• Title/Summary/Keyword: strength enhancement

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Enhancement of high temperature cycling stability in high-nickel cathode materials with titanium doping

  • Song, Jun-Ho;Bae, Joongho;Lee, Ko-woon;Lee, Ilbok;Hwang, Keebum;Cho, Woosuk;Hahn, Sang June;Yoon, Songhun
    • Journal of Industrial and Engineering Chemistry
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    • v.68
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    • pp.124-128
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    • 2018
  • Titanium doping is employed to enhance the structural strength of a high-Ni layered cathode material in lithium ion batteries during high temperature cycling. After Ti-doping, the external morphology remains similar, but the lattice parameters of the layered structure are slightly shifted toward larger values. With application of the prepared materials as cathodes in lithium-ion batteries, the initial capacities are similar but the cycling performance at $25^{\circ}C$ is enhanced by Ti-doping. During high temperature cycling at $60^{\circ}C$, furthermore, highly improved capacity retention is achieved with the Ti-doped material (95% of initial capacity at 50th cycles), while cycle fading is accelerated with the bare electrode. This enhancement is attributed to better retention of the compressive strength of the particles and retarded crack formation within the particles. In addition, impedance increase is reduced in the Ti-doped electrode, which is attributed to an improvement in the structural strength of the high-Ni cathode material with Ti-doping.

Behavior of steel-concrete jacketed corrosion-damaged RC columns subjected to eccentric load

  • Hu, Jiyue;Liang, Hongjun;Lu, Yiyan
    • Steel and Composite Structures
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    • v.29 no.6
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    • pp.689-701
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    • 2018
  • Corrosion of steel reinforcement is a principal cause of deterioration of RC columns. Making these corrosion-damaged columns conform to new safety regulations and functions is a tremendous technological challenge. This study presented an experimental investigation on steel-concrete jacketed corrosion-damaged RC columns. The influences of steel jacket thickness and concrete strength on the enhancement performance of the strengthened specimens were investigated. The results showed that the use of steel-concrete jacketing is efficient since the stub strengthened columns behaved in a more ductile manner. Moreover, the ultimate strength of the corrosion-damaged RC columns is increased by an average of 5.3 times, and the ductility is also significantly improved by the strengthening method. The bearing capacity of the strengthening columns increases with the steel tube thickness increasing, and the strengthening concrete strength has a positive impact on both bearing capacity, whereas a negative influence on the ductility. Subsequently, a numerical model was developed to predict the behavior of the retrofitted columns. The model takes into account corrosion-damage of steel rebar and confining enhancement supplied by the steel tube. Comparative results with the experimental results indicated that the developed numerical model is an effective simulation. Based on extensive verified numerical studies, a design equation was proposed and found to predict well the ultimate eccentric strength of the strengthened columns.

Effects of Contrast Agent Concentration on the Signal Intensity and Turbo Factor of TSE and Slice-selective IR in T1-weighted Contrast Imaging

  • Han, Yong Soo;Lee, Soo Chul;Lee, Dong Yong;Choi, Jiwon;Lee, Jong Woong;Kweon, Dae Cheol
    • Journal of Magnetics
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    • v.21 no.1
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    • pp.115-124
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    • 2016
  • The present study analyzes T1 TSE and T1 slice sel. IR (dark_fluid) signal strength according to the degree of gadolinium contrast agent dilution and analyzes the turbo factors with regard to changes in the maximum and overall signal strength to study correlations between changes and signal-to-noise ratios (SNRs) and compare peak-to-peak SNR (PSNR) enhancement in order to improve the quality of T1-weighted images. Enhancement TR (600 msec) evaluated to determine the T1 TSE turbo factor and obtain the maximum signal strength, T1WI were used sequentially to experiment with turbo factors_1-4. T1 slice sel. IR (dark-fluid) was used to sequentially test turbo factors_2-5 but not turbo factor_1 at a TR (1500 msec) and compare data at an increase in T1 of 900 msec. The T1 TSE was reduced according to the contrast agent concentration. Phantom signal strength increased, whereas turbo factors_1-4 exhibited maximum signal strength at a concentration of 3 mmol, followed by a gradual decrease. In the turbo factors_2-5, the signal strength increased sharply to maximum signal strength at 0.7 mmol, followed by a reduction. T1 TSE had a greater maximum signal strength than did T1 slice sel. IR (dark_fluid). A comparison of SNR found that T1 TSE imaging was superior (33.3 dB) in turbo factor_1 and T1 slice sel. IR (dark_fluid) was highest (33.9 dB) at turbo factor_5. A PSNR comparison analysis was not sufficient to distinguish between the images obtained with both techniques at 30 dB or higher under all experimental conditions.

A Study on the Prediction of Ultra-High Strength Concrete Using 80℃ Warm Water Method (80℃ 온수양생을 이용한 초고강도 콘크리트의 조기 강도 예측에 관한 연구)

  • Yu, Sang-Gil;Ha, Jung-Soo;Myung, Ro-Oun;Kim, Hak-Young;Gong, Min-Ho;Jung, Sang-Jin
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2012.11a
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    • pp.93-94
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    • 2012
  • In this study, prediction of later-age compressive strength of ultra-high strength concrete, based on the accelerated strength of concrete cured in 80℃ warm water was investigated. As a result, the nature of ultra-high strength concrete showed a rapid early strength enhancement, compressive strength using warm water method of 80℃ at 2days is same compressive at 28days using standard curing.

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Reduction of Autogenous Shrinkage of High-strength Concrete Based on Moisture Supply of Recycled Coarse Aggregate (순환 굵은골재의 수분공급에 의한 고강도 콘크리트의 자기수축 저감)

  • Kim, Han-Sic;Lee, Young-Do
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.11a
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    • pp.150-151
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    • 2021
  • This study aims to achieve an enhancement in the quality of high strength concrete through a reduction in autogenous shrinkage by supplying the moisture needed for hydration through recycled aggregates that retain high amounts of moisture. The result showed that, moisture supply increased with the higher replacement rate, autogenous shrinkage dropped by up to 45 percent.

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Influence of Ground Granulated Blast-Furnce Slag on Compressive Strength of Ultra-High Strength SFRCC (고로슬래그 미분말이 초고강도 SFRCC의 압축강도에 미치는 영향)

  • Park, Jung-Jun;Koh, Kyung-Taek;Ryu, Gum-Sung;Kang, Su-Tae;Kim, Sung-Wook
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.11a
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    • pp.399-402
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    • 2005
  • In ultra-high strength SFRCC(Steel Fiber Reinforced Cementious Composites), much silica fume are used to improve strength, flowability and durability. Silica fume have merits of filling the voids, enhancement of reheological chracteristics, production of secondary hydrates by pozzolanic reaction in reactive powder concretes. However silica fume has been imported in high-cost in domestic industry, we need to investigate replaceable material in stead of silica fume in a view of economy Therefore, in this paper, in order to investigate replacement of silica fume in ultra-high strength SFRCC we used the granulate blast-furnce slag with finess 4000, 6000, 8000. As a results, we have evaluated that the bigger the finess the more increase compressive strength of ultra-high strength SFRCC using the blast-furnce slag and there was no problem from the viewpoint of flowability and compressive strength when we use blast-furnce $50\%$ with replacement ratio of silica fume

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PERFORMANCE EVALUATION OF NEW SPACER GRID SHAPES FOR PWRS

  • Song, Kee-Nam;Lee, Soo-Bum;Lee, Sang-Hoon
    • Nuclear Engineering and Technology
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    • v.39 no.6
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    • pp.737-746
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    • 2007
  • A spacer grid, which is one of the most important structural components in a PWR fuel assembly, supports its fuel rods laterally and vertically. Based on in-house design experience, scrutiny of the design features of advanced nuclear fuels and the patents of other spacer grids, KAERI has devised its own spacer grid shapes and acquired patents. In this study, a performance evaluation of KAERI's spacer grid shapes was carried out from mechanical/structural and thermohydraulic view points. A comparative performance evaluation of commercial spacer grid shapes was also carried out. The comparisons addressed the spring characteristics, fuel rod vibration characteristics, fretting wear resistance, impact strength characteristics, CHF enhancement, and the pressure drop level of the spacer grid shapes. The results show that the performances of KAERI's spacer grid shapes are as good as or better than those of the commercial spacer grid shapes.

Effects of Carbon-Fiber Sheets on Lateral Confinement in Columns of RC Buildings in Rural Area (농어촌 지역 RC 건축물 기둥 부재의 탄소섬유시트 횡보강 효과)

  • Kim, Yoon IL;Chun, Hyung Min
    • Journal of the Korean Institute of Rural Architecture
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    • v.6 no.3
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    • pp.106-115
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    • 2004
  • In this paper, the compressive strength and ductility enhancement of concrete by lateral confinement of carbon-fiber sheets(CFS) have been studied experimentaly with cylinder specimens and square short columns reinforced externally by CFS. Test variables were amount of lateral reinforcement by CFS and space of hoop bars. Test results showed that lateral reinforcements by carbon-fiber sheets provided lateral confinement successfully for the concrete specimens and were more effective for ductility enhancement than for strength increase, and that the lateral confinement coefficient of cabon-fiber sheets increased according to narrowing the space of hoop bars in the double lateral confinement made by CFS and hoop bars.

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ADHESION STUDIES OF MAGNETRON-SPUTTERED COPPER FILMS ON INCONEL SUBSTRATES

  • Lee, G.H.;Kwon, S.C.;Lee, S.Y.
    • Journal of Surface Science and Engineering
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    • v.32 no.3
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    • pp.410-415
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    • 1999
  • The adhesion strength of sputtered copper films to Inconel substrates has been studied using the scratch test. The effects of substrate treatments before deposition such as chemical or ion bombardment etching were investigated by means of a mean critical load derived from a Weibull-like statistical analysis. It was found that the mean critical load was very weak unless the amorphous layer produced by mechanical polishing on the substrate surface was eliminated. Chemical etching in a nitric-hydrochloric acid bath was shown to have practically no effect on the enhancement of the adhesion. In contrast, the addition in this bath of nickel and copper sulphates allowed removal of the amorphous layer and an increase in the values of the mean critical load. However, it was observed that excessive chemical etching could cancel out the mean critical load enhancement. The results obtained in the case of ion bombardment etching pretreatments could be far higher than those obtained with chemical etching. Moreover, for a sufficiently long period of ion bombardment etching, the adhesion strength was so high that it was impossible to observe evidence of an adhesion failure.

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A prediction model for strength and strain of CFRP-confined concrete cylinders using gene expression programming

  • Sema, Alacali
    • Computers and Concrete
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    • v.30 no.6
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    • pp.377-391
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    • 2022
  • The use of carbon fiber-reinforced polymers (CFRP) has widely increased due to its enhancement in the ultimate strength and ductility of the reinforced concrete (RC) structures. This study presents a prediction model for the axial compressive strength and strain of normal-strength concrete cylinders confined with CFRP. Besides, soft computing approaches have been extensively used to model in many areas of civil engineering applications. Therefore, the genetic expression programming (GEP) models to predict axial compressive strength and strain of CFRP-confined concrete specimens were used in this study. For this purpose, the parameters of 283 CFRP-confined concrete specimens collected from 38 experimental studies in the literature were taken into account as input variables to predict GEP based models. Then, the results of GEP models were statistically compared with those of models proposed by various researchers. The values of R2 for strength and strain of CFRP-confined concrete were obtained as 0.897 and 0.713, respectively. The results of the comparison reveal that the proposed GEP-based models for CFRP-confined concrete have the best efficiency among the existing models and provide the best performance.