• Title/Summary/Keyword: small shifts

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A Solid-State NMR Study of Water in Poly(vinyl butyral) by Magic Angle Spinning

  • Jeong, Soon-Yong;Han, Oc-Hee
    • Bulletin of the Korean Chemical Society
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    • v.28 no.4
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    • pp.662-666
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    • 2007
  • Poly(vinyl butyral) (PVB) with different wt% water was studied gravimetrically as well as with 1H magic angle spinning (MAS) nuclear magnetic resonance (NMR). The composition of PVB samples changes during MAS NMR because of the centrifugal force. As MAS time progresses, initially free water was removed fast but bound water also was gradually depleted. More water was diminished at faster spinning speeds, longer spinning time, higher temperatures, and higher initial water contents. As water in PVB was reduced, the chemical shifts and line widths of different types of water and also those of PVB changed. Our results demonstrate that 1H MAS NMR carried out at 10 kHz in less than about 5 minutes is a convenient and sensitive technique to measure: (a) the content variations of different types of water in polymers, (b) the degree of the interaction of water and polymer, and (c) the molecular dynamics of the polymer. Our study can be extended to different soft polymers with other small molecules than water in them.

Comparison of accumulate-combine and combine-accumulate methods in multivariate CUSUM charts for mean vector

  • Chang, Duk-Joon;Heo, Sunyeong
    • Journal of the Korean Data and Information Science Society
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    • v.24 no.4
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    • pp.919-929
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    • 2013
  • We compared two basic methods, combine-accumulate method and accumulate-combine method, using the past quality information in multivariate quality control procedure for monitoring mean vector of multivariate normal process. When small or moderate shifts have occurred, accumulate-combine method yields smaller average run length (ARL) and average time to signal (ATS) than combine-accumulate method. On the other hand, we have found from our numerical results that combine-accumulate method has better performances in terms of switching behavior than accumulate-combine method. In industry, a quality engineer could select one of the two method under the comprehensive consideration about the required time to signal, switching behavior, and other physical factors in the production process.

The Buckling Characteristics of Single-Layer Latticed Domes with Initial Imperfection (초기불완전성을 고려한 단층래티스돔의 좌굴특성)

  • 권택진;한상을;이동우;주동현
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 1996.04a
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    • pp.1-8
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    • 1996
  • Many studies showed that small imperfections can also have a considerable influence on the behaviour of structures. Especially, in Single-Layer Latticed Domes, initial imperfection occurred by human error and construction error is very important to the buckling load. The definition of imperfection is that a node of structure shifts from perfect condition. For example, in the case of truss structures, imperfections are represented by shifting the location of nodal points relative to the position in which they would be for a perfect structure. This paper uses Arc-length Method in nonlinear iteration analysis, choosing star dome, in which many studies have been accomplished, as a model. The results of analysis show that initial imperfection can reduce the buckling load of structures.

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Comparison of the Efficiencies of Variable Sampling Intervals Charts for Simultaneous Monitoring the means of multivariate Quality Variables

  • Chang, Duk-Joon
    • Journal of Integrative Natural Science
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    • v.9 no.3
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    • pp.215-222
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    • 2016
  • When the linear correlation of the quality variables are considerably high, multivariate control charts may be a more effective way than univariate charts which operate quality variables and process parameters individually. Performances and efficiencies of the multivariate control charts under multivariate normal process has been considered. Some numerical results are presented under small scale of the shifts in the process to see the improvement of the efficiency of EWMA chart and CUSUM chart, which use past quality information, comparing to Shewart chart, which do not use quality information. We can know that the decision of the optimum value of the smoothing constant in EWMA structure or the reference value in CUSUM structure are very important whether we adopt combine-accumulate technique or accumulate-combine technique under the given condition of process.

Enhanced Raman Spectrum of Juglone on Ag Surface: Is It a Simile to That of Lawsone?

  • Cheong, Byeong-Seo;Cho, Han-Gook
    • Bulletin of the Korean Chemical Society
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    • v.34 no.1
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    • pp.68-74
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    • 2013
  • The surface enhanced Raman spectrum of juglone, a traditional natural dye, has been observed by a custom-built micro-Raman setup. The spectral features of juglone significantly differ from those of lawsone, a structural isomer of juglone; only small red shifts of the double bond stretching bands are observed, and strong SERS bands are observed in the lower frequency regions as well. The DFT computations reveal that juglone coordinated to an $Ag^+$ adatom with $H^+$ release best correlates with the observed vibrational characteristics in the SERS spectrum among the plausible configurations of juglone coordinated to an adatom on the Ag surface, in line with the previously studied lawsone case. The differences in the SERS spectra of juglone and lawsone are attributed to the different locations of the hydroxyl group in the two isomers.

Performances of VSI Multivariate Control Charts with Accumulate-Combine Approach

  • Chang, Duk-Joon;Heo, Sun-Yeong
    • Journal of the Korean Data and Information Science Society
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    • v.17 no.3
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    • pp.973-982
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    • 2006
  • Performances of variable sampling interval(VSI) multivariate control charts with accumulate-combine approach for monitoring mean vector of p related quality variables were investigated. Shewhart control chart is also proposed to compare the performances of CUSUM and EWMA charts. Numerical comparisons show that performances of CUSUM and EWMA charts are more efficient than Shewhart chart for small or moderate shifts, and VSI chart is more efficient than fixed sampling interval(FSI) chart. We also found that performances of the CUSUM or EWMA chart with accumulate-combine approach are substantially efficient than those of Shewhart chart.

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Multiparameter CUSUM charts with variable sampling intervals

  • Im, Chang-Do;Cho, Gyo-Young
    • Journal of the Korean Data and Information Science Society
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    • v.20 no.3
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    • pp.593-599
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    • 2009
  • We consider the problem of using control charts to monitor more than one parameter with emphasis on simultaneously monitoring the mean and variance. The fixed sampling interval (FSI) control charts are modified to use variable sampling interval (VSI) control charts depending on what is being observed from the data. In general, approaches of monitoring the mean and variance simultaneously is to use separate charts for each parameter and a combined chart. In this paper, we use three basic strategies which are separate Shewhart charts for each parameter, a combined Shewhart chart and a combined CUSUM chart. We showed that a combined VSI CUSUM chart is comparatively more efficient than any other chart if the shifts in both mean and variance are small.

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Switching properties of multivariate Shewhart control charts

  • Kim, Bo-Jung;Cho, Gyo-Young
    • Journal of the Korean Data and Information Science Society
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    • v.28 no.4
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    • pp.911-925
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    • 2017
  • We investigate the properties of multivariate Shewart control charts with VSI procedure for monitoring simultaneous monitoring mean vector and covariance matrix in term of ANSW (average number of switches), probability of switch and ASI (average sampling interval), ATS (average time to signal). From examining the ANSW values, we know that it does not switch frequently. The VSI control charts are superior to the corresponding FSI control charts in terms of ATS. And, it can be also seen that the VSI procedures have substantially fewer switches for small or moderate shifts of the mean vector and variances.

On Calculating Eigenvalues In Large Power Systems Using Modified Arnoldi Method

  • Lee, Byong-Jun;Iba, Kenjl;Hirose, Michio
    • Proceedings of the KIEE Conference
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    • 1996.07b
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    • pp.734-736
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    • 1996
  • This paper presents a method of calculating a selective number of eigenvalues in power systems, which are rightmost, or are largest modulus. The modified Arnoldi method in conjunction with implicit shift OR-algorithm is used to calculate the rightmost eigenvalues. Algorithm requires neither a prior knowledge of the specified shifts nor the calculation of inverse matrix. The key advantage of the algorithm is its ability to converge to the wanted eigenvalues at once. The method is compared with the modified Arnoldi method combined with S-matrix transformation, where the eigenvalues having the largest modulus are to be determined. The two methods are applied to the reduced Kansai system. Convergence characteristics and performances are compared. Results show that both methods are robust and has good convergence properties. However, the implicit shift OR method is seen to be faster than the S-matrix method under the same condition.

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Electronic Image Stabilization for Portable Thermal Image Camera (휴대용 열 영상 관측 장비를 위한 전자적 영상 안정화)

  • Kim, Jong-ho
    • Journal of the Korea Institute of Military Science and Technology
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    • v.19 no.3
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    • pp.288-293
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    • 2016
  • Electronic Image Stabilization(EIS) is widely used as a technique for correcting a shake of an image. The case requiring the EIS function has been increased in high magnification thermal image observation on portable military equipment. Projection Algorithm(PA) for EIS is easy to implement but its performance is sensitive to the projection area. Especially, projection profiles of thermal image have very modest change and are difficult to extract image shifts between frames. In this paper, we proposed algorithm to extract a feature image for the thermal image and compared Block Matching Algorithm(BMA) with PA using our proposed feature image. When using our proposed feature image, BMA was simply implemented using FPGA's internal small memory. And we were able to obtain 30 % PSNR improved results compared to PA.