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Design Strategies for Adsorbents with Optimal Propylene/propane Adsorptive Separation Performances (최적의 프로필렌/프로판 흡착 분리 성능을 가지는 흡착제의 개발 전략들)

  • Kim, Tea-Hoon;Lee, Seung-Joon;Kim, Seo-Yul;Kim, Ah-Reum;Bae, Youn-Sang
    • Korean Chemical Engineering Research
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    • v.57 no.4
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    • pp.484-491
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    • 2019
  • An efficient propylene/propane separation technology is needed to obtain high-purity propylene, which is a raw material for polypropylene synthesis. Since conventional cryogenic distillation is an energy-intensive process due to the similar physicochemical properties of propylene and propane, adsorptive separation has gained considerable interest. In this study, we have computationally investigated the changes in adsorption separation performances by arbitrarily controlling the adsorption strength of open metal sites in two different types of metal-organic frameworks (MOFs). Through the evaluation of adsorptive separation performances in terms of working capacity, selectivity, and Adsorption Figure of Merit (AFM), we have suggested proper density and strength of adsorption sites as well as appropriate temperature condition to obtain optimal propylene/propane adsorptive separation performances.

Effect of Thermal Grease on Thermal Conductivity for Mild Steel and Stainless Steel by ASTM D5470 (ASTM D5470 방법으로 연강과 스테인리스강의 열전도도 측정시 열그리스의 영향)

  • Cho, Young-Wook;Hahn, Byung-Dong;Lee, Ju Ho;Park, Sung Hyuk;Baeg, Ju-Hwan;Cho, Young-Rae
    • Korean Journal of Materials Research
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    • v.29 no.7
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    • pp.443-450
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    • 2019
  • Thermal management is a critical issue for the development of high-performance electronic devices. In this paper, thermal conductivity values of mild steel and stainless steel(STS) are measured by light flash analysis(LFA) and dynamic thermal interface material(DynTIM) Tester. The shapes of samples for thermal property measurement are disc type with a diameter of 12.6 mm. For samples with different thickness, the thermal diffusivity and thermal conductivity are measured by LFA. For identical samples, the thermal resistance($R_{th}$) and thermal conductivity are measured using a DynTIM Tester. The thermal conductivity of samples with different thicknesses, measured by LFA, show similar values in a range of 5 %. However, the thermal conductivity of samples measured by DynTIM Tester show widely scattered values according to the application of thermal grease. When we use the thermal grease to remove air gaps, the thermal conductivity of samples measured by DynTIM Tester is larger than that measured by LFA. But, when we did not use thermal grease, the thermal conductivity of samples measured by DynTIM Tester is smaller than that measured by LFA. For the DynTIM Tester results, we also find that the slope of the graph of thermal resistance vs. thickness is affected by the usage of thermal grease. From this, we are able to conclude that the wide scattering of thermal conductivity for samples measured with the DynTIM Tester is caused by the change of slope in the graph of thermal resistance-thickness.

Anti-melanogenic effects of Hordeum vulgare L. barely sprout extract in murine B16F10 melanoma cells

  • Choi, Jeong-Hwa;Jung, Jong-Gi;Kim, Jung-Eun;Bang, Mi-Ae
    • Journal of Nutrition and Health
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    • v.52 no.2
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    • pp.168-175
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    • 2019
  • Purpose: Barely sprout is a well-known oriental herbal medicine with a wide range of health benefits. Recent studies have provided scientific evidence of its therapeutic effects with expanded application. This study investigated anti-melanogenic effect of barley sprout water extract (BSE) in murine melanocyte B16F10. Methods: Various concentrations (0, 50, 125, and $250{\mu}g/mL$) of BSE and arbutin (150 ppm) were applied to B16F10 stimulated with or without alpha-melanocyte stimulating hormone (100 nM) for 72 hours. The whitening potency of BSE was determined altered cellular melanin contents. Activity and expression of tyrosinase and microphthalmia-associated transcription factor (MITF) were also assayed. Results: Experimental results revealed that treatment with BSE reduced cellular melanin production by approximately 40% compared to the control. Molecular findings supported that suppressed activity and expression of tyrosinase and MITF proteins by BSE were associated with declined cellular melanogenesis. Furthermore, anti-melanogenic effect of BSE ($250{\mu}g/mL$) was similar to that of arbutin, a commonly used whitening agent. Lastly, polyphenols including p-coumaric, ferulic, and vanillic acids were identified in BSE using HPLC analyses. They might be potential active ingredients showing such melanogenesis-reducing effect. Conclusion: BSE was evident to possess favorable anti-melanogenic potency in an in vitro model. As a natural food sourced material, BSE could be an effective depigmentation agent with potential application in pharmaceutical and cosmetic industries.

A new method for infill equivalent strut width

  • Tabeshpour, Mohammad Reza;Arasteh, Arash Mahdipour
    • Structural Engineering and Mechanics
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    • v.69 no.3
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    • pp.257-268
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    • 2019
  • Infills are as important members in structural design as beams, columns and braces. They have significant effect on structural behavior. Because of lots of variables in infills like material non-linear behavior, the interaction between frames and infill, etc., the infills performance during an earthquake is complicated, so have led designers do not consider the effect of infills in designing the structure. However, the experimental studies revealed that the infills have the remarkable effect on structure behavior. As if these effects ignored, it might occur soft-story phenomena, torsion or short-column effects on the structures. One simple and appropriate method for considering the infills effects in analyzing, is replacing the infills with diagonal compression strut with the same performance of real infill, instead of designing the whole infill. Because of too many uncertainties, codes and researchers gave many expressions that were not as the same as the others. The major intent of this paper is calculation the width of this diagonal strut, which has the most characteristics of infill. This paper by comprehensive on different parameters like the modulus of young or moment of inertia of columns presents a new formula for achieving the equivalent strut width. In fact, this new formula is extracted from about 60 FEM analyses models. It can be said that this formula is very efficient and accurate in estimating the equivalent strut width, considering the large number of effective parameters relative to similar relationships provided by other researchers. In most cases, the results are so close to the values obtained by the FEM. In this formula, the effect of out of plane buckling is neglected and this formula is used just in steel structures. Also, the thickness of infill panel, and the lateral force applied to frame are constant. In addition, this new formula is just for modeling the lateral stiffness. Obtaining the nearest response in analyzing is important to the designers, so this new formula can help them to reach more accurate response among a lot of experimental equations proposed by researchers.

Thermal, electrical and mechanical buckling loads of sandwich nano-beams made of FG-CNTRC resting on Pasternak's foundation based on higher order shear deformation theory

  • Arani, Ali Ghorbanpour;Pourjamshidian, Mahmoud;Arefi, Mohammad;Arani, M.R. Ghorbanpour
    • Structural Engineering and Mechanics
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    • v.69 no.4
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    • pp.439-455
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    • 2019
  • This research deals with thermo-electro-mechanical buckling analysis of the sandwich nano-beams with face-sheets made of functionally graded carbon nano-tubes reinforcement composite (FG-CNTRC) based on the nonlocal strain gradient elasticity theory (NSGET) considering various higher-order shear deformation beam theories (HSDBT). The sandwich nano-beam with FG-CNTRC face-sheets is subjected to thermal and electrical loads while is resting on Pasternak's foundation. It is assumed that the material properties of the face-sheets change continuously along the thickness direction according to different patterns for CNTs distribution. In order to include coupling of strain and electrical field in equation of motion, the nonlocal non-classical nano-beam model contains piezoelectric effect. The governing equations of motion are derived using Hamilton principle based on HSDBTs and NSGET. The differential quadrature method (DQM) is used to calculate the mechanical buckling loads of sandwich nano-beam as well as critical voltage and temperature rising. After verification with validated reference, comprehensive numerical results are presented to investigate the influence of important parameters such as various HSDBTs, length scale parameter (strain gradient parameter), the nonlocal parameter, the CNTs volume fraction, Pasternak's foundation coefficients, various boundary conditions, the CNTs efficiency parameter and geometric dimensions on the buckling behaviors of FG sandwich nano-beam. The numerical results indicate that, the amounts of the mechanical critical load calculated by PSDBT and TSDBT approximately have same values as well as ESDBT and ASDBT. Also, it is worthy noted that buckling load calculated by aforementioned theories is nearly smaller than buckling load estimated by FSDBT. Also, similar aforementioned structure is used to building the nano/micro oscillators.

Study on the Evaluation Method for EEDI of the Small Vessel using CFD (CFD 기반 소형 선박의 EEDI 평가 방법에 관한 연구)

  • Park, Dong-Woo
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.25 no.5
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    • pp.627-633
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    • 2019
  • This study aimed to predict the resistance and propulsion performance of a ship using computational fluid dynamics (CFD) and a database as well as establish an assessment method for the energy efficiency design index (EEDI) using the results. First, the total resistance of the studied ship is obtained using CFD. A flow analysis is conducted with the free surface and trim and sinkage using a commercial CFD code (STAR-CCM+). The effective power of the ship is assessed based on the CFD results. The quasi-propulsive efficiency is calculated from an empirical prediction equation using experimental data and similar material. Finally, a general calculation program for the EEDI is established based on the hydrodynamic results, ship information for principal particulars, conversion factor of $CO_2$ for fuels, and fuel consumption.

Assessment of stem cell viability in the initial healing period in rabbits with a cranial bone defect according to the type and form of scaffold

  • Kang, Seung-Hwan;Park, Jun-Beom;Kim, InSoo;Lee, Won;Kim, Heesung
    • Journal of Periodontal and Implant Science
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    • v.49 no.4
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    • pp.258-267
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    • 2019
  • Purpose: Increased bone regeneration has been achieved through the use of stem cells in combination with graft material. However, the survival of transplanted stem cells remains a major concern. The purpose of this study was to evaluate the viability of transplanted mesenchymal stem cells (MSCs) at an early time point (24 hours) based on the type and form of the scaffold used, including type I collagen membrane and synthetic bone. Methods: The stem cells were obtained from the periosteum of the otherwise healthy dental patients. Four symmetrical circular defects measuring 6 mm in diameter were made in New Zealand white rabbits using a trephine drill. The defects were grafted with 1) synthetic bone (${\beta}$-tricalcium phosphate/hydroxyapatite [${\beta}-TCP/HA$]) and $1{\times}10^5MSCs$, 2) collagen membrane and $1{\times}10^5MSCs$, 3) ${\beta}-TCP/HA+collagen$ membrane and $1{\times}10^5MSCs$, or 4) ${\beta}-TCP/HA$, a chipped collagen membrane and $1{\times}10^5MSCs$. Cellular viability and the cell migration rate were analyzed. Results: Cells were easily separated from the collagen membrane, but not from synthetic bone. The number of stem cells attached to synthetic bone in groups 1, 3, and 4 seemed to be similar. Cellular viability in group 2 was significantly higher than in the other groups (P<0.05). The cell migration rate was highest in group 2, but this difference was not statistically significant (P>0.05). Conclusions: This study showed that stem cells can be applied when a membrane is used as a scaffold under no or minimal pressure. When space maintenance is needed, stem cells can be loaded onto synthetic bone with a chipped membrane to enhance the survival rate.

Analysis on Pressure and Wearing Sensation according to the Lower Band Design of Sports Brassieres (스포츠 브래지어의 하변 밴드 설계에 따른 압력과 착용감 분석)

  • Lee, Heeran;Eom, Ran-i;Lee, Yejin
    • Fashion & Textile Research Journal
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    • v.21 no.1
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    • pp.67-74
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    • 2019
  • This study aims to investigate the relation between pressure, 3D length change, and subjective pressure sensation in sports brassieres. Seven Korean women in their 20s and 30s were chosen as subjects. In the experiment, the subjects evaluated four types of sports brassieres wherein the lower band was changed. The results of the study were as follows. The pressure according to the measurement position was lower at the front part than at the side and back parts (p<.05), and there was no difference in the pressure according to the brassiere type. It was observed that brassiere C, which had the higher extension band, was elongated more than the other brassieres when worn. In the case of brassiere B, which had a slit in the front center, it was observed that the 3D length of the front part changed very little as the slit spreads, and the back part stretched in a manner similar to those of the other brassieres. Subjective pressure sensation was statistically different only at the front and the side of the lower band. Brassiere B(with a silt) demonstrated the least subjective pressure sensation; the pressure sensation was high when wearing brassieres A and D (p<.05). Brassieres B and C were also preferred for overall comfort. In conclusion, it was observed that the substitution of material and morphological transformation affect subjective sensation.

Discarded Egg Yolk as an Alternate Source of Poly(3-Hydroxybutyrate-co-3-Hydroxyhexanoate)

  • Hong, Yun-Gi;Moon, Yu-Mi;Hong, Ju-Won;Choi, Tae-Rim;Jung, Hye-Rim;Yang, Soo-Yeon;Jang, Dae-Won;Park, Ye-Rim;Brigham, Christopher J.;Kim, Jae-Seok;Lee, Yoo-Kyung;Yang, Yung-Hun
    • Journal of Microbiology and Biotechnology
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    • v.29 no.3
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    • pp.382-391
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    • 2019
  • Many poultry eggs are discarded worldwide because of infection (i.e., avian flu) or presence of high levels of pesticides. The possibility of adopting egg yolk as a source material to produce polyhydroxyalkanoate (PHA) biopolymer was examined in this study. Cupriavidus necator Re2133/pCB81 was used for the production of poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) or poly(3HHx), a polymer that would normally require long-chain fatty acids as carbon feedstocks for the incorporation of 3HHx monomers. The optimal medium contained 5% egg yolk oil and ammonium nitrate as a nitrogen source, with a carbon/nitrogen (C/N) ratio of 20. Time course monitoring using the optimized medium was conducted for 5 days. Biomass production was 13.1 g/l, with 43.7% co-polymer content. Comparison with other studies using plant oils and the current study using egg yolk oil revealed similar polymer yields. Thus, discarded egg yolks could be a potential source of PHA.

A Multi-detection Fluorescence Dye with 5-ALA and ICG Using Modified Light Emitting Diodes

  • Yoon, Kicheol;Kim, Eunji;Kim, Kwanggi;Lee, Seunghoon;Yoo, Heon
    • Current Optics and Photonics
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    • v.3 no.3
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    • pp.256-262
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    • 2019
  • Extensive tumor resection accompanied by radiotherapy and chemotherapy is the standard of care for malignant gliomas. However, there is a significant obstacle to the complete resection of the tumor due to the difficulty of distinguishing tumor and normal brain tissue with a conventional surgical microscope. Recently, multiple studies have shown the possibility of fluorescence-guided surgery in malignant gliomas. The most used fluorescence dyes for brain tumor surgery are 5-aminolevulinic acid (5-ALA) and indocyanine green (ICG). In this paper, a new fluorescence guided operation system, which can detect both 5-ALA and ICG fluorescent images simultaneously, is presented. This operation system consists of light emitting diodes (LEDs) which emits 410 nm and 740 nm wavelengths. We have performed experiments on rats in order to verify the operation of the newly developed operation system. Oral administration and imaging were performed to observe the fluorescence of 5-ALA and ICG fluorescence in rats. When LEDs at wavelengths of 410 nm and 740 nm were irradiated on rats, 628 nm wavelength with a violet fluorescence color and 825 nm wavelength with a red fluorescence color were expressed in 5-ALA and ICG fluorescent material, respectively, thus we were able to distinguish the tumor tissues easily. Previously, due to the poor resolution of the conventional surgical microscope and the fact that the color of the vein is similar to that of the tumor, the tumor resection margin was not easy to observe, thus increasing the likelihood for cancer recurrence. However, when the tumor is observed through the fluorescence guided operation system, it is possible to easily distinguish the color with the naked eye and it can be completely removed. Therefore, it is expected that surgical removal of cancerous tumors will be possible and surgical applications and surgical microscopes for cancer tumor removal surgery will be promising in the future.