• 제목/요약/키워드: solution leakage

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새로운 막 제조 방법에 의한 고분자 전해질막의 특성 향상 (Improvement of Properties in Solid Polymer Electrolyte Using New Preparation Method)

  • 김태희;이정훈;박권필
    • 한국수소및신에너지학회논문집
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    • 제17권3호
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    • pp.331-337
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    • 2006
  • 높은 이온전도도와 충분한 기계적 강도, 전해질 누수가 적은 새로운 형태의 고분자 전해질막(pore-gel SPE)을 연구 개발하였다. 다공성 PVDF-HFP 고분자막의 기공 내에 전해질 용액을 흡수시킨 후 막 내에서 젤화를 진행시켰다. 전해질 용액은 2:2:1의 비를 갖는 PC/EC/DMA에 1M SA(Salicylic acid)를 용해하고 여기에 고분자막을 용해시킬 수 있는 아세톤을 첨가하였다. 초음파를 이용함으로써 고분자막의 용액 흡수율을 증가시키고 또 고분자막에서 젤화를 촉진 시킬 수 있었다. 이렇게 젤화한 막의 이온전도도는 젤화 전 막보다 $1{\sim}2.2$ 배 향상되었고, 인장강도는 gel-type SPE 보다 40 배 증가하였으며, 전해질 누수실험결과 hybrid-type SPE는 13%의 누수를 보였으나 본 연구의 막(pore-gel SPE)은 6%로 감소함을 보였다.

증착 온도에 따른 PZT/BFO 박막의 전기적 특성 (Electrical properties of PZT/BFO/PZT thin film deposited with various temperature)

  • 김대영;남성필;노현지;조서현;이태호;이성갑;이영희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2010년도 하계학술대회 논문집
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    • pp.197-197
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    • 2010
  • Pb(Zr,Ti)O3/BiFeO3/(PZT/BFO) multilayer thin films were coated on Pt/Ti/SiO2/Si substrates by chemical solution deposition. With increasing the annealing temperature, the dielectric and leakage current density properties of multilayered PZT/BFO/PZT thin films were improved. The current density of the PZT/BFO/PZT filmannealing at $600^{\circ}C$ was about 189.39(x10-9A/cm2) at 10V. The relative dielectric constant and the dielectric loss of the PZT/BFO/PZT thin film annealing at $600^{\circ}C$ were about 318 and 0.161%, respectively.

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사물인터넷 보안 문제제기와 대안 (Security Vulnerability of Internet of Things and Its Solution)

  • 최희식;조양현
    • 디지털산업정보학회논문지
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    • 제11권1호
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    • pp.69-78
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    • 2015
  • Internet of Things(IoT) is electronic devices and household appliances use wireless sensor network in environment of high speed wireless network and LTE mobile service. The combination of the development of Internet and wireless network led to development of new forms of service such as electronic devices and household appliances can connect to the Internet through various sensors and online servers such as a Home Network. Even though Internet of Things is useful, there are problems in Internet of Things. In environment of Internet of Things, information leakage could happens by illegal eavesdropping and spoofing. Also illegal devices of wireless communication interference can cause interfere in Internet of things service, physical damage and denial of service by modulation of data and sensor. In this thesis, it will analyze security threats and security vulnerability in environment of mobile services and smart household appliances, then it will suggest plan. To solve security issues, it is important that IT and RFID sensor related companies realize importance of security environment rather than focus on making profit. It is important to develop the standardized security model that applies to the Internet of Things by security-related packages, standard certification system and strong encrypted authentication.

Sol-Gel법으로 제조한 BST 박막의 구조 및 전기적 특성 (The Structural and Electrical Properties of the BST Thin Film Prepared by Sol-Gel method.)

  • 김경덕;정장호;배선기;이영희
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1997년도 추계학술대회 논문집 학회본부
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    • pp.291-293
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    • 1997
  • In this study, Sol-Gel derived $(Ba_{0.7}Sr_{0.3})TiO_3$ thin films were fabricated and investigated. The stock solution was synthesized and spin-coated on Pt/Ti/$SiO_2$/Si substrate at 4000(rpm] and then, annealed at $650{\sim}750[^{\circ}C]$. Crystallization condition, microstructural properties and interfacial structure were observed by XRD, AFM, SEM and TEM. It was found that the BST thin films were completely crystallized at 750[$^{\circ}C$] and showed nano-sized grains. The dielectric constant and loss of the BST thin films were 220, 0.01 at 1[kHz] respectively. Increasing the temperature, the dielectric constant and loss characteristics were not varied widely. At the applied voltage of 1.5[V], the leakage current density was under the $10^{-9}[A/cm^2]$.

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의사공진형 Hybrid IC STR-G9600을 이용한 저 노이즈 역률 개선형 전원 장치 (An Improved PFC & Low Noise Power Supply using Quasi-Resonant Mode Hybrid IC of STR-G9600)

  • 이명준;안준영;신호준;배준성
    • 전력전자학회:학술대회논문집
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    • 전력전자학회 2002년도 전력전자학술대회 논문집
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    • pp.233-236
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    • 2002
  • The solution for PFC(Power Factor Correction), as a regulation in energy Policy, is becoming a hot Issue in every country because of the shortage of electrical energy. Therefore, a new improved idea for PFC problem has been introduced in this study. A lot of merits, effective cost by simple circuit, reduced PCB size, lighter than reactor in the view of weight, lower level of screen noise by leakage inductance in CTV applications, have been stated by comparing to the earlier method of using a Reactor. All test results in this statement were done by using a power device of STR-G9600 series based on the real load condition of color television. furthermore, the study shows that the test results also meets the IEC-1000-3-2 class D, which regulates the PFC when input power of a set is more than 75watts. More improved PFC in other applications hopes to be implemented by using the proposed method.

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Deposition of Functional Organic and Inorganic Layer on the Cathode for the Improved Electrochemical Performance of Li-S Battery

  • Sohn, Hiesang
    • Korean Chemical Engineering Research
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    • 제55권4호
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    • pp.483-489
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    • 2017
  • The loss of the sulfur cathode material through dissolution of the polysulfide into electrolyte causes a significant capacity reduction of the lithium-sulfur cell during the charge-discharge reaction, thereby debilitating the electrochemical performance of the cell. We addressed this problem by using a chemical and physical approach called reduction of polysulfide dissolution through direct coating functional inorganic (graphene oxide) or organic layer (polyethylene oxide) on electrode, since the deposition of external functional layer can chemically interact with polysulfide and physically prevent the leakage of lithium polysulfide out of the electrode. Through this approach, we obtained a composite electrode for a lithium-sulfur battery (sulfur: 60%) coated with uniform and thin external functional layers where the thin external layer was coated on the electrode by solution coating and drying by a subsequent heat treatment at low temperature (${\sim}80^{\circ}C$). The external functional layer, such as inorganic or organic layer, not only alleviates the dissolution of the polysulfide electrolyte during the charging/discharging through physical layer formation, but also makes a chemical interaction between the polysulfide and the functional layer. As-formed lithium-sulfur battery exhibits stable cycling electrochemical performance during charging and discharging at a reversible capacity of 700~1187 mAh/g at 0.1 C (1 C = 1675 mA/g) for 30 cycles or more.

ULSI DRAM의 capacitor 절연막용 BST(Barium Strontium Titanate)박막의 제작과 특성에 관한 연구 (Preparation and properties of BST (Barium Strontium Titanate) thin films for the capacitor dielectrics of ULSI DRAM's)

  • 류정선;강성준;윤영섭
    • E2M - 전기 전자와 첨단 소재
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    • 제9권4호
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    • pp.336-343
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    • 1996
  • We have studied the preparation and the properties of $Ba_{1-x}$Sr$_{x}$TiO$_{3}$(BST) thin films by using the sol-gel method. Through the comparison of the effects of various solvents and additives in making solutions, we establish the production method of the stable solution which generates the high quality of BST film. We also set up the heat-treatment conditions for depositing the BST thin film through the TGA and XRD analyses. Through the comparison of the surface conditions of BST films deposited on Pt/Ta/SiO$_{2}$/Si and Pt/Ti/SiO$_{2}$/Si substrates, we find that Ta is more efficient diffusion barrier of Si than Ti so that Ta layer prevents the formation of hillocks. We fabricate the planar type capacitor and measure the dielectric properties of the BST thin film deposited on the Pt/Ta/SiO$_{2}$/Si substrate. Dielectric constant and dielectric loss tangent at 1V, 10kHz, and leakage current density at 3V of the BST thin film are 339, 0.052 and 13.3.mu.A/cm$^{2}$, respectively.ely.

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A Study on the Coatings for CP System in the Environment in which Thin Layer of Extremely Acidic Fluids are Formed

  • Chang, H.Y.;So, I.S.;Jin, T.F.;Kim, Y.S.;Yoo, Y.R.;Kang, M.S.
    • Corrosion Science and Technology
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    • 제5권1호
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    • pp.5-14
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    • 2006
  • A lot of parts in FGD (Flue Gas Desulphurization) systems of fossil-fuel power plants show the environments in which are highly changeable and extremely acidic corrosive medium according to time and locations, e.g. in duct works, coolers and re-heaters etc.. These conditions are formed when system materials are immersed in fluid that flows on them or when exhausted gas is condensed into thin layered medium to contact materials of the system walls and roofs. The environments make troublesome corrosion and air pollution problems that are occurred from the leakage of the condensed solution. The frequent shut-down and repairing works of FGD systems also demand costs and low efficiencies of those facilities. In general, high corrosion resistant materials have been used to solve this problem. However, even the super alloys and Teflon linings sometimes have not been good enough to preventing corrosion. Further more, they are expensive and not easily repairable in short periods of operation stops. In this work, new technology that is effective, economical and easily repairable has proposed to solve the corrosion problems in FGD facilities. This technology contains cathodic protection, coatings and remote monitoring-controlling systems.

PEO-PPO-PEO 블록공중합체를 사용한 마이셀 증진 한외여과법 (유해유기물의 가용화 및 분리특성) (Micellar Enhanced Ultrafiltration Using PEO-PPO-PEO Block Copolymer)

  • 최영국;이동진;김정훈;김동권;이수복
    • 한국막학회:학술대회논문집
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    • 한국막학회 1998년도 춘계 총회 및 학술발표회
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    • pp.83-86
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    • 1998
  • 1. Introduction : Low molecular harmful organics such as 1-naphthol and phenol are widely used in industries, and pose serious environmental problems. Wastewater containing low molecular harmful organics may be ejected from various sources including metal-plating industries, circuit-board manufacturing process, photographic and photo-processing industries, refineries and metal-tailing leachate. The pollution of nation harbors, waterways and ground water resources with these organics has reached critical portions, and might also give hazardous influence on human health. Micellar enhanced ultrafiltration(MEUF) is a recently developed process to remove dissolved organics and/or heavy metals present in small or trace quantities from aqueous solution. In this system, the fatal defect is leakage of surfactants especially at low concentration below CMC(critical micelle concentration), which becomes a secondary pollution. Our group proposed to use biosurfactant and polymeric micelle to solve problems mentioned above. In this study we investigated a modified MEUF using PEO-PPO-PEO (polyethyleneoxide-polypropyleneoxide-polyethyleneoxide) block copolymers for the removal of organic solutes such as 1-naphthol and phenol from aqueous wastewater. We proposed PEO-PPO-PEO block copolymers as new surfactants for forming micelles in MEUF, and investigated the solubilization characteristics and efficiency for the removal of 1-naphthol and phenol. PEO-PPO-PEO block copolymers are, environmentally mild and safe as biosurfactants.

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역행충전시 수복재와 와동 형태에 따른 변연누출의 정량적 분석 (QUANTITATIVE ANALYSIS OF MARGINAL MICROLEAKAGE IN VARIOUS RETROGRADE FILLING MATERIALS AND PREPARATION TYPES)

  • 한충경;양홍서
    • Restorative Dentistry and Endodontics
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    • 제15권1호
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    • pp.97-105
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    • 1990
  • When conventional root canal treatment is failed or contraindicated, retrograde root canal filling following apicoectomy is a valuable procedure, aimed at hermetically sealing the root canal against leakage of irritants from the canal into the periapical tissue. In this in vitro investigation, to analyze apical microleakage electrochemically in teeth with different retrograde filling materials and preparation types, single - rooted tooth was cut 2mm from the apex and each Class I and Slot preparation was prepared. Experimental groups : Group 1. Amalgam filling with cavity varnish in Class I preparation Group 2. Scotchbond 2+Silux filling in Class I preparation Group 3. Gutta percha filling with ZOE cement in Class I preparation Group 4. Amalgam filling with cavity varnish in Slot preparation Group 5. Scotchbond 2+Silux filling in Slot preparation Each specimens was immersed in 1% solution of KCl, and applied a potential of 9V external power supply. Measurements of the current flow were obtained at 1, 2, 3, 7, 9, 12, 14, 18, 21, 25 and 28 day after immerson. Marginal microleakage were compared and evaluated. The results were as follows ; 1. The group filled with composite resin with dentin bonding agent shows lower apical microleakage value than the group filled with amalgam following varnish application (P<0.01). 2. In the group filled with gutta percha, apical microleakage value was the hightest 3. There was no significant difference between Class I cavity and Slot type cavity regardless of the used materials.

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