• Elastomers and Composites
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• 제26권4호
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• pp.296-303
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• 1991

Surface of crystalline silica was sequentially reacted with silane(A 187), liquid $rubber(CTBN{\times}8)$, and vinyl monomer(GMA) in existence of TEA(triethylamine) or BPO(benzoyl peroxide). It was mixed with epoxy resin at a ratio $0{\times}60%$ (vol. % ) of total component. For mixtures, viscous properties were investigated experimentally. 1) Coating ratio depended on pH of mixture and quantity of catalyst. 2) Treated silica represented lower viscosity than untreated. 3) Thixotropic index represented best at silica_content $15{\sim}23%$ and showed more large deviation over $120^{\circ}C$. 4) Relative viscosity followed kernel's at $0{\times}10%$ of silica content and get out of Mooney's at more than 15%.

• 한국전기전자재료학회논문지
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• 제20권1호
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• pp.35-40
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• 2007

The new PEI(poly(epoxy-imide))-nano Silica film has been synthesized via in situ CS sol process, and the chemical bonding and microstructure of nano silica dispersed in resin were examined by FT-IR, TAG and SEM. The dielectric properties of these hybrid films over a given temperature and frequency ranges have been studied in a point of view of stable chemical bonding of nano Silica filler. The results from IR spectra and SEM photograph indicated that PEI-Silica hybrid film prepared with nano CS sol process has been synthesized in uniform and chemical bonding. The decrease property of dielectric constant with CS content, tangent loss consistent of given frequency and temperature has been explained in terms of the chain movement of polymer through chemical bonging and size effect of nano silica. The new PEI-CS sol hybrid film with such stable chemical and dielectric properties was expected to be used as a high functional coating application in ET, IT and electric power products.

• 한국세라믹학회지
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• 제45권1호
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• pp.48-53
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• 2008

In order to reduce signal delay in ULSI, an intermetal material of low dielectric constant is required. Ordered mesoporous silica film is proper to intermetal dielectric due to its low dielectric constant and superior mechanical properties. The ordered mesoporous silica film prepared by TEOS (tetraethoxysilane) / MTES (methyltriethoxysilane) mixed silica precursor and Brij-76 surfactant was surface-modified by HMDS (hexamethyldisilazane) treatment to reduce its dielectric constant. HMDS can substitute $-Si(CH_3)_3$ groups for -OH groups on the surface of silica wall. In order to modify interior silica wall, HMDS was treated by two different processes except the conventional spin coating. One process is that film is dipped and stirred in HMDS/n-hexane solution, and the other process is that film is exposed to evaporated HMDS. Through the investigation with different HMDS treatment, it was concluded that surface modification in evaporated HMDS was more effective to modify interior silica wall of nano-sized pores.

• 한국건설순환자원학회논문집
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• 제8권1호
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• pp.105-111
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• 2020

이 연구에서는 화학적 열화 및 생물학적 열화에 노출된 콘크리트의 보호를 위해 개발된 글라이코 캘릭스(glycocalix) 코팅재의 응결속도 및 압축강도 발현에 대한 실리케이트계 급결제 혼입의 영향을 검토하였다. 글라이코 캘릭스 코팅재의 적용처에 따라 제안된 단면 뿜어 붙이기용 및 라이닝 공법용 코팅재 배합에서 실리케이트계 급결제의 첨가량을 10mL/L, 25mL/L 및 40mL/L로 변화하였다. 글라이코 캘릭스 코팅재의 경화속도는 박테리아 고정화 재료 양에 의해서도 영향을 받았는데, 40mL/L의 급결제를 첨가한 단면 뿜어 붙이기 및 라이닝 공법용 배합의 종결시간은 각각 80분 및 318분이었다. 급결제를 첨가한 글라이코 캘릭스 코팅재의 강도 발현은 급결제 첨가량이 증가함에 따라 일반 코팅재에 비해 낮은 결과를 보였다.

• 한국구조물진단유지관리공학회 논문집
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• 제19권6호
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• pp.29-36
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• 2015

본 연구에서는 유황을 폴리머화하여 콘크리트 표면보호재로 활용가능성을 검토하기 위하여 내구성능 및 생물독성 평가를 실시하였다. 평가 결과, 콘크리트 표면보호재의 내화학성능은 산, 알칼리 용액에 대하여 화학저항성이 우수한 것으로 나타났다. 배합조건별 촉진내후성 실험 후 부착강도평가 결과 규사분말 및 플라이애시를 동시에 혼합한 배합에서 가장 우수한 강도특성을 나타내었다. 콘크리트용 표면보호재 시험체의 온냉반복 후에도 모든 배합조건에서 부착강도 1 MPa을 상회하였고, SFS배합에서 가장 높은 부착강도를 나타내었다. 표면보호재를 도포한 콘크리트의 촉진탄산화 및 염소이온침투저항성을 검토한 결과, 규사분말을 채움재로 사용한 표면보호재를 도포한 시험체에서 가장 우수한 내구성능을 나타내었다. 유황폴리머를 콘크리트 표면보호재로 사용시 생물독성 검토를 위해 어독성 실험을 수행한 결과, 유황폴리머는 생물에 미치는 영향은 없는 것으로 나타났다. 표면보호재의 내화학성, 동결융해저항성, 탄산화, 염소이온침투저항성 등을 모두 고려하여 볼 때, 본 연구범위에서는 유황폴리머에 채움재로서 규사분말과 플라이애시를 각각 20%씩 대체하는 것이 적절한 수준인 것으로 판단된다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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• pp.314.2-314.2
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• 2014

To improve the optical and electrical properties of commercialized GaN-based light-emitting diodes (LEDs), many methods are suggested. In recent years, great efforts have been made to improve the internal quantum efficiency and light extraction efficiency (LEE) and promising approaches are suggested using a patterned sapphire substrate (PSS), V-pit embedded LED structures, and silica nanostructures. In this study, we report on the enhancement of photoluminescence (PL) intensity in GaN-based LED structures by using the combination of SiO2 (silica) nanospheres and polystyrene/SiO2 core-shell nanospheres. The SiO2 nanospheres-coated LED structure shows the slightly increased PL intensity. Moreover the polystyrene/SiO2 core-shell nanospheres-coated structure shows the more increase of PL intensity comparing to that of only SiO2 spheres-coated structure and the conventional structure without coating of nanospheres. The Finite-difference time-domain (FDTD) simulation results show corresponding result with experimentally observed results. The mechanism of enhancement of PL intensity using the coating of polystyrene/SiO2 core-shell nanospheres on LED surface can be explained by the improvement in extraction efficiency by both increasing the probability of light escape by reducing Fresnel reflection and by multiple scattering within the core-shell nanospheres.

• 한국분말재료학회지
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• 제19권3호
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• pp.177-181
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• 2012

Copper composite materials have attracted wide attention for energy applications. Especially $CuInS_2$ has a desirable direct band gap of 1.5 eV, which is well matched with the solar spectrum. $CuInS_2$ nanoparticles could make it possible to develop color-tunable $CuInS_2$ nanoparticle emitter in the near-infrared region (NIR) for energy application and bio imaging sensors. In this paper, $CuInS_2$ nanoparticles were successfully synthesized by thermo-decomposition methods. Surface modification of $CuInS_2$ nanoparticles were carried out with various semiconductor materials (CdS, ZnS) for enhanced optical properties. Surface modification and silica coating of hydrophobic nanoparticles could be dispersed in polar solvent for potential applications. Their optical properties were characterized by UV-vis spectroscopy and photoluminescence spectroscopy (PL). The structures of silica coated $CuInS_2$ were observed by transmission electron microscopy (TEM).

• 한국전기전자재료학회논문지
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• 제29권3호
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• pp.168-174
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• 2016

A conductive oxide-based sapphire glass indium tin oxide/metal electrode and the optical coating, through patterning process was studied in excellent optical properties and integrated touch panel has a high strength. Indium tin oxide conductive oxides of the sapphire glass to 0.3 A at DC magnetron sputtering method of 10 min, gas flow Ar 10 Sccm Ar, $O_2$ 1.0 Sccm the formation conditions of the thin film after annealing at $550^{\circ}C$ for 30min was achieved through a 86% transmittance. In addition, the coating 130 nm hollow silica sol-gel was to improve the optical transmittance of the indium tin oxide to 91%. For the measurement by the modeling hollow silica sol by Macleod simulation and calculated the average values of silica part to the presence or absence in analogy to actual. Refractive index value and the actual value of the material on the simulation the transmittance difference is it does not completely match the air region similar to the actual value (transmission) could be confirmed that the measurement is set to a value of between 5 nm and 10 nm.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
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• pp.719-723
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• 2004

Silica coating on ZnS particles with buffer solution has been investigated. Diluted sodium silicate in water was used as the precursor material and it was diluted in water. Sodium silicate was added drop-wise in the continuously stirred suspension of ZnS in the buffer solution at room temperature. Smooth and evenly distributed silica coated ZnS phosphors has been obtained when the pH of buffer solution was 10, the concentration of sodium silicate in water was 20 wt%, firing temperature was 500 $^{\circ}C$.

• 한국고분자학회:학술대회논문집
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• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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• pp.354-354
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• 2006

Alginic acid-silica hydrogel films was prepared for testing as protective coating materials for PTFE OD membranes. Unprotected hydrophobic membranes are subject to wet-out when contacted by surface-active agents. Films were characterised using SEM, XRD, DSC, mechanical strength measurements, and water-swelling measurements. In OD trials using coated membranes, no wet-out occurred over the 15 h duration of three consecutive 5 h OD trials using orange oil-water mixtures. In the case of detergent solutions, the coating afforded protection to the membrane for 4-5 h. In a separate trial, no wet-out occurred when the coated side of the membrane was placed in contact with 1.2 wt % orange oil for 72 hours.