• Title/Summary/Keyword: solvent analysis

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The Optimum Condition Analysis of Vanadium Solvent Extraction by Alamine336 from the Synthetic Vanadium Sulfate Solution. (황산바나듐 모의용액으로부터 Alamine336에 의한 바나듐 용매추출의 최적조건 연구)

  • Ahn, Jong-Gwan;Ahn, Jae-Woo
    • Korean Journal of Metals and Materials
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    • v.46 no.12
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    • pp.823-829
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    • 2008
  • The solvent extraction process for the recovery of vanadium from leaching solution of SCR(selective catalytic reduction) spent catalyst was investigated by using Alamine336 as an extractant. The effects of experimental conditions, such as initial pH and concentration of sulfate ion, and ammonia concentration of stripping solution were studied. The extraction percentage of vanadium were increased with the increase of initial pH of leaching solution and decreased with the increase of sulfate ion. More than 99% of vanadium in leaching solution were extracted and stripped at the A/O ratio of 1.0 in 2 stages. On the basis of these results, an optimum solvent extraction process which vanadium was effectively recovered from SCR spent catalyst was proposed.

A Study on Optical Analysis and Overprinting Sequence in 2-Color Solid Overprints (2색 중첩 민인쇄의 광학적 해석과 중첩인쇄 순서에 관한 연구)

  • 강상훈
    • Journal of the Korean Graphic Arts Communication Society
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    • v.15 no.2
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    • pp.1-4
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    • 1997
  • Existing cleaning solvent using screen printing are the organic solvents including aromatic compounds carried with poisonous and stench. besides, Cleaning method of current screen printing are for the most part mixed cleaning method of dipping and polish. Using 1,1,1-TCE, CFC-113 alternative system cleaning solvent be substituted for existing cleaning solvent against screen printing ink measured the cleaning efficiency according to gravimetric analysis method and property change of gassamer according to Image Analyzer. Also, Cleaning process system carry with excellent cleaning efficiency studied which was proposed new cleaning process including ultrasonic cleaning process be substituted for existing mixed cleaning method of dipping and polish.

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Studies on the Manufacturing and Analysis of Wax for Thermostat for use in Cooling System of Automobile (자동차 냉각 시스템에 사용되는 thermostat용 wax의 제조 및 분석에 관한 연구)

  • Park, Kyoung-Suk;Choung, Suk-Jin
    • Applied Chemistry for Engineering
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    • v.7 no.1
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    • pp.1-8
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    • 1996
  • The component analysis of wax for detecting temperature in automobile thermostat of the automotive engine and manufacture of it with distillation and solvent extraction were progressed. From the lift test results of prepared samples, it was found that the solvent extracted samples were in the proper range for use as an automobile thermostat of the automotive engine. And more accurate wax could be manufactured by high vacuum fractional distillation and acid treatment after solvent extraction from crude oil pitch.

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Technology Trend Analysis of CO2 Solvent by Patent Information (특허정보를 활용한 습식 이산화탄소 포집 기술동향 분석)

  • Lee, Yun-Seock;Lee, Su-Jin;Lee, Jeong-Gu;Hong, Soon-Jik
    • Journal of the Korean Society for Heat Treatment
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    • v.28 no.5
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    • pp.250-257
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    • 2015
  • As recognized by all scientific and industrial groups, carbon dioxide ($CO_2$) capture and sequestration (CCS) could play an important role in reducing greenhouse gas emissions. This paper is aimed at identifying evolving technological trends from the objective information of patents related to carbon capture technology by solvent. In this study the patents applied in korea, japan, china, canada, US, EU from 1993 to 2013 were analyzed. The result of patent analysis could be used for R&D and policy making of domestic CCS industry.

Simultaneous Analysis of Liquiritin and Glycyrrhizin in Sagunja-tang by HPLC-PDA (HPLC-PDA에 의한 사군자탕 중 Liquiritin과 Glycyrrhizin의 동시분석)

  • Seo, Chang-Seob;Kim, Jung-Hoon;Shin, Hyeun-Kyoo
    • Korean Journal of Pharmacognosy
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    • v.42 no.3
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    • pp.240-245
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    • 2011
  • A high-performance liquid chromatography (HPLC) method was developed for quantitative analysis of liquiritin and glycyrrhizin in Sagunja-tang (SGT, Sijunzi-tang in Chinese), a traditional Korean medicine. HPLC analysis was performed using a Gemini C18 column operating at $40^{\circ}C$, and photodiode array (PDA) detection at 254 nm and 280 nm for quantification of the two components in SGT. The mobile phase using a gradient flow consisted of two solvent systems. Solvent A was 1.0% (v/v) aqueous acetic acid and solvent B was acetonitrile with 1.0% (v/v) acetic acid. Calibration curves were acquired with $r^2$ values > 0.9998, and the relative standard deviations (RSDs, %) for intra- and inter-day precision were not exceed 4.0%. The recovery of each component was in the range of 91.85 - 108.62%, with a RSD less than 4.0%. The contents of the two components in SGT were 7.94 - 13.83 mg/g.

A Study on Properties by Various Solvents of Acrylic Resin for Iron Artifact Conservation (철제유물 보존처리용 아크릴 수지의 용제별 특성 연구)

  • Cho, Hyun-Kyung;Cho, Nam-Chul
    • Journal of Conservation Science
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    • v.24
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    • pp.43-56
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    • 2008
  • When we consolidate the iron artifacts, only we used VM&P Naphtha as solvent of paraloid NAD10. After consolidating the iron artifacts using paraloid NAD10, artifacts were too glossy to exhibit and see. We choose the solvent YK-VMP as solvent of paraloid NAD10 for complementing this defect and examined characterizations of paraloid NAD10 films in each solvent. As a result of evaluation by several surface analysis such as optical microscope, measuring film thickness, adhesive strength, gloss of surface, contact angle, yellowing test and EIS, it is possible to use YK-VMP instead of VM&P Naphtha as solvent of paraloid NAD10, because YK-VMP lowered surface gloss and did not change the effect of consolidation.

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Physical and Chemical Characteristics of Solvent-Insolubles and Solvent-Solubles in Oilsands Bitumen (Oilsands Bitumen의 용매 불용분 및 용해분의 물리.화학적 특성 연구)

  • Kim, Kyoung-Hoon;Jeon, Sang-Goo;Nho, Nam-Sun;Kim, Kwang-Ho;Shin, Dae-Hyun;Lee, Ki-Bong;Park, Hyo-Nam;Han, Myung-Wan
    • Journal of Energy Engineering
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    • v.17 no.1
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    • pp.38-45
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    • 2008
  • In this work, we investigated the variation of physical and chemical characteristics of solvent-insolubles and solvent-solubles in Canada's Athabasca oil sands by solvent-insolubles experiments. N-Heptane, n-Hexane, and n-Pentane were tested for solvents and asphaltenes were separated from maltenes by using a modified ASTM D 3279 method. Elemental analysis, boiling point distribution (SIMDIS), molecular weight distribution, heavy metal contents, API gravity, viscosity and SARA fractions were measured for thorough samples. The asphaltenes-removed maltenes contained less sulfur and heavy metal amounts and had lower molecular weight than the original bitumen. N-Pentane solvent could lower sulfur and heavy metal amounts, molecular weight, and viscosity of maltenes compared to the other solvents. Eventually, we confirmed that the obtained experimental data could be used as basic informations of bitumen upgrading processes for the production of SCO (synthetic crude oil).

Preparation and Characterization Study of PET Nanofiber-reinforced PEI Membrane, Investigation of the Application of Organic Solvent Nanofiltration Membrane (PET 나노섬유 강화 PEI 막의 제조 및 특성화 연구, 그에 따른 유기용매 나노여과막 가능성 검증)

  • Sung-Bae Hong;Kwangseop Im;Dong-Jun Kwon;Sang Yong Nam
    • Journal of Adhesion and Interface
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    • v.24 no.1
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    • pp.17-25
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    • 2023
  • In this study, waste polyethylene terephthalate (PET) was recycled to produce a support and then polyetherimide (PEI) was used for environmentally friendly organic solvent nanofiltration. The prepared composite membrane was first prepared by electrospinning a PET support, then casted on the support using PEI having excellent solvent resistance, and organic solvent nanoparticles using a Non-solvent Induced Phase Separation (NIPS) method. A filtration membrane was prepared. First, the fiber diameter and tensile strength of the PET scaffold prepared prior to membrane fabrication were identified through morphology analysis, and the optimal scaffold for the organic solvent nanofiltration membrane was identified. Afterward, the PET/PEI composite membrane prepared was checked for the DEA removal rate of Congo red having a molecular weight of 697 g/mol in ethanol to understand the performance as an organic solvent nanofiltration membrane according to the concentration of PEI. Finally, the removal rate of Congo red was 90% or more.

Solvent Selection for the Detection of Siloxanes in Landfill gas (매립가스내 규소화합물류 검출을 위한 용매선택에 관한 연구)

  • Kim, Nack-Joo;Choi, Ju-Mi;Ji, Eun-Jung
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.8
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    • pp.915-921
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    • 2007
  • As a preliminary measurement of siloxanes in landfill gas(LFG), this study was conducted to determine the best suitable solvent applicable to the extraction of siloxanes in the domestic landfill using liquid-absorption method. Three solvents of n-hexane, acetone, and methanol were tested and the results obtained from GC analysis for each solvent were compared to their properties. Results showed that the resolution in the GC spectrum was the best from methanol due to the lack of overlapping of the peaks between silane and solvent. The detected siloxanes concentration were varied at maximum 2.6 times depending on the types of solvent as well as extraction velocity and impinger steps. In total, the highest concentration of siloxanes was obtained from methanol, which showed ideal pattern in the absorption of each impinger step and the least relative standard deviation. Accordingly, it is concluded that methanol is the most suitable solvent for the extraction of siloxanes in the domestic landfill. However, it is considered that solvent suitability can vary depending on the waste components and landfill record in landfills.

QSPR Analysis of Solvent Effect on Selectivity of 18-Crown-6 between $Nd^{3+}$ and $Eu^{3+}$ Ions: a Monte Carlo Simulation Study

  • Kim, Hag-Sung
    • Bulletin of the Korean Chemical Society
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    • v.27 no.12
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    • pp.2011-2018
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    • 2006
  • We have investigated the solvent effects on $\Delta log\;K_s $(the difference of stability constant of binding) and the different free energies of binding of $Nd^{3+}$ and $Eu^{3+}$ ions to 18-crown-6, i.e., the selectivity of $Nd^{3+}$ and $Eu^{3+}$ ions to 18-crown-6 using a Monte Carlo simulation of statistical perturbation theory (SPT) in diverse solvents. The stability constant ($\Delta log\;K_s $) of binding of $Nd^{3+}$ and $Eu^{3+}$ ions to 18-crown-6, in $CH_3OH$ was calculated in this study as -1.06 agrees well with the different experimental results of -0.44~-0.6, respectively. We have reported here the quantitative solvent-polarity relationships (QSPR) studied on the solvent effects the relative free energies of binding of $Nd^{3+}$ and $Eu^{3+}$ ions to 18-crown-6. From the calculated coefficients of QSPR, we have noted that solvent polarity (ET) and Kamlet -Tafts solvatochromic parameters (b ) dominate the differences in relative solvation Gibbs free energies of $Nd^{3+}$ and $Eu^{3+}$ ions but basicity (Bj) dominates the negative values in differences in the stability constant ($\Delta log\;K_s $) as well as the relative free energies of binding of $Nd^{3+}$ and $Eu^{3+}$ ions to 18-crown-6 and acidity (Aj) dominates the positive values in differences in the stability constant ($\Delta log\;K_s $) as well as the relative free energies of binding of $Nd^{3+}$ and $Eu^{3+}$ ions to 18-crown-6.