• Title/Summary/Keyword: specific heat capacity

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An analysis on the characteristics of regasification system for gas fuelled ship depending on the mixing ratio of eglycol and water (Gas Fuelled Ship용 재기화 시스템의 Eglycol Water 혼합비율에 따른 시스템 특성분석)

  • Lee, Yoon-Ho;Kim, You-Taek;Kang, Ho-Keun
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.7
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    • pp.799-805
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    • 2014
  • Recently, the regulations of the Local and Global for a variety of air pollution prevention has been enhanced by the steep rise in fuel oil prices. So, the appearance of Gas Fuelled Ships became necessary. In this study, we configured a regasification system which uses Eglycol water as a heating medium to evaporate before being supply fuel to the DF engine, then we analysed the system properties according to the Eglycol water mixing ratio. The results were as follows. When pressure, temperature, and flux of natural gas(NG) which are supplied to DF engines are uniformly kept, the higher mixing ratio of Eglycol is, the lower mixing specific heat of Eglycol water. And the cycle flux and electric power were 1.65 and 1.54 times more required. respectively, than water was used as the heating medium. Basic variables including mass flux according to the mixing ratio of Eglycol water, required electric power of operating fluid pumps, the temperature of natural gas which is supplied to the engine, and the heat exchanger's capacity were drawn from the gotten results.

Effect of Annealing Temperature on the Anode Properties of TiO2 Nanotubes for Rechargeable Lithium Batteries (열처리 온도에 따른 TiO2 나노튜브의 리튬이차전지 음전극 특성)

  • Choi, Min Gyu;Kang, Kun Young;Lee, Young-Gi;Kim, Kwang Man
    • Korean Chemical Engineering Research
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    • v.50 no.1
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    • pp.25-29
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    • 2012
  • $TiO_2$ nanotubes are prepared from rutile prticles via an alkaline hydrothermal synthesis and the consequent heat treatment at $300{\sim}500^{\circ}C$. The physical and electrochemical properties of the $TiO_2$ nanotubes are characterized for use as a anode material of rechargeable lithium battery. In particular, the microscale dusts as an impurity component occurred in the purification step after the hydrothermal reaction are completely removed to yield $TiO_2$ nanotube with a higher specific surface area and more obvious crystalline phases. As the annealing temperature increases, the specific surface area is slightly decreased due to some aggregation between the isotropically dispersed nanotubes. Highest initial discharge capacity of 250 mAh $g^{-1}$ is achieved for the $TiO_2$ nanotube annealed at $300^{\circ}C$, whereas the $400^{\circ}C$ $TiO_2$ nanotube shows the superior cycle performance and high-rate capability.

A Study on the Synthesis and Electrochemical Characteristics of Carbonized Coffee Powder for Use as a Lithium-Ion Battery Anode (리튬 이온 이차전지 음극 활물질용 탄화 커피 분말 제조 및 전기화학적인 특성연구)

  • Kim, Tae Gyun;Cho, Jin Hyuk;Pham-Cong, De;Jeon, Injun;Hwang, Jin Hyun;Kim, Kyoung Hwa;Cho, Chae Ryong
    • New Physics: Sae Mulli
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    • v.68 no.12
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    • pp.1315-1323
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    • 2018
  • We studied the carbonization due to the annealing condition of waste coffee powder for application as an active anode material for lithium-ion batteries (LIBs). The coffee powder used as an active anode material for LIBs was obtained from coffee beans, not from a coffee shells. The waste coffee powder was dried in air and heat-treated in an $Ar/H_2$ atmosphere to obtain a pore-forming activated carbon powder. The specific capacity of the sample annealed at $700^{\circ}C$ was still 303 mAh/g after 1000 cycles at a current density of 1000 mA/g and with a coulombic efficiency of over 99.5%. The number of pores and the pore size of the waste coffee powder were increased due to chemical treatment with KOH, which had the some effect as an increased specific surface area. The waste coffee powder is considered to be a very promising active anode material because of both its excellent electrochemical properties due to enhanced carrier conduction and its being a cost effective resource for use in LIBs.

Absorption Characteristics of Water-Lean Solvent Composed of 3-(Methylamino)propylamine and N-Methyl-2-Pyrrolidone for CO2 Capture (3-메틸아미노프로필아민과 N-메틸-2-피롤리돈을 포함한 저수계 흡수제의 CO2 포집 특성)

  • Shuai Wang;Jeong Hyeon Hong;Jong Kyun You;Yeon Ki Hong
    • Korean Chemical Engineering Research
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    • v.61 no.4
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    • pp.555-560
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    • 2023
  • Conventional aqueous amine-based CO2 capture has a problem in that a large amount of renewable energy is required for CO2 stripping and solvent regeneration in its industrial applications. This work proposes a water-lean absorbent that can reduce regeneration energy by lowering the water content in the absorbent with high absorption capacity for CO2. To this purpose, this water-lean solvent introduced NMP (N-methyl-2-pyrrolidone), which has a higher physical solubility in CO2 and a low specific heat capacity comparing to water, along with 3-methylaminopropylamine (MAPA), a diamine, into the absorbent. The circulating absorption capacity and absorption rate for CO2 of this water-lean solvent were measured using a packed tower. When NMP was added to the absorbent, the absorption rate was improved. In the case of the absorbent containing 2.5M MAPA was used, the maximum circulating absorption capacity was obtained when 10 wt% of NMP was included in absorbent. The overall mass transfer coefficient increased as the concentration of NMP increased. However, at loading values higher than 0.5, the increment in mass transfer coefficient decreased as the concentration of NMP increased. When the lean loading value is low, the mass transfer resistance due to viscosity of the absorbent is low, so the overall mass transfer coefficient increases with the addition of NMP. However, as the lean loading value increases, the viscosity of the absorbent increases, and the diffusivity of CO2 and MAPA decreases, resulting in sharply decreasing of the overall mass transfer coefficient.

Thermophysical Properties of the Soybean Curd and Prediction of its Thermal Conductivity 1 Measurement of Thermophysical Properties of the Soybean Curd (두부의 전열물성 및 유효열전도도의 추정 1. 두부의 전열물성의 추정)

  • KONG Jai-Yul
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.15 no.3
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    • pp.211-218
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    • 1982
  • The specific heat capacity and density of soybean oil and soy protein composing of the soybean curd were measured between $30^{\circ}C\;and\;-40^{\circ}C$. The thermal conductivity of soybean oil was measured to be 0.160 and 0.140, $W/m{\cdot}K$ at unfrozen and frozen states, respectively. The effective thermal conductivity of the soybean curd depended not only on its water content but also on its fat and protein contents.

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A Comparison of Laser Flash and the Divided-bar Methods of Measuring Thermal Conductivity of Rocks (암석 열전도도 측정을 위한 Laser Flash Method와 Divided-bar Method 비교)

  • Oh, Jae-Ho;Kim, Hyoung-Chan;Park, Jeong-Min
    • Economic and Environmental Geology
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    • v.44 no.5
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    • pp.387-397
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    • 2011
  • In this study, we conducted the study of the merits and demerits of the laser flash and the divided-bar methods for measuring the thermal conductivity of rocks and investigated applicability of the divided-bar apparatus which was developed by KIGAM. The laser flash method can measure thermal diffusivity, specific heat capacity, and thermal conductivity of rocks with even small thickness (< ~3 mm) in the high temperature range($25-200^{\circ}C$) in non-contact mode. For the laser flash method, samples must be uniform and homogeneous. In the case of the divided-bar method, the apparatus measures only thermal conductivity of rock samples at the room temperature. We measured thermal conductivities of 12 rock samples with low density and high porosity using two methods. In the laser flash method, there exist potential errors caused by the effect of pulse dispersion and reflection by various minerals and porosity in rock samples; the difference in thermal conductivity values measured on the front surface and the opposite surface ranges from 0.001 to 0.140 W/mK with the standard deviation of 0.003~0.089 W/mK, which seems to be caused by heterogeneity of rock samples. On the contrary, the divided-bar apparatus shows stable thermal conductivity measurements and relatively small measurement errors; the difference in thermal conductivity values, just as we applied to the laser frash method, is 0.001~0.016 W/mK with the standard deviation 0.001~0.034 W/mK. In turn, the divided-bar method can be applied to more thick samples that are more representative of bulk thermal conductivity.

Electrochemical Ion Separation Technology for Carbon Neutrality (탄소중립을 지향하는 전기화학적 이온 분리(EIONS) 기술)

  • Hwajoo Joo;Jaewuk Ahn;Sung-il Jeon;Jeyong Yoon
    • Applied Chemistry for Engineering
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    • v.34 no.4
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    • pp.331-346
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    • 2023
  • Recently, green processes that can be directly used in an energy-efficient and electrified society to achieve carbon neutrality are attracting attention. Existing heat and pressure-based desalination technologies that consume tremendous amounts of energy are no exception, and the growth of next-generation electrochemical-based desalination technologies is remarkable. One of the most representative electrochemical desalination technologies is electrochemical ion separation (EIONS) technology, which includes capacitive desalination (CDI) and battery desalination (BD) technology. In the research field of EIONS, various system applications have been developed to improve system performance, such as capacity and cyclability. However, it is very difficult to understand the meaning and novelty of these applications immediately because there are only a few papers that summarize the research background for domestic readers. Therefore, in this review paper, we aim to describe the technological advances and individual characteristics of each system in clear and specific detail about the latest EIONS research. The driving principle, research background, and strengths and weaknesses of each EIONS system are explained in order. In addition, this paper concluded by suggesting the future development and research direction of EIONS. Researchers who are just beginning out in EIONS research can also benefit from this study because it will help them understand the research trend.

Innovation Technology Development & Commercialization Promotion of R&D Performance to Domestic Renewable Energy (신재생에너지 기술혁신 개발과 R&D성과 사업화 촉진 방안)

  • Lee, Yong-Seok;Rho, Do-Hwan
    • Journal of Korea Technology Innovation Society
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    • v.12 no.4
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    • pp.788-818
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    • 2009
  • Renewable energy refers to solar energy, biomass energy, hydrogen energy, wind power, fuel cell, coal liquefaction and vaporization, marine energy, waste energy, and liquidity fuel made out of byproduct of geothermal heat, hydrogen and coal; it excludes energy based on coal, oil, nuclear energy and natural gas. Developed countries have recognized the importance of these energies and thus have set the mid to long term plans to develop and commercialize the technology and supported them with drastic political and financial measures. Considering the growing recognition to the field, it is necessary to analysis up-to-now achievement of the government's related projects, in the standards of type of renewable energy, management of sectional goals, and its commercialization. Korean government is chiefly following suit the USA and British policies of developing and distributing renewable energy. However, unlike Japan which is in the lead role in solar rays industry, it still lacks in state-directed support, participation of enterprises and social recognition. The research regarding renewable energy has mainly examinedthe state of supply of each technology and suitability of specific region for applying the technology. The evaluation shows that the research has been focused on supply and demand of renewable as well as general energy and solution for the enhancement of supply capacity in certain area. However, in-depth study for commercialization and the increase of capacity in industry followed by development of the technology is still inadequate. 'Cost-benefit model for each energy source' is used in analysis of technology development of renewable energy and quantitative and macro economical effects of its commercialization in order to foresee following expand in related industries and increase in added value. First, Investment on the renewable energy technology development is in direct proportion both to the product and growth, but product shows slightly higher index under the same amount of R&D investment than growth. It indicates that advance in technology greatly influences the final product, the energy growth. Moreover, while R&D investment on renewable energy product as well as the government funds included in the investment have proportionate influence on the renewable energy growth, private investment in the total amount invested has reciprocal influence. This statistic shows that research and development is mainly driven by government funds rather than private investment. Finally, while R&D investment on renewable energy growth affects proportionately, government funds and private investment shows no direct relations, which indicates that the effects of research and development on renewable energy do not affect government funds or private investment. All of the results signify that although it is important to have government policy in technology development and commercialization, private investment and active participation of enterprises are the key to the success in the industry.

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Enhanced High-Temperature Performance of LiNi0.6Co0.2Mn0.2O2 Positive Electrode Materials by the Addition of nano-Al2O3 during the Synthetic Process (LiNi0.6Co0.2Mn0.2O2 양극 활물질의 합성공정 중 나노크기 알루미나 추가에 의한 고온수명 개선)

  • Park, Ji Min;Kim, Daeun;Kim, Hae Bin;Bae, Joong Ho;Lee, Ye-Ji;Myoung, Jae In;Hwang, Eunkyoung;Yim, Taeeun;Song, Jun Ho;Yu, Ji-Sang;Ryu, Ji Heon
    • Journal of the Korean Electrochemical Society
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    • v.19 no.3
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    • pp.80-86
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    • 2016
  • High Ni content layered oxide materials for the positive electrode in lithium-ion batteries have high specific capacity. However, their poor electrochemical and thermal stability at elevated temperature restrict the practical use. A small amount of $Al_2O_3$ was added to the mixture of transition metal hydroxide and lithium hydroxide. The $LiNi_{0.6}Co_{0.2}Mn_{0.2}O_2$ was simultaneously doped and coated with $Al_2O_3$ during heat-treatment. Electrochemical characteristics of modified $LiNi_{0.6}Co_{0.2}Mn_{0.2}O_2$ were evaluated by the galvanostatic cycling and the LSTA(linear sweep thermmametry) at the constant voltage conditions. The nano-sized $Al_2O_3$ added materials show better cycle performance at elevated temperature than that of micro-sized $Al_2O_3$. As the added amount of nano-$Al_2O_3$ increased, the thermal stability of electrode also enhanced, but the use of 2.5 mol% Al showed the best high temperature performance.