The HF (Hollow fiber) extraction method was optimized to analysis seven species of pesticides in aqueous sample and analyzing samples by GC/MS. Hollow fiber extraction showed good efficiency when it was conducted under these conditions: organic solvent was toluene and agitation speed was 1200 rpm. The 15% concentration of NaCl was optimized when it was experimented between 5% and 25%. The equilibrium time was determined at 15 minutes. The pH 5 showed the best effect on the extraction efficiency. The linearities of calibration curves of seven species were good with correlation of regression ($r^2$) over 0.995 when they were experimented over a concentration range of $5{\mu}g/L$ to $50{\mu}g/L$. The analytical data exhibited the detection of limits (LODs) range of $0.37{\mu}g/L$ to $1.23{\mu}g/L$ and the limit of quantification (LOQs) range of $1.19{\mu}g/L$ to $3.91{\mu}g/L$. The optimized HF-LPME extraction method provides a simple and effective preparation and requires small amount of organic solvents and samples compared to conventional pre-treatment methods.
In Korea, the U.S. Tier-4 Final emission standards have been applied to agricultural machinery since 2015. This study was conducted to analyze the emission characteristics of agricultural tractors during plow tillage operations using PEMS (portable emissions measurement systems). The tractor working speed was set as M2 (5.95 km/h) and M3 (7.60 km/h), which was the most used gear stage during plow tillage operation. An engine idling test was conducted before the plow tillage operation was conducted because the level of emissions differed depending on the temperature of the engine (cold and hot states). The estimated level of emissions for the regular area (660 m2), which was the typical area of cultivation, was based on an implement width of 2.15 m and distance from the work area of 2.2 m. As a result, average emission of CO (carbon monoxide), THC (total hydrocarbons), NOx (nitric oxides), and PM (particulate matter) were approximately 6.17×10-2, 3.36×10-4, 2.01×10-4, and 6.85×10-6 g/s, respectively. Based on the regular area, the total emission of CO, THC, NOx, and PM was 2.62, 3.76×10-2, 1.63, and 2.59×10-4 g, respectively. The results of total emission during plow tillage were compared to Tier 4 emission regulation limits. Tier 4 emission regulation limits means maximum value of the emission per consumption power (g/kWh), calculated as ratio of the emission and consumption power. Therefore, the total emission was converted to the emission per power using the rated power of the tractor. The emission per power was found to be satisfied below Tier 4 emission regulation limits for each emission gas. It is necessary to measure data by applying various test modes in the future and utilize them to calculate emission because the emission depends on various variables such as measurement environment and test mode.
Transactions of the Korean Society of Mechanical Engineers A
/
v.37
no.11
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pp.1437-1443
/
2013
Railways are currently subject to the enforcement of speed limits for each curve as prescribed by the Railway Operating Rules in Korea. However, research is required to determine the maximum speed of trains passing through each curve that allows them to run without the risk of derailment in relation to the speed enhancement of existing railway tracks. In addition, factors affecting the running safety of railway vehicles can be classified into those in terms of vehicle aspects and those in terms of track aspects. This study sought to analyze the running safety of railway vehicles according to changes in the inclination of the rail from among the factors affecting the enhancement of safety against derailment. To increase the speed of trains passing through curves that have high derailment risk, this study also analyzed the running safety of railway vehicles according to the inclination of the rail and changes in running speed while a vehicle passes through each curve section in both the up and the down train line sections between Namsunghyun and Chungdo, which represent the actual conditions of railway tracks.
It is a fact that the straightening of track alignment is one of the undoubted ways to improve the train speed on conventional lines, while that requires huge investment resources. Therefore, the operation of a tilting train as well as the minimum improvement of track is suggested as an effective and economical alternative way for the speed-up of conventional lines. Since a driving mechanism of tilting train is different from those of existing trains, in order to make sure its operation safety and stability on conventional line, the performance of track and roadbed must be preferentially evaluated on the conventional line. Furthermore, it is necessary to estimate the tilting-train-induced roadbed response in detail since the roadbed settlement can lead to the track deformation and even derailment. In this research, the patterns of wheel load and lateral force were monitored and analyzed through the field tests, and the derailment coefficient and degree of wheel off-loading were calculated in order to evaluate the tilting train running safety depending on the running speeds (120km~180km) on the conventional line. Moreover, roadbed pressure, settlement and acceleration were also observed as tilting-train-induced roadbed responses in order to estimate the roadbed stability depending on the running speeds. Consequently, the measured derailment coefficient and degree of wheel off-loading were satisfied with their own required limits, and all of the roadbed responses were less than those of existing high-speed train (KTX) over an entire running speed range considered in this study. As a result of this study, the tilting train which will be operated in combination with existing trains is expected to give no adverse impact on the conventional line even with its improved running speed.
Park, Joon-Cheol;Kim, Yoon-Shin;Hong, Seung-Cheol;Choi, Joon-Gyu
Journal of Environmental Health Sciences
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v.34
no.5
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pp.395-402
/
2008
Road traffic noise causes considerable disturbance and annoyance in exposed inhabitants. Particularly, arterial road noise is a significant environmental problem in many urban areas in which higher traffic volume and higher car speed occur. Arterial road noise became the target of this investigation in Seoul, South Korea. Noise levels were measured at four points that were based on distance from roadside at the same measurement site and under the conditions as reported by the National Institute of Environmental Research (NIER) in 1999. The average noise levels ($L_{eq,1h}$) of the arterial road was 80.3 dBA at 5 m, 77.4 dBA at 10 m, 73.7 dBA at 20 m, 70.9 dBA at 30 m. A comparison between 1999 and 2008's measurement values has shown that in 2008 noise level is up by about 1.5 dBA, traffic volume has increased by about 15.7%, while car speed has decrease by about 8%. The relationship between 2008' measured values and predicted values using the NIER Equation is low under 10 m from the roadside. The influence range of arterial noise is calculated at 26 m for road noise limits in daytime. In relation to the comparison between traffic volume and noise level, the equivalence in traffic volume (Light car+10xHeavy car) is higher than other variables.
The effects of drum spacing, steam pressure and drum speed on drying rate of minced fish flesh on both single and double drum dryers were studied. Starch additions in the form of tapioca flour up to 2.5% have been found satisfactory for aiding in sheet formation at the doctor blade. When the retention time was adjusted to maintain a constant product moisture, the highest production rate was obtained at the smallest drum spacing and the highest steam pressure within the limits of experimental conditions considered. The operating conditions suitable for producing the flakes with 5% moisture were: 100 kPa (steam pressure), 0.1 mm (drum spacing) and 3 rpm (drum speed). The production rate and overall heat transfer coefficient under these conditions were $12.1\;kg/m^2$hr and 950 $W\;/m^2K$ respectively. The drying data were fitted well to the conventional drying model, namely $MR\;=\;A\;\exp\;(-k{\theta})$, resulting in the various drying constants depending the operating conditions.
PURPOSES : This study compared two measures of traffic flow effectiveness on roads with roundabouts and signalized intersections and determined the more appropriate measure. METHODS : In addition to average delay time, the conventionally used measure, average travel time was introduced to measure traffic flow effectiveness because it is able to be obtained through field survey and reflect different travel distances and speed limits of roundabouts and signalized intersections. Using the two measures, roundabouts and signalized intersections were compared through simulations in terms of traffic flow effectiveness. RESULTS : For one-way single-lane roads, the two measures indicated consistent results that roundabouts were more effective than were signalized intersections when the traffic volume was less than 300 vphpl but vice versa when it exceeded 450 vphpl; however, the measures yielded inconsistent results when the volume was 350~400 vphpl. For one-way double-lane roads, the two measures indicated consistent results that roundabouts were more effective than were signalized intersections when the volume was less than 200 vphpl but vice versa when it exceeded 400 vphpl; however, the measures yielded inconsistent results when the volume was 250~350 vphpl. The results obtained using the two measures differed substantially for double-lane roads because behaviors such as weaving and lane changing at roundabouts are more common in double-lane roads than in single-lane roads. CONCLUSIONS : The average delay time would be lower on roads with roundabouts, but average travel time would be lower on roads with signalized intersections. Thus, evaluating the relative effectiveness of roads with roundabouts and signalized intersections by using average delay time alone would be inappropriate, whereas using average travel time as the evaluation index would yield fairer results.
Transactions of the Korean Society of Automotive Engineers
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v.16
no.1
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pp.14-21
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2008
Synthetic gas is defined as reformed gas from hydrocarbon-based fuel and the major chemical species of the synthetic gas are $H_2$, CO and $N_2$. Among them, hydrogen from synthetic gas is very useful species in chemical process such as combustion. It is a main reason that many studies have been performed to develop an effective reforming device. Furthermore, other technologies have been studied for synthetic gas application, such as the ESGI(Exhaust Synthetic Gas Injection) technology. ESGI injects and burns synthetic gas in the exhaust pipe so that heat from hydrogen combustion helps fast warmup of the close-coupled catalyst and reduction of harmful emissions. However, it is very hard to understand combustion characteristic of hydrogen under low oxygen environment and complicated variation in chemical species in exhaust gas. This study focuses on the characteristics of hydrogen combustion under ESGI operating conditions using a CVC(Constant Volume Chamber). Measurements of pressure variation and flame speed have been performed for various oxygen and hydrogen concentrations. Results have been analyzed to understand ignition and combustion characteristics of hydrogen under lower oxygen conditions. The CVC experiments showed that under lower oxygen concentration, amount of active chemicals in the combustion chamber was a crucial factor to influence hydrogen combustion as well as hydrogen/oxygen ratio. It is also found that increase in volume fraction of oxygen is effective for the fast and stable burning of hydrogen by virtue of increase in flame speed.
Bae, SunHo;Choi, DongHee;Park, Jung-Wook;Lee, Soo Hyoung
Journal of Electrical Engineering and Technology
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v.12
no.4
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pp.1442-1448
/
2017
Recently, electric power systems have been operating with tight margins and have reached their operational limits. Many researchers consider a microgrid as one of the best solutions to relieve that problem. The microgrid is generally powered by renewable energies that are connected through power converters. In contrast to the rotational machines in the conventional power plants, the converters do not have physical rotors, and therefore they do not have rotational inertia. Consequently, a stand-alone microgrid has no inertia when it is powered by the only converter-based-generators (CBGs). As a result, the relationship between power and frequency is not valid, and the grid frequency cannot represent the power balance between the generator and load. In this paper, a superconducting flywheel energy storage system (SFESS) is applied to an inertia-free stand-alone (IFSA) microgrid. The SFESS accelerates or decelerates its rotational speed by storing or releasing power, respectively, based on its rotational inertia. Then, power in the IFSA microgrid can be balanced by measuring the rotor speed in the SFESS. This method does not have an error accumulation problem, which must be considered for the state of charge (SOC) estimation in the battery energy storage system (BESS). The performance of the proposed method is verified by an electromagnetic transient (EMT) simulation.
Purpose: The purpose of this study is to set up an anomaly detection criteria for sensor data coming from a motorcycle. Methods: Five sensor values for accelerator pedal, engine rpm, transmission rpm, gear and speed are obtained every 0.02 second from a motorcycle. Exploratory data analysis is used to find any pattern in the data. Traditional process control methods such as X control chart and time series models are fitted to find any anomaly behavior in the data. Finally unsupervised learning algorithm such as k-means clustering is used to find any anomaly spot in the sensor data. Results: According to exploratory data analysis, the distribution of accelerator pedal sensor values is very much skewed to the left. The motorcycle seemed to have been driven in a city at speed less than 45 kilometers per hour. Traditional process control charts such as X control chart fail due to severe autocorrelation in each sensor data. However, ARIMA model found three abnormal points where they are beyond 2 sigma limits in the control chart. We applied a copula based Markov chain to perform statistical process control for correlated observations. Copula based Markov model found anomaly behavior in the similar places as ARIMA model. In an unsupervised learning algorithm, large sensor values get subdivided into two, three, and four disjoint regions. So extreme sensor values are the ones that need to be tracked down for any sign of anomaly behavior in the sensor values. Conclusion: Exploratory data analysis is useful to find any pattern in the sensor data. Process control chart using ARIMA and Joe's copula based Markov model also give warnings near similar places in the data. Unsupervised learning algorithm shows us that the extreme sensor values are the ones that need to be tracked down for any sign of anomaly behavior.
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