• Title/Summary/Keyword: strategic-metals

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High Temperature Corrosion Properties of Heat Resistant Chrome Steels in SO2 Atmosphere (고온 이산화황 환경 내 내열 크롬강에 대한 부식특성 연구)

  • Lee, Han-sang;Jung, Jine-sung;Kim, Eui-hyun
    • Korean Journal of Metals and Materials
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    • v.47 no.2
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    • pp.99-106
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    • 2009
  • The high temperature corrosion properties of heat resistant steels were investigated in oxidation atmosphere including sulfur dioxide. The heat resistant steels of T22, T92, T122, T347HFG and T304H were evaluated at 620, $670^{\circ}C$ for 400 hours. The corrosion rates showed a decreasing tendency while chrome contents of those steels increased from 2 mass.% to 19 mass.%. The in crease in temperature increasement has an more effect on the corrosion rates of low chrome steels than high chrome steels. The weight gains of T22, T92, T304H at $670^{\circ}C$ were 3.7, 1.65, 1.23 times compared with those at $620^{\circ}C$. The external scale formed on T22 was composed of hematite, magnetite and Fe-Cr spinel and internal layer including iron oxide mixed with sulfide. The scales formed on T92, T122, T304H consisted of an outer layer of hematite and inner layer of chrome oxide and hematite. The proportion of chrome oxide at inner layer was increased when the chrome contents in heat resistant steels were increased.

Opportunities and Challenges in Metals Recovery from Secondary Sources - US Perspective

  • Han, Kenneth N.
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.3-8
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    • 2001
  • The mineral industry of the United States is going through a challenging time. The US as an industrial nation faces with increasing demand in raw materials to fuel various industrial sectors but, at the same time, meeting environmental constraints associated with excavating and extracting these raw materials. In addition, gradual depletion of material resources. and the necessity of handling more complex forms of resources of primary origin have led to a decline in her resource productivity, once a strategic advantage of the U.S. As a result. the United States currently relies heavily upon foreign importation of various materials such as precious and strategic metals. However, since the US is the major consumer of most of these materials, the recovery of these values from scrap would help renew her position as a resource-producing nation, and ultimately help spur its domestic economy. Furthermore. recycling would also help maintain a clean environment and reduce energy consumption. In this paper. the author attempts to discuss opportunities and challenges lied ahead of the US mineral in relation to recovering their much-needed resources from secondary sources. The need and demand in various metals in the US will be reviewed and discussed. The implication of resource recovery from secondary sources will also be discussed. Extraction methods treating secondary sources are inherently different from those for primary sources. There is a need for new technologies which are metallurgically efficient and environmentally benign in treating secondary sources. Ways to meet such a need will be examined and key factors to be considered in approaching these challenges will be discussed.

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Thermal Fatigue Behavior of Thermal Barrier Coatings by Air Plasma Spray (대기플라즈마 용사법으로 제조된 열차폐코팅의 열피로특성 평가)

  • Lee, Han-sang;Kim, Eui-hyun;Lee, Jung-hyuk
    • Korean Journal of Metals and Materials
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    • v.46 no.6
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    • pp.363-369
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    • 2008
  • Effects of top coat morphology and thickness on thermal fatigue behavior of thermal barrier coatings (TBC) were investigated in this study. Thermal fatigue tests were conducted on three coating specimens with different top coat morphology and thickness, and then the test data were compared via microstructures, cycles to failure, and fracture surfaces. In the air plasma spray specimens (APS1, APS2), top coat were 200 and $300{\mu}m$ respectively. The thickness of top coat was about $700{\mu}m$ in the perpendicular cracked specimen (PCS). Under thermal fatigue condition at $1,100^{\circ}C$, the cycles to top coat failure of APS1, APS2, and PCS were 350, 560 and 480 cycles, respectively. The cracks were initiated at the interface of top coat and thermally grown oxide (TGO) and propagated into TGO or top coat as the number of thermal fatigue cycles increased. For the PCS specimen, additive cracks were initiated and propagated at the starting points of perpendicular cracks in the top coat. Also, the thickness of TGO and the decrease of aluminium concentration in bond coat do not affect the cycles to failure.

A Study on the Design of High-Stength Titanium Alloys Using DV-Xα Molecular Orbital Method (DV-Xα 분자 궤도법을 이용한 고강도 타이타늄 합금 설계)

  • Baek, Min-Sook;Yoon, Dong-Joo;Won, Dae-Hee;Kim, Byung-Il
    • Korean Journal of Metals and Materials
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    • v.49 no.9
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    • pp.739-745
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    • 2011
  • Beta-type alloys are the most versatile class of titanium alloys. They offer the highest strength to weight ratios and very attractive combinations of strength, toughness, and fatigue resistance inlarge cross sections [1]. The present study was made to obtain useful information for the design of ${\beta}$-type titanium alloys with high-strength properties by using the $DV-X{\alpha}$ method. Employing two calculated parameters, the bond order (Bo) and the d-orbital energy level (Md) of alloying elements in ${\beta}$-type titanium alloy was introduced and used for prediction of mechanical properties. Thus, high-strength titanium alloys were designed by calculating the Md and Bo values of the previous and present titanium alloys.

Investigation on the Material Flow of Cobalt for Resource Recovery and Recycling of Strategic-Metal Scrap (戰略金屬 스크랩 資源化를 위한 코발트 物質흐름 現況調査)

  • Sohn, Jeong-Soo;Yang, Dong-Hyo;Shin, Shun-Myung;Kang, Eun-Hee
    • Resources Recycling
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    • v.14 no.2
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    • pp.43-55
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    • 2005
  • As world population increases and the world economy expalds, so does the demand for natural resources especially strategic metals such as cobalt. An accurate assesment of the nation's minerals must include not only the resources available in the ground but also those that become available through recycling. In this paper, data on domestic and international supply of cobalt and its applications by end-user were analyzed for stable security of cobalt resources and effective recycling of cobalt scraps. Also, an initial evaluation of the flow of cobalt-containing materials in the United States was prepared. In 2003, 8,000 metric tons of cobalt were consumed in the United States and an estimated 28% of U.S. cobalt supply was derived from scrap. The superalloy industry and catalyst industries have well-established recycling or cobalt recovery practices. Recycling rates of cobalt scraps from magnet alloy and cemented carbide were relatively low.

Evaluation of Some Rare Metals and Rare Earth Metals Contained in Coal Ash of Coal-fired Power Plants in Korea (국내 석탄화력발전소 석탄회 중 희유금속 가치 평가)

  • Park, Seok-Un;Kim, Jae-Kwan;Seo, Yeon-Seok;Hong, Jun-Seok;Lee, Hyoung-Beom;Lee, Hyun-Dong
    • Resources Recycling
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    • v.24 no.4
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    • pp.67-75
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    • 2015
  • The content distributions of some rare metals and rare earthe metals in coal ash (fly ash, bottom ash and pond ash) and leachate from coal-fired power plants were investigated. In case of Yttrium (Y) and Neodymium (Nd) which were strategic critical elements, their contents were ranged from about 23 ~ 75 mg/kg and it is shown they are worth to be developed for the recovery and separation method. Considering the annual amount of fly ash and bottom ash and pond ash, coal-fired power plants have great value of about 1,670 billion KRW and it is regards they are worthy as urban mines.

A comparative analysis of Cartier's and Tiffany&Co.'s strategies for brand story videos on their YouTube brand channels (까르띠에와 티파니의 유튜브 브랜드 채널을 통한 브랜드 스토리 동영상 전략 비교 분석 연구)

  • Hong, Jiyoun
    • The Research Journal of the Costume Culture
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    • v.24 no.4
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    • pp.498-510
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    • 2016
  • As social media are emerging as essential communication channels for corporates in all areas, luxury jewelry brands have implemented enhanced strategies for brand story videos by creating brand channels on YouTube. In this study, a comparative analysis of the videos made available by Cartier and Tiffany&Co. on their YouTube Brand Channels was conducted, with the aim of identifying their strategic characteristics. The research method encompassed, both literature review and empirical investigations. A quantitative analysis was conducted by means of the 'HEART' model, a type of luxury jewelry brand story, and the following common strategic elements were identified. First, in their brand story videos both brands focus primarily on 'theme'. Second, 'relationship' and 'artisanship' are emphasized in addition to 'theme'. Third, the videos incorporate high level aesthetics to stimulate the fantasies and dreams of their audiences. The strategic differences between the brands are as follows. : First, 'artisanship' is given the greatest significance along with 'theme' in Cartier videos, while 'relationship' has prime significance in Tiffany&Co. videos. Second, a difference between a European approach and an American approach towards luxury brand building is evident, with Cartier hosting exhibitions while Tiffany&Co. provides gala videos instead.

A Study on the Quantification of Market-Government Response for Import Interruption Risk of Base Metal in Korea (베이스메탈 수입중단에 대한 민관 대응 리스크 물량 산정 연구)

  • Kim, Yujeong
    • Resources Recycling
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    • v.30 no.5
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    • pp.3-9
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    • 2021
  • In Korea, base metals such as lead, zinc, copper, tin, nickel, and aluminum have a polarized supply and demand structure. Despite the presence of world-class producers of lead, zinc, and copper, and their production is insufficient. And there are no domestic producers of tin, nickel, and aluminum, Thus, most of the domestic demand is dependent on imports. Therefore, it is necessary to prepare for the risk of supply interruption, such as the disruption of the import of base metals or interruption of domestic production. In this study, we estimated the quantity required to respond to the risk of import disruption, the quantity to which the market can respond, and the quantity to which the government needs to respond for six base metals (copper, lead, zinc, aluminum, nickel, and tin).

Investigation of Ni Silicide formation at Ni/Cu/Ag Contact for Low Cost of High Efficiency Solar Cell (고효율 태양전지의 저가화를 위한 Ni/Cu/Ag 전극의 Ni Silicide 형성에 관한 연구)

  • Kim, Jong-Min;Cho, Kyeong-Yeon;Lee, Ji-Hun;Lee, Soo-Hong
    • 한국태양에너지학회:학술대회논문집
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    • 2009.04a
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    • pp.230-234
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    • 2009
  • It is significant technique to increase competitiveness that solar cells have a high energy conversion efficiency and cost effectiveness. When making high efficiency crystalline Si solar cells, evaporated Ti/Pd/Ag contact system is widely used in order to reduce the electrical resistance of the contact fingers. However, the evaporation process is no applicable to mass production because high vacuum is needed. Furthermore, those metals are too expensive to be applied for terrestrial applications. Ni/Cu/Ag contact system of silicon solar cells offers a relatively inexpensive method of making electrical contact. Ni silicide formation is one of the indispensable techniques for Ni/Cu/Ag contact sytem. Ni was electroless plated on the front grid pattern, After Ni electroless plating, the cells were annealed by RTP(Rapid Thermal Process). Ni silicide(NiSi) has certain advantages over Ti silicide($TiSi_2$), lower temperature anneal, one step anneal, low resistivity, low silicon consumption, low film stress, absence of reaction between the annealing ambient. Ni/Cu/Ag metallization scheme is an important process in the direction of cost reduction for solar cells of high efficiency. In this article we shall report an investigation of rapid thermal silicidation of nickel on silngle crystalline silicon wafers in the annealing range of $350-390^{\circ}C$. The samples annealed at temperatures from 350 to $390^{\circ}C$ have been analyzed by SEM(Scanning Electron Microscopy).

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Priority Re-setting for Future Core & Strategic Technologies in Agricultural and Environmental Science (농업환경 분야의 미래유망기술 및 전략기술에 관한 우선순위 재설정)

  • Cho, Keun-Tae;Joo, Jin-Ho;Ok, Yong-Sik;Shin, Bong-Chul;Kim, Jee-Yong;Lee, Jong-In
    • Korean Journal of Environmental Agriculture
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    • v.27 no.4
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    • pp.395-405
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    • 2008
  • The objective of this study was to set priority for future core technologies in agricultural and environmental science using analytic hierarchy process(AHP). Forty-six technologies were derived by specialist meetings. Evaluation criteria, for setting the priority were decided as 'technology', 'marketability', and 'public'. Eighteen specialists in agricultural and environmental science answered to the questionnaire for AHP. As the results, 'technology' was decided as the most important evaluation criterion. The 'Feasibility' in 'technology' criterion, 'Market Growth' in 'marketability' criterion, and 'Impact to other industry' in 'public' criterion were decided as sub-criteria in each criterion. The most important technology was 'Risk assessment of toxic heavy metals and establishment of accreditation criteria for environmentally friendly agricultural products.