• Title/Summary/Keyword: stable cathode

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Electrolytic Treatment of Emulsified Oily Wastewater Using DSA Electrode (I) - Batch Treatment - (DSA 전극을 사용한 에멀젼 함유폐수의 전해처리 (I) -회분식 전해처리-)

  • 김인수;송영채
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.2 no.1
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    • pp.67-75
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    • 1996
  • An innovative batch electrolytic system consisted of electrolytic basin, which was equipped with DSA(Dimensionally Stable Anode) type insoluble electrode, Ti/IrO2 anode and H-C metal cathode, and flotation separator was developed for the efficient treatment of shipboard emulsified oily wastewater. The electorod cleance and current density of elecrolytic basin to ensure maximum treatment efficiency of oily wastewater was evaluated as 6 mm, 3 A/dm3, respectively. The electrolytic efficiency of oily wastewater was affected by the operationtemperature, and it means that the temperature controller to ensure the stabiity of the process is required. The conductivity in the electrolytic basin was increased with the percentage of sea water in the oily wastewater, and over 90% of treatment efficiency of oily wastewater could be obtained at 7% of sea water. The oil removal rate was increased according to the increase of the quantity of electricity, and the maximum value of electrilyic rate constant was 288 mgoil/A.min. The information obtained from this study might be used for development of an efficient continuous electrolytic system treating the emulsified oily wastewater.

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Electron Emission from $Pb(Zr_xTi_{1-x})O_3$ Ferroelectrics by Pulsed Electric Field (펄스 전기장에 의한 $Pb(Zr_xTi_{1-x})O_3$ 강유전체의 전자 방출)

  • 김용태;윤기현;김태희;박경봉;곽상희
    • Journal of the Korean Ceramic Society
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    • v.37 no.1
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    • pp.6-11
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    • 2000
  • Electron emission from the Pb(ZrxTi1-x)O3 ferroelectrics by pulsed electric field has been investigated as a function of Zr/Ti ratios such as 35/65, 50/50 and 65/35 below 250kV/cm. Electrons were emitted regardless of the applied field polarity to the rear electrode. When the negative field was applied to the rear electrode, the electron emission charge was more stable. It was proved that the electrons were emitted at the edge of the upper electrode. The emission charge increased in order of 65/35>50/50>35/65. The electron emission characteristics were dependent on the ferroelectric properties such as polarization and coercive field. The emission charge and emission threshold field were affected by the polarization change and the coercive field, respectively. This result explains that the electron emission is a field emission with polarization induced surface potential by a modified Fowler-Nordheim plot of emission charge.

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Resonant Characteristics of LCC Series-Parallel for Single-Phase Power Source (단상전원에 적합한 LCC 직병렬 공진 특성)

  • Lee Dal-Eun;Yoon Shin-Yong;Kim Il Nam;Kim Cherl-Jin;Baek Soo-Hyun
    • Proceedings of the KIEE Conference
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    • summer
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    • pp.1208-1210
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    • 2004
  • The Cold-Cathode Fluorescent Lamps (CCFL) are widely used to illuminate the liquid crystal displays(LCD) used in many battery powered instrument. This paper presents analysis of fly-back converter for universal-line applications($90\sim265Vac$) and half-bridge type resonant inverter for CCFL drive for stable characteristic and life improvement of fluorescent lamp operation frequency is higher than resonant frequency for safe operation. The validity of this study was confirmed from the simulation and experiential result.

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Display Technologies for Immersive Devices and Electronic Skin (디스플레이 현황과 발전방향 -실감 및 스킨 기기로의 확대)

  • Park, Y.J.
    • Electronics and Telecommunications Trends
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    • v.34 no.2
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    • pp.10-18
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    • 2019
  • Since the introduction of CRT(Cathode Ray Tube) in the 1950s, display technologies have been developed continuously. Flat panel displays such as PDP(Plasma Display Panel) and LCD(Liquid Crystal Display) were commercialized in the late 1990s, and OLED(Organic Light Emitting Diodes) and Micro-LED(Micro-Light Emitting Diodes) are now being developed and are becoming widespread. In the future, we expect to develop ultra-realistic, flexible, embedded sensor displays. Ultra-realistic display can be applied to AR/VR(Augmented Reality/Virtual Reality) devices and spatial light modulators for holography. The sensor-embedded display can be applied to robots; electronic skin; and security devices, including iris recognition sensors, fingerprint recognition sensors, and tactile sensors. AR/VR technology must be developed to meet technical requirements such as viewing angle, resolution, and refresh rate. Holography requires optical modulation technology that can significantly improve resolution, viewing angle, and modulation method to enable wide-view and high-quality hologram stereoscopic images. For electronic skin, stable mass production technology, large-area arrays, and system integration technologies should be developed.

Nickel-Based Catalysts for Direct Borohydride/Hydrogen Peroxide Fuel Cell (직접 수소화붕소나트륨/과산화수소 연료전지를 위한 니켈 기반 촉매)

  • OH, TAEK HYUN
    • Transactions of the Korean hydrogen and new energy society
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    • v.31 no.6
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    • pp.587-595
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    • 2020
  • Nickel-based bimetallic catalysts were investigated for use in direct borohydride/hydrogen peroxide fuel cells. For anode and cathode, PdNi and AuNi catalysts were used, respectively. Nickel-based bimetallic catalysts have been investigated through various methods, such as inductively coupled plasma optical emission spectroscopy, transmission electron microscopy, scanning electron microscopy, and energy dispersive spectroscopy. The performance of the catalysts was evaluated through fuel cell tests. The maximum power density of the fuel cell with nickel-based bimetallic catalysts was found to be higher than that of the fuel cell with the monometallic catalysts. The nickel-based bimetallic catalysts also exhibited a stable performance up to 60 minutes.

Challenges and Improvements of All-Solid-State Batteries

  • Jihyun Jang
    • Journal of the Korean Chemical Society
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    • v.67 no.3
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    • pp.165-174
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    • 2023
  • The development of all-solid-state batteries (ASSBs) has been gaining attention in recent years due to their potential to offer higher energy densities, improved safety, and longer cycle life compared to conventional lithium-ion batteries. However, several challenges must be addressed to achieve the practical application of ASSBs, such as the development of high-performance solid-state electrolytes, stable electrode-electrolyte interfaces, and cost-effective manufacturing processes. In this review paper, we present an overview of the current state of ASSB research, including recent progress in solid-state electrolyte and cathode/anode materials, and cell architecture. We also summarize the recent advancements and highlight the remaining challenges in ASSB research, with an outlook on the future of this promising technology.

Characterization of Non-precious Metal for Fuel Cell Catalyst with Conducting Polymer (전도성 고분자를 이용한 연료전지용 비백금 촉매의 특성화 정량)

  • Kim, Hun-Jong;Lee, Hyo June;Ahn, Ji Eun;Kim, Hansung;Lee, Ho-Nyun
    • Applied Chemistry
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    • v.15 no.2
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    • pp.137-140
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    • 2011
  • Excellent active and stable platinum catalyst fuel cells currently being used as a catalyst. However, because of the high price of platinum catalyst, such as non-precious catalyst has been studied by a variety of fuel cell catalysts. In this study, Co/ PANi//CNT composite catalyst after synthesis through various heating process was to increase the activity of the catalyst. At 700℃ showed the best catalytic activity, using a composite catalyst was to be used as cathode electrodes in fuel cell.

The Structural and Electrochemical Properties of Thermally Aged Li[Co0.1Ni0.15Li0.2Mn0.55]O2 Cathodes

  • Park, Yong-Joon;Lee, Ju-Wook;Lee, Young-Gi;Kim, Kwang-Man;Kang, Man-Gu;Lee, Young-Il
    • Bulletin of the Korean Chemical Society
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    • v.28 no.12
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    • pp.2226-2230
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    • 2007
  • As a cathode material of lithium rechargeable batteries, charged Li[Co0.1Ni0.15Li0.2Mn0.55]O2 electrodes, which were aged thermally at 25 oC and 90 oC respectively, were characterized by means of charge/discharger, impedance spectroscopy, and X-ray diffraction. The discharge capacity diminution of the electrodes aged at 25 oC and 90 oC for 1 week was 4% and 23%, respectively. The cell aged at 25 oC was recovered on cycling. However, the capacity loss after ageing at 90 oC was not recovered in a subsequent cycling test, which demonstrates that the reaction occurring during ageing at 90 oC is irreversible. A significant impedance increase of aged electrode at 90 oC is associated with irreversible capacity loss. The structural changes including phase transformation were not detected by XRD analysis, because it could be due to out of detection limit. After ageing, impedance was slightly decreased during subsequent cycling test. It could be explained the cyclic performance of aged sample is stable. The thermal stability was not deteriorated by ageing even at the high temperature of 90 oC.

Charge/discharge Properties of $V_{6}O_{13}$ Composite/Li Cell with Solid Polymer Electrolyte (고체 고분자 전해질을 사용한 $V_{6}O_{13}$ Composite/Li Cell의 충방전 특성)

  • Kim, J.U.;Yu, Y.H.;Jeong, I.S.;Park, B.K.;Gu, H.B.;Moon, S.I.
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1414-1417
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    • 1996
  • The purpose of this study Is to research and develop $V_{6}O_{13}$ composite cathode for lithium thin film battery. $V_{6}O_{13}$ represents a class of cathode active material used in Li rechargeable batteries. In this study, we investigated cyclic voltammetry and charge/discharge characteristics of $V_6O_{13}$/SPE/Li cells. Cyclic voltammogram of $V_{6}O_{13}$/SPE/Li cell at scan rate 1mV/sec showed reduction peaks of 2.25V and 2.4V and oxidation peaks of 2.4V and 2.2V. The discharge curve of $V_{6}O_{13}$/SPE/Li cell showed 4 potential plateaus. The discharge capacity was decreased in the beginning of charge/discharge cycling. After 8th cycling, the discharge capacity was stable. The discharge capacity of 1st cycle and 15th cycle was 290mAh/g and 147mAh/g at $25^{\circ}C$, respectively.

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The Electrochemical Property of the Single-Chamber Solid Oxide Fuel Cell Based on a Zirconia Electrolyte (지르코니아 전해질을 이용한 단실형 고체산화물 연료전지의 전기화학 특성)

  • Park, Hee Jung;Joo, Jong Hoon;Yang, Jae-Kyo;Jin, Yun Ho;Lee, Kyu Hyoung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.8
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    • pp.510-515
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    • 2016
  • Single-chamber solid oxide fuel cells (SC-SOFCs) consist of only one gas chamber, in which both the anode and the cathode are exposed to the same fuel-oxidant mixture. Thus, this configuration shows good thermal and mechanical resistance and allows rapid start-up and -down. In this study, the unit cell consisting of $La_{0.8}Sr_{0.2}MnO_3$ (cathode) / $Zr_{0.84}Y_{0.16}O_{2-x}$ (electrolyte) / $Ni-Zr_{0.84}Y_{0.16}O_{2-x}$ (anode) was fabricated and its electrochemical property was investigated as a function of temperature and the volume ratio of fuel and oxidant for SC-SOFCs. Impedance spectra were also investigated in order to figure out the electrical characteristics of the cell. As a result, the cell performance was governed by the polarization resistances of the electrodes. The cell exhibited an acceptable cell-performance of $86mW/cm^2$ at $800^{\circ}C$ and stable performance for 3 hs under 0.7 V.