• 한국진공학회지
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• 제7권s1호
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• pp.30-36
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• 1998

The plasma-spray technique is currently the most frequently used method to produce calcium phosphate coatings. Hydroxyapatite(HAp), one form of calcium phosphate, is preferred by its ability to form a direct bond with living bone, resulting in improvements of implant fixation and faster bone healing. Recently, concerns have been raised regarding the viable use and long-term stability of plasma-spray HAp coatings due to its nature of comparatively thick, porous, and poor bonding strength to metal implants. Thin layers (maximum of few microns) of calcium phosphate were formed by an e-beam evaporation with and without ion bombardments. The Ca/P ration of film was controlled by either using the evaporants having the different ration of Ca/P with addition of CaO, or adjusting the ion beam assist current. The Ca/P ration had great effects on the structure formation after heat treatment and the dissolution bahavior. The calcium phosphate films produced by IBAD exhibited high adhesion strength.

• 한국재료학회지
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• 제28권5호
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• pp.308-314
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• 2018

Among the fuel cell electrolyte candidates in the intermediate temperature range, glass materials show stable physical properties and are also expected to have higher ion conductivity than crystalline materials. In particular, phosphate glass has a high mobility of protons since such a structure maintains a hydrogen bond network that leads to high proton conductivity. Recently, defects like volatilization of phosphorus and destruction of the bonding structure have remarkably improved with introduction of cations, such as Zr4+ and Nb5+, into phosphate. In particular, niobium has proton conductivity on the surface because of higher surface acidity. It can also retain phosphorus content during heat treatment and improve chemical stability by bonding with phosphorus. In this study, we fabricate niobium phosphate glass thin films through sol-gel processing, and we report the chemical stability and electrical properties. The existence of the hydroxyl group in the phosphate is confirmed and found to be preserved at the intermediate temperature region of $150-450^{\circ}C$.

• 한국전기전자재료학회논문지
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• 제20권9호
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• pp.756-760
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• 2007

Flame retardant(FR) properties were investigated with tricredyl phosphate(TCP) and tris(pentafluorophenyl)phosphine(TFPP) as additives for lithium-ion batteries. Thermal stability was improved with additives in $Li/LiNi\frac{1}{3}Mn\frac{1}{3}Co\frac{1}{3}O_2$ cells comparing to non-additive electrolytes. Oxygen evolution reaction of the cathode material was delayed to up $55^{\circ}C$, from $275^{\circ}C\;to\;330^{\circ}C$. Electrolytes with the 1 wt.% additives provided good FR properties while the resonable battery performance is maintained.

• 한국건축시공학회지
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• 제17권4호
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• pp.341-348
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• 2017

콘크리트 포장도로는 동절기 제설제에 의한 내구성 저하가 심각한 위협으로 거론되고 있고 그 보수에도 많은 비용이 소요되고 있다. 따라서 이러한 콘크리트 포장재에 대한 적절한 보수 대책의 마련과 이에 활용될 우수한 성능의 보수 재료가 요구되고 있는 상황인데, 본 연구에서는 국내에서 개발된 인산마그네슘 세라믹(Magnesium phosphate ceramics)을 대상으로 압축강도 특성 및 염소이온 침투 저항성, 길이변화 특성을 평가하여 국내 콘크리트 포장 도로의 보수 재료로 적용 가능성을 검토하였다. 평가 결과 모르타르의 유동성은 190mm의 평범한 수준을 나타내었으나 다소 점성이 높고 재료 자체의 흐름성은 크지 않았다. 응결 시간은 12분으로 매우 빠른 경화가 이루어졌으며 이에 따라 신속한 작업이 요구되었다. 모르타르의 압축강도 성능은 2시간에 38.4MPa, 24시간에 73.8MPa, 28일에 111.0MPa로 재령 초기부터 높은 수준을 나타내었다. 염소이온 침투 저항성 시험 결과 모르타르의 경우 143 Coulombs, 콘크리트의 경우 173 Coulombs으로 매우 우수한 수준을 나타내었다. 콘크리트의 길이변화 시험 결과는 재령 40일까지 $60{\times}10^{-6}$ 이하로 완만하게 감소하였으며, 보통의 시멘트 콘크리트의 길이변화 수준과 비교할 때 1/10 이하의 수준으로 우수한 체적안정성을 확보하고 있었다. 이상과 같이 인산마그네슘 세라믹은 우수한 강도 성능과 염소이온 침투 저항성, 체적 안정성을 보유하고 있음을 확인하였고, 향후 작업 시간이나 작업성에 대한 개선이 요구되며, 현장 적용시에는 이러한 부분에 대한 주의가 필요하다.

• Journal of Electrochemical Science and Technology
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• 제12권1호
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• pp.67-73
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• 2021

Nickel-rich lithium nickel-cobalt-manganese oxides (NCM) are viewed as promising cathode materials for lithium-ion batteries (LIBs); however, their poor cycling performance at high temperature is a critical hurdle preventing expansion of their applications. We propose the use of a functional electrolyte additive, triphenyl phosphate (TPPa), which can form an effective cathode-electrolyte interphase (CEI) layer on the surface of Ni-rich NCM cathode material by electrochemical reactions. Linear sweep voltammetry confirms that the TPPa additive is electrochemically oxidized at around 4.83 V (vs. Li/Li+) and it participates in the formation of a CEI layer on the surface of NCM811 cathode material. During high temperature cycling, TPPa greatly improves the cycling performance of NCM811 cathode material, as a cell cycled with TPPa-containing electrolyte exhibits a retention (133.7 mA h g-1) of 63.5%, while a cell cycled with standard electrolyte shows poor cycling retention (51.3%, 108.3 mA h g-1). Further systematic analyses on recovered NCM811 cathodes demonstrate the effectiveness of the TPPa-based CEI layer in the cell, as electrolyte decomposition is suppressed in the cell cycled with TPPa-containing electrolyte. This confirms that TPPa is effective at increasing the surface stability of NCM811 cathode material because the TPPa-initiated POx-based CEI layer prevents electrolyte decomposition in the cell even at high temperatures.

• 대한금속재료학회지
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• 제47권3호
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• pp.188-194
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• 2009

Recently, new extraction technology for manganese nodule has been developed as alternative noble metallic resources. It is important to understand thermodynamic behaviors of phosphorus in low basic slag system from the viewpoint of the refining processing optimization. Thermodynamic behaviors of phosphorus in the $FeO-MnO-CaO-SiO_2-MgO_{satd.}$ slag system were investigated at 1723 K with various oxygen potential and slag composition of low basicity. The experimental results for dependence of phosphorus on oxygen potential and slag basicity indicated that the dissolution mechanism of phosphorus into slag of low basicity could be derived as follows; $[P]+5/4O_2+(O^{2-})=({PO_{3.5}}^{2-})$ Present experimental results implied that stability of phosphorus in slag would be depended on both of $O^{2-}$ (basicity) and content of $Ca^{2+}$ in molten slag. The thermodynamic effect of FeO, MnO and $Na_2O$ on low basicity on phosphate capacity was discussed.

• Journal of Electrochemical Science and Technology
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• 제8권2호
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• pp.162-168
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• 2017

$LiNi_xCo_yMn_zO_2$ cathode materials have been the focus of much attention because of their high specific capacity. However, because of the poor interfacial stability between cathodes and electrolytes, the cycling performance of these materials fades rapidly, especially at high temperatures. In the present paper, we propose the use of tris(trimethylsilyl) phosphate (TMSPO), which contains phosphate and silyl functional groups, as a functional additive in electrolytes. The addition of TMSPO resulted in the formation of cathode electrolyte interphase (CEI) layers on the surfaces of the cathodes and effectively suppressed electrolyte decomposition reactions, even at high temperatures. As a result, cells cycled with TMSPO exhibited remarkable capacity, which remained after 50 cycles (82.0%), compared to cells cycled without TMSPO (64.6%).

• 한국광물학회지
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• 제15권4호
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• pp.315-327
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• 2002

벤토나이트에 포함된 몬모릴로나이트의 층간에 Al산화물의 기둥(pillar)을 만든 Al-층간가교 점토를 합성하였다. 이 Al-층간가교점토에 대해 XRD, DTA, 화학분석 등을 실시하여 광물학적 특성을 검토하였으며, 그리고 이 가교점토에 대하여 Batch법의 흡착실험을 통하여 인산이온의 흡착성을 검토하였다. X-선 회절분석의 결과, Al-층간가교점토는 상온에서 층간격이 $18.03 \AA$으로 증가되어 나타났고, $550\AA$가열에서도 약 $17\AA$을 나타내어 열적 안정성이 크며, 글리세롤에 의한 층간격의 팽윤은 매우 미약한 것으로 나타났다. 열분석 결과, 이 점토에는 pillar부분에 관련된 물의 탈수에 의한 것으로 보이는 $270^{\circ}C$와 $420^{\circ}C$의 특징적인 흡열반응이 나타났다. Al-층간가교 점토의 인산 이온에 대한 흡착실험의 결과, 몬모릴로나이트는 거의 흡착능력을 보이지 않는데 비하여 월등히 우수한 인산이온($PO_{4}^{3－}$ /)성을 나타냈다. 시료 2 g에 용액 20 mL의 실험에서 300 mg/L 이하의 인산 농도에서는 거의 100%의 흡착효율을 나타냈다. 그리고 인산 이온에 흡착된 시료를 $500^{\circ}C$로 가열한 후 재차 흡착실험을 행한 결과, 역시 매우 높은 흡착효율을 나타냈다. 따라서 Al-층간가교 점토의 인산 이온 흡착에 대한 재활용의 가능성이 큰 것으로 나타났다

• 한국건축시공학회지
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• 제14권1호
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• pp.68-75
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• 2014

In order to increase the integrity of the wellbore which is used to prevent the leakage of supercritical $CO_2$, it is necessary to develop a concrete that is strongly resistant to carbonation. In an environment where the concentration of $CO_2$ is exceptionally high, $Ca^{2+}$ ion concentration in pore solution of Portland cement concrete will drop significantly due to the rapid consumption of calcium hydroxide, which decreases the stability of the calcium silicate hydrate. In this research, calcium phosphates were used to modify Portland cement system in order to produce hydroxyapatite, a hydration product that is strongly resistant to carbonation under such an environment. According to the experimental results, calcium phosphates reacted with Portland cement to form hydroxyapatite. The formation of hydroxyapatite was verified using X-ray diffraction analyses with selective extraction techniques. When using dicalcium phosphate dihydrate and tricalcium phosphate, the 28-day compressive strength was lower than that of plain cement paste. However, the specimen with monocalcium phosphate monohydrate showed equivalent strength to that of plain cement paste.

• Journal of Periodontal and Implant Science
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• 제43권1호
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• pp.18-23
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• 2013

Purpose: The purpose of this study was to evaluate the osseointegration of calcium phosphate (CaP)-coated implants by ion beam assisted deposition with a lack of primary stability. Methods: A total of 20 CaP-coated implants were bilaterally placed in the mandible of five dogs. In the rotational implant group, the implants were inserted in oversized drilled sockets without mechanical engagement, while the conventional surgical protocol was followed in the control group. Each group was allowed to heal for 4 and 8 weeks. The bone-to-implant contact (BIC, %) was measured by a histometric analysis. Results: All of the implants were well-maintained and healing was uneventful. In the histologic observation, all of the implants tested were successfully osseointegrated with a high level of BIC at both observation intervals. There was no significant difference in BIC among any of the groups. Conclusions: Within the limitation of this study, successful osseointegration of CaP-coated implants could be achieved in unfavorable conditions without primary stability.