• Korean Journal of Materials Research
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• v.10 no.11
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• pp.743-748
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• 2000

Amorphous carbons(neddle cokes), which are used as anode materials for lithium ion secondary batteries, were graphitized or heat-treated at high temperature in $N_2$ atmosphere and in Ar atmosphere, after adding $B_2O_3$. After then, using transmission eletron microscopy, their surface micro-structures and the formations and distributions of the second phases were analyzed. It was studied that such analyzed results were related to the cell capacities and efficiencies.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.21 no.5
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• pp.447-452
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• 2008

We synthesized nano-sized $La_{1-x}Sr_xCoO_3$ ($x=0.1{\sim}0.4$) cathode catalyst for the zinc air secondary batteries by citrate method, And we measured the cathode's electrochemical characteristics according to content of strontium compose the cathode catalyst. We controlled the pH of precursor solution by 10 in the process of manufacturing the precursor, We heat treated the prepared precursor at various calcination temperature ($500{\sim}900^{\circ}C$), and examined the optimum calcinations temperature by XRD analysis and electrochemical evaluation. We examined the ORR (oxygen reduction reaction) and OER (oxygen evolution reaction) performance of the prepared $La_{1-x}Sr_xCoO_3$ catalyst powder. When we consider ORR and OER performance simultaneously, $La_{0.7}Sr_{0.3}CoO_3$ catalyst has shown the best performance because of its lowest voltage deference between charge and discharge.

• The Transactions of the Korean Institute of Power Electronics
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• v.24 no.3
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• pp.139-146
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• 2019

As the number of electric vehicles (EVs) in Jejudo Island increases, the secondary use of EV batteries is becoming increasingly mandatory not only in reducing greenhouse gas emissions but also in promoting resource conservation. For the secondary use of EV batteries, their capacity and performance at the end of automotive service should be evaluated properly. In this study, the battery state information from the on-board diagnostics or OBD2 port was acquired in real time while driving three distinct routes in Jejudo Island, and then the battery operating characteristics were assessed with the driving routes. The route with higher altitude led to higher current output, i.e., higher C-rate, which would reportedly deteriorate state of health (SOH) faster. In addition, the SOH obtained from the battery management system (BMS) of a 2017 Kia Soul EV with a mileage of 55,000 km was 100.2%, which was unexpectedly high. This finding was confirmed by the SOH estimation based on the ratio of the current integral to the change in state of charge. The SOH larger than 100% can be attributed to the rated capacity that was lower than the nominal capacity in EV application. Therefore, considering the driving environment and understanding the SOH estimation process will be beneficial and necessary in evaluating the capacity and performance of retired batteries for post-vehicle applications.

• Journal of the Korean Electrochemical Society
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• v.21 no.2
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• pp.28-38
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• 2018

Although the adhesion properties of composite electrodes are important for securing long-term reliability and realizing high energy density of lithium secondary batteries, related research has not been carried out extensively due to the limitation of measurement technology. However, surface and interfacial cutting analysis system(SAICAS), which can measure the adhesion properties while cutting and peeling a coating layer of $1{\sim}1000{\mu}m$ thickness, has been developed and applied for analyzing the adhesion properties of composite electrodes for lithium secondary batteries. Thus, this review presents not only the principle and measurement method of SAICAS but also comparison results between SAICAS and conventional peel test. In addition, application examples of SAICAS are introduced in the study of electrode design optimization, new binder derivation study, and binder distribution in composite electrode. This suggests that SAICAS is an analytical method that can be easily applied to investigate the adhesion properties of composite electrodes for lithium secondary batteries.

• Proceedings of the KIEE Conference
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• 1995.07c
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• pp.1054-1057
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• 1995

The pollution-free secondary Li ion battery has been developed recently. However due to short history of Li ion battery, the standards for characterized assessments and standardized testing methods have not been prepared and established yet. Also, the researches have not been done systematically regarding the operating methods of these new type of batteries. Such limited knowledge of new batteries emphasizes the importance of development of characterized assessment and the operating methods.

• Proceedings of the KIPE Conference
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• 2013.11a
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• pp.13-14
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• 2013

Multiple output converters (MOCs) are widely used for applications which require various kinds of the output voltages due to its advantages in cost, volume, and efficiency. However, most of the MOCs developed so far can regulate only one output tightly and require as many secondary windings in the transformer as the number of the outputs. In this paper, a novel Time Division Multiple Control (TDMC) method to regulate all the outputs in high precision is proposed and applied to the double ended forward converter for the multiple battery charger. Additional benefit of the proposed topology is to require only one secondary winding in the transformer for all the outputs. The proposed converter can charge two different kinds of batteries or same kind of batteries in different state of charges (SOCs) by CC/CV mode independently with the even degree of tight regulation, thereby satisfying the ripple requirements for each battery.

• Proceedings of the KIEE Conference
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• 2006.04b
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• pp.235-237
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• 2006

This paper proposes a DC-DC converter which is able to charge and discharge secondary batteries. The converter operates as a double-ended forward converter in charging process and as electrical isolated boost converter in discharging process. The converter is designed for continuous current operation. The switching frequency is selected as 100kHz to reduce the size of both the inductor and the capacitor.

• ETRI Journal
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• v.25 no.5
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• pp.412-417
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• 2003

Using a galvanostatic charge/discharge cycler and cyclic voltammetry, we investigated for the first time the electrochemical properties of iron-containing minerals, such as chalcophanite, diadochite, schwertmannite, laihuite, and tinticite, as electrode materials for lithium secondary batteries. Lithium insertion into the mineral diadochite showed a first discharge capacity of about 126 mAh/g at an average voltage of 3.0 V vs. $Li/Li^+$, accompanied by a reversible capacity of 110 mAh/g at the 60th cycle. When the cutoff potential was down to 1.25 V, the iron was further reduced, giving rise to a new plateau at 1.3 V. Although the others showed discharge plateaus at low potentials of less than 1.6 V, these results give an important clue for the development of new electrode materials.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1996.05a
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• pp.76-79
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• 1996

Polypyrrole films were electrochemically synthesized under a constant current condition ranging from 50 ${\mu}$A/$\textrm{cm}^2$ to 2 mA/$\textrm{cm}^2$ with resultant high electrical conductivity about 100 S/cm. Specific energy of 70 Wh/kg and Ah efficiency of 97% were achieved during the cycling using liquid electrolyte system. On the other hand, consequences of the cycling were 51 Wh/kg and 95% using PEO$\sub$8/LiClO$_4$PC$\sub$5/EC$\sub$5/ solid electrolyte system. Polypyrrole film can be cycled stable and Ah efficiency is excellent, so it can be applicable to the cathode of Lithium secondary batteries.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.37 no.1
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• pp.11-25
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• 2024

Lithium-ion batteries (LIBs) have attracted great attention as the common power source in energy storage fields of large-scale applications such as electrical vehicles (EVs), industries, power plants, and grid-scale energy storage systems (ESSs). Insertion, alloying, and conversion reactions are the main electrochemical energy storage mechanisms in LIBs, which determine their electrochemical properties and performances. The electrochemical reaction mechanisms are determined by several factors including crystal structure, components, and composition of electrode materials. This article reviews a new strategy to compensate for the intrinsic shortcomings of each reaction mechanism by introducing the material systems to form a single compound with different types of reaction mechanisms and to allow the simultaneous hybrid electrochemical reaction of two different mechanisms in a single solid solution phase.