• Title/Summary/Keyword: secondary batteries

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Development of Room Temperature Na/S Secondary Batteries (상온형 나트륨/유황 이차전지 개발 동향)

  • RYU, HOSUK;KIM, INSOO;PARK, JINSOO
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.6
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    • pp.753-763
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    • 2016
  • High temperature sodium/sulfur battery(Na/S battery) has good electrochemical properties, but, the battery has some problems such as explosion and corrosion at al. because of using the liquid electrodes at high temperature and production of high corrosion. Room temperature sodium/sulfur batteries (NAS batteries) is developed to resolve of the battery problem. To recently, room temperature sodium/sulfur batteries has higher discharge capacity than its of lithium ion battery, however, cycle life of the battery is shorter. Because, the sulfur electrode and electrolyte have some problem such as polysulfide resolution in electrolyte and reaction of anode material and polysulfide. Cycle life of the battery is improved by decrease of polysulfide resolution in electrolyte and block of reaction between anode material and polysulfide. If room temperature sodium/sulfur batteries (NAS batteries) with low cost and high capacity improves cycle life, the batteries will be commercialized batteries for electric storage, electric vehicle, and mobile electric items.

Electrical Characteristics of Li(Mn$_{1-}$$\delta$Nb$\delta$)$_2$O$_4$ Cathode Materials for Li-Ion Secondary Batteries (리튬 이온 이차전지 Cathode용 Li(Mn$_{1-}$$\delta$Nb$\delta$)$_2$O$_4$의 전기적 특성)

  • 오용주;유광수
    • Journal of the Korean Ceramic Society
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    • v.35 no.9
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    • pp.995-1001
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    • 1998
  • As a basic study for cathode materials of {{{{ { {LiMn }_{2 }O }_{4 } }}-based lithium-ion secondary batteries Li({{{{ { { { {Mn }_{1-$\delta$ }Nb }_{$\delta$} )}_{2 }O }_{4 } }} ($\delta$=0.05, 0.1, 0.2) materials which Nb is substituted for Mn were synthesized by the solid state reaction at 80$0^{\circ}C$ and 110$0^{\circ}C$ respectively. The second phase {{{{ { LiNbO}_{3 } }} appeared above $\delta$=0.1 As the result of im-pedance analysis as the amount of substituted Nb increased the resistivity of grain boundary increased greatly. Compared to undoped-{{{{ { {LiMn }_{2 }O }_{4 } }} the electrical conductivity of Li({{{{ { { { {Mn }_{1-$\delta$ }Nb }_{$\delta$} )}_{2 }O }_{4 } }} decreased slightly but is charging capacity and potential plateau increased.

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Ni-P Coated Sn Powders as Anode for Lithium Secondary Batteries

  • Jo, Yong-Nam;Im, Dong-Min;Kim, Jae-Jung;Oh, Seung-M.
    • Journal of the Korean Electrochemical Society
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    • v.10 no.2
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    • pp.88-93
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    • 2007
  • Nano-sized Sn particles were coated with Ni-P layer using an electroless deposition method and their anodic performance was tested for lithium secondary batteries. Uniform coating layers were obtained, of which the thickness was controlled by varying the $Ni^{2+}$ concentration in the plating bath. It was found that the Ni-P layer plays two important roles in improving the anodic performance of Sn powder electrode. First, it prevents the inter-particle aggregation between Sn particles during the charge/discharge process. Second, it provides an electrical conduction pathway to the Sn particles, which allows an electrode fabrication without an addition of conductive carbon. A pseudo-optimized sample showed a good cyclability and high capacity ($>400mAh\;g^{-1}$) even without conductive carbon loading.

Recent Developments in Anode Materials for Li Secondary Batteries (리튬이차전지용 음극 소재 기술 개발 동향)

  • Kim, Sung-Soo
    • Journal of the Korean Electrochemical Society
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    • v.11 no.3
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    • pp.211-222
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    • 2008
  • Li secondary batteries, which have been in successful commercialization, are becoming important technology as power sources in non-IT application like HEV(Hybrid Electric Vehicle) as well as in portable electronics. It is not the overstatement that the commercialization of Li secondary battery was a result of the development of carbonaceous anode material and safety mechanisms. The R&D of electrode materials of Li secondary batteries is one of the core technologies in the development and it has enormous influences on various fields as well as on the battery industry. Here, the current research of anode materials is described and the underlying problems associated with development, advantages and drawbacks is analyzed.

The Impeditive Properties and Charge/Discharge of Positive Active Material $LiMnO_2$ (정극 활물질 LiMnO2 충.방전과 임피던스 특성)

  • Wi, Seong-Dong;Kim, Jong-Ok;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05c
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    • pp.299-305
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    • 2003
  • The battery industries have been developed to the implementation of lithium ion secondary cell from the cell of Ni/Cd and Ni/MH in the past to be asked of an age of high technology from low technology. Also in resent the polymeric cell to get a good high function with an age of new advanced information system is changed from the 21 century to the secondary batteries society. The properties of lithium secondary batteries have the high energy density, the long cycle time, the low self discharge area and the high active voltage. The wanted properties of secondary batteries for the motion of an apparatuses of industries of an high skill age have a small type trend of the energy density and it is become with a strong asking of the industrial society market about the storable medium of the convenience and new power energy. The electrochemical properties is researched for the cell to be synthesised and crystallized the positive active material LiMnO2 of the secondary cell at 9250C to get a new improved data of the electric discharge for that the capacitance of the LiMnO2 thin film that is improving and researching with the properties and a merit and demerit in the this kind of asking.

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Components in Zn Air Secondary Batteries (Zinc Air 이차전지의 구성요소)

  • Lee, Junghye;Kim, Ketack
    • Journal of the Korean Electrochemical Society
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    • v.16 no.1
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    • pp.9-18
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    • 2013
  • Components of zinc-air battery and their problems are explained. Energy density of zinc air battery is superior to other commercial ones including Li-ion batteries. Cycle life of the zinc air batteries is poor because of irreversible redox reactions on both electrodes. In order to improve the performance of the zinc air battery, catalysts, passivation, and the new structure of electrodes should be developed to optimize several reactions in an electrode. Multidisciplinary efforts, such as mechanics, corrosion science, composite materials are necessary from the beginning of the research to obtain a meaningful product.

Technolgy trends for secondary battery cell and protection circuit (이차전지와 보호회로의 기술 동향)

  • Byun, Jae-in;Kim, Harksoo
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2014.05a
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    • pp.752-754
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    • 2014
  • With the rapid development of the portable devices such as laptops, cell phones, digital devices, the important of the secondary battery is increasing. In recent years, semiconductor industries, display technologies, and secondary batteries are believed to be three core business. In particular, smart phones have higher performances, but secondary batteries are not follow the trends. Recently, the stability problem by battery heat is raised. In this paper, we survey technology trends of the secondary battery and protection circuit.

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Techno-economic Analysis on the Present and Future of Secondary Battery Market for Electric Vehicles and ESS (전기차와 ESS용 이차전지 시장의 현재와 미래에 대한 기술경제적 분석)

  • Jung Seung Lee;Soo Kyung Kim
    • Journal of Information Technology Applications and Management
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    • v.30 no.1
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    • pp.1-9
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    • 2023
  • Interest in the future of the battery market is growing as Tesla announces plans to increase production of electric vehicles and to produce batteries. Tesla announced an action plan to reduce battery prices by 56% through 'Battery Day', which included expansion of factories to internalize batteries and improvement of materials and production technology. In the trend of automobile electrification, the expansion of the battery market, which accounts for 40% of the cost of electric vehicles, is inevitable, and the size of the electric vehicle battery market in 2026 is expected to increase more than five times compared to 2016. With the development of materials and process technology, the energy density of electric vehicle batteries is increasing while the price is decreasing. Soon, electric vehicles and internal combustion locomotives are expected to compete on the same line. Recently, the mileage of electric vehicles is approaching that of an internal combustion locomotive due to the installation of high-capacity batteries. In the EV battery market, Korean, Chinese and Japanese companies are fiercely competing. Based on market share in the first half of 2020, LG Chem, CATL, and Panasonic are leading the EV battery supply, and the top 10 companies included 3 Korean companies, 5 Chinese companies, and 2 Japanese companies. All-solid, lithium-sulfur, sodium-ion, and lithium air batteries are being discussed as the next-generation batteries after lithium-ion, among which all-solid-state batteries are the most active. All-solid-state batteries can dramatically improve stability and charging speed by using a solid electrolyte, and are excellent in terms of technology readiness level (TRL) among various technology alternatives. In order to increase the competitiveness of the battery industry in the future, efforts to increase the productivity and economy of electric vehicle batteries are also required along with the development of next-generation battery technology.

The Stable Rechargeability of Secondary Zn-Air Batteries: Is It Possible to Recharge a Zn-Air Battery?

  • Lee, Sang-Heon;Jeong, Yong-Joo;Lim, Si-Hyoun;Lee, Eun-Ah;Yi, Cheol-Woo;Kim, Keon
    • Journal of the Korean Electrochemical Society
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    • v.13 no.1
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    • pp.45-49
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    • 2010
  • The rechargeable Zn-air battery is considered as one of the potential candidates for the next generation secondary batteries due to its many advantages. However, its further applications and commercialization have been limited by the complexity of the reactions on air electrode which are oxygen reduction and evolution reactions (ORR/OER) upon discharging and charging processes, respectively. In the present study, lanthanum was impregnated into a commercial Pt/C gas diffusion electrode, and it clearly verified significantly enhanced cycling stability and reversibility. The results presented in this study show the possibility of repeated charge/discharge processes for Zn-air batteries with a La-loaded air electrode, and they demonstrate the potential as a promising next generation secondary battery.

Electrodeposited Porous Tungsten Oxides as Anode Materials for Lithium Secondary Batteries

  • Lee, Du-Young;Choi, Woo-Sung;Shin, Heon-Cheol
    • Journal of Electrochemical Science and Technology
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    • v.7 no.2
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    • pp.161-169
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    • 2016
  • Porous tungsten oxide thin films were prepared by electrodeposition and tested as anodes of lithium secondary batteries. The synthesized films were composed of nanoparticles of 60-140 nm size, with porosities of 30-40 %. Increasing the temperature turned out to be a more effective approach to introduce porosity in the structure than increasing the electrolyte viscosity. The assessment of the synthesized films as anodes of lithium secondary batteries revealed a much higher initial discharge capacity for the porous than the dense samples. The discharge capacity retention significantly increased with increasing porosity and was further enhanced by heat treatment. In particular, a thin film composed of particles of about 140 nm in size and with a porosity of 40 % exhibited an initial discharge capacity higher than 600 mAh/g and a remaining capacity above 300 mAh/g after 30 cycles. Following heat treatment, the remaining capacity of this sample after 30 cycles increased to about 500 mA h/g.