• Title/Summary/Keyword: shrinkage ratio

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Evaluation of Durability and Self-clearing in Concrete Impregnated with Photocatalyst-colloidal Silica (광촉매-분산 실리카 함침 콘크리트의 내구성 및 정화성능 평가)

  • Kim, Hyeok-Jung;Kim, Young-Kee;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.22 no.5
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    • pp.47-54
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    • 2018
  • Concrete undergoes various deterioration on surface. Impregnant with silicate is usually applied to concrete surface and forms insoluble hydrates, which can provide many engineering advantages. In the work, concrete impregnated with colloidal silicate is used for durability enhancement in surface and self-clearing performance is evaluated with photocatalyst-$TiO_2$ spraying. For the work, various tests are performed both for strength evaluation and durability evaluation such as absorption ratio, drying shrinkage, chloride penetration, sulfate resistance, and freezing/ thawing action. Furthermore, removal and self-clearing performance are evaluated with Acetaldehyde decomposition and Methylene blue decolorization. Through silicate impregnation and photocatalyst spraying, the impregnated concrete can have not only durability enhance but also self-clearing performance.

A Study on the Fabrication and Mechanical Properties of $WC-Co-Al_2O_3$ Ceramic Composites Using WC Powders Synthesized by SHS Method and Commercial WC Powders (SHS 화학로법에 의해 합성된 WC 분말과 상용 WC 분말을 이용한 $WC-Co-Al_2O_3$ 세라믹 복합체의 제조 및 그 기계적 특성에 관한 연구)

  • Lee, K.R.;Cho, D.H.;Lee, H.B.;Park, S.
    • Journal of the Korean Ceramic Society
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    • v.32 no.12
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    • pp.1392-1400
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    • 1995
  • WC-10wt%Co-Al2O3 ceramic composites, using both the SHS (Self-propagating High Temperature Synthesis) synthesized WC powder method and commercial WC powder, were prepared by varing WC-Co/Al2O3 vol% ratio and sintering temperature (1350℃∼1650℃) for 1 hr in Ar atmosphere. Mechanical characterization has been investigated by Instron meterial testing system and Vicker's hardness test. Compositional and structural chracterizations were carried out by energy-dispersive analysis of X-ray (EDAX) data and scanning electron microscope (SEM). Electrical characterization was carried out by the electrical resistivity measurement using 4-point probe method. As sintering period increased and Al2O3 contents decreased in WC-10wt%Co-Al2O3 ceramic composite, shrinkage and relative density increased, resulting in maximum values at 1600℃. Also the major matrix phase changed with increasing Al2O3 content from 0 to 100 vol%. It was also identified by SEM, EDAX, and electrical resistivity measurement. Based on the results of analysis of flexural strength, toughness and hardness, the mechanical properties of WC-10wt%Co-Al2O3 ceramic composites using the SHS synthesized WC powder were better than those WC-10wt%Co-Al2O3 ceramic composites using commercial WC powder because WC-10wt%Co-Al2O3 ceramic composites using the SHS synthesized WC powder were sintered very well due to small initial particle size. By the addition of 40 vol% Al2O3 [60(WC=10wt%Co)-40Al2O3], it was possible to obtain a proper candidate as a superalloy.

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Quality of High Volume Blast Furnace Slag Mortar Depending on Desulfurization Gypsum Treating Methods and Fine Aggregate Type (탈황석고의 가공법 및 잔골재종류 변화에 따른 고로슬래그 미분말 다량 치환 모르타르의 품질 특성)

  • Han, Cheon-Goo;Lee, Dong-Yun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.2
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    • pp.157-164
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    • 2016
  • In this research, based on the condition of using desulfurization gypsum(FGD) as a stimulator for high-volume blast furnace slag cement mortar, sieving and heating process methods of removing activated carbon in FGD were compared with the non-processed FGD and recycled and natural fine aggregates were compared for suitable aggregate to be used. According to the result of experiment, sieving with 0.3mm was more efficient than $500^{\circ}C$ heating for processing the FGD, and recycled fine aggregate showed more favorable result than natural fine aggregate at the FGD content was 5 to 10%. On the other hand, the mortar mixture including recycled fine aggregate had a high drying shrinkage, and absorption ratio, and thus specific limitations on applying recycled fine aggregate should be required.

Effect of Curing Conditions on the Mechanical Properties of Strain-Hardening Cement Composite (SHCC) (양생조건에 따른 변형경화형 시멘트 복합체의 역학적 특성)

  • Yun, Hyun-Do;Kim, Sun-Woo;Kim, Yong-Cheol;Jeon, Esther;Kim, Yun-Su;Ji, Sang-Kyu
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.909-912
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    • 2008
  • Fiber is an important ingredient in strain-hardening cementitious composite (SHCC), which can control fracture of cementitious composite by bridging action. The properties of reinforcing fiber, as tensile strength, aspect ratio and elastic modulus, have great effect on the fracture behavior of SHCC. But SHCC has serious problem as drying shrinkage because silica powder is used to make SHCC in order to improve bond strength between reinforcing fibers and cement matrix. Therefore, curing method (period and temperature) is very important for SHCC to show high tensile performance. a variety of experiments have being performed to access the performance of SHCC recently. This research emphasis is on the mechanical properties of SHCC made in Polyvinyl alcohol (PVA), Polyethylene (PE) fibers and steel cord (SC), and how curing method affects the composite property, and ultimately its strain-hardening performance.

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Optimization of an Injection Molding Process for Polycarbonate Car Switch Buttons Using the Taguchi Method (실험계획법에 의한 폴리카보네이트 차량 스위치 버튼의 사출성형공정 최적화)

  • Kim, Cheol;Park, Jaewoo
    • Composites Research
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    • v.29 no.1
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    • pp.7-15
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    • 2016
  • The quality of polymeric automotive parts depends highly on an injection molding process, which causes various defects, such as warpage, sink marks, weld lines, shrinkage, residual stress, etc. This study is to determine the optimum processing parameters, such as packing pressure, mold temperature, melting temperature, and packing time for the manufacture of polycarbonate buttons in cars on the basis of FEM, the Taguchi method, and analysis of variance (ANOVA). As a result, the optimum processing parameters of buttons made of polycarbonate material were obtained as follows: 140 MPa of packing pressure, $105^{\circ}C$ of mold temperature, $292.5^{\circ}C$ of melting temperature and 1 second of packing time. A gain of S/N (signal to noise) ratio, 10.2, was obtained with the optimum values. Moreover, the melting temperature was found to be the most significant factor followed by the mold temperature.

Recrystallized poly-Si TFTs on metal substrate (금속기판에서 재결정화된 규소 박막 트랜지스터)

  • 이준신
    • Electrical & Electronic Materials
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    • v.9 no.1
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    • pp.30-37
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    • 1996
  • Previously, crystallization of a-Si:H films on glass substrates were limited to anneal temperature below 600.deg. C, over 10 hours to avoid glass shrinkage. Our study indicates that the crystallization is strongly influenced by anneal temperature and weakly affected by anneal duration time. Because of the high temperature process and nonconducting substrate requirements for poly-Si TFTs, the employed substrates were limited to quartz, sapphire, and oxidized Si wafer. We report on poly-Si TFT's using high temperature anneal on a Si:H/Mo structures. The metal Mo substrate was stable enough to allow 1000.deg. C anneal. A novel TFT fabrication was achieved by using part of the Mo substrate as drain and source ohmic contact electrode. The as-grown a-Si:H TFT was compared to anneal treated poly-Si TFT'S. Defect induced trap states of TFT's were examined using the thermally stimulated current (TSC) method. In some case, the poly-Si grain boundaries were passivated by hydrogen. A-SI:H and poly-Si TFT characteristics were investigated using an inverted staggered type TFT. The poly -Si films were achieved by various anneal techniques; isothermal, RTA, and excimer laser anneal. The TFT on as grown a-Si:H exhibited a low field effect mobility, transconductance, and high gate threshold voltage. Some films were annealed at temperatures from 200 to >$1000^{\circ}C$ The TFT on poly-Si showed an improved $I_on$$I_off$ ratio of $10_6$, reduced gate threshold voltage, and increased field effect mobility by three orders. Inverter operation was examined to verify logic circuit application using the poly Si TFTs.

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Extract of Broussometia kazinoki Induces Apoptosis Through the Mitochondria/Caspase Pathway in A549 Lung Cancer Cells (A549세포에서 닥나무 추출물의 미토콘드리아/Caspase 경로를 통한 Apoptosis 유도작용)

  • Kim, Tae Hyeon;Kim, Dan Hee;Mun, Yeun Ja;Lim, Kyu Sang;Woo, Won Hong
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.30 no.3
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    • pp.150-156
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    • 2016
  • Extract of Broussometia kazinoki Rhizodermatis has been traditionally used for geopoong, diuresis, hwalhyeol. In the present study, the apoptotic effect of methanol extract of Broussometia kazinoki (MBK) were investigated. Cell viability of A549 cells was measured by MTT assay. Apoptosis-related protein and MAPK protein levels were measured by Western blot. Chromatin condensation of A549 cells was stained with DAPI. MBK inhibited cell proliferation of A549 cell. Based on DAPI staining, MBK-treated cells manifested nuclear shrinkage, condensation and fragmentation. Treatment of A549 cells with MBK resulted in activation of the caspase-3, -8, -9 and cleavage of poly ADP-ribose polymerase (PARP). In the upstream, MBK increased the expressions Bax and Bak, decreased the expression of Bcl-2, and augmented the Bax/Bcl-2 ratio. MBK-induced apoptosis was accompanied by sustained phosphorylation of JNK, p38 MAPK and apoptosis signal-regulating kinase (ASK)-1. These results suggest that MBK induced apoptosis in A549 cells through Bcl-2 family protein-mediated mitochondria/caspase-3 dependent pathway. In addition, MBK increased the activation of ASK-1, which are critical upsteam signals for JNK/p38 MAPK activation in A549 cancer cells.

Mechanical properties and microstructures of stabilised dredged expansive soil from coal mine

  • Chompoorat, Thanakorn;Likitlersuang, Suched;Sitthiawiruth, Suwijuck;Komolvilas, Veerayut;Jamsawang, Pitthaya;Jongpradist, Pornkasem
    • Geomechanics and Engineering
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    • v.25 no.2
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    • pp.143-157
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    • 2021
  • Expansive soil is the most predominant geologic hazard which shows a large amount of shrinkage and swelling with changes in their moisture content. This study investigates the macro-mechanical and micro-structural behaviours of dredged natural expansive clay from coal mining treated with ordinary Portland cement or hydrated lime addition. The stabilised expansive soil aims for possible reuse as pavement materials. Mechanical testing determined geotechnical engineering properties, including free swelling potential, California bearing ratio, unconfined compressive strength, resilient modulus, and shear wave velocity. The microstructures of treated soils are observed by scanning electron microscopy, x-ray diffraction, and energy dispersive spectroscopy to understand the behaviour of the expansive clay blended with cement and lime. Test results confirmed that cement and lime are effective agents for improving the swelling behaviour and other engineering properties of natural expansive clay. In general, chemical treatments reduce the swelling and increase the strength and modulus of expansive clay, subjected to chemical content and curing time. Scanning electron microscopy analysis can observe the increase in formation of particle clusters with curing period, and x-ray diffraction patterns display hydration and pozzolanic products from chemical particles. The correlations of mechanical properties and microstructures for chemical stabilised expansive clay are recommended.

Influence of Sulfate on Thermodynamic Modeling of Hydration of Alkali Activated Slag (알칼리 활성 슬래그의 열역학적 수화모델링에 대한 황산염의 영향)

  • Lee, Hyo Kyoung;Park, Sol-Moi;Kim, Hyeong-Ki
    • Resources Recycling
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    • v.28 no.1
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    • pp.32-39
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    • 2019
  • The present study investigated hydration of alkali activated slag incorporating sulfate as a form of anhydrite by employing thermodynamic modeling using the Gibbs free energy minimization approach. Various parameters were evaluated in the thermodynamic calculations, such as presence of sulfide, precipitation/dissolution of AFt/AFm phase, and the effect of oxic condition on the predicted reaction. The calculations suggested no significant difference in the void volume and chemical shrinkage, which might influence the performance of the mixtures, in spite of various changes of the parameters. Although the types of hydration products and their amount varied according to the input conditions, their variations were smaller range than that induced by water-to-binder ratio. Moreover, it did not affect the amount of C-(N-)A-S-H which was the most important hydration product.

Eco-friendly Leather Dyeing Using Biomass Wastes(III): Imparting Functionality by Combination Dyeing with Marigold (Tagetes erecta L.) and Hinoki Cypress(Chamaecyparis obtusa) Leave Extracts (생물자원 폐기물을 활용한 친환경 가죽염색(III): 매리골드와 편백나무 잎 추출물의 복합염색에 의한 기능성 부여)

  • Lee, Geonhee;Shin, Younsook
    • Textile Coloration and Finishing
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    • v.31 no.1
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    • pp.1-13
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    • 2019
  • In this study, eco-friendly functional leather was developed by recycling wastes such as eel skin, marigold(Tagetas erecta l.), hinoki cypress(Chamaecyparis obtusa). The hot water extracts of marigold and hinoki cypress leaves were freeze-dried at $-80^{\circ}C$ to prepare colorant powder. The dyeing of eel leather with marigold was carried out to investigate the effects of dyeing conditions, mordanting on dye uptake, color, morphological change, and color fastness. Considering shrinkage of eel leather caused by dyeing, the optimum dyeing conditions were $60^{\circ}C$ of dyeing temperature and 60 min of dyeing time at 1:100 of bath ratio, and color of the dyed eel leather was Y to YR Munsell series. In order to prevent the degradation of leather from microbe, we conducted combination dyeing with marigold and hinoki cypress leave colorants. In this case, the combination dyed eel leathers showed excellent antimicrobial activity with above 99% bacterial reduction rate against S. aurieus and K. pneumoniae. It was confirmed that all of the dyed eel leathers were sufficient to meet the Korean Standard for color fastness of leather products. It can be applied practically for the development of eco-friendly functional leather by utilizing some useful active components extracted from plant resources and by recycling food wastes.