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Synergistic Effect of Nitrogen and Molybdenum on Localized Corrosion of Stainless Steels

  • Kim, Y.S.
    • Corrosion Science and Technology
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    • v.9 no.1
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    • pp.20-28
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    • 2010
  • According to the bipolar model, ion selectivity of some species in the passive film is important factor to control the passivation. An increase of cation selectivity of outer layer of the passive film can stabilize the film and improves the corrosion resistance. Therefore, the formation and roles of ionic species in the passive film should be elucidated. In this work, two types of solution (hydrochloric or sulfuric acid) were used to test high N and Mo-bearing stainless steels. The objective of this work was to investigate the formation of oxyanions in the passive film and the roles of oxyanions in passivation of stainless steel. Nitrogen exists as atomic nitrogen, nitric oxide, nitro-oxyanions (${NO_x}^-$), and N-H species, not nitride in the passive film. Because of its high mobility, the enriched atomic nitrogen can act as a reservoir. The formation of N-H species buffers the film pH and facilitates the formation of oxyanions in the film. ${NO_x}^-$ species improve the cation selectivity of the film, increasing the oxide content and film density. ${NO_x}^-$ acts similar to a strong inhibitor both in the passive film and at active sites. This facilitates the formation of chromium oxide. Also, ${NO_x}^-$ can make more molybdate and nitric oxide by reacting with Mo. The role of Mo addition on the passivation characteristics of stainless steel may differ with the test environment. Mo exists as metallic molybdenum, molybdenum oxide, and molybdate and the latter facilitates the oxide formation. When nitrogen and molybdenum coexist in stainless steel, corrosion resistance in chloride solutions is drastically increased. This synergistic effect of N and Mo in a chloride solution is mainly due to the formation of nitro-oxyanions and molybdate ion. Oxyanions can be formed by a 'solid state reaction' in the passive film, resulting in the formation of more molybdate and nitric oxide. These oxyanions improve the cation selectivity of the outer layer and form more oxide and increase the amount of chromium oxide and the ratio of $Cr_2O_3/Cr(OH)_3$ and make the film stable and dense.

Measurement of Organic Solvent from Painting Work Inside the Steel Box Girder of Bridge (교량 스틸박스거더 도장공사의 유기용제 측정 실험)

  • Lee, Jung-Woo;Son, Ki-Sang
    • Journal of the Korean Society of Safety
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    • v.20 no.3 s.71
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    • pp.134-142
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    • 2005
  • This study is to find out how organic solvent will be propagated from painting inside the steel box girder of bridge. $2.9m{\times}3.0m$ of inside size of steel box girder is not suitable for painters to do his work comfortably and hygienically. Substance density(ppm)inside the space of the box unsatisfactory hygienical condition. Most of organic solvent(mainly toluene) came down to 0.5m in two minutes and 53sec. But personal protection for painter should be properly kept against flying this heavy organic solvent. longitudinally 27.1m in length is a cell unit of the whole length of bridge. Model XP-3l6A made in Japan is a main instrumentation adjusted to sense organic solvent especially toluene which can be measured up to 10,000ppm. Scenario analysis by computer program, safer release 2.0 has been performed first to estimate how the organic solvent will be propagated. And then actual test was done as a model. This has been measured for approximately five(5) minutes, with 30 sec interval. Actual measurement results showed much higher $10{\sim}20%$ than result analyzed by the computer program, meaning that this painting work can give worse effect to the worker who is painting inside the box girder of the bridge. The first meas urement level over the floor set up at 30cm height from the floor, because organic solvent was estimated to stay at the level. and then, they were measured at 1.0m, 1.5m level respectively, more.

Reliability Analysis of Fatigue Truck Model Using Measured Truck Traffic Statistics (통행차량 특성을 반영한 강교량 피로설계트럭의 피로파괴 신뢰도해석)

  • Shin, Dong Ku;Kwon, Tae Hyung;Park, Young Suk
    • Journal of Korean Society of Steel Construction
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    • v.19 no.2
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    • pp.211-221
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    • 2007
  • A structural reliability analysis of fatigue truck model for fatigue failure of highway steel bridges was performed by applying the Miner's fatigue damage rule expressed as a function of various random variables affecting fatigue damage. Among the variables, the statistical parameters for equivalent moment, impact factor, and loadometer were obtained by analyzing recently measured domestic traffic data, whereas the parameters on fatigue strength, girder distribution factor, and headway factor of the measured data available in the literature were used. The effects of various fatigue truck models, fatigue life, ADTT, fatigue detail category, loadometer, and gross vehicle weight of fatigue truck on the reliability index of fatigue damage were analyzed. It is expected that the analytical results presented herein can be used as a basic background material in the calibration of both fatigue design truck and fatigue load factor of LRFD specification.

Statistical bias indicators for the long-term displacement of steel-concrete composite beams

  • Moreno, Julian A.;Tamayo, Jorge L.P.;Morsch, Inacio B.;Miranda, Marcela P.;Reginato, Lucas H.
    • Computers and Concrete
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    • v.24 no.4
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    • pp.379-397
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    • 2019
  • Steel-concrete composite beams are widely employed in constructions and their performance at the serviceability stage is of concern among practitioners and design regulations. In this context, an accurate evaluation of long-term deflections via various rheological concrete models is needed. In this work, the performance and predict capability of some concrete creep and shrinkage models ACI, CEB, B3, FIB and GL2000 are ascertained, and compared by using statistical bias indicators. Ten steel-concrete composite beams with existing experimental and numerical results are then modeled for this purpose. The proposed modeling technique uses the finite element method, where the concrete slab and steel beam are modeled with shell finite elements. Concrete is considered as an aging viscoelastic material and cracking is treated with the common smeared approach. The results show that when the experimental ultimate shrinkage strain is used for calibration, all studied rheological models predict nearly similar deflections, which agree with the experimental data. In contrast, significance differences are encountered for some models, when none calibration is made prior to. A value between twenty and thirty times the cracking strain is recommended for the ultimate tensile strain in the tension stiffening model. Also, increasing the relative humidity and decreasing the ambient temperature can lead to a substantial reduction of slab cracking for beams under negative flexure. Finally, there is not a unique rheological model that clearly excels in all scenarios.

Experimental study on models of cylindrical steel tanks under mining tremors and moderate earthquakes

  • Burkacki, Daniel;Jankowski, Robert
    • Earthquakes and Structures
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    • v.17 no.2
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    • pp.175-189
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    • 2019
  • The aim of the study is to show the results of complex shaking table experimental investigation focused on the response of two models of cylindrical steel tanks under mining tremors and moderate earthquakes, including the aspects of diagnosis of structural damage. Firstly, the impact and the sweep-sine tests have been carried out, so as to determine the dynamic properties of models filled with different levels of liquid. Then, the models have been subjected to seismic and paraseismic excitations. Finally, one fully filled structure has been tested after introducing two different types of damages, so as to verify the method of damage diagnosis. The results of the impact and the sweep-sine tests show that filling the models with liquid leads to substantial reduction in natural frequencies, due to gradually increasing overall mass. Moreover, the results of sweep-sine tests clearly indicate that the increase in the liquid level results in significant increase in the damping structural ratio, which is the effect of damping properties of liquid due to its sloshing. The results of seismic and paraseismic tests indicate that filling the tank with liquid leads initially to considerable reduction in values of acceleration (damping effect of liquid sloshing); however, beyond a certain level of water filling, this regularity is inverted and acceleration values increase (effect of increasing total mass of the structure). Moreover, comparison of the responses under mining tremors and moderate earthquakes indicate that the power amplification factor of the mining tremors may be larger than the seismic power amplification factor. Finally, the results of damage diagnosis of fully filled steel tank model indicate that the forms of the Fourier spectra, together with the frequency and power spectral density values, can be directly related to the specific type of structural damage. They show a decrease in the natural frequencies for the model with unscrewed support bolts (global type of damage), while cutting the welds (local type of damage) has resulted in significant increase in values of the power spectral density for higher vibration modes.

Characteristics of Static Buckling Load of the Hexagonal Spatial Truss Models using Timber (목재를 이용한 육각형 공간 트러스 모델의 정적좌굴하중 특성)

  • Ha, Hyeonju;Shon, Sudeok;Lee, Seungjae
    • Journal of Korean Association for Spatial Structures
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    • v.22 no.3
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    • pp.25-32
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    • 2022
  • In this paper, the instability of the domed spatial truss structure using wood and the characteristics of the buckling critical load were studied. Hexagonal space truss was adopted as the model to be analyzed, and two boundary conditions were considered. In the first case, the deformation of the inclined member is only considered, and in the second case, the deformation of the horizontal member is also considered. The materials of the model adopted in this paper are steel and timbers, and the considered timbers are spruce, pine, and larch. Here, the inelastic properties of the material are not considered. The instability of the target structure was observed through non-linear incremental analysis, and the buckling critical load was calculated through the singularities and eigenvalues of the tangential stiffness matrix at each incremental step. From the analysis results, in the example of the boundary condition considering only the inclined member, the critical buckling load was lower when using timber than when using steel, and the critical buckling load was determined according to the modulus of elasticity of timber. In the case of boundary conditions considering the effect of the horizontal member, using a mixture of steel and timber case had a lower buckling critical load than the steel case. But, the result showed that it was more effective in structural stability than only timber was used.

IBS Beam Element for Nonlinear Seismic Analysis of Steel Moment Frames (강재 모멘트 골조의 비선형 지진 해석을 위한 IBS 보 요소)

  • Kim, Dal Sung;Kim, Dong Seong;Kim, Kee Dong;Ko, Man Gi
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.2A
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    • pp.233-242
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    • 2008
  • This study presents a non-prismatic beam element for modeling the elastic and inelastic behavior of steel beams, which have the post-Northridge(cover plate) connections in steel moment frames that are subjected to earthquake ground motions. The elastic stiffness matrix for non-prismatric members with increased beam section (IBS) connection is in the closed-form. The plasticity model is of a discrete type and is composed of a series of nonlinear hinges connected by rigid links. The hardening rules can model the inelastic behavior for monotonic and random cyclic loading, and the effects of local buckling. Moreover the determination of yield surfaces, stiffness parameters, and hardening (or softening) rule parameters for IBS beam element were described. Analytical results of the IBS beam element show good correlation with test data and FEM results.

Limit Analysis of Steel Structures by Right-Bodies Spring Model (강체 스프링 모델에 의한 철골구조물의 극한해석)

  • 박강근
    • Computational Structural Engineering
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    • v.17 no.2
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    • pp.42-49
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    • 2004
  • 강체스프링 모델은 분할된 요소를 강체라고 가정하고, 각 요소는 스프링 시스템을 연결되어 있다고 생각하여 구조물을 해석하는 방법이다. 먼저 보의 휨 문제에 대한 강체스프링 모델의 개념을 설명하고자 한다. (중략)

Applicability Evaluation of Modified Overlay Model on the Cyclic Behavior of 316L Stainless Steel at Room Temperature (316L 스테인리스강의 상온 반복 거동에 대한 수정 다층 모델의 적용성 검토)

  • Lim Jae-Yong;Lee Soon-Bok
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.28 no.10
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    • pp.1603-1611
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    • 2004
  • The validity of 'modified overlay model' to describe the cyclic behavior of annealed 316L stainless steel at room temperature was investigated. Material parameters(~f$_{i}$, m$_{i}$b, η, E) fur the model were obtained through constant strain amplitude test. The strain amplitude dependency of elastic limit and cyclic hardening, which were the characteristics of this model, were considered. Eight subelements were used to describe the nonlinearity of the hysteresis loops. The calculated hysteresis curve in each condition (0.5%, 0.7%, 0.9% train amplitude test) was very close to the experimental one. Two tests, incremental step test and 5-step test, ere performed to check the validity of 'modified overlay model'. The elastic limit was saturated to the one of the highest strain amplitudes of the block in the incremental step test, so it seemed to be Masing material at the stabilized block. Cyclic hardening was successfully described in the increasing sequence of the strain amplitude in 5-step test. But, the slight cyclic softening followed by higher strain amplitude would not be able to simulate by'modified overlay model'. However, the discrepancy induced was very small between the calculated hystereses and the experimental ones. In conclusion,'Modified overlay model'was proved to be appropriate in strain range of 0.35%~ 1.0%..0%.

Investigation of Pile Behaviour according to Interface Properties - Comparison between Pile Model Test Using Close Range Photogrammetry and Numerical Analysis (경계면 물성치에 따른 말뚝 거동 분석 - 근거리 사진계측을 이용한 모형시험과 수치해석 비교)

  • Lee, Jung-Min;Lee, Yong-Joo
    • Journal of the Korean Geotechnical Society
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    • v.30 no.9
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    • pp.29-39
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    • 2014
  • In this study, model pile-load test with numerical analysis was carried out to compare and analyze pile behaviour according to interface properties. In the model test, Close Range Photogrammetry (CRP) was chosen to measure the ground deformation. In addition, model steel and concrete piles were used. Based on the model pile test, interface elements around the model pile were used to simulate the slip effect. Interface properties were adopted as interface reduction factor $R_{inter}$. Interface reduction factor, $R_{inter}$ plays a key role in the interface properties. Through this study, it was found that the model ground behaviour measured by CRP corresponded well to the one predicted by the numerical analysis. And, the interface strength reduction factor, $R_{inter}$ value of the steel pile was higher than that of the concrete pile.