• Title/Summary/Keyword: secondary materials

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Suppression of Boron Penetration into Gate Oxide using Amorphous Si on $p^+$ Si Gated Structure (비정질 실리론 게이트 구조를 이용한 게이트 산화막내의 붕소이온 침투 억제에 관한 연구)

  • Lee, U-Jin;Kim, Jeong-Tae;Go, Cheol-Gi;Cheon, Hui-Gon;O, Gye-Hwan
    • Korean Journal of Materials Research
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    • v.1 no.3
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    • pp.125-131
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    • 1991
  • Boron penetration phenomenon of $p^{+}$ silicon gate with as-deposited amorphous or polycrystalline Si upon high temperature annealing was investigated using high frequency C-V (Capacitance-Volt-age) analysis, CCST(Constant Current Stress Test), TEM(Transmission Electron Microscopy) and SIMS(Secondary Ion Mass Spectroscopy), C-V analysis showed that an as-deposited amorphous Si gate resulted in smaller positive shifts in flatband voltage compared wish a polycrystalline Si gate, thus giving 60-80 percent higher charge-to-breakdown of gate oxides. The reduced boron penetration of amorphous Si gate may be attributed to the fewer grain boundaries available for boron diffusion into the gate oxide and the shallower projected range of $BF_2$ implantation. The relation between electron trapping rate and flatband voltage shift was also discussed.

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Qualitative Analysis of Patents Concerning Cathode Active Materials for Lithium-Ion Secondary Batteries Based on Layer Structure (층상구조기반의 리튬이차전지용 양극 활물질에 관한 특허정성분석)

  • Kim, Byung-Nam;Lim, Yong-Hwan;Lee, Chul-Tae
    • Applied Chemistry for Engineering
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    • v.26 no.3
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    • pp.294-305
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    • 2015
  • We have quantitatively analyzed 1,294 effective patents on "Quantitative Analysis of Patents Concerning Cathode Active Materials for Lithium-Ion Secondary Batteries Based on Layer Structure" from Korea, USA, Japan, Europe and PCT (WO). The importance of technological and patent values of the aforesaid patents were evaluated by the factors shown in Table 1, and 104 major and 20 core patents were selected in compliance with the evaluation from the patents. The technological flow chart over time regarding the selected major and core patents was prepared, and the applying time and development process of patents, as well as the position of core patents were established on the time scale investigated. Finally, the differentiation plans and patent avoidance strategies for the next technology development, in comparison with the technologies of patents already applied and registered, were suggested.

Sizing Efficiency of AKD in Causticizing Calcium Carbonate Filled Paper

  • Wang, Jian;Liu, Ling;Xu, Yong-Jian
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.46 no.2
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    • pp.1-7
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    • 2014
  • Causticizing calcium carbonate (CCC) is produced as a by-product in the causticization step of the kraft pulping process. It is often calcined in a rotary lime kiln after being dewatered and reused in the causticizing process. But for the China mill, the conventional recycled way is difficult because the CCC is mainly obtained from non-wood pulping materials, which higher silicon content led to serious silicon obstacle. So it is often discarded as solid waste or used in landfill after dewatering and secondary pollution is brought. In order to prevent its secondary pollution, recent years, the CCC is used as a filler in China papermaking industry. In mill trials, the CCC can be used to replace an amount of precipitated calcium carbonate (PCC). Unfortunately, the application scope and dosage of CCC have been limited due to its lower sizing efficiency than PCC. In this study, the reason for the lower sizing efficiency of alkyl ketene dimer (AKD) when CCC was used as a filler was investigated. The results showed that the materials in green liquid, such as insoluble matter in green liquid, silicon and metal ions, were a little influence on the sizing efficiency of AKD. The higher BET and BJH pore volume of the CCC were the main reason for lower sizing efficiency of AKD when it was used as filler.

Coating of two kinds of bioactive glass on Ti6Al4V alloy (Ti6Al4V 합금에 두 종류의 생체활성화 유리 코팅)

  • Kang, Eun-Tae;Lee, Nam-Young;Choi, Hyun-Bin
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.28 no.5
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    • pp.206-210
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    • 2018
  • Two kinds of bioactive glass were coated on the Ti6Al4V alloy by the enameling technique. In order to reduce the thermal stress due to the difference in expansion coefficient with the alloy with the secondary coating forming hydroxyapatite, the difference in expansion coefficient between the alloy and the two glasses was adjusted at $2{\times}10^{-6}/^{\circ}C$ intervals. FE-SEM and EDS analysis showed that good adhesion was formed between the Ti6Al4V alloy and the primary coating by diffusion bonding. After immersion in SBF solution, it was confirmed from FT-IR that hydroxycarbonate apatite formed in the secondary coating was not different from bulk bioactive glass.

Electrochemical Characteristics of Metal Coated Graphite for Anodic Active Material of Lithium Secondary Battery (금속 코팅된 흑연 입자로 제조된 전극의 전기화학적 특성)

  • Choi, Won-Chang;Lee, Joong-Kee;Byun, Dong-Jin;Cho, Byung-Won
    • Journal of the Korean Electrochemical Society
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    • v.6 no.2
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    • pp.103-112
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    • 2003
  • Various kinds of metals were coated on synthetic graphite in order to investigate the relationship between film characteristics and their electrochemical performance. Gas suspension spray coating method was employed for the coating of synthetic graphite. In our experimental range, all of the metal coated synthetic graphite showed the higher capacity than that of raw material at high C-rate mainly due to decrease in impedance of passivation film. In cyclic voltammetry experiments, silver-coated and tin-coated graphite anodes found the lithium-alloy reaction. Considering smaller amount of metal coating, the most increase in discharge capacity was caused by improvement of conductivity of the electrode. When single-component metal was coated, silver-coated graphite anode exhibited the highest discharge capacity and better cycleability. Double components of silver-nickel coated active material showed the highest discharge capacity, rate capability and the best cycle performance in the range of our experiments.

Probing α/β Balances in Modified Amber Force Fields from a Molecular Dynamics Study on a ββα Model Protein (1FSD)

  • Yang, Changwon;Kim, Eunae;Pak, Youngshang
    • Bulletin of the Korean Chemical Society
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    • v.35 no.6
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    • pp.1713-1719
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    • 2014
  • 1FSD is a 28-residue designed protein with a ${\beta}{\beta}{\alpha}$ motif. Since this protein displays most essential features of protein structures in such a small size, this model protein can be an outstanding system for evaluating the balance in the propensity of the secondary structures and the quality of all-atom protein force fields. Particularly, this protein would be difficult to fold to its correct native structure without establishing proper balances between the secondary structure elements in all-atom energy functions. In this work, a series of the recently optimized five amber protein force fields [$ff03^*$, $f99sb^*$-ildn, ff99sb-${\phi}^{\prime}$-ildn, ff99sb-nmr1-ildn, ff99sb-${\Phi}{\Psi}$(G24, CS)-ildn] were investigated for the simulations of 1FSD using a conventional molecular dynamics (MD) and a biased-exchange meta-dynamics (BEMD) methods. Among those tested force fields, we found that ff99sb-nmr1-ildn and ff99sb-${\Phi}{\Psi}$(G24, CS)-ildn are promising in that both force fields can locate the native state of 1FSD with a high accuracy (backbone rmsd ${\leq}1.7{\AA}$) in the global free energy minimum basin with a reasonable energetics conforming to a previous circular dichroism (CD) experiment. Furthermore, both force fields led to a common set of two distinct folding pathways with a heterogeneous nature of the transition state to the folding. We anticipate that these force fields are reasonably well balanced, thereby transferable to many other protein folds.

Degradation Mechanism of MoxW1-xSi2 Heating Elements Fabricated by SHS Process (SHS 공정에 의해 제조된 MoxW1-xSi2 발열체의 열화메커니즘)

  • Lee, Dong-Won;Lee, Sang-Hun;Kim, Yong-Nam;Lee, Sung-Chul;Koo, Sang-Mo;Oh, Jong-Min
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.10
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    • pp.631-636
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    • 2017
  • The degradation mechanism of $Mo_xW_{1-x}Si_2$ ultrahigh-temperature heating elements fabricated by self-propagating high-temperature synthesiswas investigated. The $Mo_xW_{1-x}Si_2$ specimens (with and without post-annealing) were subjected to ADTs (accelerated degradation tests) at temperatures up to $1,700^{\circ}C$ at heating rates of 3, 4, 5, 7, and $14^{\circ}C/min$. The surface loads of all the specimen heaters were increased with the increase in the target temperature. For the $Mo_xW_{1-x}Si_2$ specimens without annealing, many pores and secondary-phase particles were observed in the microstructure; the surface load increased to $23.9W/cm^2$ at $1,700^{\circ}C$, while the bending strength drastically reduced to 242 MPa. In contrast, the $Mo_xW_{1-x}Si_2$ specimens after post-annealing retained $single-Mo_xW_{1-x}Si_2$ phases and showed superior durability after the ADT. Consequently, it is thought that the formation of microcracks and coarse secondary phases during the ADT are the main causes for the degraded performance of the $Mo_xW_{1-x}Si_2$ heating elements without post-annealing.

Secondary School Science Teachers' Perception of Inquiry Learning (탐구 학습에 관한 중등 과학 교사들의 인식)

  • Park, Jeung-Hee;Park, Ye-Ri;Kim, Jeong-Yul
    • Journal of the Korean earth science society
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    • v.25 no.8
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    • pp.731-738
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    • 2004
  • Secondary school science teachers' preception on inquiry learning was investigated by using questionnaires. According to these results, science teachers, who are participants of the current Korea National Science Curriculum, responded that raising the 'interest in science' was the most important objective of science education, and using practical scientific subject matters in class will do such. More than 72% of science teachers have used reconstructed materials. When reconstructed textbook contents were used, teachers through that the most important object is the 'acquirement of scientific knowledge'. Most science teachers perceived inquiry leaning as a student centered open investigation. Among factors that disturb inquiry leaning, critical ones were 'entrance examination', 'lake of teaching-leaning materials', 'little understanding of inquiry leaning', and 'lake of student's will to inquiry'.

Development and Dissemination of the Teaching Materials for the Creative Activity in Geoscience Area: The Case of the KIGAM's Creative Geo Educamp (지질과학분야 창의적 체험활동 지도자료 개발 및 보급: 한국지질자원연구원 Creative Geo Educamp 사례를 중심으로)

  • Cho, Hyun-Jun;Kim, Jong-Rang
    • Journal of the Korean earth science society
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    • v.32 no.1
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    • pp.57-72
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    • 2011
  • The purpose of this study is to identify the effects of Creative Geo Educamp-the thematic trips with geoscientist, donation of KIGAM's intellectual properties. It was carried out twice and each time took professional development programs for 16 hours. There were 35 secondary science teachers (2010. 7.6.-8.) and 31 elementary teachers (2010. 7.20.-22.). This program was designed to contribute the public education by using intellectual properties of KIGAM. Textbooks and kits were developed for the creative activities according to 2009 Curriculum Revision and they were donated as educational materials. The survey showed that the participants have a high satisfaction of the textbooks and kits developed. Its figures are 4.45 of secondary science teachers and 4.8 of elementary teachers out of 5 points.

Microwave dielectric properties of $(1-x)CaWO_4-xYNbO_4$ ceramics ($(1-x)CaWO_4-xYNbO_4$계 세라믹스의 마이크로파 유전특성)

  • Kim, Su-Jung;Kim, Eung-Soo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.17 no.5
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    • pp.217-222
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    • 2007
  • Microwave dielectric properties of $(1-x)CaWO_4-xYNbO_4$ ceramics have been investigated as a function of $YNbO_4$ content($0.05{\leq}x{\leq}0.4$). A single phase with tetragonal scheelite structure was obtained up to x=0.10 and then the secondary phase with fergusonite structure was increased. With the increase of $YNbO_4$ content, apparent densities of the specimens were decreased. This results were due to the lower theoretical density of $YNbO_4(5.581g/cm^3)$ than that of $CaWO_4(6.117g/cm^3)$. Dielectric constant(K) and quality factor(Qf) were decreased with $YNbO_4$ content which could be attribute to the decrease of density and the increase of secondary phase. Temperature coefficient of resonant frequency (TCF) of the specimens with the $YNbO_4$ content was depended on dielectric mixing rule.