• Title/Summary/Keyword: secondary materials

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An Overview of Chemically/Surface Modified Cubic Spinel LiMn2O4 Electrode for Rechargeable Lithium Batteries

  • Jung, Kyu-Nam;Pyun, Su-Il
    • Journal of the Korean Electrochemical Society
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    • v.9 no.4
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    • pp.158-169
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    • 2006
  • The present article is concerned with the overview of the chemically/surface modified cubic spinel $LiMn_2O_4$ as a cathode electrode far lithium ion secondary batteries. Firstly, this article presented a comprehensive survey of the cubic spinel structure and its correlated electrochemical behaviour of $LiMn_2O_4$. Subsequently, the various kinds of the chemically/surface modified $LiMn_2O_4$ and their electrochemical characteristics were discussed in detail. Finally, this article reviewed our recent research works published on the mechanism of lithium transport through the chemically/surface modified $Li_{1-\delta}Mn_2O_4$ electrode from the kinetic view point by the analyses of the experimental potentiostatic current transients and ac-impedance spectra.

Growth of GaN on ZnO Substrate by Hydride Vapor-Phase Epitaxy (ZnO 기판 위에 Hydride Vapor-Phase Epitaxy법에 의한 GaN의 성장)

  • Jo, Seong-Ryong;Kim, Seon-Tae
    • Korean Journal of Materials Research
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    • v.12 no.4
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    • pp.304-307
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    • 2002
  • A zinc oxide (ZnO) single crystal was used as a substrate in the hydride vapor-phase epitaxy (HVPE) growth of GaN and the structural and optical properties of GaN layer were characterized by x- ray diffraction, transmission electron microscopy, secondary ion mass spectrometry, and photoluminescence (PL) analysis. Despite a good lattice match and an identical structure, ZnO is not an appropriate substrate for application of HVPE growth of GaN. Thick film could not be grown. The substrate reacted with process gases and Ga, being unstable at high temperatures. The crystallinity of ZnO substrate deteriorated seriously with growth time, and a thin alloy layer formed at the growth interface due to the reaction between ZnO and GaN. The PL from a GaN layer demonstrated the impurity contamination during growth possibly due to the out-diffusion from the substrate.

Generalization of 'Gakdeungbyeonhyeongseupyu' by utilizing GeoGebra (GeoGebra를 활용한 각등변형습유(各等邊形拾遺)의 일반화)

  • Yang, Seonghyun
    • Journal for History of Mathematics
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    • v.29 no.2
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    • pp.73-88
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    • 2016
  • To introduce materials related to our traditional mathematics and to reinterpret modernly them could be a good tool to find the cultural values of them. We analyzed the degree for utilization of the history of mathematics in the middle school textbooks developed depending on the 2009 revised mathematics curriculum. Through this, we suggest the need for research on concrete and practical teaching and learning materials development utilizing the history of mathematics. We reinterpret, in modern style based on the curriculum, two subjects dealt with in 'GakDeungByeonHyeongSeupYu', the first theme of 'SanSulGwanGyeon' written by Lee Sang Hyuk. We expansively reconstruct the original samples up to regular decagon so that students might figure out the situation of all regular polygon using a kind of mathematics software GeoGebra. Also this process is constructed on the basis of the curriculum for an implementation the secondary school classes.

Solidification Structure of Al-2.7wt%Li Alloys by Cooling Rate Controlled (냉각속도에 따른 Al-2.7wt%Li 합금계의 응고조직)

  • Shim, Deung-Seub;Choe, Jeong-Cheol;Cho, Hyung-Ho;Kwon, Hae-Wook
    • Journal of Korea Foundry Society
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    • v.11 no.5
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    • pp.398-405
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    • 1991
  • Al-Li alloy has a high strength with low density. Practically this alloy should use by the material which made from the rapid solidification. Therefore we examine the solidification structures of alloy with cooling rate. According to cooling rate increased, grain size and secondary dendrite arm spacing were smaller. Also grain size was further smaller by Zr added. To obtain more fine solidification structure, rapid solidification by single roll melt spinning was performed. According to higher wheel speed, cooling rate increased and cell size was smaller. Because of locally different cooling rate, different cell size was obtained in same specimen. More than cooling rate $10^6^{\circ}C$ /sec, zone A(insensible zone to corrosion)was obtained.

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The Effects and the Development of Learning Materials for the Discussion in Science Classes of the Secondary School - Focussing on the Concepts of Force and Motion - (중학교 과학과 토의 학습을 위한 자료개발과 적용 효과 - 힘과 운동 개념을 중심으로 -)

  • Choi, Kyung-hee;Cho, Hee-Hyung;Kim, Dai-Shik;Kim, Sung-Won
    • Journal of The Korean Association For Science Education
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    • v.20 no.4
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    • pp.510-518
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    • 2000
  • The purpose of this study was to develop learning materials for the discussion and examine the effects of the discussion learning over the students' conceptual change on force and motion. The subjects consisted of 360 middle school students, comprising of 5 discussion groups of 185 students and 5 traditional learning groups of 175 students. The results indicated that students in the discussion groups showed higher achievement than those in the traditional learning groups. Therefore this study supported the importance of discussion in conceptual change. However further research should be conducted to examine other educational effects of discussion.

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The Investigation of the Status of Environmental Education in Schools through Analysis of Goals for Environmental Education (환경교육목표 분석을 통한 학교 환경교육의 실태조사)

  • Lee, Sun-Kyung;Chang, Nam-Kee
    • Journal of The Korean Association For Science Education
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    • v.14 no.1
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    • pp.12-23
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    • 1994
  • This study was conducted to investigate the status and the problem of environmental education in schools. For this investigation, sub-goals to the general goal for environmental education such as knowledge, awareness, attitude, skill, participation, and evaluation were classified. The contents and objects of the environment-related chapters in elementary and secondary school science texts and of the materials for environmental education were analyzed. Resultingly, the content and objects focused on the cognitive domain such as knowledge and skill category in science texts($85{\sim}92\;%$) and in the materials for environmental education($70{\sim}84\;%$). The result indicated that the objects of the cognitive domain were heavily emphasized in the present environmental education.

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The Electrochemical Properties of Heat Treated Poly(p-phenylene) Based Carbon for Li rechargeable batteries (리튬 2차 전지용 Poly(p-phenyllene) based carbon의 열처리 온도에 따른 전기화학적 특성)

  • 김주승;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.11a
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    • pp.373-377
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    • 1996
  • Carbon materials have become a major interestings of research directed toward the development for anode of lithium batteries of enhanced cell capacity. The purpose of this study is to research and develop poly(p-phenylene)(PPP)-based carbon as a anode of lithium secondary batteries. We have synthesized PPP from benzen by chemical reaction. And then disordered carbon materials were obtained by heat-treating PPP in a nitrogen atmosphere at 40$0^{\circ}C$ to 100$0^{\circ}C$ for 1 hour. The carbon prepared by heat treatment showed a broad x-ray diffraction peak around 2$\theta$=23$^{\circ}$. Electrodes were charged and discharged at a current density of 0.1㎃/$\textrm{cm}^2$. Excellent reversible capacity of 275㎃h/g and 97% of charge/discharge efficiency were observed heat treated PPP-based carbon a $700^{\circ}C$.

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Anti-fungal materials Produced by Streptomyces albogriseus Isolated in Korean soil

  • Kwon, Hyuk-Ku;Kang, Byeong-Kon;Lee, Jang-Hoon
    • Proceedings of the Korean Environmental Health Society Conference
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    • 2004.06a
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    • pp.165-168
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    • 2004
  • An anti-fungal material producing actinomycete was isolated from domestic soil. This strain was identified as Streptomyces albogriseus by 16S rDNA sequence. YEME (yeast extract 4g, malt extract 10g, glucose 4g, D.W 1l , pH $7.0{\pm}0.2$) medium was used for production of anti-fungal materials. S. albogriseus was cultured in a shaking incubator for 2 weeks at 150 rpm and $25{\pm}1^{\circ}C$. An anti-fungal material produced by S. albogriseus was identified at 340nm by uv/vis- spectrometer and it showed powerful anti-fungal activity. This is the first report that secondary metabolite produced by S. albogriseus showed an activity against phytopathogenic fungi such as Collectrichum coccodes, Botrytis cinerea, Cladosporium cucumerinum, Didymella bryoniae.

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A Case Study on the Teaching Method of the "Noise" Unit (소음 단원의 교수-학습 모형 개발 및 적용에 관한 현장 연구)

  • 송호열
    • Hwankyungkyoyuk
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    • v.15 no.2
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    • pp.14-29
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    • 2002
  • The environment of the world becomes deteriorated rapidly as the result of the development of technology, the increase of the standard of living, and the growth of population. These circumstances called for environmental education in Korea, creating an environment course in the middle and high school in 1995. Despite the increasing importance of environmental education, however, the situation has not developed in its favor because of the current system of the university entrance examination. The school has failed to develop the curriculum of environmental education in the secondary education. This paper solves this problem internally in terms of the improvement of the contents, organization, teaching method (role-playing game), and teaching materials of environmental education, with a case study of the “noise” unit in 10th grade. This case study expects to change the attitude toward noise, increase the interest and knowledge in environment, and lead to responsible environmental behavior.

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Computational modelling for description of rubber-like materials with permanent deformation under cyclic loading

  • Guo, Z.Q.;Sluys, L.J.
    • Interaction and multiscale mechanics
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    • v.1 no.3
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    • pp.317-328
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    • 2008
  • When carbon-filled rubber specimens are subjected to cyclic loading, they do not return to their initial state after loading and subsequent unloading, but exhibit a residual strain or permanent deformation. We propose a specific form of the pseudo-elastic energy function to represent cyclic loading for incompressible, isotropic materials with stress softening and residual strain. The essence of the pseudo-elasticity theory is that material behaviour in the primary loading path is described by a common elastic strain energy function, and in unloading, reloading or secondary unloading paths by a different strain energy function. The switch between strain energy functions is controlled by the incorporation of a damage variable into the strain energy function. An extra term is added to describe the permanent deformation. The finite element implementation of the proposed model is presented in this paper. All parameters in the proposed model and elastic law can be easily estimated based on experimental data. The numerical analyses show that the results are in good agreement with experimental data.