• Title/Summary/Keyword: stability of oil

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Effects of Extraction Method on the Thermal Oxidative Stability of Seed Oils from Camellia sinensis L. (녹차 종실유의 제조법에 따른 열산화 안정성 비교)

  • Kim, Mi-Sun;Lee, Jae-Hwan;Kim, Myong-Ae
    • Journal of the Korean Society of Food Culture
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    • v.25 no.6
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    • pp.788-794
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    • 2010
  • Camellia sinensis L. (green tea) seed oils were prepared by roasting at $213^{\circ}C$ and pressing (RP), pressing (P), and nhexane extraction (H). The physico-chemical properties of the RP, P, and H samples, including fatty acid composition, color, and sensory characteristics were analyzed. RP, P and H samples were thermally oxidized at $180^{\circ}C$, and oxidative stability was determined by DPPH, CDA, and p-AV at 0, 20, 40, 60, and 80 min. Compared to the P and H samples, RP resulted in significantly higher thermal oxidative stability according to the DPPH, CDA, and p-AV results (p<0.05). The ratio of unsaturated fatty acids to saturated fatty acids among RP, P, and H samples were significantly different (p<0.05). The oleic acid and linoleic acid contents in green tea seed oils were 58 and 23%, respectively. Hunter's color value of lightness (L) for the RP, P, and H samples was not significant. Redness (a) of RP was $3.47{\pm}0.119$ and yellowness (b) of H was $60.10{\pm}2.483$, which were significantly different. Compared to RP samples, H and P samples had the highest color and off-odor values in the sensory evaluation. RP samples showed the highest taste value and were significant overall (p<0.05). The thermal stability of RP extraction was more stable than any other method. Camellia sinensis L. seed oil extracted by RP had better sensory characteristics than other edible oils, including soybean oil, grape seed oil, and extra virgin olive oil.

A Study on the Combustion Characteristics of Petrochemical Process By-Product (석유화학 공정부산물의 연소특성에 대한 연구)

  • Lee, Yong-Il
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.11
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    • pp.1578-1584
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    • 2002
  • Combustion stability is one of the most important factors that must be considered in burning of heavy fuel oil, especially low-grade oil. This paper describes the combustion characteristics of petrochemical process by- product in the combustion furnace of heavy fuel oil. Main experimental parameters were combustion load, excess 02, fuel preheating temperature and air/fuel ratio. The capacity of CRF(combustion research facility) used in this study was 1.0 ton/hr and the burner is steam jet type suitable far heavy oil combustion and manufactured by UNIGAS in Italy. The fuel used in this experiment were 0.5 B-C, petrochemical process by-product and 3 kinds of 0.5 B-C/process by-product mixtures. The combustion stability was monitored and exhaust gases such as CO, NOx, SOx and particulates were measured with the excess $O_2$ and combustion load. The main purpose of this study is to clarify whether process by-product can be used as a boiler fuel or not in consideration of flame stability and emission properties.

Oxidative Stability of Fatty Acids and Tocopherols in the Fats and Oils during Microwave Heating (Microwave 오븐 가열에 의한 유지의 지방산과 토코페롤의 안정성)

  • 주광지;김은미
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.24 no.2
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    • pp.234-241
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    • 1995
  • Effect of microwave heating on the oxidative stability of the soybean oil, sesame oil, butter and margarine were investigated by mearsuring fatty acids amout and tocopherol losses. The index for chemical properteis, free fatty acid, peroxide value, anisidine value, carbonyl value, conjugated diene and triene levels were also mearsured in the oil samples for 5, 10, 15 and 20 min of heating in a microwave oven. No significant difference was observed on the fatty acids composition in the fats and oils before and after microwave heating. During microwave treatment, the oxidative degradation of the tocopherols in the samples became greater with increasing heating time. The amount of tocopherols in the soild fats, butter and margarine, dropped drastically after 5 min of heating and reduced to 95% of their original levels after 20min heating ${\gamma}$-tocopherol in butter showed the most unstable states and completely destroyed during microwave treatment for 20min. On the other hand, 80% of tocopherols in the liquid oils were still remained after 5min of heating except $\delta$-tocopherol in sesame oil.

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Studies on the Find out of Optimum Condition with Treated Antioxidants for the Stability of PALM Oil after Frying (팜(PALM) 기름 안정성 향상을 위한 항산화제 적정첨가조건 조사)

  • 이형재;이성갑
    • Journal of the Korean Professional Engineers Association
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    • v.31 no.5
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    • pp.110-120
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    • 1998
  • The effect of heat treatment and the order of antioxidants treatment toward the thermally oxidized palm oil which has been stored at 60 $^{\circ}C$ was studied. The summerized results of this study are as follows; 1. In the accelerated autoxidation condition, tocopherol showed no distinct effect on the changes of peroxide of value between added tocopherol samples pre-and post treatment by heating. But, rosemary extract showed opposite result. It was supposed that rosemary extract had lower thermostability then tocopherol, because rosemary extract lost it's antioxidative activity during heating process. 2. The changes of acid value and anisidine value were more affected by heat treatment than the order of antioxidant treatment. 3. The oxidative stability measured by OSI showed same tendency as peroxide value. That is, the antioxidative activity of tocopherol in palm oil was more dependent on addition of antioxidants than heat treatment, but the rosemary extract had opposite character for antioxidative action in palm oil.

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Effects of Filtration or Centrifugation on the Oxidative Stabilities of Sesame Oil (여과 및 원심 분리가 참기름의 산화 안정성에 미치는 영향)

  • Choe, Eun-Ok;Moon, Soo-Yeun
    • Applied Biological Chemistry
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    • v.37 no.3
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    • pp.168-174
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    • 1994
  • Effects of filtration and centrifugation on the oxidative stabilities of sesame oils during storage at $70^{\circ}C$ were studied by combination of determining peroxide values and conjugated dienoic acid values of oils and measuring the hexanal formation using headspace gas chromatography. Crude sesame oil from roasted seeds contained more free fatty acids, conjugated dienes, and metals (Fe, Cu, Mg and Zn); on the other hand, higher contents of moisture and ${\gamma}-tocopherol$ were found in the filtered or centrifuged oil. Only filtered oil contained more peroxides than the crude oil in spite of the color advantage of the highest L and b values among three oils. All the oils showed the tendency of increasing in total color difference during storage at $70^{\circ}C$, fatty acid compositions were relatively constant except for decreasing tendency of linoleic acid in filtered oil. No significant difference at 1% in the oxidative stabilities was observed between centrifuged oil and crude oil with higher susceptibility to the oxidation in the filtered oil. Centrifuged sesame oil was the best in the aspect of both oxidative stability and the oil color.

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Influence of pH, Emulsifier Concentration, and Homogenization Condition on the Production of Stable Oil-in-Water Emulsion Droplets Coated with Fish Gelatin

  • Surh, Jeong-Hee
    • Food Science and Biotechnology
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    • v.16 no.6
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    • pp.999-1005
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    • 2007
  • An oil-in-water (O/W) emulsion [20 wt% com oil, 0.5-6.0 wt% fish gelatin (FG), pH 3.0] was produced by high pressure homogenization, and the influence of pH, protein concentration, and homogenization condition on the formation of FG-stabilized emulsions was assessed by measuring particle size distribution, electrical charge, creaming stability, microstructure, and free FG concentration in the emulsions. Optical microscopy indicated that there were some large droplets ($d>10\;{\mu}m$) in all FG-emulsions, nevertheless, the amount of large droplets tended to decrease with increasing FG concentration. More than 90% of FG was present free in the continuous phase of the emulsions. To facilitate droplet disruption and prevent droplet coalescence within the homogenizer, homogenization time was adjusted in O/W emulsions stabilized by 2.0 or 4.0 wt% FG. However, the increase in the number of pass rather promoted droplet coalescence. This study has shown that the FG may have some limited use as a protein emulsifier in O/W emulsions.

Encapsulation of Flavors by Molecular Inclusion Using $\beta$-Cyclodextrin: Comparison with Spray-drying Process Using Carbohydrate-based Wall Materials

  • Cho, Young-Hee;Park, Ji-Yong
    • Food Science and Biotechnology
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    • v.18 no.1
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    • pp.185-189
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    • 2009
  • Microencapsulation of flavor was carried out by molecular inclusion process using $\beta$-cyclodextrin (${\beta}CD$). ${\beta}CD$-flavor complex was prepared at various flavor-to-${\beta}CD$ ratios (1:6-1:12) to determine the effect of ${\beta}CD$ concentration on the inclusion efficiency. Maximum total oil retention and minimal surface oil content were obtained at flavors to ${\beta}CD$ ratio of 1:10. The physical properties and controlled release pattern of flavors from ${\beta}CD$-flavor complex were measured and compared with spray-dried microcapsules prepared using carbohydrate wall system. ${\beta}CD$-flavor complex showed higher total oil retention and surface oil contents, smaller mean particle size, lower moisture uptake, and higher oxidation stability than spray-dried microcapsule. Oxidative stability of flavor was correlated with hygroscopicity of wall materials. The controlled release mechanism was highly affected by temperature and characteristics of wall materials.

Effect of pH, Chemical Composition and Additives on Stability of Soymilk Suspension (pH, 화학적 조성 및 첨가제가 두유(豆乳)의 현탁안정성에 미치는 영향)

  • Kim, Eun-Soo;Chung, Seong-Soo;Jo, Jae-Sun
    • Korean Journal of Food Science and Technology
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    • v.22 no.3
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    • pp.319-324
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    • 1990
  • The effects of pH, protein and fat content, addition of emulsifiers, stabilizer, sugar, salt and calcium salt on the stability of soymilk suspension were investigated by analyzing the cream separated and precipitates of soymilk which is prepared by various conditions. In the alkaline region of pH, soymilk showed a good stability of the suspension and particularly, above pH 10, precipitates were not formed. When 1.5% of palm oil with 0.4% of glycerine monostearate was added to soymilk in the hydrophile-lipophile balance (HLB) value of 4 to 7, resulted maximal emulsion stability occured below H LB 6. The stability was decreased with increasing the fat concentration and soy oil showed better emulsion stability than that of palm oil. Among the commercial stabilizers, 0.03% of carrageenan was most effective. The stability was not decreased by addition of sugar up to 3% while it was decreased by addition of sodium salt and calcium salt at low level.

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Effects of Basil and Majoram Essential Oils with or without Ascorbic Acid on Color and Oxidative and Microbial Stability of Beef Patties

  • Chung, Hai-Jung
    • Preventive Nutrition and Food Science
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    • v.9 no.1
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    • pp.1-6
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    • 2004
  • Fresh ground beef was mixed with ascorbic acid, basil essential oil, majoram essential oil, or each essential oil combined with ascorbic acid and stored at 1 $\pm$ 1$^{\circ}C$ for 7 days. Color, lipid oxidation (TBARS formation), aerobic bacterial counts and pH were determined. Basil and majoram essential oils were effective in inhibiting color deterioration, lipid oxidation and bacterial growth. The combined addition of basil and ascorbic acid showed the highest protection against color fading, followed by majoram + ascorbic acid, and ascorbic acid alone. Basil and majoram essential oils were most effective in delaying TBARS formation (p < ().01). Ascorbic acid did not exert an antioxidative effect and even exhibited a pro-oxidant effect. The pH values of all samples increased slightly, but no significant differences were observed, either among treatments or throughout the storage time (p > 0.05).

Stability evaluation and microseismic monitoring around Large Underground Oil Storage Cavern in Over-stressed Rock Mass (과지압 암반 내 대규모 지하 유류비축기지 안정성 평가 및 Microseismic 계측)

  • Lee Hee-Suk;Lee Dae-Hyuck;Kim Ho-Yeong;Hong Jee-Soo;Choi Young-Tae;Kim Seok-Jin;Park Yeon-Jun
    • 한국터널공학회:학술대회논문집
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    • 2005.04a
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    • pp.189-201
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    • 2005
  • Brittle failure has been detected in over-stressed rock mass during the construction of oil storage cavern. The main characteristics of stress induced brittle failure of the site are introduced. Various evaluation and measures are sought to stabilize the over-stressed rock mass. The major results from numerical analysis of the cavern are presented, and from current microseismic monitoring to detect hazard from brittle failure are presented.

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