• Title/Summary/Keyword: shear-thickening

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Drag Reduction Characteristics of Surfactant by a Rotating Disk Apparatus (회전원판장치를 이용한 계면활성제의 마찰저항감소)

  • Kim, C.A.;Choi, H.J.;Yoon, H.K.;Park, S.Y.;Kim, J.Y.
    • Applied Chemistry for Engineering
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    • v.9 no.1
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    • pp.149-154
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    • 1998
  • The characteristics of drag reduction and rheological behaviors were investigated using cationic surfactants, whose microstructures are known to change when concentration of the surfactant exceeds CMC. The firstly formed spherical micelles change to rodlike or disklike micelles because of packing between surfactants micells, and of thermodynamic perference. The drag reduction becomes significant when the concentration increases over this micellar transient point. Drag reductions were measured as a function of concentration, and rheological characteristics of the surfactant were further investigated to understand the correlation between their rheological properties and drag reduction. Micelles show the non-Newtonian behavior, and shear thickening behaviors were observed due to the structural development. In addition, structural developments were determined by adding the counter-ion in case of DOBON-G.

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Temperature and Timing of the Mylonitization of the Leucocratic Granite in the Northeastern Flank of the Taebaeksan Basin

  • Kim, Hyeong-Soo
    • Journal of the Korean earth science society
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    • v.33 no.5
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    • pp.434-449
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    • 2012
  • The Mesozoic leucocratic granite in the northeastern margin of the Taebaeksan Basin was transformed to protomylonite and mylonite. Mylonitic foliations generally strike to NWWNW and dip to NE with the development of a sinistral strike-slip (top-to-the-northwest) shear sense. Grain-size reduction of feldspar in the mylonitized leucocratic granite occurred due to fracturing, myrmekite formation and neocrystallization of albitic plagioclase along the shear fractures of K-feldspar porphyroclasts. As the deformation proceeded, compositional layering consisting of feldspar-, quartz- and/or muscovite-rich layers developed in the mylonite. In the feldspar-rich layer, fine-grained albitic plagioclase and interstitial K-feldspar were deformed dominantly by granular flow. On the other hand, quartz-rich layers containing core-mantle and quartz ribbons structures were deformed by dislocation creep. Based on calculations from conventional two-feldspar and ternary feldspar geothermometers, mylonitization temperatures of the leucocratic granite range from 360 to $450^{\circ}C$. It thus indicates that the mylonitization has occurred under greenschist-facies conditions. Based on the geochemical features and previous chronological data, the leucocratic granite was emplaced during the Middle Jurassic at volcanic arc setting associated with crustal thickening. And then the mylonitization of the granite occurred during the late Middle to Late Jurassic (150-165 Ma). Therefore, the mylonitization of the Jurassic granitoids in the Taebaeksan Basin was closely related to the development of the Honam shear zone.

Surface Properties of Silane-Treated Titania Nanoparticles and Their Rheological Behavior in Silicone Oil

  • Hwang, Joon-Sik;Lee, Jeong-Woo;Chang, Yoon-Ho
    • Macromolecular Research
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    • v.13 no.5
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    • pp.409-417
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    • 2005
  • The surface of rutile titania nanoparticles was chemically modified by reacting with alkoxy silane. The surface and rheological properties in silicone oil having a wide range of viscosity were investigated. Total surface free energy($\gamma_S$) of the titania particles decreased from 53.12 to 26.94 mJ/$m^2$ as the silane used for surface treatment was increased from 0 to 5.0 wt$\%$. The surface free energy of neat silane was 25.5 mJ/$m^2$, which is quite close to that oftitania particles treated with 5.0 wt$\%$ silane. Due to the hydrophobic nature oftreated-titania, the contact angle was accordingly higher for polar solvent in the order of water>ethylene glycol> formamide>$\alpha$-bromonaphthalene. In sum of rheological behavior, as the applied shear stress or viscosity of the silicone oil increased, the titania particles tend to form layers and agglomerated clusters, showing shear-thinning and shear-thickening behaviors, sequentially. A good dispersion of discrete titania particles obeying a Newtonian flow behavior was achieved at a surface energy or low concentration of silane-treated titania particles in hydrophobic silicone oil.

Analysis of effects of shrinkage of concrete added to widen RC girder bridge

  • Madaj, Arkadiusz;Siekierski, Wojciech
    • Computers and Concrete
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    • v.23 no.5
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    • pp.329-334
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    • 2019
  • Traffic flow capacity of some old road bridges is insufficient due to limited deck width. In such cases bridge deck widening is a common solution. For multi-girder reinforced concrete (RC) bridges it is possible to add steel-concrete composite girders as the new outermost girders. The deck widening may be combined with bridge strengthening thanks to thickening of the existing deck slab. Joint action of the existing and the added parts of such bridge span must be ensured. It refers especially to the horizontal plane at the interface of the existing slab and the added concrete layer as well as to the vertical planes at the external surfaces of the initially outermost girders where the added girders are connected to the existing bridge span. Since the distribution of the added concrete is non-uniform in the span cross-section the structure is particularly sensitive to the added concrete shrinkage. The shrinkage induces shear forces in the aforementioned planes. Widening of a 12 m long RC multi-girder bridge span is numerically analysed to assess the influence of the added concrete shrinkage. The analysis results show that: a) in the vertical plane of the connection of the added and the existing deck slab the longitudinal shear due to the shrinkage of the added concrete is comparable with the effect of live load, b) it is necessary to provide appropriate longitudinal reinforcement in the deck slab over the added girders due to tension induced by the shrinkage of the added concrete.

The Effects of Flow Wave form on the Flow Characteristics in Tapered Vascular Grafts (유량 파형이 데이퍼형 인조혈관 유동에 미치는 영향)

  • Lee, H. C.;Seok, K. W.;Jon, C. W.;Lee, J.;Lee, Y. S.;Kim, S. H.
    • Journal of Biomedical Engineering Research
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    • v.17 no.3
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    • pp.337-346
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    • 1996
  • The patency of small size vascular grafts is poor, and the blood flow characteristics in the artery graft anastomosis are suspected as one of the important factors influencing intimal hyperplasia. Disturbed flow patterns caused by sixte and compliance mismatch generate unfavorable flow environment which promotes intimal thickening. Tapered vascular yuts are suggested in order to reduce sudden expansion near the anastomosis. The photochromic flow visualization method is used to measure the flout fields in the end-to-end anastomosis model under the carotid and femoral artery flow wave form. The results show that flow disturbance near the anastomosis is diminished in the tapered grafts comparing to the tubular graft. As the divergent ang1e decreases, we can reduce the low and oscillatory wall shear stress zone which is prone to intimal hyperplasia. The flow wave form effects the wall shear rate dis- tribution significantly. The steep deceleration and back flow in the femoral flow wAve form cause low mean wall shear rate and high oscillatory shear index.

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Dilutant flow characteristics model of coarse particle suspensions with uniform size distribution

  • Ookawara, Shinichi;Ogawa, Kohei
    • Korea-Australia Rheology Journal
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    • v.15 no.1
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    • pp.35-41
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    • 2003
  • It is expected that particle size distribution of any portion obtained through screening, is of more uniform than that of the original mixture, typically following such as log-normal, Rosin-Rammler distributions and so on. In this study, therefore, a new relation between parameters of the uniform distribution and flow characteristics of the coarse particle suspensions is derived based on the continuous polydisperse model (Ookawara and Ogawa, 2002b), which is derived from the discrete polydisperse model (Ookawara and Ogawa,2002a). The derived model equation predicts a linear increase of viscosity with shear rate, viz., dilutant flow characteristics. Further, the increase of viscosity is expected to be proportional to the square of volume fraction of particles, and to show the linear dependency on density and average diameter of particles. It is also shown that the uniform distribution model includes additional term that expresses the effect of distribution width. For verification of the model, the experimental results of Clarke (1967) are cited as well as in our previous work for the monodisperse model (Ookawara and Ogawa,2000) since most parameters were varied independently in his work. It is suggested that the newly introduced term expands the applicable range compared with the monodisperse model.

Pulsatile Flow in the Artery with Stenosis (협 부가 있는 동맥 내부에서의 맥동유동)

  • Son, Jeong-Rak;Ju, Sang-U;Seo, Sang-Ho;Sim, Eun-Bo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.1
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    • pp.39-44
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    • 2002
  • The arterial stenosis related to the intimal thickening of the arterial wall is the main cause of many diseases in human cardiovascular system. Hemodynamic behavior of the blood flow is influenced by the presence of the arterial stenosis. In this study, effects of the pulsatile flow, caused by the periodic motion of the heart, on the blood flow and its interaction with the arterial stenosis are analyzed by the FEM-based computational fluid dynamics. As a result, it was found that the characteristics of the pulsatile flow in the artery with stenosis are quite different from those of the steady flow. And, the pulsatile flow condition affects the wall shear stress, which is one of the most important physiological parameters in the hemodynamics.

Cashew Nut Oil: Extraction, Chromatographic and Rheological Characterisation.

  • Vincent Okechuwku ANIDIOBU;Chioma Oluchi ANIDIOBU
    • The Korean Journal of Food & Health Convergence
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    • v.9 no.4
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    • pp.11-18
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    • 2023
  • Oil was extracted from cashew nuts. The physicochemical parameters of the oil were determined. A chromatographic assay of the oil was carried out using Gas Chromatography-Mass Spectrometry. Seventeen compounds were detected: Phenol, Phenol 2-methyl-, Cyclohexene 4, 4-dimethyl-, m-Fluoro-2-diazoacetophenone 4-dimethyl-, Tetradecanoic acid, Phenol 4-octyl-, n-Hexadecanoic acid. Others are 9, 12-Octadecadienoic acid (Z, Z) - methyl ester, Hexadecanoic acid methyl ester, Methyl stearate, Dodecanoic acid methyl ester, 9, 12, 15-Octadecatrienoic acid methyl ester, 9, 12, 15-Octadecatrienoic acid (Z, Z, Z)-, Oleic acid, Octadecanoic acid, Tetracosanoic acid and 9-Octadecenoic acid methyl ester. Among the components are omega three and omega six essential free fatty acids. The rheological profiling and flow properties of cashew nut oil were determined using a Programmable Rheometer. Cashew nut oil exhibits slight dilatant behaviour at the low end of shear rate. The long chain and high molecular weight of its constituents controlled its rheology. Long-chained 9-Octadecenoic acid methyl ester, 9, 12-Octadecadienoic acid (Z, Z) - methyl ester, Tetracosanoic acid and methyl stearate, coupled with their high molecular weights are responsible for the shear thickening effect observed. Two models, Carreau-Yasuda and Ostwald-de Waele Power Law were employed to fit the rheological data. The Carreau-Yasuda model followed well the data.

Functional and Rheological Properties of ${\gamma}$-Polyglutamic Acid Produced by Alkalophilic Alcaligenes sp. (호 알카리성 Alcaligenes sp.가 생산하는 ${\gamma}$-Polyglutamic Acid의 기능성 및 리올로지 특성)

  • 이신영;강태수
    • KSBB Journal
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    • v.10 no.5
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    • pp.547-552
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    • 1995
  • Some functional and rheological properties of the ${\gamma}$-polyglutamic acid(${\gamma}$-PGA) produced from alkalophilic Alcaligenes sp. were investigated. Viscosity synergism with thickening agents, capacities for gelling, entrapig of heavy metals, and flocculability of ${\gamma}$-PGA were not observed, but the relatively good compatability with various polyvalent metallic ins, excellent absorption ability and spinability were observed. The ${\gamma}$-PGA solution showed non-Newtonian flow behavior and exhibited pseudoplastic property with a yield stress at above 1% concentration. The values of flow index for 1% solution were in the range of 0.41∼0.75 showing shear rate dependency and the value of yield stress was 2.28 Pa. The value of consistency index was 0.868 Pa$.$Sn and was exponentially dependent on concentration.

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Full-Scale Blasting Experiment and Field Verification Research Using Shock-Reactive Smart Fluid Stemming Materials (고속충격 반응형 스마트유체 전색재료를 적용한 실 규모 발파실험 및 현장실증 연구)

  • Younghun, Ko;Seunghwan, Seo;Youngjun, Jeong;Sanglim, Noh;Sangho, Cho;Moonkyung, Chung
    • Explosives and Blasting
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    • v.41 no.1
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    • pp.1-18
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    • 2023
  • Stemming is a process applied to blast holes to prevent gases from escaping during detonation. A stemming material helps confine the explosive energy for longer and increases rock fragmentation. This study developed a stemming material based on a shear-thickening fluid (STF) that reacts to dynamic shock. Two blasting experiments were conducted to Field-verify the performance of the STF-based stemming material. In the first experiment, the pressure inside the blast hole was directly measured based on applying the stemming material. In the second field verification, tunnel blasting was performed, and the blasting results of sand stemming and, that of the STF-based stemming case were compared. The measurement results of the pressure in the blast hole showed that when the STF-based stemming material was applied, the pressure at the top of the blast hole was lower than in the sand stemming case, and the stemming ejection was also lower. The results of the field application verify that the excavation performance of the STF-based stemming case in the tunnel blasting was superior to that of the sand stemming case.