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Influence of Anodic Oxidation Film Formed on Titanium onto Cell Attachment and Proliferation (양극 산화에 의해 티타늄 표면에 형성된 산화 피막이 세포 부착 및 성장에 미치는 영향)

  • Noh, Se-Ra;Lee, Yong-Ryeol;Song, Ho-Jun;Park, Yeong-Joon
    • Korean Journal of Materials Research
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    • v.16 no.10
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    • pp.606-613
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    • 2006
  • This study was purposed to evaluate the influence of anodically oxidized film on titanium (Ti) onto MG-63 osteoblast-like cell attachment and activity. Only scratch lines created by polishing were seen in ASR and ANO-1 groups. About $1.5{\mu}m$-thick homogeneous oxide film which has pores of about $0.5{\mu}m$ diameter were formed in ANO-12. The crystalline structure of the oxide films formed by anodization in phosphoric acid electrolyte was $TiP_2O_7$. The total protein amounts of ANO-1 and ANO-12 groups showed higher values of maximum protein amount than that of AS-R group. At 3 days of incubation, total protein amount showed higher value in ANO-2 when comparing to that of AS-R (p<0.05). Based on the results of ALPase activity test, the degree of MG-63 cell differentiation for initial mineralization matrix formation was similar. For all the test groups after 1 day of incubation, MG-63 cells grew healthily in mono-layer with dendritic extensions. After incubation for 3 days, the specimen surfaces were covered more densely by cells, and numerous micro filaments were extruding to the extracellular matrix.

Friction Characteristics of Automotive Friction Materials with Ceramic Powder Contents (자동차용 마찰재에 함유된 세라믹분말의 함량에 따른 마찰특성)

  • Lee, Yong-Jin;Ryu, Jae-Kyung;Kim, Taik-Nam
    • Korean Journal of Materials Research
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    • v.19 no.7
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    • pp.403-406
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    • 2009
  • The friction characteristics of automotive brake friction materials that contained different ceramic content were investigated. Several kinds of raw materials, such as resin-based binder, reinforcing fiber, friction restraint, abrasive, and filling materials were mixed, pressed, and heated in order to make the brake friction materials. The contents of SiC and $BaSO_4$ changed from 5 vol% to 20 vol%, respectively. In addition to this, the content of $Al_2O_3$ adjusted from 1 vol% to 16 vol%. The surface morphology of the SiC containing sample appeared rough while more debris was observed when the contents of SiC increased. This implies that the SiC containing brake composite was not adequate for the automobile. However, the relatively smooth surface was observed in samples that contained the $Al_2O_3$. But the roughness was low with a content of 11 vol% $Al_2O_3$ compared to the other samples. This is consistent with the abrasive properties of the samples. In the case of $BaSO_4$ containing samples, the smoothes surface was observed in the contents of 15 vol% $BaSO_4$. Thus, it was concluded that the 11 vol% $Al_2O_3$ and 15 vol% $BaSO_4$ containing composite would be the optimum content for the brake composite. Similar to the results of the surface morphology, the abrasion resistance consistently decreased when the content of SiC increased. On the contrary, the sample that contained 11 vol% $Al_2O_3$ and 15 vol% $BaSO_4$ showed the highest abrasion resistance compared to the other samples.

Effect of Polymeric Binders on Green body Properties of WC-Co Cemented Carbides (초경합금 성형체 특성 변화에 미치는 유기물 결합제의 영향)

  • Lim, Young-Soo;Ahn, Sun-Yong;Lim, Jae-Suk;Paek, Yeong-Kyeun;Chung, Tai-Joo
    • Journal of Powder Materials
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    • v.29 no.4
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    • pp.291-296
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    • 2022
  • The green body of WC-Co cemented carbides containing polymeric binders such as paraffin, polyethylene glycol (PEG), and polyvinyl acetate (PVA) are prepared. The green density of the WC-Co cemented carbides increases with the addition of binders, with the exception of PVA, which is known to be a polar polymeric substance. The green strength of the WC-Co cemented carbides improves with the addition of paraffin and a mixture of PEG400 and PEG4000. In contrast, the green strength of the WC-Co does not increase when PEG400 and PEG4000 is added individually. The compressive strength of the green body increases to 14 MPa, and the machinability of the green body improves when more than 4-6 wt% paraffin and a mixture of PEG400 and PEG4000 is used. Simultaneously, the sintered density of WC-Co is as high as 99% relative density, similar to a low binder addition of 1-2 wt%.

The Influence of Soil Content on the Settlement Behavior of Gravel Embankement (토사 함량에 따른 자갈 성토재료의 침하특성 분석)

  • Suhyung Lee;Jiho Kim;Beomjun Kim;Chanyoung Yune
    • Journal of the Korean GEO-environmental Society
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    • v.24 no.11
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    • pp.41-49
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    • 2023
  • In this study, we analyzed the settlement characteristics of rockfill embankments mixed with soil by confirming the physical properties of soil materials mixed with silty materials and analyzing the compression characteristics of gravel materials according to the mixing ratio of soil materials. For this, we mixed silty materials into sandy soil to analyze the compression characteristics of soil materials, and we constructed a foundation by mixing various ratios of soil into rockfill materials with a particle distribution similar to that of river gravel, and conducted a one-dimensional compression experiment using a medium-sized chamber. As a result of the experiment, in the case of mixed soil materials, the Transition Fine Content (TFC) appeared in the range of 21~26% depending on the load condition, and in the case of rockfill materials mixed with soil, as the void filling ratio of soil in gravel samples increases, both total compression and creep compression decreases, but after a 50% mixing ratio, the settlement of amount increases again.

Environment-friendly Adhesives for Fancy Veneer Bonding of Engineered Flooring to Reduce Formaldehyde and TVOC Emissions

  • Kim, Sumin;Kim, Hyun-Joong;Xu, Guang Zhu;Eom, Young Geun
    • Journal of the Korean Wood Science and Technology
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    • v.35 no.5
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    • pp.58-66
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    • 2007
  • The objective of this research was to develop environment-friendly adhesives for face fancy veneer bonding of engineered flooring. Urea-formaldehyde (UF)-tannin and melamine-formaldehyde (MF)/PVAc hybrid resin were used to replace UF resin in the formaldehyde-based resin system in order to reduce formaldehyde and volatile organic compound (VOC) emissions from the adhesives used between plywoods and fancy veneers. Wattle tannin powder (5 wt%) was added to UF resin and PVAc (30 wt%) to MF resin. These adhesive systems showed better bonding than commercial UF resin with a similar level of wood penetration. The initial adhesion strength was sufficient to be maintained within the optimum initial tack range. The standard formaldehyde emission test (desiccator method) and VOC analyzer were used to determine the formaldehyde and VOC emissions from engineered flooring bonded with commercial UF resin, UF-tannin and MF/PVAc hybrid resin. By desiccator method, the formaldehyde emission level of UF resin showed the highest but was reduced by replacing with UF-tannin and MF/PVAc hybrid resin. MF/PVAc hybrid satisfied the $E_1$ grade (below $1.5mg/{\ell}$). VOC emission results by VOC analyzer were similar with the formaldehyde emission results. TVOC emission was in the following order: UF > UF-tannin > MF/PVAc hybrid resin.

THE STRESS ANALYSIS OF SUPPORTING TISSUE AND IMPLANT ACCORDING TO CROWN RESTORATIVE MATERIALS AND TYPE OF IMPLANT (수복재료와 임플랜트 종류에 따른 임플랜트 및 지지조직의 응력분포)

  • Choi Chang-Hwan;Oh Jong-Suk;Vang Mong-Sook
    • The Journal of Korean Academy of Prosthodontics
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    • v.40 no.1
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    • pp.53-67
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    • 2002
  • This study was aimed to analyze the stress distribution of implant and supporting tissue in single tooth implant restoration using Branemark $system^{(R)}$(Nobel Biocare, Gothenberg, Sweden) and Bicon system(Bicon Dental Implants, Boston, MA). Two dimensional finite element analysis model was made at mandibular first premolar area As a crown materials porcelain, ceromer, ADA type III gold alloy were used. Tests have been performed at 25Kgf vertical load on central fossa of crown portion and at 10Kgf load with $45^{\circ}$ lateral direction on cusp inclination. The displacement and stresses of implant and supporting structures were analyzed to investigate the influence of the crown material and the type of implant systems by finite element analysis. The results were obtained as follows : 1. The type of crown material influenced the stress distribution of superstructure, but did not influence that of the supporting alveolar bone. 2. The stress distribution of ceromer and type III gold alloy and porcelain is similar. 3. Stress under lateral load was about twice higher than that of vertical load in all occlusal restorative materials. 4. In Bicon system, stress concentration is similar in supporting bone area but CerOne system generated about 1.5times eater stress more in superstructure material. 5. In Branemark models, if severe occlusal overload is loaded in superstvucture. gold screw or abutment will be fractured or loosened to buffer the occlusal overload but in Bicon models such buffering effect is not expected, so in Bicon model, load can be concentrated in alveolar bone area.

Water-Assisted Synthesis of Carbon Nanotubes at Low Temperature and Low Pressure (물을 첨가한 탄소나노튜브의 저온 저압 합성)

  • Kim, Young-Rae;Jeon, Hong-Jun;Lee, Nae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.395-395
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    • 2008
  • Water-assisted synthesis of carbon nanotubes (CNTs) has been intensively studied in recent years, reporting that water vapor enhances the activity and lifetime of metal catalyst for the CNT growth. While most of these studies has been focused on the supergrowth of CNTs at high temperature, rarely has the similar approach been made for the CNT synthesis at low temperature. Since the metal catalyst are much less active at lower temperature, we expect that the addition of water vapor may increase the activity of catalyst more largely at lower temperature. We synthesized multi-walled CNTs at temperature as low as $360^{\circ}C$ by introducing water vapor during growth. The water addition caused CNTs to grow ~3 times faster. Moreover, the water-assisted growth prolonged the termination of CNT growth, implying the enhancement of catalyst lifetime. In general, a thinner catalyst layer is likely to produce smaller-diameter, longer CNTs. In a similar manner, the water vapor had a greater effect on the growth of CNTs for a smaller thickness of catalyst in this study. To figure out the role of process gases, CNTs were grown in the first stage and then exposed to each of process gases in the second stage. It was shown that water vapor and hydrogen did not etch CNTs while acetylene led to the additional growth of CNTs even faster in the second stage. As-grown CNTs were characterized by scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), atomic force microscopy (AFM), and Raman spectroscopy.

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The Effects of Sewing Thread Materials and Sewing Methods on Mechanical Properties of Knitwear (봉제원사와 봉제방법에 따른 니트웨어의 역학적 특성)

  • Kang, Sook-Nyeo;Kwen, Jin
    • Journal of the Korean Society of Costume
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    • v.57 no.2 s.111
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    • pp.1-10
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    • 2007
  • This study aims at the improvement of sewing function through understandings of dynamic property about the sewing methods and the thread material selection in knitwear. The tensile strength and shear of KES-FB and the Instron were measured for the analysis of the mechanical properties. The knit cloth was structured In the plain stitch, $1\times1$ rib stitch and $2\times1$ rib stitch with the combination of wool and cotton. With regard to the sewing method, intralooping and interlacing were applied. For thread materials, polyester, cotton, wool and silk were used. Since silk has the lowest extension and similar values regardless of its construction in intralooping, it is available knit apparel with uniform elastic recoverv. It also has small shearing resistance. It can be used in apparel which needs big mobility, but it causes rutting problem. Therefore, it is suitable to use intralooping. When the same sewing yarn and textile are use, it can lower shearing resistance and extension in intralooping, Since wool needs a lot of extension energy and it can be cut, intralooping is more suitable than interlacing in sewing of wool. In interlacing using polyester, extension and shearing resistance are high. Therefore, it is suitable for knit sewing with high massing. Silk is not suitable for interlacing since it can be rut. Even though knit materials are different, the RT values of polyester and cotton are similar in same construction. Therefore, they can be substituted each other considering resilience after sewing.

A Study on Processing and Physical Properties of Isoprene Rubber Involving Norbornene Dialkyl Ester (Norbornene Dialkyl Ester가 첨가된 Isoprene Rubber의 가공성 및 물성에 관한 연구)

  • Jeong, Hye-in;Jo, Nam-chol;Woo, Je-Wan
    • Applied Chemistry for Engineering
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    • v.27 no.3
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    • pp.259-264
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    • 2016
  • In this study, we applied six different norbornene dialkyl esters as a plasticizer to an isoprene rubber (IR) and evaluated replaceability of DEHP which is an endocrine disruptor. IR test sheets were prepared by blending IR, norbornene dialkyl ester, vulcanizing agent, etc. and processing properties of the IR were evaluated by measuring Toque, scorch time, cure time and mooney viscosity. Mechanical properties of IR test sheet including hardness, tensile strength, 100% modulus and elongation were also measured and the physical properties of norbornene dialkyl ester applied as a plasticizer were compared to those using DEHN. Both the maximum and minimum toque for the norbornene dialkyl ester as a plasticizer were similar to those of using DEHP. In addition, the scorch and cure time of the former were slightly longer than those of the latter. The mooney viscosity for the case of DEHN was slightly lower than that of the latter. DEHN was also superior to DEHP in terms of processing. The hardness and thermal properties of all IR test sheets were measured to be similar to each other. The linear alkyl chain of norbornene compounds also exhibited good tensile characteristics.

Effect of Basic Oxygen Furnace Slag used as Structural Filling Materials on the Subsurface Environment (성·복토용으로 사용된 전로제강슬래그가 주변 토양환경에 미치는 영향)

  • Lee, Hosub;Nam, Taekwoo;Jho, Eun Hea;Nam, Kyoungphile
    • Journal of Soil and Groundwater Environment
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    • v.21 no.3
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    • pp.6-13
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    • 2016
  • The effect of blast oxygen furnace (BOF) slag used as filling materials on the soil environment was studied using column tests that simulated the flow of the BOF slag leachate through the soil layer. The Cu, Mn, Zn, Ni, and F contents of the leachate affected soil were similar to that of the controls (i.e., soils that were not affected by the leachate). The As, Cd, and Pb contents were lower in the leachate affected soils than the controls. The changes in these contaminants contents can be attributed to the interactions between anions such as alkalinity generating anions (e.g., CO32−, HCO3, OH) or calcium ions with heavy metals or F, which consequently affected the fate of heavy metals and F in the leachate affected soils. The germination and growth of Spinapis alba in the soils affected by the leachate and the controls were also similar. However, the proportion of alkalophilic bacteria in the soils affected by the leachate significantly increased, and this can be explained by the increased soil pH due to the alkaline leachate. Overall, this study shows that the alkalinity of the BOF slag leachate, rather than the presence of heavy metals and F in the leachate, needs to be considered when the BOF slag is to be reused as structural filling materials.