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Adsorption of Ni(II), Co(II), and Mg(II) from Sulfuric Acid Solution by Diphonix Resin for the Utilization of Laterite Ore (라테라이트광 활용을 위한 황산용액에서 Diphonix 수지의 니켈, 코발트, 마그네슘 흡착)

  • Lee, Man-Seung;Kim, Sang-Bae;Chae, Jong-Gwee
    • Journal of the Mineralogical Society of Korea
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    • v.23 no.3
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    • pp.183-189
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    • 2010
  • It is of importance to separate Ni(II) and Co(II) from Mg(II) in solution which was leached from nickel laterite ore. In order to investigate the possibility of separating Ni(II) and Co(II) from Mg(II), adsorption behavior of the three metals from individual and mixed sulfate solutions was investigated by using Diphonix resin. The concentration of each metal in solution was fixed at 100 ppm and the pH of the sulfuric acid solution was changed from 5 to 7. At ambient temperature, the adsorption behavior of the three metal ions followed Langmuir adsorption isotherm. The loading capacity of Diphonix resin for the three metal ions was obtained from the Langmuir isotherm. Since adsorption behavior of the three metal ions from the mixed solution was similar to each other, it was found to be difficult to separate Ni(II) and Co(II) from Mg(II) by using Diphonix resin.

Effect of Cu/Al powder mixing on Dy diffusion in Nd-Fe-B sintered magnets treated with a grain boundary diffusion process (입계확산처리된 Nd-Fe-B 소결자석에서 Dy의 확산에 미치는 Cu와 Al 분말의 혼합 효과)

  • Lee, Min Woo;Jang, Tae Suk
    • Journal of Powder Materials
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    • v.23 no.6
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    • pp.432-436
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    • 2016
  • We investigate the microstructural and magnetic property changes of $DyH_2$, $Cu+DyH_2$, and $Al+DyH_2$ diffusion-treated NdFeB sintered magnets with the post annealing (PA) temperature. The coercivity of all the diffusion-treated magnets increases with increasing heat treatment temperature except at $910^{\circ}C$, where it decreases slightly. Moreover, at $880^{\circ}C$, the coercivity increases by 3.8 kOe in Cu and 4.7 kOe in Al-mixed $DyH_2$-coated magnets, whereas this increase is relatively low (3.0 kOe) in the magnet coated with only $DyH_2$. Both Cu and Al have an almost similar effect on the coercivity improvement, particularly over the heat treatment temperature range of $790-880^{\circ}C$. The diffusivity and diffusion depth of Dy increases in those magnets that are treated with Cu or Al-mixed $DyH_2$, mainly because of the comparatively easy diffusion path provided by Cu and Al owing to their solubility in the Nd-rich grain boundary phase. The formation of a highly anisotropic $(Nd,\;Dy)_2Fe_{14}B$ phase layer, which acts as the shell in the core-shell-type structure so as to prevent the reverse domain movement, is the cause of enhanced coercivity of diffusion-treated Nd-Fe-B magnets.

Automatic Method for Transforming Image into Tactile Map Based on Cognitive Characteristics of Visually Impaired Persons (시각장애인 인지특성을 기반으로 한 영상자료의 촉각지도 자동 변환 방법)

  • Kim, Hye-Young;Cho, Jin-Soo
    • The Journal of the Korea Contents Association
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    • v.13 no.4
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    • pp.452-458
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    • 2013
  • In this paper, we propose the method for automatically transfers images into tactile maps information based on cognition characteristics of visually impaired persons to more easily provide various image information for visually impaired persons. The proposed method automatically classify color images into row complexity and high complexity based on intensity information and transfer images into tactile map information using each different transformation process. Experimental evaluation, We performed with visually impaired five persons experiments for evaluating the recognition and satisfaction that tactile maps of the proposed automatic transforming method and the manually generated tactile maps of braille textbooks. Experimental results, the recognition and satisfaction that the tactile maps of the proposed method generated are very similar to those of the tactile maps of braille textbooks. Therefore, it could hugely be reduced the time and money of production education materials, and it could greatly improved educative results because it can add more easily that many image data of education materials.

The Influence of Heat Treatment Temperature on Microstructure and Corrosion Behavior of SDSS Tube (SDSS (Super Duplex Stainless Steel) 강관의 미세조직 및 부식특성에 미치는 열처리 온도의 영향)

  • Lee, Insup;Cheon, Chang-seok;Yim, Tai-Hong;Han, Yoon-Ho;Lee, Myon-Hag
    • Journal of Surface Science and Engineering
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    • v.48 no.6
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    • pp.329-334
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    • 2015
  • The aim of this paper is to determine the proper heat treatment temperature for SDSS tube production without ${\sigma}$-phase precipitation. When Mother steel tube was heat treated at $800^{\circ}C$ temperature, relatively a large amount of ${\sigma}$-phase precipitated and grain refinement of ferrite phase occurred simultaneously. However, in Pilgered and Drawn steel tubes, grain refinement of the ferrite phase did not occur and a small amount of ${\sigma}$-phase precipitated. For all three types of steel tubes, the pitting potential was reduced to 2/5 or less compared with the untreated one and corrosion also occurred in the salt spray test due to the precipitation of ${\sigma}$-phase. When heat treatment temperature was $900^{\circ}C$, grain refinement of the ferrite phase occurred and very little ${\sigma}$-phase precipitated in Pilgered and Drawn steel tubes. But when heat treatment was done at $1,000^{\circ}C$ temperature, all three types of steel tubes had a similar corrosion properties of that of untreated one and also corrosion did not occur in the salt spray test, as ${\sigma}$-phase did not precipitate. Therefore, the optimum heat treatment temperature range is determined to be more than $1000^{\circ}C$ for the SDSS at which corrosion does not occur.

Effects of Alloying Elements on the High Pressure Wear Characteristics of Ductile Cast Iron I-Cu, Mn (구상흑연주철의 고압하 마멸특성에 미치는 합금원소의 영향 I-Cu, Mn)

  • Bang, Woong-Ho;Kang, Choon-Sik;Park, Jae-Hyun;Kweon, Young-Gak
    • Journal of Korea Foundry Society
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    • v.20 no.4
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    • pp.230-239
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    • 2000
  • High pressure wear characteristics of DCI(Ductile Cast Iron) were investigated through unlubricated pin-on-disc wear test. Wear test were carried out at speed of 23m/min, under pressure of 3MPa and 3.3 MPa. Cu and/or Mn were added to examine the effect of alloying elements on the high pressure wear characteristics of DCI. To investigate the relationship between wear characteristics and mechanical properties of DCI, Brinell hardness and V-notched Charpy impact energy were tested. Wear surface of each specimen was observed by SEM to determine the wear mechanism of DCI under high pressure wear condition. In the mild wear region, wear characteristics of alloyed DCI specimens were very similar to that of unalloyed DCI. But mild-severe wear transition was occurred at different wear distance and wear rate of DCI specimens were changed by alloying elements. In severe wear condition, wear rate of DCI was dramatically increased by the addition of Mn. Although the addition of Cu 0.46wt% did not decrease the wear rate of DCI in the severe wear region, but it delayed the mild-severe wear transition. Under high pressure wear condition, wear rate and mild-severe wear transition were not concerned with hardness of DCI specimens, but they were deeply associated with impact energy changed by alloying elements.

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Studies on Long-wavelength Infrared Detector using Multiple Stacked InAs Quantum Dot Layers (다층 InAs 양자점을 이용한 장파장 적외선 수광소자에 관한 연구)

  • Kim, Jong-Wook;Oh, Jae-Eung;Hong, Seong-Chul
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.37 no.8
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    • pp.42-47
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    • 2000
  • Long-wavelength infrared (LWIR) detectors made of self-assembled quantum dots embedded in the channel region of high electron mobility transistor (HEMT) is demonstrated. Above 180 K, the detector shows low dark currents due to strong confinement effect of electrons in InAs quantum dots and exhibits the broad spectral response ranging from 7 mm to 11 mm. The peak detectivity ($D^*$) of $1.93{\times}10^{10}cmHz^{1/2}/W$ is obtained at 9.4 mm. The photocurrent characteristics as a function of applied bias are similar to that of normal FETs, while the photocurrent decreases as the applied electric field exceeds $2{\times}10^3V/cm$ because of the increased dark current.

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Tension-Compression Asymmetry in the Off-Axis Nonlinear Rate-Dependent Behavior of a Unidirectional Carbon/Epoxy Laminate at High Temperature and Incorporation into Viscoplasticity Modeling

  • Kawai, M.;Zhang, J.Q.;Saito, S.;Xiao, Y.;Hatta, H.
    • Advanced Composite Materials
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    • v.18 no.3
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    • pp.265-285
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    • 2009
  • Off-axis compressive deformation behavior of a unidirectional CFRP laminate at high temperature and its strain-rate dependence in a quasi-static range are examined for various fiber orientations. By comparing the off-axis compressive and tensile behaviors at an equal strain rate, the effect of different loading modes on the flow stress level, rate-dependence and nonlinearity of the off-axis inelastic deformation is elucidated. The experimental results indicate that the compressive flow stress levels for relatively larger off-axis angles of $30^{\circ}$, $45^{\circ}$ and $90^{\circ}$ are about 50 percent larger than in tension for the same fiber orientations, respectively. The nonlinear deformations under off-axis tensile and compressive loading conditions exhibit significant strain-rate dependence. Similar features are observed in the fiber-orientation dependence of the off-axis flow stress levels under tension and compression and in the off-axis flow stress differential in tension and compression, regardless of the strain rate. A phenomenological theory of viscoplasticity is then developed which can describe the tension-compression asymmetry as well as the rate dependence, nonlinearity and fiber orientation dependence of the off-axis tensile and compressive behaviors of unidirectional composites in a unified manner. It is demonstrated by comparing with experimental results that the proposed viscoplastic constitutive model can be applied with reasonable accuracy to predict the different, nonlinear and rate-dependent behaviors of the unidirectional composite under off-axis tensile and compressive loading conditions.

Experimental Assessment of Mechanical Properties of Geo-grid Reinforced Material and Long-Term Performance of GT/HDPE Composite

  • Seo, Jung-Min;Min, Kyung-Ho;Hwang, Beong-Bok;Lee, In-Chul;Ruchiranga, Jayasekara Vishara;Jeon, Han-Yong;Jang, Dong-Hwan;Lim, Joong-Yeon
    • Advanced Composite Materials
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    • v.17 no.3
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    • pp.247-258
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    • 2008
  • This paper is concerned with the long-term performance of geo-textile (GT) composites in terms of creep deformation and frictional properties. Composites of PVA GT and HDPE GM were made to investigate the advanced properties of long-term performance related to waste landfill applications. The same experiments were also performed for typical polypropylene and polyester GT and compared to PVA GT/HDPE GM composites. We also develop high performance GT composites with GM by using PVA GT, which is capable of improving the frictional properties and thus enhances long-term performance of GT composites. Experimental study reveals that the friction coefficient of GT composites is relatively large compared with those of polyester and polypropylene non-woven GT as long as the friction media has similar size to the particles of domestic standard earth. In addition, the geo-composites bonded with geo-grid by a chemical process were investigated experimentally in terms of strain evaluation and creep response values. Geo-grid plays an important role as a reinforcing material. Three kinds of geo-grid were prepared as strong yarn polyester and they were woven type, non-woven type, and wrap knitted type. The sample geo-grids were then coated with PVC. The rib tensile strength tests were conducted to evaluate geo-grid products in terms of tensile strength with regard to single rib. The test was performed according to GRI-GGI. It was concluded again from the experiments that the tensile and creep strains of the geo-grid showed such stable values that the geo-grid prepared in this study could protect geo-textile partially in practical structures.

Hydrogneation and Electrochemical Characteristics of Gas-atomized Zr-based $AB_2$ Hydride for Ni-MH Secondary Battery (기체분무형 공정으로 제조된 Zr계 금속수소화물의 수소화반응 및 Ni-MH 2차전지 전극 특성에 관한 연구)

  • Kim, Jin-Ho;Hwang, Kwang-Taek;Kim, Byung-Kwan;Han, Jeong-Seb
    • Journal of Hydrogen and New Energy
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    • v.20 no.6
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    • pp.505-511
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    • 2009
  • The hydriding and electrochemical characteristics of Zr-based $AB_2$ alloy produced by gas atomization have been extensively examined. For the particle morphology of the as-cast and gas-atomized powders, it can be seen that the mechanically crushed powders are irregular, while the atomized powder particles are spherical. The increase of jet pressure of gas atomization process results in the decrease of hydrogen storage capacity and the slope of plateau pressure significantly increases. TEM and EDS studies showed the increase of jet pressure in the atomization process accelerated the phase separation within grain of the gas-atomized alloy, which brought about a poor hydrogenation property. However, the gas-atomized $AB_2$ alloy powders produced by jet pressure of 50 bar kept up the reversible $H_2$ storage capacity and discharge capacity similar to the mechanically crushed particles. In addition, the electrode of gas-atomized Zr-based $AB_2$ alloy of 50 bar showed improved cyclic stability over that of the cast and crushed particulate, which is attributed to the restriction of crack propagation by grain boundary and dislocation with ch/discharging cycling.

Characteristics of Electronically Controlled 13L LNG-Diesel Dual Fuel Engine (13L급 LNG-디젤 혼소엔진의 기초 성능 특성 연구)

  • Lee, Seok-Hwan;Lee, Jin-Wook;Heo, Seong-Joon;Yoon, Sung-Shik;Roh, Yun-Hyun
    • Journal of the Korean Institute of Gas
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    • v.11 no.4
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    • pp.54-58
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    • 2007
  • The trailers with electronically controlled diesel engine was converted to dual fuel engine system. To estimate economical efficiency, test vehicles have been operated on a certain driving route repeatedly. Fuel economy, mximum driving distance per refueling and driveability are examined on the road including a free way. Developed vehicle can be operated over 500 km with dual Hel and shows 85% of diesel substitution ratio. Driveability is similar with but passing acceleration. It will be improved by calibration process. Test engine was set up for investigating power output, thermal efficiency and emission. ND 13-mode tests were performed for the test cycle. The emission result of dual fuel meets K2006 regulation and the engine performance of dual fuel engine was equivalent to the performance of diesel engine.

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