• Journal of Welding and Joining
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• 제19권2호
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• pp.182-190
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• 2001

A marine structural material was well known to have high tensile strength, good weldability and proper corrosion resistance. Cu-containing high strength low alloy(HSLA) steel was recently developed for their purposes mentioned above. And the steel is free about preheating for welding, therefore it is reported that shipbuilding cost by using it can be saved more or less. However the marine structural materials like Cu-containing HSLA steel are being generally adopted with cathodic protection method in severe corrosive environment like natural sea water but the high strength steel may give rise to Hydrogen Embrittlement due to over protection at high cathodic current density for cathodic protection. In this study Cu-containing HSLA steel using well for marine atructure was investigated about the susceptibility of Hydrogen Embrittlement as functions of tensile strength, strain ratio, fracture time, and fracture mode, etc. and an optimum cathodic protection potential by slow strain rate test(SSRT) method as well as corrosion properties in natural sea water. And its corrosion resistance was superior to SS400 steel, but Hydrogen Embrittlement susceptibility of Cu-containing HSLA steel was higer than that of SS400 steel. However Hydrogen Embrittlement of its steel by SSRT method was showed with pheonomena such as decreasing of fracture time, strain ratio and fracture mode of QC(quasi-cleavage). Eventually it is suggested that an optimum cathodic protection potential not presenting Hydrogen Embrittlement of Cu-containing of HSLA steel by SSRT method was from-770mv(SCE) to - 900mV(SCE)under natural sea water.

• 한국재료학회지
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• 제28권12호
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• pp.738-747
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• 2018

For the aerospace structural application of high-strength 2xxx series aluminum alloys, stress corrosion cracking(SCC) behavior in aggressive environments needs to be well understood. In this study, the SCC sensitivities of 2024-T62, 2124-T851 and 2050-T84 alloys in a 3.5 % NaCl solution are measured using a constant load testing method without polarization and a slow strain rate test(SSRT) method at a strain rate of 10-6 /sec under a cathodic applied potential. When the specimens are exposed to a 3.5 % NaCl solution under a constant load for 10 days, the decrease in tensile ductility is negligible for 2124-T851 and 2050-T84 specimens, proving that T8 heat treatment is beneficial in improving the SCC resistance of 2xxx series aluminum alloys. The specimens are also susceptible to SCC in a hydrogen-generating environment at a slow strain rate of $10^{-6}/sec$ in a 3.5 % NaCl solution under a cathodic applied potential. Regardless of the test method, low impurity 2124-T851 and high Cu/Mg ratio 2050-T84 alloys are found to have relatively lower SCC sensitivity than 2024-T62. The SCC behavior of 2xxx series aluminum alloys in the 3.5 % NaCl solution is discussed based on fractographic and micrographic observations.

• 대한용접접합학회:학술대회논문집
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• 대한용접접합학회 1999년도 특별강연 및 춘계학술발표대회 개요집
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• pp.241-244
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• 1999

The purpose of this study is to examine the characteristics of stress corrosion cracking(SCC) and acoustic emission(AE) signals for the weld HAZ of HT-60 steel under corrosion control in synthetic seawater. Corrosive environment was controlled by potentiostat, and SCC experiment was conducted using a slow strain rate test method at strain rate of 10$^{-5}$ /sec. In order to verify the miroscopic fracture behaviour of the weldment during SCC phenomena, AE test was done simultaneously. Besides, correlationship between mechanical parameters and AE ones was investigated. In case of the parent, reduction of area(ROA) at -0.5V was samller than any other applied voltage such as -0.8V and -1.1V. In addition, reduction of area for the PWHT specimens at -0.8mV was larger than that of the weldment due to the softening effect according to PWHT. In case of the weldment, a lots of events was produced because of the singularities of the weld HAZ compared with the parent.

• Corrosion Science and Technology
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• 제21권6호
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• pp.503-513
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• 2022

As part of eco-friendly policies, interest in hydrogen vehicles is growing in the automotive industry to reduce carbon emissions. In particular, it is necessary to investigate the application of aluminum alloy for light weight hydrogen valves among hydrogen supply systems to improve the fuel efficiency of hydrogen vehicles. In this research, we investigated mechanical characteristics of aluminum alloys after hydrogen embrittlement considering the operating environment of hydrogen valves. In this investigation, experiments were conducted with strain rate, applied voltage, and hydrogen embrittlement time as variables that could affect hydrogen embrittlement. As a result, a brittle behavior was depicted when the strain rate was increased. A strain rate of 0.05 mm/min was selected for hydrogen embrittlement research because it had the greatest effect on fracture time. In addition, when the applied voltage and hydrogen embrittlement time were 5 V and 96 hours, respectively, mechanical characteristics presented dramatic decreases due to hydrogen embrittlement.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 1995년도 춘계학술대회논문집
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• pp.238-251
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• 1995

Creep of metals has been explained conventionally by dislocation climb and grain boundary sliding indiffusion controlled process. The reorienations of the atoms in the grain by three dimensional crystallizing $\pi$-bondings are visualized as grain rotatins during slow deformation, fold formatin at triple point, increased crevice dspace between grains. grain boundary sliding, grain boundary micration and formation of cracks at the grain boundaries . And also the rupture time and average creep strain rate are explained by the three-dimensional crystallizing $\pi$- bondings and they can be determined by uniaxial tensile test.

• Journal of Welding and Joining
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• 제15권1호
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• pp.46-54
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• 1997

The object of this paper is to evaluate SCC(stress corrosion cracking) susceptibility for parent metal and bond line region of weld joints which have the various weld heat input condtions in TMCP(thermo-mechanical control process) steel by SP-SSRT(small punch-slow strain rate test) method. And the SCC test results of TMCP steel are compared with those of the conventional HT50 steel which has te almost same tensile strength level like TMCP steel. The loading rate used was $3\times10^{-4}$mm/min and the corrosive environment was synthetic sea water. According to the test results, in the case of parent metal, TMCP steel showed higher SCC susceptibility than HT50 steel because of the high plastic strain level of ferrite microstructure obtained by accelerated cooling. And in the case of bond line, the both TMCP steel and HT50 steel showed low load-displacement behaviors and higher SCC susceptibility above 0.6. These results may be caused by theembrittled martensite structure on HT50 steel and by the coarsened grain and the proeutectoid ferrite structure obtained by the impart of accelerated cooling effect on TMCP steel.

• Journal of Advanced Marine Engineering and Technology
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• 제30권1호
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• pp.157-168
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• 2006

Recently, interest in using Al alloys in ship construction instead of fiber-reinforced plastic (FRP) has increased because of the advantages of A) alloy ships over FRP ships, including high speed, increased load capacity. and ease of recycling. This paper investigated the mechanical and electrochemical properties of Al alloys in a slow strain rate test under various potential conditions. These results will provide reference data for ship design by determining the optimum protection potential regarding hydrogen embrittlement and stress corrosion cracking. In general, Al and Al alloys do not corrode on formation of a film that has resistance to corrosion in neutral solutions. In seawater, however, $Cl^-$ ions lead to the formation and destruction of a Passive film. In a potentiostatic experiment. the current density after 1200 sec in the Potential range of $-0.68\~-1.5\;V$ was low. This low current density indicates the protection potential range. Elongation at an applied potential of 0 V was high in this SSRT. However, corrosion protection under these conditions is impossible because the mechanical properties are worse owing to decreased strength resulting from the active dissolution reaction in parallel parts of the specimen. A film composed of $CaCO_3\;and\;Mg(OH)_2$ confers corrosion resistance. However, at potentials below -1.6 V forms non-uniform electrodeposition coating, since there is too little time to form a coating. Therefore, we concluded that the mechanical properties are poor because the effect of hydrogen gas generation exceeds that of electrodeposition. Comparison of the maximum tensile strength, elongation, and time to fracture indicated that the optimum protection potential range was from -1.45 to -0.9 V (SSCE).

• Corrosion Science and Technology
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• 제2권6호
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• pp.283-288
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• 2003

The cathodic protection method is being widely used in marine structural steel, however a high tensile steel like RE 36 steel for marine structural steel is easy to get hydrogen embrittlement due to over protection during cathodic protection as well as preferential corrosion of HAZ(Heating Affected Zone) part. In this paper, corrosion resistance and mechanical properties such as elongation and hydrogen embrittlement were investigated with not only in terms of electrochemical view but also SSRT(Slow Strain Rate Test) method with applied constant cathodic potential, analysis of SEM fractography in case of both As-welded and PWHT(Post-Weld Heat Treatment) of $550^{\circ}C$. The best effect for corrosion resistance was apparently indicated at PWHT of $550^{\circ}C$ and elongation was increased with PWHT of $550^{\circ}C$ than that of As-welded condition. On the other hand. Elongation was decreased with applied potential shifting to low potential direction which may be caused by hydrogen embrittlement, however the susceptibility of hydrogen embrittlement was decreased with PWHT of $550^{\circ}C$ than that of As-welded condition and Q.C(quasi cleavage) fracture mode was also observed significantly according to increasing of susceptibility of hydrogen embrittlement. Eventually it is suggested that an optimum cathodic protection potential range not causing hydrogen embrittlernent is from -770 mV(SCE) to -850 mV(SCE) in As-welded condition while is from -770 mV(SCE) to -875 mV(SCE) in PWHT of $550^{\circ}C$.

• 한국재료학회지
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• 제32권11호
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• pp.466-473
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• 2022

The effect of Cr and Mo contents on the hydrogen embrittlement of tempered martensitic steels was investigated in this study. After the steels with different Cr and Mo contents were austenitized at 820 ℃ for 90 min, they were tempered at 630 ℃ for 120 min. The steels were composed of fully tempered martensite with a lath-type microstructure, but the characteristics of the carbides were dependent on the Cr and Mo contents. As the Cr and Mo contents increased, the volume fraction of film-like cementite and prior austenite grain size decreased. After hydrogen was introduced into tensile specimens by electrochemical charging, a slow strain-rate test (SSRT) was conducted to investigate hydrogen embrittlement behavior. The SSRT results revealed that the steel with lower Cr or lower Mo content showed relatively poor hydrogen embrittlement resistance. The hydrogen embrittlement resistance of the tempered martensitic steels increased with increasing Mo content, because the reduction in the film-like cementite and prior austenite grain size plays an important role in improving hydrogen embrittlement resistance. The results indicate that controlling the Cr and Mo contents is essential to achieving a tempered martensitic steel with a combination of high strength and excellent hydrogen embrittlement resistance.

• 한국자동차공학회논문집
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• 제3권1호
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• pp.1-12
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• 1995

Isothermal and thermal-mechanical fatigue characteristics of 12Cr heat resisting steel used for high temperature applications were investigated including hold time effects. Isothermal low cycle fatigue test at $600^{\circ}C$ and in-phase, out-of-phase thermal-mechanical fatigue test at 350 to $600^{\circ}C$ were conducted using smooth cylindrical hollow specimen under strain-control with total strain ranges from 0.006 to 0.015. Regardless of thermal-mechanical and isothermal fatigue tests, cyclic softening behavior was observed and much more pronounced in the thermal-mechanical fatigue tests with hold times due to the stress relaxation during the hold time. The phase difference between temperature and strain in thermal-mechanical fatigue tests resulted in significantly shorter fatigue life for out-of-phase compared to in-phase. The differences in fatigue lives were dependent upon the magnitudes of plastic strain ranges and mean stresses. During the hold time in the strain-controlled fatigue tests, the increase in the plastic strain range and the stress relaxation were observed. It appeared that the increase in plastic strain range per cycle and the introduction of creep damage made important contributions to the reduction of thermal-mechanical fatigue life with hold time, and the life reduction tendency was more remarkable in the in-phase than in the out-of-phase thermal-mechanical fatigue. Isothermal fatigue tests performed under the combination of fast and slow strain rates at $600^{\circ}C$ showed that the fatigue life decreased as the strain rate and frequency decreased,especially for the low strain ranges.