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Thermal Properties of Diglycidyl Ether of Terephthalylidene-bis-(4-amino-3-methylphenol) (Diglycidyl ether of terephthalylidene-bis-(4-amino-3-methylphenol)의 열적 성질에 대한 연구)

  • Hyun, Ha-Neul;Choi, Ji-Woo;Cho, Seung-Hyun
    • Composites Research
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    • v.35 no.2
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    • pp.53-60
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    • 2022
  • This study uses Diglycidyl ether of terephthalylidene-bis-(4-amino-3-methylphenol) (DGETAM), an amine hardener 4,4'-diaminodiphenylethane (DDE) and cationic catalyst N-benzylpyrazinium hexafluoroantimonate (BPH) to make epoxy film. For analysis, 1H_NMR and FT-IR were used to verify proper synthesis, and the liquid crystallinity of DGETAM was checked using Differntial Scanning Calorimetry and Polarized Optical Microscopy. Thermal conductivity of the sample was measured using Laser Flash Apparatus. Thermal stability as well as thermal conductivity is important when used as a packaging material. Activated energy is the energy needed to generate a response, which can be used to estimate the energy required to maintain physical properties. It was obtained using the Arrhenius equation based on the data measured by isothermal decomposition using Thermogravimetric Analysis. Measurement of the thermal conductivity of epoxy films showed higher thermal conductivity when DDE was used, and it was found that thermal conductivity had an effect on thermal stability, given that it represented an activation energy similar to a film with BPH upon 5% decomposition.

Analysis of Radiation Fusion Shielding Performance of Ytterbium Oxide, a Radiation Impermeable Substance (방사선 불투과성 물질 산화이테르븀(Ytterbium oxide)의 방사선 융합 차폐성능 분석)

  • Kim, Seon-Chil
    • Journal of the Korea Convergence Society
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    • v.12 no.4
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    • pp.87-94
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    • 2021
  • While the shielding substances of radiation shields in medical institutions are beginning to be replaced by environmentally friendly materials, radiation protection according to the shielding properties of environmentally friendly substances is becoming an important factor rather than the existing lead shielding properties. Tungsten and barium sulfate are representative shielding materials similar to lead, and are made in sheets or fiber form with eco-friendly materials. Ytterbium is an impermeable material used as a fluorine compound in the dental radiation field. This study aims to evaluate the shielding performance in the x-ray shielding area by comparing the shielding properties of ytterbium by energy band and that of existing eco-friendly materials. When three types of shielding sheets were fabricated and tested under the same process conditions, the shielding performance of the medical radiation area was about 5 % difference from tungsten. Furthermore, shielding performance was superior to barium sulfate. In the cross-sectional structure of the shielding sheet, there was a disadvantage that the arrangement of particles was not uniform. Ytterbium oxide showed sufficient potential as a medical radiation shielding material, and it is thought that it can improve the shielding performance by controlling the particle arrangement structure and particle size.

A Study on the Effect of Macro-geometry and Gear Quality on Gear Transmission Error (기어 제원 및 기어 가공정밀도가 기어 전달오차에 미치는 영향에 대한 연구)

  • Lee, Ju-Yeon;Moon, Sang-Gon;Moon, Seok-Pyo;Kim, Su-Chul
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.20 no.11
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    • pp.36-42
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    • 2021
  • This study was conducted to analyze the effect of the gear specification and gear quality corresponding to the macro geometry on the gear transmission error. The two pairs of gears with large and small transmission errors were selected for calculation, and two pairs of gears were manufactured with different gear quality. The test gears were manufactured by two different gear specifications with ISO 5 and 8 gear quality, respectively. The transmission error measurement system consists of an input motor, reducer, encoders, gearbox, torque meter, and powder brake. To confirm the repeatability of the test results, repeatability was confirmed by performing three repetitions under all conditions, and the average value was used to compare the transmission error results. The transmission errors of the gears were analyzed and compared with the test results. When the gear quality was high, the transmission error was generally low depending on the load, and the load at which the decreasing transmission error phenomenon was completed was also lower. Even when the design transmission error according to the gear specification was different, the difference of the minimum transmission error was not large. The transmission error at the load larger than the minimum transmission error load increased to a slope similar to the slope of the analysis result.

Analysis of Digital Fashion Design Elements Focusing on Overseas Digital Fashion Brands (해외 디지털 패션브랜드에 나타난 패션디자인 요소의 특징에 관한 연구)

  • Yun Jung Hong
    • Journal of Fashion Business
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    • v.27 no.1
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    • pp.77-109
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    • 2023
  • This study attempted to understand current status of overseas virtual fashion brands and analyze attributes of common digital fashion brands. Based on brand analysis criteria of previous studies, digital fashion brands were analyzed for brand concept, price range, characteristic elements, and attributes. Digital fashion design elements of items, colors, materials, patterns, and effects were analyzed by collecting images of brands' digital fashion design products. Digital fashion brands could be divided into experimental and creative digital fashion brands and digital fashion brands aiming for popular brands. This study introduces a creative fashion collection that experiments sustainability and future value. It shares a new way of self-expression and a playful culture centered on the younger generation. In terms of fashion design elements, fashion items were similar to the existing fashion category, but included other accessories that reflected the lifestyle of Generation Z. Silhouette expressed a minimalistic futuristic image centered on straight silhouettes. Color showed a bold and modern color image through black and color contrast. Unique patterns reflecting the concept of the brand appeared, centering on abstract and geometric patterns. Regarding materials and effects, new elements differentiated from existing fashion design area, showing meaningful characteristics. Digital materials are developed and proposed for sustainability. Materials (such as metal, glass, plastic) and effects (such as weightlessness, flames) expand impossible senses in reality and enable new fashion experiences. This is a case study of digital fashion brands. It is meaningful in that it identifies characteristics and discusses their values and meanings.

Acceleration signal-based haptic texture recognition according to characteristics of object surface material using conformer model (Conformer 모델을 이용한 물체 표면 재료의 특성에 따른 가속도 신호 기반 햅틱 질감 인식)

  • Hyoung-Gook Kim;Dong-Ki Jeong;Jin-Young Kim
    • The Journal of the Acoustical Society of Korea
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    • v.42 no.3
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    • pp.214-220
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    • 2023
  • In this paper, we propose a method to improve texture recognition performance from haptic acceleration signals representing the texture characteristics of object surface materials by using a Conformer model that combines the advantages of a convolutional neural network and a transformer. In the proposed method, three-axis acceleration signals generated by impact sound and vibration are combined into one-dimensional acceleration data while a person contacts the surface of the object materials using a tool such as a stylus , and the logarithmic Mel-spectrogram is extracted from the haptic acceleration signal similar to the audio signal. Then, Conformer is applied to the extracted the logarithmic Mel-spectrogram to learn main local and global frequency features in recognizing the texture of various object materials. Experiments on the Lehrstuhl für Medientechnik (LMT) haptic texture dataset consisting of 60 materials to evaluate the performance of the proposed model showed that the proposed method can effectively recognize the texture of the object surface material better than the existing methods.

Comparison of the metabolic profile of the mycelia and fruiting bodies of artificially cultured Cordyceps militaris

  • Ha, Si Young;Jung, Ji Young;Park, Han Min;Yang, Jae-Kyung
    • Journal of Mushroom
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    • v.20 no.1
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    • pp.13-21
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    • 2022
  • Cordyceps militaris, a well-known traditional Chinese medicine, has multiple health-promoting effects. It is used as a herbal remedy and health food in Asian countries. Cultured mycelia are often used as a substitute for natural C. militaris. In the present study, the mycelia and fruiting bodies of artificially cultured C. militaris were analyzed using a metabolomics approach. The protein and crude fat contents of the mycelia were substantially higher than those of the fruiting bodies. The top three abundant amino acids in the mycelia were proline (3.9 g/100 g), aspartic acid (2.9 g/100 g), and glutamic acid (2.7 g/100 g). The carbohydrate content was similar in the fruiting bodies and mycelia. Analysis revealed that both the fruiting bodies and mycelia are rich in phenolic compounds and exhibit antioxidant activity. Further, six metabolites were significantly different between the mycelia and fruiting bodies. The levels of Ca, glucose, Mg, and Se were higher in the mycelia than in the fruiting bodies. In contrast, mannitol and Zn were more abundant in the fruiting bodies. The current study provides a comprehensive metabolic profile of the mycelia and fruiting bodies of artificially cultured C. militaris. Such an exercise is potentially important for understanding the metabolism of C. militaris and facilitating the use of cultured mycelia as a supplement to C. militaris fruiting bodies in traditional Chinese medicine.

Fabrication of IZO thin films for flexible organic light emitting diodes by RF magnetron sputtering

  • Jun, D.G.;Cho, H.H.;Jo, D.B.;Lee, K.M.
    • Journal of Ceramic Processing Research
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    • v.13 no.spc2
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    • pp.260-264
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    • 2012
  • We have investigated the effect of ambient gases on the structural, electrical, and optical characteristics of IZO thin films intended for use as anode contacts in the organic light emitting diodes (OLED) devices. These IZO thin films were deposited on the PES film by radio frequency (RF) magnetron sputtering under different ambient gases (Ar, Ar + O2, and Ar + H2) at room temperature. In order to investigate the influences of the ambient gases, the flow rate of oxygen and hydrogen in argon has been changed from 0.1 sccm to 0.5 sccm, respectively. All the IZO thin film has an (222) preferential orientation regardless of ambient gases. The electrical resistivity of the IZO film increased with increasing O2 flow rate, whereas the electrical resistivity decreased sharply under an Ar + H2 atmosphere and was nearly similar regardless of the H2 flow rate. The change of electrical resistivity with changes in the ambient gas composition was mainly interpreted in terms of the charge carrier concentration rather than the charge carrier mobility. All the films showed the average transmittance over 85% in the visible range. The OLED device was fabricated with different IZO substrates made with the configuration of IZO/α-NPD/DPVB/Alq3/LiF/Al in order to elucidate the performance of the IZO substrate. The current density and the luminance of OLED devices with IZO thin films deposited in 0.5 sccm H2 ambient gas are the highest amongst all other films.

Efficacy of reciprocating instruments and final irrigant activation protocols on retreatment of mesiobuccal roots of maxillary molars: a micro-CT analysis

  • Lilian Tietz;Renan Diego Furlan;Ricardo Abreu da Rosa;Marco Antonio Hungaro Duarte;Murilo Priori Alcalde;Rodrigo Ricci Vivan;Theodoro Weissheimer;Marcus Vinicius Reis So
    • Restorative Dentistry and Endodontics
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    • v.47 no.1
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    • pp.13.1-13.13
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    • 2022
  • Objectives: This study evaluated the efficacy of 3 reciprocating systems and the effects of 2 instruments for irrigant activation on filling material removal. Materials and Methods: Forty mesiobuccal roots of maxillary molars were prepared up to size 25.06 and obturated. Micro-computed tomography (micro-CT) examination #1 was performed. Teeth were then divided into 4 groups (n = 10), according to the retreatment protocol: (1) manual, (2) Reciproc Blue, (3) WaveOne Gold, and (4) X1 Blue. Micro-CT examinations #2 and #3 were performed after filling removal and repreparation, respectively. Next, all teeth were divided into 2 new groups (n = 20) according to the irrigant activation protocol: XP Clean (XP Clean size 25.02) and Flatsonic (Flatsonic ultrasonic tip). Micro-CT examination #4 was performed after irrigant activation. Statistical analysis was performed with a significance level set at 5%. Results: WaveOne Gold removed a significantly greater amount of filling material than the manual group (p < 0.05). The time to reach the WL was similar for all reciprocating systems (p > 0.05). X1 Blue was faster than the manual group (p < 0.05). Only manual group improved the filling material removal after the repreparation stage (p < 0.05). Both activation protocols significantly improved the filling material removal (p < 0.05), without differences between them (p > 0.05). Conclusions: None of the tested instruments completely removed the filling material. X1 Blue size 25.06 reached the working length in the shortest time. XP Clean and Flatsonic improved the filling material removal.

Synthesis of Ce-doped In2O3 nanoparticles via a microwave-assisted hydrothermal pathway and their application as an ultrafast breath acetone sensor

  • Byeong-Hun Yu;Sung Do Yun;Chan Woong Na;Ji-Wook Yoon
    • Journal of Surface Science and Engineering
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    • v.56 no.6
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    • pp.393-400
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    • 2023
  • Acetone, a metabolite detected from the exhaled breath of people doing a diet, can be used for non-invasive monitoring of diet efficiency. Thus, gas sensors with rapid response and recovery characteristics to acetone need to be developed. Herein, we report ultrafast acetone sensors using Ce-doped In2O3 nanoparticles prepared by the one-pot microwave-assisted hydrothermal method. The pure In2O3 sensor shows a high response and fast response time (τres = 6 s) upon exposure to 2 ppm acetone at 300 ℃, while exhibiting a relatively sluggish recovery speed (τrecov = 1129 s). When 20 wt% Ce is doped, the τrecov of the sensor significantly decreased to 45 s withholding the fast-responding characteristic (τres = 6 s). In addition, the acetone response (resistance ratio, S) of the sensor is as high as 5.8, sufficiently high to detect breath acetone. Moreover, the sensor shows similar acetone sensing characteristics even under a highly humid condition (relative humidity of 60%) in terms of τres (6 s), τrecov (47 s), and S (4.7), demonstrating its high potential in real applications. The excellent acetone sensing characteristics of Ce-doped In2O3 nanoparticles are discussed in terms of their size, composition, phase, and oxygen adsorption on the sensing surface.

Rotordynamic Analysis Using a Direction Frequency Response Function (방향성 주파수 응답 함수를 이용한 회전체 동역학 해석)

  • Donghyun Lee;Byungock Kim;Byungchan Jeon;Hyungsoo Lim
    • Tribology and Lubricants
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    • v.39 no.6
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    • pp.221-227
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    • 2023
  • A rotordynamic system consists of components that undergo rotational motion. These components include shafts, impellers, thrust collars, and components that support rotation, such as bearings and seals. The motion of this type of rotating system can be modeled as two-dimensional motion and, accordingly, the equation of motion for the rotordynamic system can be represented using complex coordinates. The directional frequency response function (dFRF) can be derived from this complex coordinate system and used as an effective analytical tool for rotating machinery. However, the dFRF is not widely used in the field because most previous studies and commercial software are based on real coordinate systems. The objective of the current study is to introduce the dFRF and show that it can be an effective tool in rotordynamic analysis. In this study, the normal frequency response function (nFRF) and dFRF are compared under rotordynamic analysis for isotropic and unisotropic rotors. Results show that in the nFRF, the magnitude of the response is the same for both positive and negative frequencies, and the response is similar under all modes. Consequently, the severity of the mode cannot be identified. However, in the dFRF, the forward and backward modes are clearly distinguishable in the frequency domain of the isotropic rotor, and the severity of the mode can be identified for the unisotropic rotor.