• 제목/요약/키워드: solution mixing

검색결과 794건 처리시간 0.024초

SCR 시스템의 요소용액 미립화 및 분해반응 특성 예측에 관한 전산 해석 연구 (A Research on the Characteristics of Spray-Induced Mixing and Thermal Decomposition of Urea Solution in SCR System)

  • 김주연;민병수;하지수;류승협
    • Journal of Advanced Marine Engineering and Technology
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    • 제28권5호
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    • pp.818-826
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    • 2004
  • The spray-induced mixing characteristics and thermal decomposition of aqueous urea solution into ammonia have been studied to design optimum sizes and geometries of the mixing chamber in SCR(Selective Catalytic Reduction) system. The cold flow tests about the urea-injection nozzle were performed to clarify the parameters of spray mixing characteristics such as mean diameter and velocity of drops and spray width determined from the interactions between incoming air and injected drops. Discrete particle model in Fluent code was adopted to simulate spray-induced mixing process and the experimental results on the spray characteristics were used as input data of numerical calculations. The simulation results on the spray-induced mixing were verified by comparing the spray width extracted from the digital images with the simulated Particle tracks of injected drops. The single kinetic model was adopted to predict thermal decomposition of urea solution into ammonia and solved simultaneously along with the verified spray model. The hot air generator was designed to match the flow rate and temperature of the exhaust gas of the real engines The measured ammonia productions in the hot air generator were compared with the numerical predictions and the comparison results showed good agreements. Finally, we concluded that the design capabilities for sizing optimum mixing chamber were established.

Development of a Low-cost Metering Device for Automatic Mixing of Nutrient-Solution

  • Ryu, K.H.;Lee, K.C.;Lee, J.H.
    • 한국농업기계학회:학술대회논문집
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    • 한국농업기계학회 1996년도 International Conference on Agricultural Machinery Engineering Proceedings
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    • pp.1117-1125
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    • 1996
  • A low-cost and precise metering device, which is suitable to automatic mixing of nutrient-solution for hydroponic culture, was developed for small-scale growers. The metering accuracy of the metering device developed was compared with commercial metering pumps. The mixing performance through the control of EC and pH was also evaluated. The accuracy of the metering device in terms of the full -scale error was $\pm$0.3% , which was much better compared to $\pm$2.45% and $\pm$1.38% for the two types of commercial metering pumps. The mixing system of nutrient-solution with the metering device showed a satisfactory control performance with the accuracies of $\pm$0.05mS/cm and$\pm$0.2pH for EC and pH, respectively.

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퍼지제어를 이용한 양액 자동공급 시스템 개발 (Development of an Automatic Nutrient-Solution Supply System Using Fuzzy Control)

  • 황호준;류관희;조성인;이규철;김기영
    • Journal of Biosystems Engineering
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    • 제23권4호
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    • pp.365-372
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    • 1998
  • This study was carried out to develop a nutrient-solution mixing-and-supplying system, which used a low-cost metering device instead of expensive metering pumps and a fuzzy logic controller. A low cost and precise overflow-type metering device was developed and evaluated by testing the flow discharge for the automatic nutrient-solution mixing-and-supplying system for snail-scale hydroponic sewers. The fuzzy logic controllers, which could predict and meet the desired values of EC and supply rate of nutrient solution were developed and verified by simulation and experiment. this fuzzy logic controller, whose algorithm consists of four crisp inputs, two crisp outputs and nine rules, was developed to predict the desired value of EC and supply rate of nutrient solution and two crisp inputs, one crisp output and nine rules used to control EC to the desired values. The nutrient-solution mixing-and-supplying system showed satisfactory EC control performance with the maximum overshooting of 0.035 mS/cm and the maximum settling time of 15 minutes in case of increasing 0.7 mS/cm. also, the accuracy of the overflow-type metering device in terms of the full-scale error was 2.29% when using solenoid valve only and 0.2% when using solenoid valve and flow control valve together.

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Thermodynamic Properties of $NiFe_2O_4-NiFe_2O_4$ Spinel Solid Solution

  • 박봉훈;김동수
    • Bulletin of the Korean Chemical Society
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    • 제20권8호
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    • pp.939-942
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    • 1999
  • The tie lines delineating ion-exchange equilibria between NiFe2O4-NiCr2O4 spinel solid solution and Fe2O3-Cr2O3 corundum solid solution were determined at 900, 1000, and 1200 ℃ by electron microprobe and energy dispersive X-ray analysis of oxide phases, using the flux growth technique. Activities of the spinel components were calculated from the tie lines, assuming Temkin's ideal mixing in the corundum solid solution. The spinel phase could be expressed by a regular solution with negative deviations from ideality. The Gibbs free energies of mixing for spinel solid solution were discussed in terms of the cation distribution model, based on site preference energies and assuming random mixing on both tetrahedral and octahedral sites.

이온전극을 이용한 순환식 양액 자동 조제에 관한 연구 (Study on Automatic Mixing of Nutrient Solution Using ion Electrodes for Closed-Loop Hydroponics)

  • 김민규;류관희;장유섭;김기영
    • Journal of Biosystems Engineering
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    • 제27권5호
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    • pp.425-432
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    • 2002
  • This study was carried out to develop an automatic mixing system of nutrient solution for closed-loop hydroponics using ion electrodes. The results of the study are summarized as follows: 1. It appeared that ion-electrodes had not to be soaked into nutrient solution for a long time since it was much less durable than EC or PH sensors. Once ion-electrodes were soaked into real nutrient solution for a long time, they became unstable. 2. ion measurement modules, which were able to sample recirculated nutrient solution and easily wash and dry ion-electrodes, were developed in order to use ion-electrodes continuously. 3. The results of calibration tests on three kinds of ion electrodes presented that the time required to read measurement data was over 30 seconds. Using the calibration data the regression equations for the ion electrodes were developed. 4. An automatic nutrient-solution mixing system using the three kinds of ion electrodes was developed and then its accuracy was examined. The control errors of the mixing system using ion electrodes were in the range of 9.8 to 12%.

마이크로 채널에서 두 유체 혼합 (Two-Fluid Mixing in a Microchannel)

  • 류임정;김병재;성형진
    • 한국전산유체공학회지
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    • 제8권2호
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    • pp.16-23
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    • 2003
  • A numerical study of the mixing of two fluids(pure water and a solution of glycerol in water) in a microchannel was carried out. By varying the glycerol content of the glycerol/water solution, the variation in mixing behavior with changes in the difference of the properties of the two fluids(e.g., viscosity, density, diffusivity) was investigated. The mixing phenomena were tested for three micromixers: a square mixer, a three-dimensional serpentine mixer, and a staggered herringbone mixer. The governing equations of continuity, momentum and solute mass fraction were solved numerically. To evaluate mixing performance, a criterion index of mixing of mixing uniformity was proposed. In the systems considered, the Reynolds numbers based on averaged properties were 1 and 10. For low Reynolds number (Re = 1), the mixing performance varied inversely with mass fraction of glycerol due to the dominance of molecular diffusion. The mixing performance by diffusion deteriorated due to a significant reduction in the residence time of the fluid inside the mixers.

혼성 Cresol과 $POCl_3$의 반응에 의한 tri-Cresyl Phosphate의 분리공정 연구 (Study on separation process of tri-cresyl phosphate by reaction of $POCl_3$ with mixed cresol)

  • 김장규;원성호;양승남;이상석;김남기
    • 한국안전학회지
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    • 제13권2호
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    • pp.109-115
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    • 1998
  • Tri-cresyl phosphate(TCP) was synthesized by reaction of phosphorus chloride with mixed cresol(mixture of m-cresol, p-cresol, and others) in the presence of $AlCl_3$. Some of unwanted products and unreactants colored TCP. In order to separate TCP from these, vaccume distillation was carried twice, but colorless TCP could not be producted. Separation of unwanted materials by 2% NaOH solution was introduced before first and second distillation and optimal separation conditions such as NaOH concentration, mixing volume ratio, mixing time, and rpm were investigated for new batch separation and production of colorless TCP Optimal conditions were 2% NaOH solution, 35% mixing volume ratio of 2% NaOH solution, 1.5 hours of mixing time, and 20 rpm.

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마이크로 믹서에서 와도 지수와 혼합 지수의 관계;비용해성 물질 (The Relation between Vortex Index and Mixing Index in Micromixer;Insoluble Solution;Insoluble Solution)

  • 맹주성;김범중;조일대
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2004년도 춘계학술대회
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    • pp.1841-1844
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    • 2004
  • 'Mixing Index($D_I$)'s generally used to measure the degree of mixing. A new method to calculate $D_I$ was proposed, when insoluble solution flows in micromixer. 'Vortex Index (${\Omega}_I$)'which indicate the degree of chaotic advection, is defined and formulated. A lots of arbitrary shaped microchannels were tested to calculate the $D_I$ and ${\Omega}_I$. And then a simple algebraic equation, $D_I=A{\Omega}_I+B$, was obtained. This equation may be used instead of partial differential equation, concentration equation.

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과산화수소 혼합냉각기 내의 노즐배치 및 가스분사 방식 변화에 따른 혼합율 개선에 대한 전산해석적 연구 (CFD Analysis on the Effect of the Nozzle Arrays and Spray Types in the Hydrogen Peroxide Mixing Quencher to Improve the Mixing Efficiency)

  • 구성모;장혁상
    • 청정기술
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    • 제23권1호
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    • pp.42-53
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    • 2017
  • 탈질과 탈황을 동시에 수행하는 과산화수소($H_2O_2$) 수용액 세정탑의 반응효율을 증가시키기 위해 예혼합이 이루어지는 혼합 냉각기(mixing quencher) 영역 내부의 유체유동에 대한 수치해석이 수행되었다. 산업공정에서 상용화되고 있는 세정탑 전단부의 혼합냉각기에서 과산화수소 수용액이 주입되는 노즐의 분사방식은 배기가스와 과산화수소 수용액의 혼합에 중요한 역할을 하며, 혼합냉각기에서의 혼합도는 세정탑 의 효율을 결정하는 중요 요소가 된다. 본 연구에서는 혼합냉각기 내부유체의 농도분포 개선을 목적으로 하여 혼합냉각기 내의 노즐 관의 배열을 조절하거나 노즐 팁 각도를 변경하며 유체혼합을 최적화하였다. 전산해석은 이 냉각기영역의 내부유동 및 각 유체 농도에 대한 RMS (root mean square) 값을 계산하여 내부유체의 혼합도의 개선을 확인하였다. 세부적으로는 노즐 관의 위치를 조절할 때 변경되는 냉각기 영역 후단의 농도 RMS 값을 확인하여 난류형성위치에 따른 최적화된 혼합도를 확인하였으며 기본형상 대비 난류형성방향을 조절하는 목적의 노즐 팁 각도를 증감하여 농도분포의 균질화를 비교하였다. 노즐 관의 배열에 따라 난류형성위치와 그에 따른 유체혼합이 해석되었다. 또한 노즐 팁 각도를 조절하는 경우에는 유동방향과의 각도에 따라, 흐름이 병류와 향류에 따라 혼합도의 최적화를 확인할 수 있었다. 노즐 관의 위치는 0.3 m, 노즐 팁은 병류의 $15^{\circ}$일 때 최적의 조건을 가지며 가장 낮은 RMS 값인 12.4%를 가졌다.

마이크로 믹서에서 와도 지수에 의한 비용해성 물질의 혼합 예측 (Prediction of Degree of Mixing for Insoluble Solution with Vortex Index in a Passive Micromixer)

  • 조일대;김범중;맹주성
    • 대한기계학회논문집B
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    • 제29권2호
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    • pp.232-238
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    • 2005
  • The 'Mixing Index($D_I$)' is used as a conventional guidance measuring the degree of mixing for multiphase flows. For the case when insoluble solutions flow in a passive micromixer, a new method to calculate $D_I$ is proposed. The 'Vortex Index(${\Omega}_I$)' is suggested and formulated. We infer that ${\Omega}_I$ relates to the degree of chaotic advection. Various arbitrary shaped microchannels were tested to calculate the $D_I\;and\;{\Omega}_I$, and then a simple algebraic equation, $D_I=Aexp(B{\Omega}_I)$, is obtained. This equation may be used instead of the conventional partial differential equation, concentration equation, to estimate the degree of mixing.