• Title/Summary/Keyword: solid concentration

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Feasibility of Fibrous Solid Phase Extraction to Alkylphenols Analysis (섬유상 고상 추출물질을 이용한 알킬페놀 화합물 분석 가능성)

  • Jung, Yong Jun
    • Journal of Korean Society on Water Environment
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    • v.27 no.3
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    • pp.329-333
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    • 2011
  • p-phenylene-2,5-benzobisoxazole (PBO; Zylon$(R)$) fibers as an adsorbent were employed for solid phase extraction of aqueous alkylphenols. The removal ratios for 10 kinds of alkylphenols at initial concentration of $100{\mu}gL^{-1}$ were in the range of 16.8-96.3% and the removals increased with the increase of the phase ratio (fiber weight/solution volume). The plots of the logarithm of partition coefficient (log K) were correlated with the logarithm of the n-octanol/water partition coefficient (log P). The adsorbed alkylphenols were completely desorbed with the mixture of acetonitrile and dichloromethane.

Effect of Sludge Concentration on Removal of Heavy Metals from Digested Sludge by Thiobacillus ferrooxidans (Thiobacillus ferrooxidans를 이용한 소화 슬러지의 중금속 제거에 미치는 슬러지 농도의 영향)

  • 류희욱;김윤정;조경숙;강근석;최형민
    • KSBB Journal
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    • v.13 no.3
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    • pp.279-283
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    • 1998
  • To investigate the feasibility of the microbial process for removal of heavy metals from the high solid content sludge, the effect of sludge concentration on the solubilization of heavy metals by an iron oxidizing bacterium Thiolbacillus ferrooxidans was examined. With increasing the sludge concentration, the removal efficiency of heavy metals and the oxidation rate of iron were inhibited. Especially, when the sludge concentration is over 5% (w/v), the activity of T. ferrooxidans was remarkably inhibited. This inhibition is considered to occur due to the dissolved inhibitory materials such as organic compounds, heavy metals, and others which were extracted from the sludge during incubation period. In conclusion, the microbial process by T. ferrooxidans is only effectively used in ranges of 1.3 to 4.0% (w/v) sludge concentration.

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Effects of Enzymatic Hydrolysis and Concentrations of Sugar and Salt on Kimchi Juice Fermentation of Outer Leaves of Chinese Cabbage (배추 겉잎을 이용한 김치쥬스 제조시 효소분해, 당, 소금농도가 발효에 미치는 영향)

  • 전윤기;윤석권;김우정
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.26 no.5
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    • pp.788-793
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    • 1997
  • Addition of sugar, enzymatic hydrolysis and salt concentration were evaluated for their effects on the changes in some characteristics of Kimchi juice during fermentation. The Kimchi juice was prepared by brining and grinding of outer layer leaves of chinese cabbage, one of the wastes products of Kimchi processing, followed by fermentation proceeded significantly faster. Addition of sucrose or glucose at the ange of 0.5~2.0 % also improved the fermentation but the concentration effect was little. Enzymatic hydrolysis on the brined cabbage prior to fermentation with a commercial polysaccharides hydrolases also increased the fermentation. However the solid concentration in Kimchi juice was rather decreased by higher concentration of NaCl and enzymatic hydrolysis. The reducing sugar content showed a rapid decrease from 24 hours of fermentation and the effect of enzymatic hydrolysis was little.

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Settling Mode of the Dredged Soil (준설토의 침강형태에 관한 연구)

  • 윤상묵;장병욱;차경섭
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.45 no.1
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    • pp.63-73
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    • 2003
  • The settling of the dredged soil may vary with mineral composition, grain size distribution, initial water content and salt concentration of suspension of the site. A series of settling column test was performed to investigate the behaviour of solid suspension material from dredging and reclamation. Settling mode was divided into four types from the observation of interface and settling curves of clay minerals and marine clay samples, and the relationship charts of salt concentration and the initial water content were established to use in the dredging operation with any salt concentration. The critical initial water content which was defined as a threshold of zone settling and the consolidation settling was varied with salt concentration of water and was proportional to the plasticity of soil in sea water.

A Study on the Wear Characteristics of Molybdenum Disulphide in Lube-Oils (이류화 몰리브덴윤활유의 마모특성에 관한 연구)

  • 최웅수;한홍구;권오관
    • Tribology and Lubricants
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    • v.5 no.2
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    • pp.87-93
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    • 1989
  • The effect of the Concentration of solid lubricant, MoS$_2$ alone and in presence of other additives, ZDDP and DEP on the wear characteristics of liquid lubricants has been studied using the Four Ball Wear tester and Falex E.P. tester. On the basis of the experimental result, it showed that the concentration of MoS$_2$ and compatibility with other additives is very cbncerned with wear performance.

Major Factors Affecting PM2.5 Water Content in Seoul and Gosan (서울과 고산의 미세입자 수분함량에 영향을 미치는 주요 인자)

  • Choi E. K;Kim Y.P
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.6
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    • pp.803-810
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    • 2004
  • Water contents in fine particles at Seoul and Gosan are estimated by using a gas/particle equilibrium model, SCAPE (Simulating Composition of Atmospheric Particles at Equilibrium). Also, sensitivity of particulate inorganic ionic concentrations on the total ionic species is estimated. Water content at Gosan is more sensitive to ambient relative humidity (RH) than Seoul. At both sites water content is most sensitive to sulfate concentration among sulfate, nitrate, and ammonium. Solid salts levels and compositions are also studied.

A Study on Reaction Rate of Solid SCR for NOx Reduction of Exhaust Emissions in Diesel Engine (디젤엔진 배출가스 질소산화물 저감을 위한 Solid SCR의 반응률에 관한 연구)

  • Lee, Hoyeol;Yoon, Cheon Seog;Kim, Hongsuk
    • Transactions of the Korean Society of Automotive Engineers
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    • v.21 no.6
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    • pp.183-194
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    • 2013
  • Liquid urea based SCR has been used in the market to reduce NOx in the exhaust emission of the diesel engine vehicle. This system has several problems at low temperature, which are freezing below $-12^{\circ}C$, solid deposit formation in the exhaust, and difficulties in dosing system at exhaust temperature below $200^{\circ}C$. Also, it is required complicated exhaust packaging equipment and mixer due to supply uniform ammonia concentration. In order to solve these issues, solid urea, ammonium carbonate, and ammonium carbamate are selected as ammonia sources for the application of solid SCR. In this paper, basic research on reaction rate of three ammonia-transporting materials was performed. TGA (Thermogravimetric Analysis) and DTA (Differential Thermal Analysis) tests for these materials are carried out for various heating conditions. From the results, chemical kinetic parameters such as activation energy and frequency factor are obtained from the Arrhenius plot. Additionally, from test results of DSC (Differential Scanning Calorimeter) for these materials, chemical kinetic parameters using the Kissinger method are calculated. Activation energies of solid SCR from this experiment are compared with proper data of literature study, then obtained data of this experiment are used for the design of reactor and dosing system for candidate vehicle.

Process Development for the Recovery of Sialic Acid Fraction by Enzymatic Hydrolysis of Egg Yolk Protein (난황 단백질의 효소 가수분해에 의한 sialic acid의 회수 공정 개발)

  • Kang Byung Chul;Lee Kwang Hyun
    • Journal of Life Science
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    • v.15 no.1 s.68
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    • pp.9-14
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    • 2005
  • Batch enzymatic hydrolysis of egg yolk protein by protease was carried out at laboratory scale coupled to an ultrafiltration module. Effect of ethanol concentrations on the performance of enzymatic hydrolysis was studied to determine the optimum condition of recovery of hydrolysate. The enzymatic hydrolysis was conducted stepwise with following conditions, $50^{\circ}C$, pH 10.0 and pH 6.5. Ethanol concentration was changed from 10 to $40\%$ (w/w). As ethanol concentration was increased, the recovery yield of total solid and protein in enzymatic hydrolysate was also increased. The content of sialic acid and protein in hydrolysate was independent of ethanol concentration. We also investigated the effect of ethanol concentration on the performance of ultrafiltration. As the concentration of ethanol in yolk protein was increased, the recovery yield of product was increased. Ultra­filtration of egg yolk protein hydrolysate was conducted to increase the content of sialic acid. Four ultrafiltation modules were used in this study, and we evaluated the performance of the UF modules. When Amicon module was used, the recovery percentage of total solid in retentate was $6.0\%$, which is the highest among the modules used. In spite of the difference in the recovery yield of total solid, the purity of sialic acid in retentate was about $2.0\%$, which was 5 times higher than that in feed. It was concluded that the recovery yield and the purity of sialic acid did not correlate with the types of modules and the size of MWCO.

Comparative Analyses of the Flavors from Hallabong (Citrus sphaerocarpa) with Lemon, Orange and Grapefruit by SPTE and HS-SPME Combined with GC-MS

  • Yoo, Zoo-Won;Kim, Nam-Sun;Lee, Dong-Sun
    • Bulletin of the Korean Chemical Society
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    • v.25 no.2
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    • pp.271-279
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    • 2004
  • The aroma component of Hallabong peel has been characterized by GC-MS with two different extraction techniques: solid-phase trapping solvent extraction (SPTE) and headspace solid-phase microextraction (HSSPME). Aroma components emitted from Hallabong peel were compared with those of other citrus varieties: lemon, orange and grapefruit by SPTE and GC-MS. d-Limonene (96.98%) in Hallabong was the main component, and relatively higher peaks of cis- ${\beta}$-ocimene, valencene and -farnesene were observed. Other volatile aromas, such as sabinene, isothujol and ${\delta}$-elemene were observed as small peaks. Also, principal components analysis was employed to distinguish citrus aromas based on their chromatographic data. For HSSPME, the fiber efficiency was evaluated by comparing the partition coefficient ($K_{gs}$Kgs) between the HS gaseous phase and HS-SPME fiber coating, and the relative concentration factors (CF) of the five characteristic compounds of the four citrus varieties. 50/30 ${\mu}$m DVB/CAR/PDMS fiber was verified as the best choice among the four fibers evaluated for all the samples.

Fabrication and Characteristics of Amperometric NO2 Gas Sensors (전류검출형 NO2가스 센서의 제작과 특성평가)

  • Kim, Gwi-Yeol
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.9
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    • pp.821-827
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    • 2007
  • The nitrogen oxides, NO and $NO_2$, abbreviated usually as NOx, emitted from combustion facilities such as power plants and automobiles are the typical air-pollutants causing acid rain and photochemical smog. In order to solve the NOx-related pollution problems effectively, we need efficient techniques to monitor NOx in the combustion exhausts and in environments. Development of solid-state electrochemical devices for detecting NOx is demonstrated based on various combination of solid electrolytes and auxiliary sensing materials. The object of this research is to develop various sensor performance for solid state amperometric sensor, and to test gas sensor performance manufactured. So we try to present a guidance for developing amperometric gas sensor. We concentrated on development of manufacturing process and performance test. Amperometric Nitrogen dioxide sensor was fabricated using NASICON and an $NaNO_2$ layer deposited on the counter electrode. The current response was almost linear with Nitrogen dioxide concentration in the range 1-350 ppb at $150^{\circ}C$.