• Title/Summary/Keyword: size-dependent

Search Result 2,009, Processing Time 0.03 seconds

Chemical Activation Characteristics of Pitch-Based Carbon Fibers by KOH

  • Jang, Jeen-Seok;Lee, Young-Seak;Kim, In-Ki;Yim, Going
    • Carbon letters
    • /
    • v.1 no.2
    • /
    • pp.69-75
    • /
    • 2000
  • Naphtha cracking bottom oil was reformed with heat treatment and then spun at $310^{\circ}C$. These pitch-based carbon fibers were carbonized at $1000^{\circ}C$ after oxidation at $280^{\circ}C$, for 90 min. These fibers were chemically activated with molar ratio of KOH/CF (1 : 1) at different temperatures ($250{\sim}900^{\circ}C$) for 1 hr. The process of activation was characterized with DTA, TGA, BET surface area and pore size distribution. The activation of fibers by KOH was performed by several process. One is the reduction process that carbon fiber was reacted with $K_2O$ produced from dehydration process above $400^{\circ}C$. The other is the process that $K_2CO_3$ was directly reacted with carbon fiber. At $800^{\circ}C$, the activation was performed by catalyzed mechanism that $K_2O$ was obtained from the reaction of metal potassium with $CO_2$, then was changed to $K_2CO_3$. At $870^{\circ}C$, the activation was also observed that activation mechanism was promoted by metal catalyst with $CO_2$ from decomposition of $K_2CO_3$. The specific surface area of prepared activated carbon fibers was dependent on the activation mechanism. The specific surface area was in the range of $1519{\sim}2000\;cm^3/g$ and was the largest prepared at $870^{\circ}C$. The pores developed were mostly micropores which was very narrow and uniform. The total pore volume was $0.58{\sim}0.77\;cm^3/g$.

  • PDF

Regimes for the Improvement on Education and Training for Environmental Mangers on site (환경관리인의 교육.훈련 현황 및 개선 방안 연구)

  • 전의찬;조순철
    • Hwankyungkyoyuk
    • /
    • v.13 no.2
    • /
    • pp.74-90
    • /
    • 2000
  • The environmental quality in Korea was significantly deteriorated though the past economic development period. Even though the government has spent huge sum of resources on the policies and projects to improve the environmental quality, it is much removed from what the people hope for. To solve the environmental problems effectively, pollutants generated at source should be kept as minimum as possible, and possible, and pollutants from source be controlled before leaving the sources, and most of all, environmental strategies and systems be established and enforced properly. So, it is not too much to say that nation's environmental quality is entirely dependent on the education and training of the environmental managers such as environmental employees for air, water, and noise discharge facilities, technicians at environmental plants, and environmental officers of central and local governments. Regimes for the improvement of the education and training for environmental managers are suggested into four categories-educational institute, circular of the study, training contents and trainees. Referring to the improvement of integrated institute, and to improvement on educational institute, it is necessary to investigate the feasibility of integrated institute, and to recommend the inclusion of the local colleges and universities, and environmental societies. For the improvement on training courses, it is necessary that the non-obligatory course be expanded, and the courses be developed in such a way to meet the needs from the field. As for the improvement on training contents. It is suggested that the practical training on size be strengthened, and also full time environmental specialist and integrated committee be required to develop the effective circular and selection of proper lectures. Finally, environmental education for high ranked officers of autonomies, and international courses for developing countries are suggested.

  • PDF

Characterization of Surface Morphology and Light Scattering of Transparent Conducting ZnO:Al Films as Front Electrode for Silicon Thin Film Solar Cells (실리콘 박막 태양전지 전면 전극용 ZnO : Al 투명전도막의 표면형상 및 산란광 특성)

  • Kim, Young-Jin;Cho, Jun-Sik;Lee, Jeong-Chul;Wang, Jin-Suk;Song, Jin-Soo;Yoon, Kyung-Hoon
    • Korean Journal of Materials Research
    • /
    • v.19 no.5
    • /
    • pp.245-252
    • /
    • 2009
  • Changes in the surface morphology and light scattering of textured Al doped ZnO thin films on glass substrates prepared by rf magnetron sputtering were investigated. As-deposited ZnO:Al films show a high transmittance of above 80% in the visible range and a low electrical resistivity of $4.5{\times}10^{-4}{\Omega}{\cdot}cm$. The surface morphology of textured ZnO:Al films are closely dependent on the deposition parameters of heater temperature, working pressure, and etching time in the etching process. The optimized surface morphology with a crater shape is obtained at a heater temperature of $350^{\circ}C$, working pressure of 0.5 mtorr, and etching time of 45 seconds. The optical properties of light transmittance, haze, and angular distribution function (ADF) are significantly affected by the resulting surface morphologies of textured films. The film surfaces, having uniformly size-distributed craters, represent good light scattering properties of high haze and ADF values. Compared with commercial Asahi U ($SnO_2$:F) substrates, the suitability of textured ZnO:Al films as front electrode material for amorphous silicon thin film solar cells is also estimated with respect to electrical and optical properties.

Adsorption Behavior of Monosubstituted-Halophenols by Amberlite XAD Resins (Amberlite XAD 수지에 대한 일치환 할로 페놀들의 흡착거동에 관한 연구)

  • Lee, Taek Hyeok;Lee, Dae Un
    • Journal of the Korean Chemical Society
    • /
    • v.34 no.3
    • /
    • pp.267-279
    • /
    • 1990
  • The adsorption mechanisms of phenols on XAD-2 and XAD-7 resins were studied by using the distribution coefficient(log Kd) measured in the optimum adsorption conditions. It was observed that the Langmuir adsorption isotherm, indicating a molecular size-dependent adsorption, was appropriate for characterizing the adsorption behaviors of phenols on XAD-2 and XAD-7 resins. The adsorption energies of phenols on XAD resins were calculated by Lennard-Jones potential equation. In the calculation of the adsorption energy, the molecular radii and dipole moments of the resins and phenols were calculated by their van der Waals volumes and Debye equation, respectively. The stacking factor (F) were determined from the radio of the equilibrium distance to the stacking distance of molecules. In order to explain the adsorption energy calculated from the stacking factor it was compared with the adsorption enthalpy for each of phenols which was experimentally determined by batch adsorption shake method. It was observed that the adsorption enthalpy of phenolate ions on the XAD resins was likely to be more seriously affected by dispersion interaction than by a dipole or a charge interaction.

  • PDF

A quantitative modeling approach to estimate the risks posed by the smuggled animal products contaminated with Foot-and-Mouth Disease (FMD) virus

  • Hong, Ki-Ok;Lee, Gil-Hong;Pak, Son-Il
    • Korean Journal of Veterinary Research
    • /
    • v.45 no.2
    • /
    • pp.223-231
    • /
    • 2005
  • A quantitative risk assessment tool was used to provide estimates of the probability that foot-and-mouth (FMD) virus-contaminated, smuggled animal products are fed to susceptible swine in Korea. Sensitivity analyses were conducted to attempt to distinguish between parameter uncertainty and variability, using different assumptions on the effect of cooking at home, the effect of the fresh meat, and the effect of heat treatment at garbage processing facility. The median risk estimate was about 20.1% with a mean value of 27.4%. In a scenario regarding all beef and pork were considered as fresh meat the estimated median risk was 3.4%. The risk was greatly dependent on the survival parameters of the FMD virus during the cooking or heat treatment at garbage processing facility. Uncertainty about the proportion of garbage that is likely contaminated with FMD had a major positive influence on the risk, whereas conversion rate representing the size of a load had a major negative effect. This model was very useful in assessing the risk explored. However, the model also requires enhancements, such as the availability of more accurate data to verify the various assumptions considered such as FMD prevalence in a specific country, proportion of garbage which is recycled as feed, proportion of food discarded as garbage. Other factors including the effect of selection of animals for slaughter, ante- and post-mortem inspection, the domestic distribution of the smuggled products, and susceptible animals other than pigs, are need to be taken into account in the future model development.

Effects of Heat Therapy according to the Application Time among the Elderly with Osteoarthritis (퇴행성관절염 노인을 위한 온요법의 적용시기에 따른 효과)

  • Kim, Su-Hyeun;Kim, Myung-Hee;Kim, Ju-Sung
    • Journal of muscle and joint health
    • /
    • v.10 no.1
    • /
    • pp.7-18
    • /
    • 2003
  • This study was to investigate the effects(pain, discomfort, and range of motion) of heat therapy according to the application time among the elderly with osteoarthritis. Study participants were 27 elderly women, who were diagnosed as osteoarthritis, suffered from it for more than 6 months, and who were staying at a nursing home in Busan. The independent variable was heat therapy, which was applied for 20minutes, one time per week according to 3 timetable(before waking up, while in daily living, before going to bed) over 6 weeks. The dependent variables were pain and discomfort measured by 20 points visual analog scales, and range of extension and flexion measured by goniometery. The data were analyzed by descriptive statistics and repeated measures ANOVA. The results were as follows ; 1) There were significant differences for pain(F=9.77 p=.0001), discomfort(F=8.07 p=.001), range of extension(F=3.05 p=.05), and flexion(F=9.67 p=.0001) among heat therapy application times. 2) There were significant differences for pain(F=58.18 p=.0001), discomfort(F=63.68 p=.0001), range of extension(F=11.59 p=.001), and flexion(F=17.59 p=.0001) between before and after applying heat therapy. 3) There were not statistically significant differences for pain(F=.64 p=.531), discomfort(F=.18 p=.836), range of extension(F=1.33 p=.270), and fiexion(F=.26 p=.773) between before and after applying heat therapy according to the heat therapy application times. In conclusion, heat therapy was effective in reducing pain and discomfort, and in improving ROM for the elderly with osteoarthritis, but the effect of it was not different according to the time of application. We recommended further studies with larger sample size, longer and more repeatedly applied to investigate the effect of heat therapy according to the time of application.

  • PDF

How Factors Inside University Can Influence Technology-Based Spin-offs? (대학 내부 특성이 기술기반 스핀오프에 미치는 영향 연구)

  • Kim, HanJun;Kim, YoungJun
    • Journal of Korea Technology Innovation Society
    • /
    • v.21 no.2
    • /
    • pp.560-586
    • /
    • 2018
  • This study empirically analyzes how factors inside university influence the creation of technology-based spin-offs, employing unique data sets. We posit a two-year time lag between the explanatory variables and the dependent one using total 270 university data sets for 5 years in Korea. The results show that universities with experienced technology licensing offices (TLO), those with R&D personnel size, those in possession of incubation policies or business incubators have an edge in creating technology-based spin-offs. The findings provide policy implications. By making more informed decisions on fostering technology-based spin-offs at universities, policymakers can promote the creation of new industries and lead them to create jobs in line with the national economic growth policy.

Characterization of a Glutamate Decarboxylase (GAD) from Enterococcus avium M5 Isolated from Jeotgal, a Korean Fermented Seafood

  • Lee, Kang Wook;Shim, Jae Min;Yao, Zhuang;Kim, Jeong A;Kim, Hyun-Jin;Kim, Jeong Hwan
    • Journal of Microbiology and Biotechnology
    • /
    • v.27 no.7
    • /
    • pp.1216-1222
    • /
    • 2017
  • To develop starters for the production of functional foods or materials, lactic acid bacteria producing ${\gamma}-aminobutyric$ acid (GABA) were screened from jeotgals, Korean fermented seafoods. One isolate producing a high amount of GABA from monosodium $\text\tiny{L}$-glutamate (MSG) was identified as Enterococcus avium by 16S rRNA gene sequencing. E. avium M5 produced $18.47{\pm}1.26mg/ml$ GABA when incubated for 48 h at $37^{\circ}C$ in MRS broth with MSG (3% (w/v)). A gadB gene encoding glutamate decarboxylase (GAD) was cloned and overexpressed in E. coli BL21 (DE3) using the pET26b (+) expression vector. Recombinant GAD was purified through a Ni-NTA column and the size was estimated to be 53 kDa by SDS-PAGE. Maximum GAD activity was observed at pH 4.5 and $55^{\circ}C$and the activity was dependent on pyridoxal 5'-phosphate. The $K_m$ and $V_{max}$ values of GAD were $3.26{\pm}0.21mM$ and $0.0120{\pm}0.0001mM/min$, respectively, when MSG was used as a substrate. Enterococcus avium M5 secretes a lot of GABA when grown on MRS with MSG, and the strain is useful for the production of fermented foods containing a high amount of GABA.

Solidification/stabilization of simulated cadmium-contaminated wastes with magnesium potassium phosphate cement

  • Su, Ying;Yang, Jianming;Liu, Debin;Zhen, Shucong;Lin, Naixi;Zhou, Yongxin
    • Environmental Engineering Research
    • /
    • v.21 no.1
    • /
    • pp.15-21
    • /
    • 2016
  • Magnesium potassium phosphate cement (MKPC) is an effective agent for solidification/stabilization (S/S) technology. To further explore the mechanism of the S/S by MKPC, two kinds of Cd including $Cd(NO_3)_2$ solution (L-Cd) and municipal solid waste incineration fly ash (MSWI FA) adsorbed Cd (S-Cd), were used to compare the effects of the form of heavy metal on S/S. The results showed that all the MKPC pastes had a high unconfined compressive strength (UCS) above 11 MPa. For L-Cd pastes, Cd leaching concentration increased with the increase of Cd content, and decreased with the increase of curing time. With the percentage of MSWI FA below 20%, S-Cd pastes exhibited similar Cd leaching concentrations as those of L-Cd pastes, while when the content of MSWI FA come up to 30%, the Cd leaching concentration increased significantly. To meet the standard GB5085.3-2007, the highest addition of S-Cd was 30% MSWI FA (6% Cd contained), with the Cd leaching concentration of 0.817 mg/L. The S/S of L-Cd is mainly due to chemical fixation, and the hydration compound of Cd was $NaCdPO_4$, while the S/S of S-Cd is due to physical encapsulation, which is dependent on the pore/crack size and porosity of the MKPC pastes.

AN EXPERIMENTAL STUDY ON PHYSICAL PROPERTIES OF VARIOUS POSTERIOR RESTORATIVE COMPOSITE RESINS (수종(數種) 구치부(臼齒部) 충전용(充塡用) 복합(複合)레진의 물리적(物理的) 성질(性質)에 관(關)한 실험적(實驗的) 연구(硏究))

  • Park, Sun-Jae;Park, Sang-Jin;Min, Byang-Soon;Choi, Ho-Young
    • Restorative Dentistry and Endodontics
    • /
    • v.12 no.1
    • /
    • pp.7-24
    • /
    • 1986
  • The purpose of this study was to observe the compressive strength, compressive fatigue strength, surface hardness, water sorption and solubility of eight different posterior restorative composite resins. Eight composite resins were tested for their strength of the compressive and compressive fatigue with prepared two different types of specimens (I and T-type) using a Instron universal testing machine (model No. 1332). The hardness was measured with a Knoop hardness tester (MVH-2, Tokyo) for each cylindrical specimen, 7mm in diameter and 5mm thick. The water sorption and solubility were evaluated with the prepared composite resin disks, 20mm in diameter and 1mm thick. The results were as follows: 1. The compressive strength, compressive fatigue strength and hardness were noticed to be Increased by increasing the volume content of filler. 2. The compressive strength was appeared to be independent on the type of specimen, but the compressive fatigue strength was found to be greatly influenced by the type of specimens. 3. The composite resins having higher compressive strength had also higher compressive fatigue limits. 4. The compressive fatigue limits at $10^5$ stress cycles were about 50-80% of the compressive strength and were showen to be dependent on the materials and type of specimens. 5. The larger the filler particle size was, the lower was the water sorption. And the water sorption of BIS-GMA resin was higher than that of urethane resin. 6. The visible light-cured composite resin had a higher value of solubility than the chemically- cured composite resin. And the solubility tended to decrease by increasing the volume content of filler.

  • PDF