• Title/Summary/Keyword: selective catalytic reduction

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Overlook of carbonaceous adsorbents and processing methods for elemental mercury removal

  • Bae, Kyong-Min;Kim, Byung-Joo;Park, Soo-Jin
    • Carbon letters
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    • v.15 no.4
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    • pp.238-246
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    • 2014
  • People have been concerned about mercury emissions for decades because of the extreme toxicity, persistence, and bioaccumulation of methyl Hg transformed from emitted Hg. This paper presents an overview of research related to mercury control technology and identifies areas requiring additional research and development. It critically reviews measured mercury emissions progress in the development of promising control technologies. This review provides useful information to scientists and engineers in this field.

Numerical Study on the Arrangement of AIG for Determining the $NH_3$ Concentration Distribution in the Package Type of Small Scale SCR System (패키지형 소형 SCR 시스템 내 $NH_3$ 농도분포 제어를 위한 AIG의 배치에 관한 전산해석적 연구)

  • Park, Seon-Mi;Chang, Hyuk-Sang;Zhao, Tong
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.5
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    • pp.368-377
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    • 2011
  • A package type of SCR (selective catalytic reduction) system that was proposed for removing the $NO_x$ found in flue gas from the small scale of air pollution sources was evaluated. The efficiency of the SCR system is determined by the proper utilization of catalytic media installed inside of the system, and the proper distribution of flow velocity and $NH_3$ concentration in the flue gas is a crucial factor for using the catalytic media. In this study, the distributions of $NH_3$ concentration were estimated under the various arrays and shapes of AIG at the given gas flow condition. The value of RMS (%) in $NH_3$ concentration is 95.3% at co-current flow (at $0^{\circ}$) injection but it is 90.1% at the condition of counter-current flow (at $120^{\circ}$) condition, which implies the counter-current injection is more favorable. By rearranging the $NH_3$ injection flow rates based on the distribution of velocity and $NH_3$ distribution in basic calculation, the value of RMS (%) in $NH_3$ concentration was reduced to 62.8%. The enhanced effect of $NH_3$ mixing by the combined effect of arrays and shapes are complied in the study.

An Experimental Study on $NO_x$ Reduction Efficiency and $NH_3$ Conversion Efficiency under Various Conditions of Reductant Injection on SCR and AOC (SCR 촉매와 AOC 촉매에서 환원제 분사에 따른 $NO_x$ 저감효율과 $NH_3$ 변환효율에 관한 실험적 연구)

  • Dong, Yoon-Hee;Choi, Jung-Hwang;Cho, Yong-Seok;Lee, Seang-Wock;Lee, Seong-Ho;Oh, Sang-Ki;Park, Hyun-Dae
    • Transactions of the Korean Society of Automotive Engineers
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    • v.18 no.5
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    • pp.85-90
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    • 2010
  • As the environmental regulation of vehicle emission is strengthened, investigations for $NO_x$ and PM reduction strategies are popularly conducted. Two current available technologies for continuous $NO_x$ reduction onboard diesel vehicles are Selective Catalytic Reduction (SCR) using aqueous urea and lean $NO_x$ trap (LNT) catalysts. The experiments were conducted to investigate the $NO_x$ reduction performance of SCR system which can control the ratio of $NO/NO_2$, temperature and SV(space velocity), and the model gas was used which is similar to a diesel exhaust gas. The maximum reduction efficiency is indicated when the $NO:NO_2$ ratio is 1:1 and the SV is 30,000 $h^{-1}$ in $300^{\circ}C$. Generally, ammonia slip from SCR reactors are rooted to incomplete conversion of $NH_3$ over the SCR. In this research, slip was occurred in 6cases (except low SV and $NO:NO_2$ ratio is 1:1) after SCR. Among 6 case of slip occurrence, the maximum conversion efficiency is observed when SV is 60,000 $h^{-1}$ in $400^{\circ}C$.

The Selective Catalytic Oxidation of Ammonia: Effect of Physicochemical Properties on Pt/TiO2 (Pt/TiO2 촉매의 물리화학적 특성이 NH3-SCO 반응활성에 미치는 영향)

  • Shin, Jung Hun;Kim, Dong Ho;Hong, Sung Chang
    • Applied Chemistry for Engineering
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    • v.28 no.3
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    • pp.279-285
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    • 2017
  • In this study, the study of the selective catalytic oxidation (SCO) for controlling the $NH_3$ at $200{\sim}350^{\circ}C$ range was investigated. Physicochemical properties of the catalysts were determined using XRD and XPS analysis. In the case of catalytic activity according to thermal treatment condition, the reduction catalyst showed better activity than that of using the calcination catalyst. It was confirmed that the valence state of reduction catalyst was mainly $Pt^{2+}$ and $Pt^0$ as analyzed by XPS. Also, when comparing the reaction activities of $Pt/TiO_2$ catalysts according to the reduction temperature, the $NH_3$ conversion of the catalyst reduced at $700^{\circ}C$ showed the most excellent activity. However, the best activity of $NH_3$ conversion to $N_2$ was obtained for the catalyst reduced at $600^{\circ}C$.

NOx Removal of NH3-SCR Catalysts with Operating Conditions (공정조건에 따른 NH3-SCR용 촉매의 질소산화물 제거특성)

  • Park, Kwang Hee;Cha, Wang Seog
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.11
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    • pp.5610-5614
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    • 2012
  • Performance of catalyst was studied with various operating conditions for selective catalytic reduction of $NO_x$ with $NH_3$. It is confirmed that catalysts containing Mn and Cu have a good efficiency in the usage of oxygen by the $H_2$-TPR analysis. In the case of catalyst #1, $NO_x$ conversion was decrease with the increase of reaction temperature. But in the case of catalyst #2, $NO_x$ conversion was increased and then remained constant with the increase of reaction temperature. This phenomenon is due to the difference of the $NH_3$ oxidation of both catalysts.

The Application of Dump Combustor for Evaluation of After-Treatment System (후처리장치 성능 평가를 위한 Dump Combustor의 활용)

  • Nam, Youn-Woo;Lee, Won-Nam;Oh, Kwang-Chul;Lee, Chun-Beom
    • Journal of the Korean Society of Combustion
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    • v.12 no.3
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    • pp.16-23
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    • 2007
  • Employing an after-treatment system has almost become a mandatory requirement for Diesel vehicles, which results from a reinforced exhaust regulations as the number of vehicles powered by a Diesel engine increases. The Diesel Particulate Filter (DPF) system is considered as one of the most efficient method to reduce particulate matter (PM); however, the improvement of a regeneration performance at any engine operation point presents a considerable challenge by itself. Temperature, gas composition and flow rate of exhaust gas are important parameters in DPF evaluation processes, especially during a regeneration process. Engine dynamometer and segment tester are generally used in DPF evaluation so far. These test methods, however, could not completely evaluate the effect of various parameters on real DPF, such as oxygen concentration, amount of soot and exhaust gas temperatures. The evaluation of DPF systems using a dump combustor has been verified experimentally and this dump combustor system is likely to be appropriate for the DOC (Diesel Oxidation Catalyst) and SCR (Selective Catalytic Reduction) assessments test, too.

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