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Study of Air-Breathing Polymer Electrolyte Membrane Fuel Cell Using Metal-Coated Polycarbonate as a Material for Bipolar Plates (도금된 폴리카보네이트 분리판을 이용한 공기 호흡형 고분자 전해질막 연료전지에 관한 연구)

  • Park, Taehyun;Lee, Yoon Ho;Chang, Ikwhang;Ji, Sanghoon;Paek, Jun Yeol;Cha, Suk Won
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.2
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    • pp.155-161
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    • 2013
  • In this study, a metal-plated polycarbonate was adopted as a material for bipolar plates in a polymer electrolyte membrane fuel cell (PEMFC). The coated layers included 40-${\mu}m$-thick copper, 10-${\mu}m$-thick nickel, and 0.3-${\mu}m$-thick gold that respectively played the roles of current conduction, adhesion between copper and gold, and minimization of surface corrosion. The maximum power of the air-breathing PEMFC with polycarbonate bipolar plates was $120mW/cm^2$, which was similar to that of graphite bipolar plates. Finally, the maximum power of a 12-cell stack of polycarbonate bipolar plates was $132.7mW/cm^2$, and it had an operating time of 12 h. Therefore, this was considered a suitable material for bipolar plates in PEMFCs.

Geochemistry and Sm-Nd isotope systematics of Precambrian granitic gneiss and amphibolite core at the Muju area, middle Yeongnam Massif (영남육괴 중부 무주 지역에 위치하는 선캠브리아기 화강편마암 및 앰피볼라이트 시추코아의 Sm-Nd 연대 및 지구화학적 특징)

  • Lee Seung-Gu;Kim Yongje;Kim Kun-Han
    • The Journal of the Petrological Society of Korea
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    • v.14 no.3 s.41
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    • pp.127-140
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    • 2005
  • The Samyuri area of Jeoksang-myeon, Muju-gun at the Middle Yeongnam Massif consists of granitic gneiss, porphyroblastic gneiss and leucocratic gneiss, which correspond to Precambrian Wonnam Series. Here we discuss a geochemical implication of the data based on major element composition, trace element, rare earth element (REE), Sm-Nd and Rb-Sr isotope systematics of the boring cores in the granite gneiss area. The boring cores are granitic gneiss (including biotite gneiss) and amphibolite. The major and trace element compositions of granitic gneiss and amphibolite suggest that the protolith belongs to TTG (Tonalite-Trondhjemite-Granodiorite) and tholeiitic series, respectively. Chondrte-normalized REE patterns vary in LREE, HREE and Eu anomalies. The granitic gneiss and amphibolite have Sm-Nd whole rock age of $2,026{\pm}230(2{\sigma})$ Ma with an initial Nd isotopic ratio of $0.50979{\pm}0.00028(2{\sigma})$ (initial ${\epsilon}_{Nd}=-4.4$), which suggests that the source material was derived from old crustal material. Particularly, this initial ${\epsilon}$ Nd value belongs to the range of the geochemical evolution of Archean basement in North-China Craton, and also corresponds to the initial Nd isotope evolution line by Lee et al. (2005). In addition, chondrite-normalized REE pattern and initial Nd value of amphibolite are very similar to those of juvenile magma in crustal formation process.

The proposal on the new method for accurate to measure the plastic limits (정확한 소성한계 측정을 위한 새로운 실험법 제안)

  • Ko, Jae-Min;Lee, Byung-Suk
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.6
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    • pp.68-79
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    • 2018
  • An examination of the characteristics of the ground material in is very important in a ground investigation. Casagrande classified soil using the material properties of soils. The liquid-plastic limit test is useful for obtaining basic information of soil, and is an effective method for classifying silt and clay, as well as the material properties, such as shear strength, shrinkage, and expansion. Unlike the liquid limit test, the plasticity limit test is due to the ambiguity of the test procedure. Many geotechnical engineers and scholars have questioned the test results. In this study, a new plasticity limit method was used to compare with the thread rolling method with kaolinite, ilite and bentonite at a certain ratio, and samples were collected from the west coast of Korea. As a result of the comparison, the test value of the new test method showed high reproducibility because the error range of the test value of the conventional thread rolling test was only 10% but the error range of the new test values decreased to 2%. The difference in the slope of the existing plasticity test values was 0.1519 ~ 0.1925, and the results of the test were similar or coincided with each other. Aone - point method was proposed to make it easier to apply the new test method.

Food Component Characterization of Muscle From Salmon Frame (연어 Frame 육의 식품성분 특성)

  • Heu, Min-Soo;Kim, Hyung-Jun;Yoon, Min-Seok;Park, Do-Yeong;Park, Kwon-Hyun;Kim, Jin-Soo
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.37 no.11
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    • pp.1452-1456
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    • 2008
  • For the effective use of salmon processing by-products, the food components of salmon frame muscle were investigated and compared with those of fillet muscle. The proximate composition of salmon frame muscle was 73.2 g/100 g muscle for the moisture, 76.9 g/100 g dry material for the protein, 15.7 g/100 g dry material for the lipid and 4.1 g/100 g dry material for the ash. pH and volatile basic nitrogen (VBN) content of salmon frame muscle were 6.63 and 16 mg/100 g, respectively. The proximate composition, pH and VBN of salmon frame muscles were similar to those of salmon fillet muscle. The Hunter values of salmon frame muscle were 55.34 for L value, 16.60 for a value, 19.99 for b value and 48.83 for ${\Delta}E$ value, which were different compared to the salmon fillet muscle. The trichloroacetic acid (TCA) soluble-N content of salmon frame muscle was 542 mg/100 g, which was lower than that of salmon fillet muscle. No difference was found in fatty acid composition, total amino acid, calcium, phosphorus contents and sensory evaluation between salmon frame muscle and salmon fillet muscle. These results suggested that muscle from salmon frame could be used as resources for seafood processing.

Electrochemical Properties of Lithium Secondary Battery and the Synthesis of Spherical Li4Ti5O12 Powder by Using TiCl4 As a Starting Material (TiCl4를 출발원료로한 구형 Li4Ti5O12 분말합성 및 리튬이차 전지특성)

  • Choi, Byung-Hyun;Ji, Mi-Jung;Kwon, Yong-Jin;Kim, Eun-Kyung;Nahm, Sahn
    • Korean Journal of Materials Research
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    • v.20 no.12
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    • pp.669-675
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    • 2010
  • One of the greatest challenges for our society is providing powerful electrochemical energy conversion and storage devices. Rechargeable lithium-ion batteries and fuel cells are among the most promising candidates in terms of energy and power density. As the starting material, $TiCl_4{\cdot}YCl_3$ solution and dispersing agent (HCP) were mixed and synthesized using ammonia as the precipitation agent, in order to prepare the nano size Y doped spherical $TiO_2$ precursor. Then, the $Li_4Ti_5O_{12}$ was synthesized using solid state reaction method through the stoichiometric mixture of Y doped spherical $TiO_2$ precursor and LiOH. The Ti mole increased the concentration of the spherical particle size due to the addition of HPC with a similar particle size distribution in a well in which $Li_4Ti_5O_{12}$ spherical particles could be obtained. The optimal synthesis conditions and the molar ratio of the Ti 0.05 mol reaction at $50^{\circ}C$ for 30 minutes and at $850^{\circ}C$ for 6 hours heat treatment time were optimized. $Li_4Ti_5O_{12}$ was prepared by the above conditions as a working electrode after generating the Coin cell; then, electrochemical properties were evaluated when the voltage range of 1.5V was flat, the initial capacity was 141 mAh/g, and cycle retention rate was 86%; also, redox reactions between 1.5 and 1.7V, which arose from the insertion and deintercalation of 0.005 mole of Y doping is not a case of doping because the C-rate characteristics were significantly better.

Analysis of Characterization on Ancient Ink Stick (고대 먹의 특성 분석)

  • Nam, Tae-Gwang;Shin, Soo-Jeong;Park, Won-Kyu;Kim, Byung-Ro
    • Journal of Conservation Science
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    • v.28 no.2
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    • pp.165-173
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    • 2012
  • In this work, scientific and systematic analysis was conducted for finding out the methods and techniques of ancient ink stick making. Analysis the ancient ink stick on ancient documents and wooden writing as letter or painting, we concluded as followings. From the analysis of ancient wood by dendrochronology, wood was cut at 1899, which provided the information on the year of ink stick's made on writing on ancient wood. Single particle size for soot of ancient ink stick was 107 nm for ink on the roof-filling timber in Sinsunwonjeon of Changdeok Palace, compared to 38 to 86 nm on the letter on ancient 12 paper document. Aggregate particle size was 370 nm for ink on the roof-filling timber in Sinsunwonjeon of Changdeok Palace, but 206 to 318 nm for aggregate particle size on 12 paper documents. There was similar pattern between single particle size and aggregate particle size of soot, which might provide the information of raw material for ancient ink. From infra-red and Raman spectroscopic analysis of sheet of writing on paper or wood, there was severe interference from background material (paper or wood). From Raman spectroscopic analysis of ancient ink carefully separated from ancient wood, spectrum pattern was closer to ink stick made by the soot from pine burning.

Development of Three-Dimensional Finite Element Model for Structural Analysis of Airport Concrete Pavements (공항 콘크리트 포장 구조해석을 위한 3차원 유한요소 모형 개발)

  • Park, Hae Won;Shim, Cha Sang;Lim, Jin Seon;Joe, Nam Hyun;Jeong, Jin Hoon
    • International Journal of Highway Engineering
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    • v.19 no.6
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    • pp.67-74
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    • 2017
  • PURPOSES : In this study, a three-dimensional nonlinear finite element analysis (FEA) model for airport concrete pavement was developed using the commercial program ABAQUS. Users can select an analysis method and set the range of input parameters to reflect actual conditions such as environmental loading. METHODS : The geometrical shape of the FEA model was chosen by considering the concrete pavement located in the third-stage construction site of Incheon International Airport. Incompatible eight-node elements were used for the FEA model. Laboratory test results for the concrete specimens fabricated at the construction site were used as material properties of the concrete slab. The material properties of the cement-treated base suggested by the Federal Aviation Administration(FAA) manual were used as those of the lean concrete subbase. In addition, preceding studies and pavement evaluation reports of Incheon International Airport were referred for the material properties of asphalt base and subgrade. The kinetic friction coefficient between the concrete slab and asphalt base acquired from a preceding study was used for the friction coefficient between the layers. A nonlinear temperature gradient according to slab depth was used as an input parameter of environmental loading, and a quasistatic method was used to analyze traffic loading. The average load transfer efficiency obtained from an Heavy falling Weight Deflectomete(HWD) test was converted to a spring constant between adjacent slabs to be used as an input parameter. The reliability of the FEA model developed in this study was verified by comparing its analysis results to those of the FEAFAA model. RESULTS : A series of analyses were performed for environmental loading, traffic loading, and combined loading by using both the model developed in this study and the FEAFAA model under the same conditions. The stresses of the concrete slab obtained by both analysis models were almost the same. An HWD test was simulated and analyzed using the FEA model developed in this study. As a result, the actual deflections at the center, mid-edge, and corner of the slab caused by the HWD loading were similar to those obtained by the analysis. CONCLUSIONS : The FEA model developed in this study was judged to be utilized sufficiently in the prediction of behavior of airport concrete pavement.

Feasibility Study on the Applicability of Fly Ash as a Barrier Material in Containment System

  • Myung Dong-Il;Lee Gwang-Hun;Lee Seung-Hak;Park Jun-Boum;Kim Hyung-Suk
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2005.04a
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    • pp.202-210
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    • 2005
  • In this study, the fly ash was employed as a possible alternative to the bentonite for its high sorption capacity against cationic heavy metal. To consider the constituents of barrier possibly used, the specimens were mixed with different material contents (fly ash : weathered soil : bentonite), then sorption test was performed. Also the specimens were molded on the wet side of optimum moisture contents like mixing ratio of sorption test and their hydraulic conductivities were measured in flexible-wall permeameters. And to confirm the effect of dissolved cations, the hydraulic conductivity tests were repeated by converting the permeant liquids from water to $Cd^{2+}$ solution. Finally, the Cd-concentration at the effluent was analyzed for 500hrs to compare the effectiveness of each specimen in contaminant retardation. Test results showed that the more the ratio of fly ash increase, the more Kd value increase, and the hydraulic conductivity of weathered soil/bentonite (95:5) mixture was the lowest $(2.9*10^{-8}cm/sec)$, and specimens made of fly ash and fly ash/weathered soil mixtures showed similar hydraulic conductivity. Although the permeant liquid was changed from water to $Cd^{2+}$ solution, the hydraulic conductivity of all specimens except for weathered soil maintained similarly like before. Consequently, the initial breakthrough point of Cd in weathered soil specimen was observed at about 5hrs after the test started while that of fly ash specimens was not observed during the whole test period of 500hrs. The results implied that fly ash had a sufficient retardation capacity against contaminant transport possibly by its high sorption capacity although it showed little effect on the reduction of hydraulic conductivity. Based on the test results, it could be concluded that the fly ash can be possibly used as a suitable barrier material in containment system to attenuate the contaminant transport for its high retardation capacity and for the low cost.

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Germination and Physical Characteristics of Pelleted Sesame Seed with Different Materials (참깨종자의 과위화 재료에 따른 발아 및 물리적 특성)

  • 오명규;김종태;유숙종;고종철;박문수;이중용
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.42 no.5
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    • pp.497-502
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    • 1997
  • A seed pelleting technique was developed for easy handling of small sesame seeds (Chinbaeckkae) and for direct seeding in field. The mixture of pelleting material, binder(sodium alginate) and seeds were dropped in 100mM CaCl$_2$ solution. Charcoal was appeared as a best material among all to make pellets with the characters of hardness, breakdown, destruction rate and germination percentage. Zeolite formed the hardest pellet seeds among the materials and 1~3 seeds contained in a pellet on the treatment of 87g of sesame seeds mixed in 1$\ell$ CaCl$_2$ solution was estimated optimum rate of seed mixure with few appearance of seedless pellet. The moisture absorption rate was greater in the order of peat+charcoal > peat > charcoal > zeolite. Germination percentage of pelleted seeds with charcoal was the best and similar to that of common non-treated seeds. Germination percentage of pelleted seeds by sowing depth of exposing a quarter of pellet seeds on the surface of vermiculite germination test box and were 92% in charcoal treatment and was the best among all released materials.

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Physical Characteristics and Germination of Pelleted Tobacco Seeds Depending on Moulding Materials (성형재료에 따른 담배 펠렛 종자의 물리적 틀성과 발아율)

  • 민태기;박민숙;이석순
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.41 no.5
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    • pp.535-541
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    • 1996
  • A seed pelleting technique was developed for easy handling of small tobacco seeds (variety, NC82) and for direct seeding in temperary planting bed or in field. The mixture of pelleting material, binder and seeds were moulded in cylindrical holes sized 2 mm diameter and 2 mm height in a plastic plate. Bentonite and cellulose powder were good materials to make pellets with CMC as binder, and bentonite formed the hardest pelleted seeds among the materials. The number of the pelleted seeds made with the same weight of the materials was different with materials used and the number of seeds contained in a pelleted seed could be controlled by mixture ratio of materials and seeds. The seedless pellets ranged 6.9 to 16.0% at the ratio of pelleting material and seed for 2~3 seeds in a pellet. The moisture absorption rate at 100% RH and $25^{\circ}C$ was greater in the order of clay < bentonite < cellulose. Germination rates of pelleted seeds with bentonite and cellulose were similar to that of usual seed, but it was significantly lower with clay pelleted seeds.

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