• 제목/요약/키워드: small shifts

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Interactions between Water-Soluble Polyparacyclophanes and Drugs (II) -Interaction between Water-Soluble Polyparacyclophanes and Fluorescent Hydrophobic Naphthalene Derivatives in Aqueous Solution- (수용성 폴리파라시클로판류와 약물과의 상호작용(제 2보) -수용액중 수용성 폴리파라시클로판류와 형광 소수 나프탈렌 유도체류와의 상호 작용-)

  • Chun, In-Koo;Lee, Min-Hwa;Kim, Shin-Keun
    • Journal of Pharmaceutical Investigation
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    • 제18권3호
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    • pp.113-123
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    • 1988
  • A series of water-soluble polyparacyclophanes bearing two diphenylmethane or two diphenyl ether skeletons were investigated to develop useful host compounds by using 1-anilinonaphthalene-6-sulfonate (ANS) and 2-p-toluidinylnaphthalene-6-sulfonate (TNS) as fluorescent hydrophobic substrates in aqueous solution. It was noteworthy that remarkable fluorescent enhancements and blue shifts of ANS and TNS were observed only in the presence of 1,6,20,25-tetraaza[6.1.6.1] paracyclophane (CPM 44) and 1,6,21,27-tetraaza [7.1.7.1] paracyclophane (CPM 55) for diphenylmethane skeleton, and 1,7,21,27-tetraaza-14,34-dioxa [7.1.7.1] paracyclophane (CPE 55) and 1,8,22,29-tetraaza-15,36-dioxa [8.1.8.1] paracyclophane (CPE 66) for diphenyl ether skeleton, comparing with ${\alpha}-\;and\;{\beta}-cyclodextrins$. However, their acyclic analogues such as 4,4'-dimethylaminodiphenylmethane and 4,4'-dimethylaminodiphenyl ether, and paracyclophanes whose cavities were smaller showed only small effects under the same conditions. These facts suggested that hosts and substrates were in an intimate contact which would not occur without larger structures, and thus that guest molecules were strongly incorporated in the hydrophobic cavities of these larger paracyclophanes. The effects of pH on the fluorescent intensity of ANS-CPM 44, ANS-CPM 55, ANS-CPE 55, ANS-CPE 66, TNS-CPM 44, TNS-CPM 55, TNS-CPE 55 and TNS-CPE 66 systems were not significant below pH 2.0, but their fluorescent intensities were markedly reduced with increasing ionic strength.

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Spatio-Temporal Dynamics of Immigrant Self-employment: A Case Study of Korean Immigrants in Chicago (도시 내 이민자 자영업의 시공간적 역동성 - 시카고 거주 한국인 이민자를 사례로 -)

  • Chung, Su-Yeul;Yim, Seok-Hoi
    • Journal of the Economic Geographical Society of Korea
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    • 제15권3호
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    • pp.376-389
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    • 2012
  • Ethnic entrepreneurship, an important means by which immigrants improve economic status, is widely believed to be facilitated by their residential concentration, i.e. ethnic enclaves. However, the recent immigrants' residential dispersion and re-clustering in some selected well-to-do suburbs portend changes in the role of ethnic enclave as a nest of immigrant entrepreneurship. This paper investigates the impacts of the residential dispersal on ethnic entrepreneurship with a case study of Korean small businessmen in Chicago, Illinois PMSA. The research utilizes the Public Use Microdata Sample (PUMS) to know the overall changes in Korean entrepreneurship through 1990s and conducts a survey to understand reactions and surviving strategies of Korean enclave businessmen to the residential shifts. Relevant to those analyses is the enclave-economy hypothesis which argues benefit from spatial clustering of co-ethnic entrepreneurs by yielding more business opportunities and higher returns.

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Comparative Analysis from Perspective of Kinesiology between Korean Athletes and Gold and Bronze Medalists in Glide-Type Shot Put at Daegu World Athletic Championships in 2011 (2011 대구세계육상선수권대회 Gilde Type 포환던지기 한국선수와 결승 1, 3위 선수와의 운동학적 비교분석)

  • Oh, Chow-Hwan;Choi, Su-Nam;Shin, Eui-Su;Lee, Jeong-Tae;Jeong, Ik-Su;Bae, Jae-Hee;Park, Seung-Bum
    • Korean Journal of Applied Biomechanics
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    • 제21권5호
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    • pp.645-652
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    • 2011
  • The purpose of this study was to analyze, in real time, the glide motion and release motion of domestic athletes and gold and bronze medalists employing the glide technique for the men's shot put at the Daegu World Athletic Championship in 2011. In the glide motion, the Korean athletes had a relatively high body center and shot put heights and lager stretching angles for their hips and knees. In the delivery phase, which shifts to the release phase, the Korean athletes showed slower vertical body center and shot put speeds, and they changed the phase, to the release phase by using a small body angle. In the release phase, the Korean athletes showed differences in their projection speeds and vertical body center speeds. The world-famous players showed high angle speeds, which refer to the composition of the rotation force at the moment of release (body, hip, and shoulder line). In the release phase, the Korean athletes did not have fully stretched hip and knee angles, which might have negatively influenced the vertical speed. Because the Korean athletes showed relatively low projection heights and projection angles. it was found that they need to enhance the muscular power of their, throwing arms and lower limbs.

A Basic Study on the Koreanness of Contemporary Korean Landscape Architecture (한국 현대 조경의 한국성 논의를 위한 기초 연구)

  • Choi, Jung-Min;Choi, Key-Soo
    • Journal of the Korean Institute of Landscape Architecture
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    • 제35권4호
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    • pp.1-15
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    • 2007
  • The purpose of this study is to mate a basic foundation for the discourse of Koreanness of contemporary Korean landscape architecture by way of searching the conceptual definitions of Koreanness through analysis of Koreanness discourses. The results are that discourses of Koreanness are to be classified in aesthetics type, spatial-temporal type, and cultural type. Aesthetics type is understood as style in terms of formal and design representation planning principles of spatial composition and immanence in terms of philosophy. Spatial-temporal type is understood as contemporaneity. This is classified as the concept of connoting of tradition, and separating and keeping a distance from tradition. Cultural type is prescribed as cultural identity. This is classified as unity, generality and individuality. The intension of Koreanness of these types is represented as an aspect changing and shifting from one regulation to another regulation. First, in the concerns of substantial archetypes like Korean original form, decorative element, spatial composition aesthetic perception and philosophy, Koreanness shifts to the point of view of contemporaniety which is created and defined in history. Second, Koreanness as contemporaniety shows a trend of shifting the point of view which is to be found through the reconsideration on modem history and modernism. Third, Koreanness defined as cultural identity shows a trend to emphasize the differences in other cultures and includes all the modem cultural agents. The number of views understood as individuality and denial are small but provide important points. Programmatic definition of Koreanness is not suitable. This basic study uses a stipulative or operational definition of Koreanness in many ways such as spatial and regional identity. Koreanness study for Korean contemporary landscape architecture requires a systematic understanding of modernity and colonization relating to identity. Also, it is needed to elaborate on the discourse to divide the meaning of a concept of identity.

Effects of Exercise on Rat Skeletal Muscle Perfused with Glucose (포도당으로 Perfusion한 쥐의 다리근육에 운동(運勳)이 미치는 영향)

  • Cho, Sung-Hee;Yoon, Jae-Man
    • Journal of the Korean Society of Food Science and Nutrition
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    • 제13권4호
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    • pp.437-443
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    • 1984
  • Muscular exercise induced by electrical stimulation of femoral nerves in perfused rat hindquarters(5 contractions per sec) in the presence of insulin and glucose effected a rapid increase(c. a. two-fold) in the level of citric acid cycle intermediates. The highest values were found within one minute of stimulation. The tissue concent ratios of lactate, pyruvate and alanine increased rapidly on initiation of exercese. Release of lactate also increased rapidly, whereas that of pyruvate was only moderately elevated. In the course of three minute exercese, the sum of alanine, glutamate and aspartate was only transiently elevated. A fall in creatine-p and ATP in the stimulated muscle was accompanied by increases in tissue level of AMP and release of ammonia into perfusing medium. However, the changes in glutamine were small. It is concluded that the pool of citric acid cycle intermediates is expanded during muscular work due (a) to an elevated level of pyruvate, leading to shifts in the levels of alanine and cycle intermediates vie trans-amination reactions and (b) to stimulation of the purine nucleotide cycle due to elevated AMP, resulting in generation of cycle intermediates and ammonia at the expense of aspartate.

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Similar Trajectory Store Scheme for Efficient Store of Vehicle Historical Data (효율적인 차량 이력 데이터 저장을 위한 유사 궤적 저장 기법)

  • Kwak Ho-Young;Han Kyoung-Bok
    • The Journal of the Korea Contents Association
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    • 제6권1호
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    • pp.114-125
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    • 2006
  • Since wireless Internet services and small mobile communication devices come into wide use as well as the use of GPS is rapidly growing, researches on moving object, whose location information shifts sequently in accordance with time interval, are being carried out actively. Especially, the researches on vehicle moving object are applied to Advanced traveler information system, vehicle tracking system, and distribution transport system. These systems are very useful in searching previous positions, predicted future positions, the optimum course, and the shortest course of a vehicle by managing historical data of the vehicle movement. In addition, vehicle historical data are used for distribution transport plan and vehicle allocation. Vehicle historical data are stored at regular intervals, which can have a pattern. For example, a vehicle going repeatedly around a specific section follows a route very similar to another. If historical data of the vehicle with a repeated route course are stored at regular intervals, many redundant data occur, which result in much waste of storage. Therefore this thesis suggest a vehicle historical data store scheme for vehicles with a repeated route course using similar trajectory which efficiently store vehicle historical data.

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Simultaneous Measurement of Strain and Damage Signal in Composite Structures Using a Fiber Bragg Grating Sensor (광섬유 브래그 격자 센서를 이용한 복합재 구조물의 변형률 및 파손신호 동시 측정)

  • Koh, Jong-In;Bang, Hyung-Joon;Kim, Chun-Gon;Hong, Chang-Sun
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • 제32권7호
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    • pp.43-50
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    • 2004
  • For the simultaneous measurement of strain and damage signal a fiber Bragg grating sensor system with a dual demodulator was proposed. The dual demodulator is composed of a demodulator using a tunable Fabry-Perot filter measuring the low-frequency signal with large magnitude such as strain and the other using a passive Mach-Zehnder interferometer detecting the high-frequency signal with small amplitude such as impact or damage signal. Using the proposed fiber Bragg grating sensor system, both the strain and damage signals of a cross-ply laminated composite beam under tensile loading were simultaneously measured. The strain and damage signals detected by single fiber Bragg grating sensor showed that sudden strain shifts were accompanied with vibration at a maximum frequency of several hundreds of kilohertz at the instant of matrix crack propagation in the 90 degree layer in composite beam.

Interleaving Phenomena of the North Pacific Intermediate Water in the Offshore Area of the Kuroshio

  • Yang, Sung-Kee;Lee, Byung-Gul
    • Journal of Environmental Science International
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    • 제12권5호
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    • pp.521-527
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    • 2003
  • To study the intruded phenomena of North Pacific Ocean around Boso peninsular, water property distribution in the adjacent seas to Japan is studied using the hydrographic data obtained by Japan Maritime Agency and Japan Fisheries Agency from 1973 to 1996, The scattering of water type in T-5 diagram is relatively small in the Kuroshio Region. Both the envelopes of saline side and of fresh side of the scattered data points shifts gradually from saline side to fresh side as the observation Line moves from southwest to northeast. In mixed water region, the scattering of water type increases rapidly as the observation line moves north; the envelope of fresh cold side moves towards fresh cold side much faster than that of saline side. This suggests that the water does not advect along the salinity minimum layer, but the salinity minimum layer can be understood as a boundary of two different waters aligned vertically, We defined the typical water masses as the Oyashio Water and the Kuroshio Water. The water mass below the salinity minimum layer may be created by isopycnal mixing of these two water masses with a fixed mixing rate. While the water mass above the salinity minimum cannot be created simply by isopycnal mixing. The salinity minimum layer may be eroded from upper side due to active minxing processes in the surface layer, while the water of the salinity minimum layer moves gradually southward. This appears to give an explanation why the thermosteric anomaly value at salinity minimun decereases towards south.

Cable with discrete negative stiffness device and viscous damper: passive realization and general characteristics

  • Chen, Lin;Sun, Limin;Nagarajaiah, Satish
    • Smart Structures and Systems
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    • 제15권3호
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    • pp.627-643
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    • 2015
  • Negative stiffness, previously emulated by active or semi-active control for cable vibration mitigation, is realized passively using a self-contained highly compressed spring, the negative stiffness device (NSD).The NSD installed in parallel with a viscous damper (VD) in the vicinity of cable anchorage, enables increment of damper deformation during cable vibrations and hence increases the attainable cable damping. Considering the small cable displacement at the damper location, even with the weakening device, the force provided by the NSD-VD assembly is approximately linear. Complex frequency analysis has thus been conducted to evaluate the damping effect of the assembly on the cable; the displacement-dependent negative stiffness is further accounted by numerical analysis, validating the accuracy of the linear approximation for practical ranges of cable and NSD configurations. The NSD is confirmed to be a practical and cost-effective solution to improve the modal damping of a cable provided by an external damper, especially for super-long cables where the damper location is particularly limited. Moreover, mathematically, a linear negative stiffness and viscous damping assembly has proven capability to represent active or semi-active control for simplified cable vibration analysis as reported in the literature, while in these studies only the assembly located near cable anchorage has been addressed. It is of considerable interest to understand the general characteristics of a cable with the assembly relieving the location restriction, since it is quite practical to have an active controller installed at arbitrary location along the cable span such as by hanging an active tuned mass damper. In this paper the cable frequency variations and damping evolutions with respect to the arbitrary assembly location are then evaluated and compared to those of a taut cable with a viscous damper at arbitrary location, and novel frequency shifts are observed. The characterized complex frequencies presented in this paper can be used for preliminary damping effect evaluation of an adaptive passive or semi-active or active device for cable vibration control.

Exponentially Weighted Moving Average Chart for High-Yield Processes

  • Kotani, Takayuki;Kusukawa, Etsuko;Ohta, Hiroshi
    • Industrial Engineering and Management Systems
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    • 제4권1호
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    • pp.75-81
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    • 2005
  • Borror et al. discussed the EWMA(Exponentially Weighted Moving Average) chart to monitor the count of defects which follows the Poisson distribution, referred to the $EWMA_c$ chart, as an alternative Shewhart c chart. In the $EWMA_c$ chart, the Markov chain approach is used to calculate the ARL (Average Run Length). On the other hand, in order to monitor the process fraction defectives P in high-yield processes, Xie et al. presented the CCC(Cumulative Count of Conforming)-r chart of which quality characteristic is the cumulative count of conforming item inspected until observing $r({\geq}2)$ nonconforming items. Furthermore, Ohta and Kusukawa presented the $CS(Confirmation Sample)_{CCC-r}$ chart as an alternative of the CCC-r chart. As a more superior chart in high-yield processes, in this paper we present an $EWMA_{CCC-r}$ chart to detect more sensitively small or moderate shifts in P than the $CS_{CCC-r}$ chart. The proposed $EWMA_{CCC-r}$ chart can be constructed by applying the designing method of the $EWMA_C$ chart to the CCC-r chart. ANOS(Average Number of Observations to Signal) of the proposed chart is compared with that of the $CS_{CCC-r}$ chart through computer simulation. It is demonstrated from numerical examples that the performance of proposed chart is more superior to the $CS_{CCC-r}$ chart.