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Adsorption and Desorption Dynamics of Ethane and Ethylene in Displacement Desorption Process using Faujasite Zeolite (제올라이트(faujasite)를 이용한 치환탈착공정에서 에탄, 에틸렌의 흡, 탈착 동특성)

  • Lee, Ji-In;Park, Jong-Ho;Beum, Hee-Tae;Yi, Kwang-Bok;Ko, Chang-Hyun;Park, Sung Youl;Lee, Yong-taek;Kim, Jong-Nam
    • Korean Chemical Engineering Research
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    • v.48 no.6
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    • pp.768-775
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    • 2010
  • Adsorption dynamics of ethane/ethylene mixture gas and desorption dynamics during the displacement desorption with propane as a desorbent in the column filled with faujasite adsorbent were investigated experimentally and theoretically. The simulation that adopted heat and mass balance and an ideal adsorbed solution theory (IAST) for the multicomponent adsorption equilibrium well predicted the experimental breakthrough curves of the adsorption and desorption. At the adsorption breakthrough experiments, roll-ups of ethane increased as the adsorption pressure increased and the adsorption temperature decreased. During the displacement desorption with propane in the column saturated with ethane/ethylene mixture gas, almost 100% of ethylene was obtained for a certain time interval. The adsorption strength of the desorbent greatly affected the adsorption and re-adsorption dynamics of ethylene. The re-adsorption capacity for ethylene has been greatly reduced when iso-propane, which is stronger desorbent than propane, was used as desorbent. It was found from the simulation that the performance of the displacement desorption process would be superior when the ratio of ${(q_s{\times}b)}_{C_2H_4}/{(q_s{\times}b)}_{C_3H_s}$ was 0.83, that is, the adsorption strengths of ethylene and the desorbent were similar.

A Study on Emulsion Stability of O/W and W/S Emulsion according to HLB of Emulsifier (유화제의 HLB에 따른 O/W 및 W/S 에멀젼의 유화 안정성에 관한 연구)

  • Yeon, Jae Young;Shin, Bo Ram;Kim, Ta Gon;Seo, Jeong Min;Lee, Cheong Hee;Lee, Sang Gil;Pyo, Hyeong Bae
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.40 no.3
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    • pp.227-236
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    • 2014
  • In this study, O/W and W/S emulsions were prepared by combining oils having different required hydrophilic lipophilic balance (HLB) values under the diverse conditions of HLB values composed of a hydrophilic surfactant and a lipophilic surfactant and their stability was investigated. Results showed that the higher the viscosity of O/W emulsions was as the lower the HLB value of emulsifier and emulsion particle showed a tendency to be a smaller and compact and stabler in centrifugal filtration. W/S emulsions also showed a similar tendency to be a smaller and compact as HLB values of emulsifier was higher and stabler in centrifugal filtration. However, the viscosity of W/S emulsion tended to get lower in HLB conditions of all emulsifiers as the time passed. This indicated that the emulsions had an unstable feature in long-term stability. In conclusion, the results showed opposite to the known theory that O/W emulsion is proper to be applied by nonionic surfactant with a high HLB value and W/S emulsion to be applied by nonionic surfactant with a low HLB value and provide useful information for the cosmetics research and related areas.

Comparison of Yanluozi's and Huatuo's visceral figures (『연라자내경도(煙蘿子內境圖)』와 『화타선생내조도(華佗先生內照圖)』의 비교)

  • Koo, In-Mo;Kim, Hag-Dong;Kim, Ki-Wook;Lee, Byung-Wook
    • Journal of Korean Medical classics
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    • v.28 no.4
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    • pp.41-56
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    • 2015
  • Objectives : This research is aimed to compare the visceral figures published during the Song Dynasty, and to reveal the differences between anatomical and physiological knowledge in the presence of Taoist theoretical background and in its absence. It is also aimed to discuss the theoretical differences among existing medicines. Methods : First, we will find the commonalities and the differences in the drawings describing the internal organs of a human body in the two publications, and study what made such commonalities and differences and how they affected medical theories. Secondly, we will analyze and update the internal organ data specified in the two publications as it relates to the five viscera and six bowls. Finally, we will analyze the commonalities and the differences, and study the background and the significance of medical theories. Results & Conclusions : 1. The positions of the liver and the spleen in the drawing of the Yanluozi's and Huatuo's visceral figures are inverted in the drawing of the Huatuo's visceral figures. The positions of other internal organs are similar. 2. The section of the five viscera in the Yanluozi's and Huatuo's visceral figures describes the Taoist gods necessary to build up discipline by the means of meditation. 3. In the Zhutidian's visceral theory, a belly button is recognized as a very important organ for the activity of life. 4. In the Huatuo's visceral figures, the 'Zangzhen' generated from foods is described as the energy source for the vitality of the five viscera. 5. The Huatuo's visceral figures mentioned the functionality of a gall bladder and an Tripple Energizer, which was not mentioned in the Yanluozi's and Huatuo's visceral figures. 6. Both the "Yanluozi's and Huatuo's visceral figures" and the "Huatuo's visceral figures" specify that the moisture filtered through small intestines turns into urine.

Validation of Net Radiation Measured from Fluxtower Based on Eddy Covariance Method: Case Study in Seolmacheon and Cheongmicheon Watersheds (에디공분산 방법 기반의 플럭스 타워 순 복사에너지 검증: 설마천, 청미천 유역)

  • Byun, Kyuhyun;Shin, Jiyae;Lee, Yeon-Kil;Choi, Minha
    • Journal of Korea Water Resources Association
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    • v.46 no.2
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    • pp.111-122
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    • 2013
  • The necessity of clear understanding of water and energy cycles has been attracted recently due to the climate change. The micrometeorological flux tower networks play a role of cornerstone of the hydrological and ecological analyses. Although the eddy covariance techniques used for flux tower have been proven to be applicable for estimation of latent heat flux, the raw data are often underestimated and needs to be corrected. Among several methods, the Bowen ratio is recognized as the most useful method in which the net radiation and other flux data (Ground heat flux, Sensible heat flux) are used and needed to be validated. In this study, in order to validate the net radiation from flux tower in Seolmacheon and Cheongmicheon watersheds, we compare it with two version of calculated net radiation: (1) FAO 56 Daily net radiation proposed by Allen et al. (1998). (2) Instantaneous net radiation proposed by Bastiaanssen (1995). The results showed that the net radiation from the flux data had similar tendency with those calculated based on physical theory. In addition, after it was applied to Bowen ratio method, the corrected latent heat flux was considerably improved with making the energy balance much more closed.

Analysis of Airborne LiDAR-Based Debris Flow Erosion and Deposit Model (항공LiDAR 자료를 이용한 토석류 침식 및 퇴적모델 분석)

  • Won, Sang Yeon;Kim, Gi Hong
    • Journal of Korean Society for Geospatial Information Science
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    • v.24 no.3
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    • pp.59-66
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    • 2016
  • The 2011 debris flow in Mt. Umyeonsan in Seoul, South Korea caused significant damages to the surrounding urban area, unlike other similar incidents reported to have occurred in the past in the country's mountainous regions. Accordingly, landslides and debris flows cause damage in various surroundings, regardless of mountainous area and urban area, at a great speed and with enormous impact. Hence, many researchers attempted to forecast the extent of impact of debris flows to help minimize the damage. The most fundamental part in forecasting the impact extent of debris flow is to understand the debris flow behavior and sedimentation mechanism in complex three-dimensional topography. To understand sedimentation mechanism, in particular, it is necessary to calculate the amount of energy and erosion according to debris flow behavior. The previously developed debris flow models, however, are limited in their ability to calculate the erosion amount of debris flow. This study calculated the extent of damage caused by a massive debris flow that occurred in 2011 in Seoul's urban area adjacent to Mt. Umyeonsan by using DEM, created from aerial photography and airborne LiDAR data, for both before and after the damage; and developed and compared a debris flow behavioral analysis model that can assess the amount of erosion based on energy theory. In addition, simulations using the existing debris flow model (RWM, Debris 2D) and a comprehensive comparison of debris flow-stricken areas were performed in the same study area.

Internal Growth Type Character and Popular Sympathy of Heroic Narrative (영웅서사의 내적 성장형 캐릭터와 대중적 공감형성 - 마블과 DC의 시네마틱 유니버스를 기반으로 -)

  • Jeon, Yeongdon
    • The Journal of the Korea Contents Association
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    • v.20 no.1
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    • pp.364-377
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    • 2020
  • Although it is never easy to create charming characters that people can relate to, well-formed characters have the power to enable the audience to not only empathize but identify with them. Thus, there is a need for us to examine the parts that make up a well-formed character. According to empathy theory, when the character in the play has a human face that is not different from me, I can feel familiarity and human empathy. Rather than perfection without loopholes, I relate to and sympathize with someone who looks similar to me, with many mistakes and some lack. This study aims to examine the attractiveness of characters in narrative dramas in terms of defects and internal growth. To do this, we tried to compare the setting, evaluation, and performance of characters based on the movie worldviews of two famous brands (DC and Marble), which can be compared directly. I looked at it. In conclusion, the work of hero character but human character setting based on internal growth not only has high evaluation and public evaluation, but also high sales, and thus direct and indirect correlation with the public favorability is significant.

Measurement of GPR Direct Wave Velocity by f-k Analysis and Determination of Dielectric Property by Dispersive Guided Wave (f-k 분석에 의한 레이다파 속도 측정 및 레이다파의 분산성 가이드 현상을 이용한 지하 물성 계산)

  • Yi, Myeong-Jong;Endres, Anthony L.;Kim, Jung-Ho
    • Geophysics and Geophysical Exploration
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    • v.9 no.4
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    • pp.304-315
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    • 2006
  • We have examined the applicability of f-k analysis to the GPR direct wave measurement for water content to characterize vadose zone condition. When the vadose zone consists of a dry surface layer over wet substratum, we obtained f-k spectra where most of the energy is bounded by the air and dry soil velocities. In this case, dry soil velocity was successfully estimated by using high frequency data. On the other hands, when wet soil overlies dry substratum, the f-k spectra show a contrasting response where most of the energy travels with the velocity bounded by dry and wet soil velocities. In this case, the radar waves are trapped and guided within wet soil layer, exhibiting velocity dispersion. By adopting modal propagation theory, we could formulae a simple inversion code to find two layer's dielectric constants as well as layer thickness. By inverting the velocity dispersion curve obtained from f-k spectra of synthetic modeling data, we could obtain good estimates of dielectric constants of each layer as well as first layer thickness. Moreover, we could obtain more accurate results by including the higher mode data. We expect this method will be useful to get the quantitative property of real subsurface when the field condition is similar.

Shear Behavior of Reinforced Concrete Beams according to Replacement Ratio of Recycled Coarse Aggregate (순환 굵은골재 치환율에 따른 철근콘크리트 보의 전단거동)

  • Kim, Sang-Woo;Jeong, Chan-Yu;Jung, Chang-Kyo;Kim, Kil-Hee
    • Journal of the Korea Concrete Institute
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    • v.24 no.2
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    • pp.157-164
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    • 2012
  • This study evaluates the shear performance of reinforced concrete beams with recycled coarse aggregates. A total of six specimens with various replacement ratios of recycled coarse aggregates (0%, 50%, and 100%) and different amount of shear reinforcement were cast and tested in this study. A finite element analysis was performed to predict the shear behavior of the specimens with natural or recycled coarse aggregates. The FE analysis was performed using a two-dimensional nonlinear FE analysis program based on the disturbed stress field model (DSFM), which is an extension of the modified compression field theory (MCFT). Experimental results showed that the specimens with 50% and 100% replacement ratios of recycled coarse aggregates had the similar shear strength compared to the specimen with natural aggregates, regardless of the replacement ratios of recycled coarse aggregates and the amount of the shear reinforcement. Furthermore, the comparison between experimental and analytical results showed that the proposed numerical modeling methods and the analytical model, DSFM, can be successfully used to predict the shear behavior of reinforced concrete beams with recycled coarse aggregates.

Sleep-Wake Cycles in Man (인간의 수면-각성 주기)

  • Kim, Leen
    • Sleep Medicine and Psychophysiology
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    • v.4 no.2
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    • pp.147-155
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    • 1997
  • To assess the reliability of chronobiological models of sleep/wake regulation, it is necerssary that the models predict the data which has been studied in sleep research, and they should be generalized across all ages. To date, many adult human data on such models have accumulated, yet it is evident that a comprehensive theory of the biorhythmic aspects of sleep/wake states has not established. Circadian rhythms such as the time going to bed, sleep onset, slow wave sleep pressure, periodicity of REM sleep, daytime performance, and early evening alertness are resumed everyday. Even in adult humans, sleep is inherently polyphasic. In both the disentrained and entrained states, naps when allowed tend to recur in a temporally lawful manner. The monophasic sleep pattern of most industrial societies therefore appears to be purely of social origin. The endogenous biorhythmic nature of circasemidian sleep tendency is supported by the ubiquity of the phenomenon across all ages. The NREM/REM sleep cycle within sleep with its inherent physiological, endocrine, and neurochemical fluctuations represents the best-documented ultradian sleep rhythms. Also, a daytime ultradian variation in sleepiness with a periodicity similar to nocturnal NREM/REM cycle(BRAC hypothesis) is suggested. This review article provides a brief synoptic review of the evidences for circadian, circasemidian, and ultradian sleep/wake rhythms, and then the authour will suggest the issues which expedite fuller modeling of sleep/wake system, to be further discussed.

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A Study on the Behavior Characteristics of Large Deep Foundations (대형 깊은 기초의 지지거동 특성에 관한 연구)

  • Park, Choon-Sik;Jung, Kwang-Min
    • Journal of the Korean Geosynthetics Society
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    • v.19 no.1
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    • pp.83-91
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    • 2020
  • In this study, the characteristics of support behavior according to the change of ground condition of the cast-in-place pile and the large Caisson foundation, which are increasingly used as foundations of large structures and bridges. the allowable bearing capacity calculated using the yield load analysis method was analyzed to calculate similar allowable bearing capacity for each method. In addition, the allowable bearing capacity calculated by the ultimate load analysis method was found to have a large difference in bearing capacity for each method. Through this point, it can be usefully used as an empirical formula for evaluating the settlement characteristics of piles in future design and construction. In addition, as a result of examining the ground force distribution during sedimentation of large caissons, the section of the weathered rock layer showed almost constant ground force distribution as ground forces decreased after yield occurred at the base corner. And in the bed rock layer section, the foundation's center was transformed into a ground force in the form of a convex downward due to an increase in the ground resistance of the central part. Using these results, the theory previously presented by Fang (1991) and Kőgler (1936) was proved.