• 제목/요약/키워드: secondary materials

검색결과 1,920건 처리시간 0.031초

기계화학적 방법에 의한 CuSbS2와 CuSbSe2 나노입자의 합성 (Synthesis of CuSbS2 and CuSbSe2 Nanocrystals by a Mechanochemical Method)

  • 박보인;이승용;이도권
    • Current Photovoltaic Research
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    • 제5권4호
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    • pp.140-144
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    • 2017
  • $CuSbS_2$ (CAS) and $CuSbSe_2$ (CASe) nanocrystals (NCs), which consist of earth-abundant elements, were synthesized by a mechanochemical method. Elemental precursors such as copper, antimony, sulfur, and selenium were used without adding any organic solvents or additives. The NCs were synthesized by milling for a few hours. The sudden phase changes occurred by self-ignition and propagation, as previously observed in other mechanochemical synthetic processes. The XRD, Raman, and TEM analysis were carried out to determine the crystallinity and secondary phase of the as-synthesized CAS and CASe NCs, confirming the phase-pure synthesis of CAS and CASe. Optical properties were investigated by UV-Vis spectroscopy and it was observed that the band gap energies were about 1.1 and 1.5 eV, respectively for CAS and CASe, suggesting the potential for the use as solar cell materials. The NC colloids dispersed in anhydrous ethanol were prepared and coated on Mo substrates by a facile doctor-blade method. The investigation on the solar cell properties of the as-synthesized materials is underway.

Utilization of Fly Ash in Asphaltic Concrete Mixtures

  • Min, Jeong-Ki
    • 한국농공학회지
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    • 제42권
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    • pp.85-91
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    • 2000
  • Dwindling supplies and increasing costs of conventional highway materials used in road construction as well as concerns over shrinking landfill spaces prompt researchers to investigate the use of waste products, such as fly ash, as substitute materials in highway construction. The highway industry is capable of utilizing waste materials in large quantities if their effect on pavement performance proves to be technically, economically and environmentally satisfactory. This research examines the effects of fly ash when used as partial replacement of aggregate in asphaltic concrete mixtures. And measuring the effect of fly ash on bulk specific gravity, air void, indirect tensile strength (ITS) under dry and wet conditioning as well as the tensile strength ratio (TSR) of asphaltic concrete mixture. The results indicated that asphaltic concrete mixtures containing 2% and 5% fly ash produced about the same TSR value as control mixture. And all of the mixtures met the minimum ITS and TSR requirements established by the South Carolina Department of Transportation (SC DOT) for Type 1A surface courses. At this point and with this limited study, these asphaltic concrete mixtures is recommended in several applications such as parking lot, secondary roads and driveways.

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Surface Discharge Characteristics of New Flat Fluorescent Lamp Enhanced by MgO Nano-Crystals

  • Lee, Yang-Kyu;Heo, Seung-Taek;Lee, You-Kook;Lee, Dong-Gu
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.687-690
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    • 2009
  • It has been recently reported that nano-sized MgO single crystal powders emit ultraviolet by stimulation of electrons under vacuum condition. Therefore, in this study, nano-crystalline MgO powders were applied to a xenon plasma flat fluorescent lamp for LCD backlight to improve emission efficiency of the lamp by help of extra ultraviolet from nano-MgO. For comparison with nano-crystalline MgO powders, MgO nano-thin film was applied directly on phosphors inside a lamp panel through e-beam evaporation The luminance and efficiency of FFL with an addition of MgO nano-crystal powders on phosphors were improved by around 20%. Application of MgO thin film to phosphors worsened the emission characteristics of FFLs, even rather than FFL without MgO. The reason came from insufficient stimulation of phosphors by UV, crystallinity of MgO, and low secondary electron coefficient.

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비정질 하프늄인듐징크옥사이드 산화물 반도체의 공정 파워에 따른 트랜지스터의 전기적 특성 연구 (Study on the Electrical Properties of Amorphous HfInZnO TFTs Depending on Sputtering Power)

  • 유동윤;정유진;김도형;주병권;이상렬
    • 한국전기전자재료학회논문지
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    • 제24권8호
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    • pp.674-677
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    • 2011
  • The dependency of sputtering power on the electrical performances in amorphous HIZO-TFT (hafnium-indium-zinc-oxide thin film transistors) has been investigated. The HIZO channel layers were prepared by using radio frequency (RF) magnetron sputtering method with different sputtering power at room temperature. TOF-SIMS (time of flight secondary ion mass spectrometry) was performed to confirm doping of hafnium atom in IZO film. The field effect mobility (${\mu}FE$) increased and threshold voltage ($V_{th}$) shifted to negative direction with increasing sputtering power. This result can be attributed to the high energy particles knocking-out oxygen atoms. As a result, oxygen vacancies generated in HIZO channel layer with increasing sputtering power resulted in negative shift in Vth and increase in on-current.

Green Machining of the Warm Compacted Sinter Hardenable Material

  • Cheng, Chao-Hsu;Chiu, Ken;Guo, Ray
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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    • pp.295-296
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    • 2006
  • High hardness of P/M parts can be obtained in the cooling section of the sintering furnace by using sinter hardenable materials, thus the post-sintering heat treatment can be eliminated. However, the sinter hardened materials would have difficulties in secondary machining if it is required, which will limit the applications of sinter hardenable materials in the machined parts. Recent development in warm compaction technology can enable us not only to achieve the high green density up to $7.4\;g/cm^3$, but also the high green strength which is needed for green machining. Therefore by using warm compaction technology, the green machining can be applied to sinter hardenable materials for the high density, strength and hardness P/M parts. In the present study, a pre-alloyed steel powder, ATOMET4601, was used by mixing with 2.0% copper, 1.0% nickel, 0.9% graphite and a proprietary lubricant using a binder treatment process - FLOMET. The specimens were compacted and green machined with different machining parameters. The machined surface finish and part integrity were evaluated in selecting the optimal conditions for green machining. The possibility of applying the green machining to the high-density structural parts was explored.

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P122강 용접부의 대기중 고온산화 부식속도와 스케일 분석 (High-Temperature Oxidation Kinetics and Scales Formed on P122 Steel Welds in Air)

  • 박상환;이동복
    • 대한금속재료학회지
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    • 제49권9호
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    • pp.699-707
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    • 2011
  • P122 steel, with a composition of Fe-10.57%Cr-1.79%W-0.96Cu-0.59Mn was arc-welded and oxidized between $600^{\circ}C$ and $800^{\circ}C$ in air for up to 6 months. The oxidation rates increased in the order of the base metal, weld metal, and heat-affected zone (HAZ), depending on the microstructure. The scale morphologies of the base metal, weld metal, and HAZ were similar because it was determined mainly by the alloy chemistry. The scale consisted primarily of a thin $Fe_2O_3$ layer at $600^{\circ}C$ and $700^{\circ}C$ and an outer $Fe_2O_3$ layer and an inner ($Fe_2O_3$, $FeCr_2O_4$)-mixed layer at $800^{\circ}C$. The microstructural changes resulting from heating between $600^{\circ}C$ and $800^{\circ}C$ coarsened the carbide precipitates, secondary Laves phases, and subgrain boundaries in the matrix, resulting in softening of the base metal, weld metal, and HAZ.

Interaction of Detonation Nanodiamonds with Hispidin

  • Rhee, Changkyu;Kim, Whungwhoe;Burov, Andrey E.;Puzyr, Alexey P.;Bondar, Vladimir S.
    • 한국분말재료학회지
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    • 제27권6호
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    • pp.458-463
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    • 2020
  • Hispidin is a secondary metabolite found in numerous medicinal mushrooms that has attracted significant attention, owing to its distinct biological effects, including antioxidant, anti-inflammatory, antitumor, and cytoprotective properties. Experiments are being carried out to study the interaction of detonation nanodiamonds (DNDs) with synthetic and natural hispidin sourced from extracts of Pholiota sp. fungus. The bioluminescence method is used to determine the adsorption/desorption properties of DNDs toward hispidin. It is found that hispidin forms strong conjugates with DNDs, and the use of various eluents does not result in a significant release of the adsorbed hispidin molecules. DND-bovine serum albumin (BSA) complex, where DNDs serve as a carrier for the protein and the latter acts as a hispidin sorbent, has been developed and applied in hispidin adsorption/desorption tests. The results support the use of the DNDs as a carrier for hispidin in medical applications. They also advocate the application of the DND-BSA complex for isolating the substance from fungal extracts.

Developing an approach for fast estimation of range of ion in interaction with material using the Geant4 toolkit in combination with the neural network

  • Khalil Moshkbar-Bakhshayesh;Soroush Mohtashami
    • Nuclear Engineering and Technology
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    • 제54권11호
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    • pp.4209-4214
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    • 2022
  • Precise modelling of the interaction of ions with materials is important for many applications including material characterization, ion implantation in devices, thermonuclear fusion, hadron therapy, secondary particle production (e.g. neutron), etc. In this study, a new approach using the Geant4 toolkit in combination with the Bayesian regularization (BR) learning algorithm of the feed-forward neural network (FFNN) is developed to estimate the range of ions in materials accurately and quickly. The different incident ions at different energies are interacted with the target materials. The Geant4 is utilized to model the interactions and to calculate the range of the ions. Afterward, the appropriate architecture of the FFNN-BR with the relevant input features is utilized to learn the modelled ranges and to estimate the new ranges for the new cases. The notable achievements of the proposed approach are: 1- The range of ions in different materials is given as quickly as possible and the time required for estimating the ranges can be neglected (i.e. less than 0.01 s by a typical personal computer). 2- The proposed approach can generalize its ability for estimating the new untrained cases. 3- There is no need for a pre-made lookup table for the estimation of the range values.

칼슘 도핑을 통한 고 에너지 밀도를 가지는 Ni-rich 층상 구조형 양극 소재의 안정화 (Stabilization of Nickel-Rich Layered Cathode Materials of High Energy Density by Ca Doping)

  • 강범희;홍순현;윤홍관;김도진;김천중
    • 한국재료학회지
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    • 제28권5호
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    • pp.273-278
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    • 2018
  • Lithium-ion batteries have been considered the most important devices to power mobile or small-sized devices due to their high energy density. $LixCoO_2$ has been studied as a cathode material for the Li-ion battery. However, the limitation of its capacity impedes the development of high capacity cathode materials with Ni, Mn, etc. in them. The substitution of Mn and Ni for Co leads to the formation of solid solution phase $LiNi_xMn_yCo_{1-x-y}O_2$ (NMC, both x and y < 1), which shows better battery performance than unsubstituted $LiCoO_2$. However, despite a high discharge capacity in the Ni-rich compound (Ni > 0.8 in the metal site), poor cycle retention capability still remains to be overcome. In this study, aiming to improve the stability of the physical and chemical bonding, we investigate the stabilization effect of Ca in the Ni-rich layered compound $Li(Ni_{0.83}Co_{0.12}Mn_{0.05})O_2$, and then Ca is added to the modified secondary particles to lower the degree of cationic mixing of the final particles. For the optimization of the final grains added with Ca, the Ca content (x = 0, 2.5, 5.0, 10.0 at.%) versus Li is analyzed.

레이저 직접 용착공정으로 형성된 스테인레스/인코넬 합금 계면의 미세조직 분석 (Investigation on Interfacial Microstructures of Stainless Steel/Inconel Bonded by Directed Energy Deposition of alloy Powders)

  • 엄영성;김경태;정수호;유지훈;양동열;최중호;심철용;안승준
    • 한국분말재료학회지
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    • 제27권3호
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    • pp.219-225
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    • 2020
  • The directed energy deposition (DED) process of metal 3D printing technologies has been treated as an effective method for welding, repairing, and even 3-dimensional building of machinery parts. In this study, stainless steel 316L (STS316L) and Inconel 625 (IN625) alloy powders are additively manufactured using the DED process, and the microstructure of the fabricated STS316L/IN625 sample is investigated. In particular, there are no secondary phases in the interface between STS316L and the IN625 alloy. The EDS and Vickers hardness results clearly show compositionally and mechanically transient layers a few tens of micrometers in thickness. Interestingly, several cracks are only observed in the STS 316L rather than in the IN625 alloy near the interface. In addition, small-sized voids 200-400 nm in diameter that look like trapped pores are present in both materials. The cracks present near the interface are formed by tensile stress in STS316L caused by the difference in the CTE (coefficient of thermal expansion) between the two materials during the DED process. These results can provide fundamental information for the fabrication of machinery parts that require joining of two materials, such as valves.