• Bulletin of the Korean Chemical Society
• /
• v.28 no.2
• /
• pp.263-270
• /
• 2007

New mono- and bis-Cu(II)-triazacyclononane(tacn) complex that conjugated with 9-aminoacridine were synthesized, and their binding modes and DNA cleavage activity were investigated in this study. When the classic intercalator, 9-aminoacridine, was conjugated to mono- and bis-Cu(II)-tacn complexes, a significant red-shift and hypochromism in absorption spectrum was apparent in the acridine absorption region upon binding to DNA. Furthermore, the magnitude of the negative reduced linear dichroism signal in the substrate absorption region appeared to be larger than that in the DNA absorption region. These spectral observations indicated that the acridine moiety intercalated when the Cu(II)-tacn complex was conjugated. In contrast, from a close analysis of the circular and linear dichroism spectrum, the aminoacridine-free bis-Cu(II)-tacn complex was concluded to bind at the phosphate groups of DNA. The 9-aminoacridine-free-bis-Cu(II)-tacn complex produces the nicked and linear DNA. On the other hand, 9-aminoacridine conjugated mono-and bis-Cu(II)-tacn complexes showed unspecific binding with negligible DNA cleavage.

• Journal of Institute of Control, Robotics and Systems
• /
• v.16 no.2
• /
• pp.202-205
• /
• 2010

When we render 3D sound images using headphones or speakers, the main key of this technology is the Head-related transfer function (HRTF) database. Even though there are various HRTF databases, they have some drawbacks such as detrimental effects caused by imperfect measuring environment and insufficient measurement points. Moreover there is no database with Korean subjects. We are planning to develop the HRTF database for Korean. As a first step to establish the HRTF database aimed at Korean, the new HRTF measurement system with minimized aforementioned drawbacks is designed. In this paper, the newly designed HRTF measurement system is introduced and the overall effects caused by the diffraction of the apparatus, especially the headrest and backrest of the chair, are analyzed. The backrest of the chair does not distort the HRTFs significantly while the headrest makes significant distortion on the HRTFs and it could have significant effects on directional perception. We determined acceptable head rotation angle and head position of the subject for accurate HRTF measurement based on the experiments with B&K HATS. We conclude that the 3 degrees of the head rotation and the 1.5cm front/back/left/right shift of the head do not distort the HRTFs significantly.

• Archives of Pharmacal Research
• /
• v.19 no.6
• /
• pp.551-553
• /
• 1996

A genuine dammarane glycoside, named ginsenoside $Rg_{5}$, has been isolated by repeated column chromatography and preparative HPLC from the MeOH extract of Korean red ginseng (Panax ginseng C.A. Meyer). The chemical structure of ginsenoside$ Rg_{5}$ was determined as $3-O-[{\beta}-D-glucopyranosyl (1{\rightarrow}2)-{\beta}-D-glucopyranosyl]$ dammar-20(22), $24-diene-3{\beta},12{\beta}-diol$ by spectral and chemical methods. The stereostructure of a double bond at C-20(22) of ginsenoside $Rg_{5}$ was characterized as (E) from the chemical shift of C-21 in the $^{13}C-NMR $and a NOESY experiment in the $^{1}H-NMR$.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
• /
• v.23 no.8
• /
• pp.853-860
• /
• 2012

In this paper, We shed light on radio spectrum policy and strategic planning of the United States of America and draw some conclusions. First of all, as the radio technology evolves with time, paradigm shift from command & control to market-based approach and spectrum commons is reviewed. Strategic spectrum planning of USA is also analyzed and some suggestions are drawn. In particular, USA plan for developing dynamic spectrum access(DSA) technologies and implementation of the test-bed for the DSA spectrum sharing is discussed, which improves the spectral utilization. Finally We deal with spectrum re-farming issue for mobile broadband and implicative points based on the National Broadband Plan.

• Bulletin of the Korean Chemical Society
• /
• v.7 no.4
• /
• pp.267-271
• /
• 1986

The ionomeric blend and the ionic aggregation studies by using a Fourier-transform infrared spectroscopy(FT-IR) are presented. Two ionomers were prepared, one is barium polyacrylate and the other is barium polystyrenesulfonate. The blend of the two ionomers of the barium salts shows intermolecular ionic interaction between the carboxylated ionomer and the sulfonated ionomer. This interaction leads to considerable differences between the spectrum of the blend and the sum of the spectra of the pure ionomers. From our results, it is shown that ionic interactions must play an important role in the compatibility of the two ionomers. In the ionic aggregation study, the bands due to asymmetric stretching mode of carboxylate anion(COO-) in the carboxylated ionomer and the ionomer blend increase in intensity with increasing the divalent barium cations. These results indicate the formation of ion pairs. The doublet due to the asymmetric stretching modes of the carboxylate anion(COO-) is concerned with a sort of local structure found in the ion aggregation. By considering a possible structure for multiplets in the blend, the spectral splitting and the frequency shift are well explained.

• Journal of Positioning, Navigation, and Timing
• /
• v.9 no.4
• /
• pp.293-304
• /
• 2020

In this paper, various modulation techniques, including the legacy Global Navigation Satellite System (GNSS) signal modulation techniques, are introduced and the spectral characteristics and correlation characteristics of signals with various modulation techniques are analyzed based on numerical simulation. With the development of various GNSS services, the limited frequency band has become increasingly saturated, and issues of interoperability and compatibility have emerged in the new GNSS design. Since the efficient allocation of frequency resources is closely related to spectrum design, modulation techniques are one of the important signal design parameters of new signal design. Signal modulation techniques are closely related to various figure of merits (FoMs) as well as spectrum characteristic, and in some cases there is a complicated trade-off between FoMs. Thus, the FoMs associated with modulation technology should be analyzed and the best signal candidates should be chosen carefully via the trade-off analysis for FoMs. In this paper, we define the modulation technique based on Phase Shift Keying (PSK), Binary Offset Carrier (BOC) and Continuous Phase Modulation (CPM) for the design of KPS signals, and the FoMs of signals in terms of spectrum and correlation function are evaluated. Signals with various modulation techniques are implemented through a numerical simulation, and the relevant FoMs are analyzed.

• The Bulletin of The Korean Astronomical Society
• /
• v.46 no.2
• /
• pp.71.2-71.2
• /
• 2021

Using multi-epoch spectra of active galactic nuclei (AGN) obtained from the Sloan Digital Sky Survey, we identify 16 spectrally variable sources, for which the spectral shapes of broad emission lines significantly vary with a time scale of yrs. Out of them, 3 AGNs are already known as changing-look (CL) AGNs by previous studies. 6 AGNs are newly identified as CL AGNs from our study. A majority of these AGNs are relatively faint and their variability in the continuum is small, which may explain their non-detection in the previous studies. 7 sources are known as binary AGN candidates based on the systematic velocity offset between broad emission lines and narrow emission lines. For those sources and 3 CL AGNs, we find that the peak of broad emission lines had been shifted up to a few thousands km/s for ~10 years, implying that those can be promising candidates for pc-scale binary AGNs or recoiling black holes. We plan to conduct multiwavelength follow-up studies to nail down the physical origin of the velocity shift.

• Bulletin of the Korean Chemical Society
• /
• v.24 no.4
• /
• pp.446-452
• /
• 2003

Some new nanohybrid materials have been synthesized by intercalating the oxotitanium(IV) meso-tetrakis(4- sulfonatophenyl) porphyrin$(O=Ti^{(IV)} TSPP)$ into the Zn/Al layered double hydroxides (LDHs), and their structures and photophysical properties have been investigated by various laser spectroscopic techniques. According to the XRD pattern of the synthesized nanohybrid materials, the macrocycle plane of $O=Ti^{(IV)}$ TSPP are grafted perpendicular to the LDH layers. The $O=Ti^{(IV)}$ TSPP-intercalated LDH exhibits band broadening of the absorption spectrum and a blue shift of Q-band as compared to that observed in solution. Resonance Raman spectral measurements demonstrate that the positively charged LDHs give rise to a slight decrease of the electronic density of the porphyrin ring accompanying a small change of the electronic distribution of the $O=Ti^{(IV)}$ TSPP. Consequently the LDH environment affects the energies of the two highest occupied molecular orbitals (HOMOs) of the $O=Ti^{(IV)}$) TSPP, $a_{1u}$ and $a_{2u}$, producing a mixed orbital character. Being consistent with these electronic structural changes of $O=Ti^{(IV)}$ TSPP in LDH, both the fluorescence spectral change and the fsdiffuse reflectance transient measurements imply that the photoexcitation of the $O=Ti^{(IV)}$ TSPP intercalated into LDH undergoes fast relaxation to the O=Ti(IV) $TSPP^+-LDH^- $charge transfer (CT) state within a few picoseconds, followed by a photoinduced electron transfer between the O=Ti(IV) TSPP and LDHs with a rate constant greater than %1×10^{10}S^{-1}$. No evidence is found for back electron transfer. In conclusion, the $O=Ti^{(IV)}$ TSPP intercalated LDH seems to be a possible candidate for an artificial reaction center for an efficient solar energy conversion system.

• Applied Biological Chemistry
• /
• v.39 no.1
• /
• pp.89-94
• /
• 1996

Three sesquiterpene ortho-naphthoquinones were isolated from the methanolic extract of root bark of Ulmus davidiana Planch whose stem and root bark have been used as an oriental medicine for the treatment of edema, mastitis, gastric cancer and inflammation. The structures of these compounds were established on the basis of spectral data obtained from UV-vis, IR, HR-EIMS and NMR spectrometry, including the pulse field gradient (PFG)-HMQC and HMBC techniques. Their structures were determined as 2,3-dihydro-3,6,9-trimethylnaphtho(1,8-b,c)pyran-7,8-dione, 3,6,9-trimethylnaphtho(1,8-b,c)pyran-7,8-dione and 2,3-dihydro-4-hedroxy-3,6, 9-trimethylnaphtho(1,8-b,c)pyran-7,8-dione, which were identified as mansonones E. F and H, respectively. These compounds have originally been isolated from Mansonia altissima Chev, but have never been isolated from Ulmus davidiana Planch. Especially, mansonone H was isolated for the first time from Ulmaceae. The mismatched carbon chemical shifts of mansonones E and F in the reported literature were corrected by the aid of the PFG-HMBC spectral data.

• Korean Journal of Optics and Photonics
• /
• v.19 no.2
• /
• pp.127-131
• /
• 2008

A refractometric glucose biosensor incorporating a vertically coupled microring resonator in polymers was proposed and realized. The ring was covered with a target analyte of glucose solution with a certain concentration, so that its effective refractive index could be altered and, as a result, the resonance wavelength of the sensor was shifted. Therefore the concentration of the glucose solution can be estimated by observing the shift in the resonance wavelength. Two schemes were exploited for enhancing the sensitivity of the sensor. First, the effective refractive index of the polymeric waveguide used for the resonator sensor was adjusted to approach that of the target analyte as best as possible. Second, the ring waveguide, which serves as a crucial sensing part, was appropriately over-etched to enlarge its contact area with the analyte. The proposed resonator sensor was designed with the beam propagation method. The refractive indices of the core and cladding polymer involved were 1.430 and 1.375 respectively, leading to the waveguide's effective refractive index of ${\sim}1.390$, which is faiirly close to that of the glucose solution of ${\sim}1.333$. The prepared ring resonator with the $400-{\mu}m$ radius exhibited the free spectral range of 0.66 nm, the bandwidth of 0.15 nm, and the quality factor of 10,000. For the sensor operating at 1,550 nm wavelength, the achieved sensitivity was as great as 0.28 pm/(mg/dL), which is equivalent to 200 nm/RIU.