• Title/Summary/Keyword: specific surface areas

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Trace Metals in Surface Sediments of Garolim Bay, Korea (가로림만 표층 퇴적물 내 미량금속 분포 특성)

  • PARK, KYOUNGKYU;CHOI, MANSIK;JOE, DONGJIN;JANG, DONGJUN;PARK, SOJUNG
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.25 no.2
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    • pp.9-25
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    • 2020
  • In 2010 and 2015, total 77 surface sediment samples were collected to assess the anthropogenic effects of trace metals in surface sediments of Garolim Bay, and the physical characteristics (particle size and specific surface area) and geochemical components (major (Al, Ca, Fe, K, Ba) and trace metals (Mn, Cs, Cr, Co, Ni, Cu, Zn, Pb), organic carbon and calcium carbonate) were analyzed. Mean grain size of Garolim Bay surface sediments ranged from 0.51-5.58 Ø (mean 3.98 Ø) and increased from the inlet of bay to the inner bay, and from the waterway to the land. Most of the metal concentrations except for some elements showed the similar distribution to those of mean grain size and specific surface area. As the particle size decreased and the specific surface area increased, the metal concentration increased. In order to estimate the factors controlling the concentration of trace metals, factor analysis was performed, and three factors were extracted (92.7% of the total variation). Factor 1 accounted for 71.3% of the total variation, which was a grain size factor. Factor 2 accounted for 14.2% of the total variation, Factor 3 accounted for 7.2% of the total variance. Enrichment factor was calculated using the particle size corrected background concentration. Metals with a enrichment factor of 1.5 or higher and the number of samples were 4 for Cr (St. 1, 16, 27, 39) and 1 for Pb (St. 39), but there were little differences in the concentrations of 1M HCl leached metals for these metals. The percentage of 1M HCl leached fraction to total metal concentration decreased in the order of Pb~Co>Cu>Zn~Mn>Ni>Cr. Comparing this value with contaminated and clean sediments in other coastal areas, the percentages for each metal were similar regardless of the trace metal levels in all regions. This fact might be resulted from the reaction between the 1M HCl solution and the different sediment constituents, indicating that there is a limit to apply this percentage of leached metal to the estimation of the contamination extent.

Characterization and Preparation of Al-Pillared Clay (Aluminium-Pillared Clay의 제조 및 특성)

  • Park, Se-Jun;Ha, Baik-Hyon;Jeong, Soon-Yong;Suh, Jeong-Kwon;Lee, Jung-Min
    • Applied Chemistry for Engineering
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    • v.10 no.2
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    • pp.304-309
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    • 1999
  • Aluminum-pillared clay was prepared by the intercalation of Al-hydroxy oligomer into domestic bentonite. The solid products are characterized by XRD, nitrogen adsorption/desorption, EDX, and SEM. The solid products show relatively high specific surface areas in the range of $104{\sim}228m^2/g$, and their specific surface area, micropore surface area, and micropore volume increase with increasing the mole ratio of OH/Al. From the results of pore size distribution calculated by BJH equation, it was found that aluminum-pillared clay also contains much mesopore near $40{\AA}$. These results indicate that Al-hydroxy oligomer was intercalated into bentonite, and aluminum oxide was pillared among the layers of bentonite, and micropore and mesopore was finally developed into layers. As OH/Al mole ratio increases, the thermal stability of aluminum-pillared clay increases. This result can be explained by the fact that the density of layers is increased due to the formation of aluminum pillars.

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Understanding of Non-Thermal Atmospheric Pressure Plasma Characteristics Produced in Parallel Plate Type Geometry

  • Choe, Wonho;Moon, Se Youn;Kim, Dan Bee;Jung, Heesoo;Rhee, Jun Kyu;Gweon, Bomi
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.144-144
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    • 2013
  • Non-thermal atmospheric pressure plasmas have recently garnered much attention due to their unique physical and chemical properties that are sometimes significantly different from those of low pressure plasmas. It can offer many possible application areas including nano and bio/medical areas. Many different types of plasma sources have been developed for specific needs, which can be one of the important merits of the atmospheric pressure plasmas since characteristics of the produced plasma depend significantly on operating parameters such as driving frequency, supply gas type, driving voltage waveform, gas flow rate, gas composition, geometrical factor etc. Among many source configurations, parallel plate type geometry is one of the simplest configurations so that it can offer many insights for understanding basic underlying physics. Traditionally, the parallel plate type set up has been studied actively for understanding low pressure plasma physics along with extensive employment in industries for the same reason. By considering that understanding basic physics, in conjunction with plasma-surface interactions especially for nano & bio materials, should be pursued in parallel with applications, we investigated atmospheric pressure discharge characteristics in a parallel plate type capacitive discharge source with two parallel copper electrodes of 60 mm in diameter and several millimeters in gap distance. In this presentation, some plasma characteristics by varying many operating variables such as inter-electrode distance, gas pressure, gas composition, driving frequency etc will be discussed. The results may be utilized for plasma control for widening application flexibility.

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A review of ground camera-based computer vision techniques for flood management

  • Sanghoon Jun;Hyewoon Jang;Seungjun Kim;Jong-Sub Lee;Donghwi Jung
    • Computers and Concrete
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    • v.33 no.4
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    • pp.425-443
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    • 2024
  • Floods are among the most common natural hazards in urban areas. To mitigate the problems caused by flooding, unstructured data such as images and videos collected from closed circuit televisions (CCTVs) or unmanned aerial vehicles (UAVs) have been examined for flood management (FM). Many computer vision (CV) techniques have been widely adopted to analyze imagery data. Although some papers have reviewed recent CV approaches that utilize UAV images or remote sensing data, less effort has been devoted to studies that have focused on CCTV data. In addition, few studies have distinguished between the main research objectives of CV techniques (e.g., flood depth and flooded area) for a comprehensive understanding of the current status and trends of CV applications for each FM research topic. Thus, this paper provides a comprehensive review of the literature that proposes CV techniques for aspects of FM using ground camera (e.g., CCTV) data. Research topics are classified into four categories: flood depth, flood detection, flooded area, and surface water velocity. These application areas are subdivided into three types: urban, river and stream, and experimental. The adopted CV techniques are summarized for each research topic and application area. The primary goal of this review is to provide guidance for researchers who plan to design a CV model for specific purposes such as flood-depth estimation. Researchers should be able to draw on this review to construct an appropriate CV model for any FM purpose.

Simulation of Grape Downy Mildew Development Across Geographic Areas Based on Mesoscale Weather Data Using Supercomputer

  • Kim, Kyu-Rang;Seem, Robert C.;Park, Eun-Woo;Zack, John W.;Magarey, Roger D.
    • The Plant Pathology Journal
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    • v.21 no.2
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    • pp.111-118
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    • 2005
  • Weather data for disease forecasts are usually derived from automated weather stations (AWS) that may be dispersed across a region in an irregular pattern. We have developed an alternative method to simulate local scale, high-resolution weather and plant disease in a grid pattern. The system incorporates a simplified mesoscale boundary layer model, LAWSS, for estimating local conditions such as air temperature and relative humidity. It also integrates special models for estimating of surface wetness duration and disease forecasts, such as the grapevine downy mildew forecast model, DMCast. The system can recreate weather forecasts utilizing the NCEP/NCAR reanalysis database, which contains over 57 years of archived and corrected global upper air conditions. The highest horizontal resolution of 0.150 km was achieved by running 5-step nested child grids inside coarse mother grids. Over the Finger Lakes and Chautauqua Lake regions of New York State, the system simulated three growing seasons for estimating the risk of grape downy mildew with 1 km resolution. Outputs were represented as regional maps or as site-specific graphs. The highest resolutions were achieved over North America, but the system is functional for any global location. The system is expected to be a powerful tool for site selection and reanalysis of historical plant disease epidemics.

Prediction of Strong Ground Motion in Moderate-Seismicity Regions Using Deterministic Earthquake Scenarios

  • Kang, Tae-Seob
    • Journal of the Earthquake Engineering Society of Korea
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    • v.11 no.4
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    • pp.25-31
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    • 2007
  • For areas such as the Korean Peninsula, which have moderate seismic activity but no available records of strong ground motion, synthetic seismograms can be used to evaluate ground motion without waiting for a strong earthquake. Such seismograms represent the estimated ground motions expected from a set of possible earthquake scenarios. Local site effects are especially important in assessing the seismic hazard and possible ground motion scenarios for a specific fault. The earthquake source and rupture dynamics can be described as a two-step process of rupture initiation and front propagation controlled by a frictional sliding mechanism. The seismic wavefield propagates through heterogeneous geological media and finally undergoes near-surface modulations such as amplification or deamplification. This is a complex system in which various scales of physical phenomena are integrated. A unified approach incorporates multi-scale problems of dynamic rupture, radiated wave propagation, and site effects into an all-in-one model using a three-dimensional, fourth-order, staggered-grid, finite-difference method. The method explains strong ground motions as products of complex systems that can be modified according to a variety of fine-scale rupture scenarios and friction models. A series of such deterministic earthquake scenarios can shed light on the kind of damage that would result and where it would be located.

Interconnected meso/microporous carbon derived from pumpkin seeds as an efficient electrode material for supercapacitors

  • Gopiraman, Mayakrishnan;Saravanamoorthy, Somasundaram;Kim, Seung-Hyun;Chung, Ill-Min
    • Carbon letters
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    • v.24
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    • pp.73-81
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    • 2017
  • Interconnected meso/microporous activated carbons were prepared from pumpkin seeds using a simple chemical activation method. The porous carbon materials were prepared at different temperatures (PS-600, PS-700, PS-800, and PS-900) and demonstrated huge surface areas ($645-2029m^2g^{-1}$) with excellent pore volumes ($0.27-1.30cm^3g^{-1}$). The well-condensed graphitic structure of the prepared activated carbon materials was confirmed by Raman and X-ray diffraction analyses. The presence of heteroatoms (O and N) in the carbon materials was confirmed by X-ray photoemission spectroscopy. High resolution transmission electron microscopic images and selected area diffraction patters further revealed the porous structure and amorphous nature of the prepared electrode materials. The resultant porous carbons (PS-600, PS-700, PS-800, and PS-900) were utilized as electrode material for supercapacitors. To our delight, the PS-900 demonstrated a maximum specific capacitance (Cs) of $303F\;g^{-1}$ in 1.0 M $H_2SO_4 $ at a scan rate of 5 mV. The electrochemical impedance spectra confirmed the poor electrical resistance of the electrode materials. Moreover, the stability of the PS-900 was found to be excellent (no significant change in the Cs even after 6000 cycles).

ESTIMATION OF LONG-TERM POLLUTANT REMOVAL EFFICIENCIES OF WET RETENTION/DETENTION BASINS USING THE WEANES MODEL

  • Youn, Chi-Hyueon;Pandit, Ashok;Cho, Han-Bum
    • Proceedings of the Korea Water Resources Association Conference
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    • 2005.05b
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    • pp.215-219
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    • 2005
  • A macro spreadsheet model, WEANES (Wet Pond Annual Efficiency Simulation Model), has been developed to predict the long-term or annual removal efficiencies of wet retention/detention basins. The model uses historical, site-specific, multi-year, rainfall data, usually available from a nearby National Oceanic and Atmospheric Administration (NOAA) climatological station to estimate basin efficiencies which are calculated based on annual mass loads. Other required input parameters are: 1) watershed parameters; drainage area, pervious curve number, directly connected impervious area, and ti me of concentration, 2) pond parameters; control and overflow elevations, pond side slopes, surface areas at control elevation and pond bottom; 3) outlet structure parameters; 4) pollutant event mean concentrations; and 5) pond loss rate which is defined as the net loss due to evaporation, infiltration and water reuse. The model offers default options for parameters such as pollutant event mean concentrations and pond loss rate. The model can serve as a design, planning, and permitting tool for consulting engineers, planners and government regulators.

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Effect of Bacterial Cellulose Addition on the Property of Chemithermomechanical Pulp Sheet (박테리아 셀룰로오스의 첨가가 화학열기계펄프의 종이물성에 미치는 영향)

  • 조남석;최태호;서원성
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.30 no.4
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    • pp.42-48
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    • 1998
  • The bacterial cellulose(BC) has many unique properties that are potentially and commercially beneficial. In order to enhance inherently inferior physical property of chemithermomechanical pulp(CTMP) sheet, chemical pulp has been used widely. Bacterial cellulose also has an enhanced sheet strength because of its unique physical and morphological features. This study was carried out to inverstigate the effect of BC addition on physical properties of CTMP sheets. The effect of BC addition on its optical properties was also discussed. The apparent density, internal bond strength, Young's modulus, tensile strength and folding endurance of CTMP sheet are increasing with increase of BC contents. This strength increase would be attributed to the increase of relative bonding sites among pulp fibers by addition of BC which has microfibrillar structure with very high specific surface areas. There were not so significant changes in opacity of CTMP sheet upto 20% addition level of BC, while over 40% addition, the opacity gradually decreased and levelled off. Porosity is decreased with addition of BC. This decrease would be attributed to densification of sheet by fine and filamentous structure of BC fibers.

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Catalytic Conversion of 1,2-Dichlorobenzene Using V2O5/TiO2 Catalysts by a Thermal Decomposition Process (기상고온합성 V2O5/TiO2 촉매에 의한 1,2-Dichlorobenzene 제거 특성)

  • Chin, Sung-Min;Jurng, Jong-Soo;Lee, Jae-Heon
    • Journal of Environmental Science International
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    • v.17 no.11
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    • pp.1273-1279
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    • 2008
  • This study examined the catalytic destruction of 1,2-dichlorobenzene on ${V_2}{O_5}/TiO_2$ nanoparticles. The ${V_2}{O_5}/TiO_2$ nanoparticles were synthesized by the thermal decomposition of vanadium oxytripropoxide and titanium. The effects of the synthesis conditions, such as the synthesis temperature and precursor heating temperature, were investigated. The specific surface areas of ${V_2}{O_5}/TiO_2$ nanoparticles increased with increasing synthesis temperature and decreasing precursor heating temperature. In addition, the removal efficiency of 1,2-dichlorobenzene was promoted by a decrease in heating temperature. However, the removal efficiency of 1,2-dichlorobenzene was decreased by an anatase to rutile phase transformation at temperatures $1,300^{\circ}C$.