary columns did not affect much on load bearing capacity or stiffness degradation of the system. However, applying SFRC in boundary columns showed significant enhancement on load bearing capacity. Numerical simulation also shows that the structural performances of RC wall-SFRC column system were comparable to a wall-column system fully with SFRC.

• Nuclear Engineering and Technology
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• v.44 no.3
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• pp.297-310
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• 2012

Aging-related degradation of nuclear power plant components is an important aspect to consider in securing the long term safety of the plant, especially the seismic safety, since the degradation of the components affects not only their seismic capacity but their response. This can cause a change in the seismic margin of a component and the overall seismic safety of a system. To better understand the status and characteristics of degradation of components in Nuclear Power Plants (NPPs), the degradation occurrences of components in the U.S. NPPs were identified by reviewing recent publicly available information sources and the characteristics of these occurrences were evaluated and compared to observations from the past. Ten categories of components that are of high risk significance in Korean NPPs were identified, comprising anchorage, concrete, containment, exchanger, filter, piping systems, reactor pressure vessels, structural steel, tanks, and vessels. Software tools were developed to expedite the review process. Results from this review effort were compared to previous data in the literature to characterize the overall degradation trends.