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광촉매-분산 실리카 함침 콘크리트의 내구성 및 정화성능 평가

Evaluation of Durability and Self-clearing in Concrete Impregnated with Photocatalyst-colloidal Silica

  • 김혁중 (한경대학교 산학협력단) ;
  • 김영기 (한경대학교 화학공학과) ;
  • 권성준 (한남대학교 건설시스템공학과)
  • 투고 : 2018.05.02
  • 심사 : 2018.07.06
  • 발행 : 2018.09.01

초록

콘크리트는 장기간 사용환경에 노출되면서 다양한 표면열화과정을 거친다. 실리케이트 기반 함침제는 콘크리트 표면에 적용되어 불용성 수화물을 형성하는데, 이 과정에서 다양한 공학적 장점을 기대할 수 있다. 본 연구는 분산형 실리케이트를 사용하여 표면의 내구성능을 강화하고 이후 광촉매를 분무함으로서 표면 함침된 콘크리트의 자기정화능력을 평가하는 것이다. 이를 위해 실리케이트 함침 콘크리트에 대하여 압축강도 뿐 아니라, 흡수성, 건조 수축, 염소이온저항성, 황산저항성, 동결융해 저항성 등과 같은 내구성 실험이 수행되었다. 또한 아세트 알데이드 및 메틸렌블루 반응 평가를 통하여 독성카스의 제거와 자기정화성능을 평가하였다. 실리케이트 함침 후 광촉매 도포를 함으로서 광촉매의 부착성을 확보할 수 있었으며, 콘크리트의 내구성 개선과 광촉매 고유의 정화성능을 유지할 수 있었다.

Concrete undergoes various deterioration on surface. Impregnant with silicate is usually applied to concrete surface and forms insoluble hydrates, which can provide many engineering advantages. In the work, concrete impregnated with colloidal silicate is used for durability enhancement in surface and self-clearing performance is evaluated with photocatalyst-$TiO_2$ spraying. For the work, various tests are performed both for strength evaluation and durability evaluation such as absorption ratio, drying shrinkage, chloride penetration, sulfate resistance, and freezing/ thawing action. Furthermore, removal and self-clearing performance are evaluated with Acetaldehyde decomposition and Methylene blue decolorization. Through silicate impregnation and photocatalyst spraying, the impregnated concrete can have not only durability enhance but also self-clearing performance.

키워드

참고문헌

  1. Alonso, C., Castellote, M., and Andrade, C. (2002), Chloride threshold dependence of pitting potential of reinforcements, Electrochimica Acta, 47(21), 3469-3481. https://doi.org/10.1016/S0013-4686(02)00283-9
  2. Benoit-Marquie, F., Wilkenhoner, U., and Simon, V. (2000), VOC photodegradation at the gas-solid interface of a $TiO_2$ photocatalyst, photochemistry and photobiology, 132(3), 225-232. https://doi.org/10.1016/S1010-6030(00)00196-9
  3. Dageuji, K., Murasawa, S., and Ibusuki, D. (2000), World of Photocatalyst, Daeyeongsa, 27.
  4. Emmons, P. H., (1994), Concrete Repair and Maintenance Illustrated, R.S. Means Company.
  5. EX : Korea Expressway Corporation Research Institute. (2006). Increasing the Quality of Recycled Aggregate by Surface Treatment and Durability evaluation of concrete, Gyeonggi-do, Korea, 227-228.
  6. Kim, H. J. (2010), A Study on the Development of Functional Concrete Using Permeating Agents and Photocatalyst, Ph. D. dissertation, Jeolabuk-do, Jeonbuk University, Civil Engineering.
  7. Kim, H. W., Jung, B. W., Park, J. Y., Choi, Y. J., and Kim, W. J. (2001), A basic study on development of photocatalystic block to purify polluted air, Korea Concrete Institute, 13(2), 1117-1122.
  8. Kwon, S. J. (2017), Current Trends of Durability Design and Government Support in South Korea: Chloride Attack, Sustainability, 2017(9), 1-18.
  9. Kwon, S. J. (2017), Service life variation in RC columns exposed to chloride attack: a time-dependent deterministic and probabilistic examination, International Journal of Sustainable Building Technology and Urban Development, 2017, 1-14.
  10. Kwon, S. J., Park, S. S., Lee, S. M., and Kim, J. H. (2007), A study on durability improvement for concrete structures using surface impregnant, Journal of Korea Structure Maintenance Institute, 11(4), 79-88.
  11. Lee, W. A., Yang, J., Ryu, J. S., and Lee, J. R. (2001), A Study on the Development for Photocatalytic Concrete with Waste Gas Reduction and Self-cleaning, Korea Concrete Institute, 13(2), 265-270.
  12. Maekawa, K., Inhida, T., and Kishi, T. (2003), Multi-Scale Modeling of Concrete Performance, Journal of advanced Concrete Technolgy, 1(2), 91-126. https://doi.org/10.3151/jact.1.91
  13. Moon, H. Y., Kim, S. S., Ahn, T. S., and Kim, H. S. (1999), Effect of Concrete Coating Materials for the Improvement of Concrete Durability, Korea Concrete Institute, 11(1), 433-436.
  14. Moon, H. Y., Shin, D. G., and Choi, D. S. (2007), Evaluation of the durability of mortar and concrete applied with inorganic coating material and surface treatment system, Construction and Building Materials, 21(2), 362-369. https://doi.org/10.1016/j.conbuildmat.2005.08.012
  15. Park, H. (2005), A Study on the Removal Characteristics of Photocatalytic Titania produced by Anodic Oxidation, Masters course. dissertation, Seoul, Kyounggi University, Department of Chemical Engineering, 32-33.
  16. Park, J. Y., Kim, H. W., Jung, B. W., Choi, Y. J., Kim, Y. H., and Kim, W. J. (2001), An Experimental Study on the $NO_x$ Removal Properties of photocatalystic paint, Korea Concrete Institute, 13(2), 1123-1128.
  17. Park, R. S. (2007), A Study on the Characteristics of Concrete Using the Surface Coated Recycled Aggregate, Ph. D. dissertation, Jeolabuk-do, Jeonbuk University, Civil Engineering, 36-37.
  18. Park, S. S., Kim, Y. Y., Lee, B. J., and Kwon, S. J. (2014), Evaluation of Concrete Durability Performance with Sodium Silicate Impregnants, Advances in Materials Science and Engineering, 2014, 1-11.
  19. Park, S. S., Kwon, S. J., and Jung, S. H. (2012), Analysis technique for chloride penetration in cracked concrete using equivalent diffusion and permeation, Construction and Building Materials, 29, 183-192. https://doi.org/10.1016/j.conbuildmat.2011.09.019
  20. Pi, U. H. (2005), Study of behavior of strength and clean of air condition using photocatalyst($TiO_2$) for concrete, Masters course, dissertation, Daegu, Gyeongbuk National University, Department of Construction Engineering, 66-67.
  21. Sano, T., Negishi, N., Takeuchi, K., and Matsuzawa, S. (2004), Degradation of toluene and acetaldehyde with Pt-loaded $TiO_2$ catalyst and parabolic trough concentrator, Association for Applied Solar Energy, 77(5), 543-552.
  22. Thomas, M. D. A., and Bamforth, P. B. (1999), Modeling chloride diffusion in concrete: Effect of fly ash and slag, Cement and Concrete Research, 29(4), 487-495. https://doi.org/10.1016/S0008-8846(98)00192-6
  23. Yamaguchi, S. (2004), Decomposition of Gaseous Volatile Organic Chloride Compounds, Journal of environmental hi-technology, 12(2), 32-38.
  24. Yang, K. H., Song, J. K., and Song, K. I. (2013), Assessment of $CO_2$ reduction of alkali-activated concrete, Journal of Cleaner Production, 39, 265-272. https://doi.org/10.1016/j.jclepro.2012.08.001

피인용 문헌

  1. 제올라이트와 활성 황토를 혼입한 시멘트 모르타르의 광촉매(TiO2) 코팅에 따른 NOx 저감성능평가 vol.8, pp.4, 2018, https://doi.org/10.14190/jrcr.2020.8.4.483