• Title/Summary/Keyword: single grain

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Fast Abnormal Grain Growth Behavior and Electric Properties of Lead-Free Piezoelectric (K,Na)NbO3-Ba(Cu,Nb)O3 Grains through Transient Liquid Phase (과 액상 형성에 의한 비납계 압전 (Na,K)NbO3-Ba(Cu,Nb)O3 결정립의 비정상 성장 거동 및 전기적 특성)

  • Lim, Ji-Ho;Lee, Ju-Seung;Lee, SeungHee;Jung, Han-Bo;Park, Chun-kil;Ahn, Cheol-Woo;Yoo, Il-Ryeol;Cho, Kyung-Hoon;Jeong, Dae-Yong
    • Korean Journal of Materials Research
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    • v.29 no.4
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    • pp.205-210
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    • 2019
  • $Pb(Zr,Ti)O_3$ (PZT) is used for the various piezoelectric devices owing to its high piezoelectric properties. However, lead (Pb), which is contained in PZT, causes various environment contaminations. $(K,Na)NbO_3$ (NKN) is the most well-known candidate for a lead-free composition to replace PZT. A single crystal has excellent piezoelectric-properties and its properties can be changed by changing the orientation direction. It is hard to fabricate a NKN single crystal due to the sodium and potassium. Thus, $(Na,K)NbO_3-Ba(Cu,Nb)O_3$ (NKN-BCuN) is chosen to fabricate the single crystal with relative ease. NKN-BCuN pellets consist of two parts, yellow single crystals and gray poly-crystals that contain copper. The area that has a large amount of copper particles may melt at low temperature but not the other areas. The liquid phase may be responsible for the abnormal grain growth in NKN-BCuN ceramics. The dielectric constant and tan ${\delta}$ are measured to be 684 and 0.036 at 1 kHz in NKN-BCuN, respectively. The coercive field and remnant polarization are 14 kV/cm and $20{\mu}C/cm^2$.

Agronomic Characteristics of Rice Recombinant Inbred Lines (RILs) Developed from a Cross of Nonganbyeo and BG 279

  • Lee, Jeom-Ho;Kim, Nam-Soo;Cho, Youn-Sang;Song, Moon-Tae;Hwang, Hung-Goo;Moon, Huhn-Pal
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.44 no.1
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    • pp.86-94
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    • 1999
  • A set of rice recombinant inbred lines was developed from a cross between a Tongil type variety, Nonganbyeo, and an indica variety, BG276, by the single seed descent method. The number of the lines in the population was 272. All the agronomic characters studied except ADV (alkali-digestion value) showed continuous variation among the RILs, implying that their inheritance mode should be quantitative. The patterns of the variation in the RILs were either normal or skewed distribution. ADVs of RILs were segregated into two groups with 1:1 ratio, indicating that ADVs in this KIL population might be controlled by one major gene. Transgressive variations were also observed in all characters. Heritability values of the characters varied from 0.488 in brown/rough rice ratio to 0.895 in alkali-digestion value. In the analysis of genotypic and phenotypic correlations, the character of yield was positively correlated with 8 different agronomic characters. The number of panicles per hill was negatively correlated with culm length, panicle length, and number of spikelets per panicle. Grain length was positively correlated with grain width, grain thickness, grain length/width ratio, white belly, ADV, and amylose. However, grain length/width ratio was negatively correlated with grain width. White core was also negatively correlated with white belly and ADV.

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Sintering Behavior of Al2O3-15v/o ZrO2(+3m/o Y2O3) Ceramics Prepared by Precipitation Method (침전법으로 제조한 Al2O3-15v/o ZrO2(+3m/o Y2O3)계 세라믹스의 소결거동)

  • 홍기곤;이홍림
    • Journal of the Korean Ceramic Society
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    • v.26 no.3
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    • pp.423-437
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    • 1989
  • Al2O3/ZrO2 composites were prepared by precipitation method using Al2(SO4)3.18H2O, ZrOCl2.8H2O and YCl3.6H2O as starting materials and NH4OH as a precipitation agent. Al2O3/ZrO2 composites(series A) were prepared by mixing Al2O3 powder obtained by single precipitation method with ZrO2(+3m/o Y2O3) powder obtained by co-predipitation method. Al2O3/ZrO2 composites (series B) were prepared by co-precipitation method using the three starting materials. In all cases, the composition was controlled as Al2O3-15v/o ZrO2(+3m/o Y2O3). The composites of series A showed higher final relative densities than those of series B and tetagonal ZrO2 in all cases was retained to about 95% at room temperature. ZrO2 particles were coalesced more rapidly in grain boundary of Al2O3 than within Al2O3 grain. ZrO2 particles were located at 3-and 4-grain junction of Al2O3 and limited the grain growth of Al2O3. It was observed that MgO contributed to densification of Al2O3 but limited grain growth of Al2O3 by MgO was not remarkable. In all Al2O3/ZrO2 composites, exaggerated grain growth of Al2O3 was not observed and Al2O3/ZrO2 composites were found to have homogeneous microstructures.

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Reorientation of Colloidal Crystalline Domains by a Thinning Meniscus

  • Im, Sang-Hyuk;Park, O-Ok
    • Macromolecular Research
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    • v.12 no.2
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    • pp.189-194
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    • 2004
  • When water is evaporated quickly from a water-based colloidal suspension, colloidal particles protrude from the water surface, distorting it and generating lateral capillary forces between the colloidal particles. The protruded colloidal particles are then assembled into ordered colloidal crystalline domains that float on the water surface on account of their having a lower effective density than water. These colloidal crystal domains then assemble together by lateral capillary force and convective flow; the generated colloidal crystal has grain boundaries. The single domain size of the colloidal crystal could be controlled, to some extent, by changing the rate of water evaporation, but it seems very difficult to fabricate a single crystal over a large area of the water's surface without reorienting each colloidal crystal domain. To reorient such colloidal crystal domains, a glass plate was dipped into the colloidal suspension at a tilted angle because the meniscus (airwaterglass plate interface) is pinned and thinned by further water evaporation. The thinning meniscus generated a shear force and reoriented the colloidal crystalline domains into a single domain.

A Fabrication of YBCO Single Crystal using Infiltration and Growth Method (용융침투성장법을 이용한 YBCO 단결정 제조)

  • Han, Sang-Chul;Jeong, Neyon-Ho;Han, Young-Hee;Sung, Tae-Hyun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.6
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    • pp.550-554
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    • 2007
  • Large and single-grain Y-Ba-Cu-O(YBCO) bulk superconductors have been fabricated by using a seeded infiltration and growth method. $Y_2BaCuO_5$(Y211) precursor pellets and $YBa_2Cu_3O_x$(Y123) liquid source pellets were prepared using commercial powder and were processed by infiltration and growth method to achieve low pore and high trapped field property. The superconductor properties of the single crystal are measured and analyzed in relation with the density and size of the Y211 particle in the Y123 matrix. An optimum processing condition is suggested based on the analyzed results.