• 제목/요약/키워드: self -assembly

검색결과 690건 처리시간 0.031초

해상시위의 기본권성과 집시법적용가능성 고찰 (The Legal Study on the Demonstration-on-sea)

  • 이기춘
    • 한국항해항만학회지
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    • 제29권3호
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    • pp.235-244
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    • 2005
  • 과거 집시법이 예정하지 못했던 우발적 시위, 긴급집회, 해상시위, 자동차전용도로상의 시위 등 시간적, 장소적 특성을 지니는 새로운 유형의 집회시위가 사회적으로 문제되고 있다. 특히 이 중에서 해상시위에 대하여 집시법을 적용할 수 있는지, 있다면 어떠한 논리를 전개해야 한지 내지 적용할 수 없다면 어떠한 법을 적용해야 한지가 공법영역에서 문제되고 있다. 그 동안 학설은 소극적, 적극적 입장으로 대립하여 왔지만, 해상시위는 장소적 자가결정권에 입각한 헌법상 집회시위자유권의 하나로 보장되어야 한다, 이에 따라 집시법상 집회시위개념은 헌법에 합치되는 방향으로 해석되어야 하므로 해상시위와 같은 집시법상 비전형적 집회에 집시법을 유추적용 한다든지 아니면 경찰관직무집행법과 감은 일반경찰법을 적용하여야 한다간 견해간 설득력이 없다. 그리고 현대적 시위상황에 비추어 해상시위도 소수자보호를 위한 민주주의적 기능을 보유한다는 것을 그려할 때 집시법을 직접 적용하여 규율함이 정당하다.

누적외상성질환 위험 요인의 정량적 평가 및 관리를 위한 점검표 개발 -자동차 조립 작업을 중심으로- (The Development of a Checklist for Quantitative Assessment of Risk Factors and Management of Cumulative Trauma Disorders : Application to Automobile Assembly Lines)

  • 이윤근;김현욱;임상혁;박희석
    • 한국산업보건학회지
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    • 제11권1호
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    • pp.56-69
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    • 2001
  • Objectives : This study was designed to develop and standardize a checklist for ergonomic risk factors, and to provide ergonomic guidelines for managing cumulative trauma disorders (CTDs) in automobile assembly lines. Methods : The Checklist for Ergonomic Risk Factors (CERF-1) was developed based on the results of previous studies, and then modified after performing pilot study. Information on the symptoms possibly related with CTDs was obtained using a self-reported Questionnaire from 465 automobile assembly workers. Their job conditions were examined to assess risk factors through both direct observation and video analysis. Results : Rate of detecting risky job through CERF-1 was 85.6%, and was similar to that (88.8%) by Occupational Safety and Health Adminstration(OSHA) checklist but higher than that (63.7%) by American National Standards Institute(ANSI) Z-365. Relationship of the exposure scores derived from CERF-1 with levels of symptom was greater (r=0.49) than OSHA (r=0.28) and ANSI Z-365 (r=0.22). Considering the relationship, jobs scoring higher than 16 could be classified as the Risk Job. and lower than 16 as the Low Risk Job. Sensitivity and specificity of the Risk Job were 92.5 % and 31.5 %, respectively. Odds ratio (OR) after age adjustment was 5.69 (95 % confidence interval 3.15-10.29) for the Risk Job, and these ORs were significantly different from those of the Low Risk Job. The exposure scores were Quite valid, in that the scores at the main survey were significantly correlated with those at the follow-up survey, as suggested by test-retest(r=0.88) and inter-rater reliability(r=0.80). Conclusions : The CERF-1, developed in this study, will be an efficient tool for evaluation of risk jobs for CTDs in automobile assembly lines, and can be used easily by health care providers.

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SWCNT 다중채널 FET용 표면 프로그램된 APTES와 OTS 패턴을 이용한 공정에 대한 연구 (Programmed APTES and OTS Patterns for the Multi-Channel FET of Single-Walled Carbon Nanotubes)

  • 김병철;김주연;안호명
    • 한국정보전자통신기술학회논문지
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    • 제8권1호
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    • pp.37-44
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    • 2015
  • 본 논문에서 전계효과 트랜지스터 (field effect transistor; FET) 제작을 위한 표면 프로그램된 aminopropylethoxysilane(APTES)와 1-octadecyltrichlorosilane(OTS) 패턴을 이용하여 단일벽 탄소 나노튜브(single-walled carbon nanotube; SWCNT)를 실리콘 기판 위에 선택적으로 흡착시키는 공정방법을 제안하였다. 양성 표면 분자 패턴을 만들기 위해 형성된 APTES 패턴은 많은 양의 SWCNT의 흡착을 위해 제작되었고, OTS 만을 이용한 공정보다 효과적인 SWCNT 흡착이 가능하다. 산화막(silicon dioxide)이 형성된 실리콘 기판 위에 사진공정(photolithography process)을 이용하여 임의의 감광액(photoresist; PR) 패턴이 형성되었다. PR 패턴이 형성된 기판은 헥산 용매를 이용하여 1:500 (v/v)로 희석된 OTS 용액 속에 담가진다. OTS 박막이 표면 전체에 만들어지고, PR 패턴이 제거되는 과정에서 PR 위에 형성되었던 OTS 박막도 같이 제거되어, 선택적으로 형성된 OTS 박막 패턴을 얻을 수 있다. 이 기판은 다시 에탄올 용매를 이용하여 희석된 APTES 용액 속에 담가진다. APTES 박막은 OTS 박막 패턴이 없는 노출된 산화막 위에 형성된다. 마지막으로 이처럼 APTES와 OTS에 의해 표면 프로그램된 기판은 SWCNT가 분산된 다이클로로벤젠(dichlorobenzene) 용액 속에 담가진다. 결과적으로 SWCNT는 양 극성을 띠는(positive charged) APTES 박막 패턴 위에만 흡착된다. 반면 중성O TS 박막 패턴 위에는흡착되지 않는다. 이러한 표면 프로그램 방법을 사용하여 SWCNT는 원하는 영역에 자기 조립시킬 수 있다. 우리는 이 방법을 이용하여 소오스와 드레인 전극사이에 SWCNT가 멀티 채널로 구성된 다중채널 FET를 성공적으로 제작하였다.

Oxide 표면에 Self-Assembly Monolayers를 이용한 전도성 고분자 Poly(3-hexylthiophene)(P3HT) 증착 및 Patterning 연구 (Deposition of Poly(3-hexylthiophene)(P3HT) by Vapor Deposition and Patterning Using Self-Assembled Monolayers)

  • 팽일선;김현호;김성수;이재갑
    • 한국재료학회지
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    • 제18권12호
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    • pp.664-668
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    • 2008
  • Vapor phase polymerization of a conductive polymer on a $SiO_2$ surface can offer an easy and convenient means to depositing pure and conductive polymer thin films. However, the vapor phase deposition is generally associated with very poor adhesion as well as difficulty when patterning the polymer thin film onto an oxide dielectric substrate. For a significant improvement of the patternability and adhesion of Poly(3-hexylthiophene) (P3HT) thin film to a $SiO_2$ surface, the substrate was pre-patterned with n-octadecyltrichlorosilane (OTS) molecules using a ${\mu}$-contact printing method. The negative patterns were then backfilled with each of three amino-functionalized silane self-assembled monolayers (SAMs) of (3-aminopropyl) trimethoxysilane (APS), N-(2-aminoethyl)-aminopropyltrimethoxysilane (EDA), and (3- trimethoxysilylpropyl)diethylenetriamine (DET). The quality and electrical properties of the patterned P3HT thin films were investigated with optical and atomic force microscopy and a four-point probe. The results exhibited excellent selective deposition and significantly improved adhesion of P3HT films to a $SiO_2$ surface. In addition, the conductivity of polymeric thin films was relatively high (${\sim}13.51\;S/cm$).

Performance of self-compacting geopolymer concrete with and without GGBFS and steel fiber

  • Al-Rawi, Saad;Taysi, Nildem
    • Advances in concrete construction
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    • 제6권4호
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    • pp.323-344
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    • 2018
  • The study herein reports the impact of Steel Fiber (SF) and Ground Granulated Blast Furnaces slag (GGBFS) content on the fresh and hardened properties of fly ash (FA) based Self-Compacting Geopolymer Concrete (SCGC). Two series of self-compacting geopolymer concrete (SCGC) were formulated with a constant binder content of $450kg/m^3$ and at an alkaline-to-binder (a/b) ratio of 0.50. Fly ash (FA) was substituted with GGBFS with the replacement levels being 0%, 25%, 50%, 75%, and 100% by weight in each SCGC series. Steel fiber (SF) wasn't employed in the assembly of the initial concrete series whereas, within the second concrete series, an SF combination was achieved by a constant additional level of 1% by volume. Fresh properties of mixtures were through an experiment investigated in terms of slump flow diameter, T50 slump flow time, V-funnel flow time, and L-box height ratio. Moreover, the mechanical performance of the SCGCs was evaluated in terms of compressive strength, splitting tensile strength, and fracture toughness. Furthermore, a statistical analysis was applied in order to judge the importance of the experimental parameters, like GGBFS and SF contents. The experimental results indicated that the incorporation of SF had no vital impact on the fresh characteristics of the SCGC mixtures whereas GGBFS aggravated them. However, the incorporation of GGBFS was considerably improved the mechanical properties of SCGCs. Moreover, the incorporation of SF with the total different quantity of GGBFS replacement has considerably increased the mechanical properties of SCGCs, by close to (65%) for the splitting strength and (200%) for compressive strength.

3-D Hetero-Integration Technologies for Multifunctional Convergence Systems

  • 이강욱
    • 마이크로전자및패키징학회지
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    • 제22권2호
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    • pp.11-19
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    • 2015
  • Since CMOS device scaling has stalled, three-dimensional (3-D) integration allows extending Moore's law to ever high density, higher functionality, higher performance, and more diversed materials and devices to be integrated with lower cost. 3-D integration has many benefits such as increased multi-functionality, increased performance, increased data bandwidth, reduced power, small form factor, reduced packaging volume, because it vertically stacks multiple materials, technologies, and functional components such as processor, memory, sensors, logic, analog, and power ICs into one stacked chip. Anticipated applications start with memory, handheld devices, and high-performance computers and especially extend to multifunctional convengence systems such as cloud networking for internet of things, exascale computing for big data server, electrical vehicle system for future automotive, radioactivity safety system, energy harvesting system and, wireless implantable medical system by flexible heterogeneous integrations involving CMOS, MEMS, sensors and photonic circuits. However, heterogeneous integration of different functional devices has many technical challenges owing to various types of size, thickness, and substrate of different functional devices, because they were fabricated by different technologies. This paper describes new 3-D heterogeneous integration technologies of chip self-assembling stacking and 3-D heterogeneous opto-electronics integration, backside TSV fabrication developed by Tohoku University for multifunctional convergence systems. The paper introduce a high speed sensing, highly parallel processing image sensor system comprising a 3-D stacked image sensor with extremely fast signal sensing and processing speed and a 3-D stacked microprocessor with a self-test and self-repair function for autonomous driving assist fabricated by 3-D heterogeneous integration technologies.

Development and Implementation of a Skill Transfer System for a Self-Tapping Screw-Tightening Operation

  • Matsumoto, Toshiyuki;Doyo, Daisuke;Shida, Keisuke;Kanazawa, Takashi
    • Industrial Engineering and Management Systems
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    • 제10권3호
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    • pp.209-220
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    • 2011
  • Self-tapping screws have some operational peculiarities. In spite of their economical advantage that requires no prior tapping operation, a weakness of self-tapping screw-tightening operations is that screws can easily be tightened at a non-right angle, thus resulting in an improper tightening strength. Increases in outsourced workers have reduced labor costs, but the accompanying high worker fluidity means that new workers are more frequently introduced into factories. It is necessary to train new workers for self-tapping screw-tightening operations, which occupies a considerable portion of ordinary assembly works. The purpose of this study is to develop and implement a skill transfer system for the operation. This study (1) proposes a set of characteristic values for evaluating the quality of the operation and develops a device that can measure these values; (2) proposes criteria for evaluating the resultant quality of the tightening; and (3) develops a skill training system for better work performance. Firstly, sets of characteristic values for evaluating the quality of the operation, namely, torque, vertical pressure forces and horizontal vibration forces, are proposed. A device that can measure these values is developed. Secondly, criteria for evaluating the resultant quality of the tightening are identified, involving tightening torque, maximum vertical pressure and timing, vibration area during the processing and tightening period, and work angle. By using such parameters, workers with the proper aptitude can be identified. Thirdly, a skill training system for the operation is developed. It consists of screwdriver operation training and screw-tightening training with feedback information about the results of the operation. Finally, the validity of the training system is experimentally verified using new operators and actual workers.

Layer-by-Layer 자기조립법에 의한 Poly(ethyiene-alt-maleic anhydride)i Poly(4-vinyl pyrtdine) 다층막 제조 (Fabrication of an Alternating Multilayer Film of Poly(ethylene-alt-maleic anhydride) and Poly(4-vinyl pyridine) by Layer-by-Layer Self-Assembly Method)

  • 이준열;홍숙영
    • 폴리머
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    • 제29권4호
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    • pp.392-398
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    • 2005
  • Layer-by-layer(LbL) 흡착에 의한 poly(ethylene-alt-m미? anhydride) (PEMAh)/poly(4-vinyl pyridine) (P4VP) 자기조립 다층박막을 제조하였다. 자기조립 다층막을 이루는 PEMAh/P4VP 두 고분자 사이의 수소 결합과 정전기적 인력이 다층막을 이루는 원동력이라는 것이 푸리에 변환 적외선(FT-IR) 분광분석에 의해서 확인되었다. 다층막의 균일한 자기조립 과정은 PEMAh/P4VP 이중층막의 적층 수 증가에 따른 UV-vis 스펙트럼의 256 nm에서 나타나는 P4VP 특성 흡수 피크의 선형적 증가에 의해서 확인할 수 있었다. 다층막을 이루는 고분자 전해질 담지 용액의 조건 변화가 다층막 형성에 미치는 영향을 살펴보기 위하여 두 고분자 용액의 농도 및 PEMAh 담지용액의 pH를 변화시키면서 다층막을 제조하였다. 다층막의 두께, 흡착된 고분자 전해질 질량 및 표면 거칠기의 변화를 UV-vis 분광 분석, 수정진동자 미량저울(quartz crystal microbalance;QCM) 및 원자 힘 현미경(atomic force microscopy;AFM)을 이용하여 측정하였다.

Physicochemical Characterization and Carcinoma Cell Interaction of Self-Organized Nanogels Prepared from Polysaccharide/Biotin Conjugates for Development of Anticancer Drug Carrier

  • Park Keun-Hong;Kang Dong-Min;Na Kun
    • Journal of Microbiology and Biotechnology
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    • 제16권9호
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    • pp.1369-1376
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    • 2006
  • Self-organized nanogels were prepared from pullulan/biotin conjugates (PU/Bio) for the development of an effective anticancer drug delivery system. The degree of biotin substitution was 11, 19, and 24 biotin groups per 100 anhydroglucose units of pullulan. The physicochemical properties of the nanogels (PU/Bio1, 2 and 3) in aqueous media were characterized by dynamic light scattering, transmission electron microscopy, and fluorescence spectroscopy. The mean diameter of all the samples was less than 300 nm with a unimodal size distribution. The critical aggregation concentrations (CACs) of the nanoparticles in distilled water were $2.8{\times}10^{-2},\;1.6{\times}10^{-2}$, and $0.7{\times}10^{-2}mg/ml$ for the PU/Bio1, 2, and 3, respectively. The aggregation behavior of the nanogels indicated that biotin can perform as a hydrophobic moiety. To observe the specific interaction with a hepatic carcinoma cell line (HepG2), the conjugates were labeled with rhodamine B isothiocyanate (RITC) and their intensities measured using a fluorescence microplate reader. The HepG2 cells treated with the fluorescence-labeled PU/Bio nanoparticles were strongly luminated compared with the control (pullulan). Confocal laser microscopy also confirmed internalization of the PU/Bio nanogels into the cancer cells. Such results demonstrated that the biotin in the conjugate acted as both a hydrophobic moiety for self-assembly and a tumor-targeting moiety for specific interaction with tumor cells. Consequently, PU/Bio nanogels would appear to be a useful drug carrier for the treatment of liver cancer.

Comparative Study of Tetrahydrothiophene and Thiophene Self Assembled Monolayers on Au(111): Structure and Molecular Orientation

  • Ito, Eisuke;Hara, Masahiko;Kanai, Kaname;Ouchi, Yukio;Seki, Kazuhiko;Noh, Jaegeun
    • Bulletin of the Korean Chemical Society
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    • 제30권8호
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    • pp.1755-1759
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    • 2009
  • Surface structure and molecular orientation of self-assembled monolayers (SAMs) formed by the spontaneous adsorption of tetrahydrothiophene (THT) and thiophene (TP) on Au(111) were investigated by means of scanning tunneling microscopy (STM) and carbon K-edge near edge X-ray absorption fine structure (NEXAFS) spectroscopy. STM imaging revealed that THT SAMs have a commensurate (3 ${\times}\;2\sqrt[]{3}$) structure containing structural defects in ordered domains, whereas TP SAMs are composed of randomly adsorbed domains and paired molecular row domains that can be described as an incommensurate packing structure. The NEXAFS spectroscopy study showed that the average tilt angle of the aliphatic THT ring and $\pi$-conjugated TP ring in the SAMs were calculated to be about $30^o\;and\;40^o$, respectively, from the surface normal. It was also observed that the $\pi$* transition peak in the NEXAFS spectrum of the TP SAMs is very weak, suggesting that a strong interaction between $\pi$-electrons and the Au surface arises during the self-assembly of TP molecules. In this study, we have clearly demonstrated that the surface structure and adsorption orientation of organic SAMs on Au(111) are strongly influenced by whether the cyclic ring is saturated or unsaturated.