• Title/Summary/Keyword: s-PDMS

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Solvent Resistance and Gas Permeation Property of PEI-PDMS Hollow Fiber Composite Membrane for Separation and Recovery of VOCs (VOCs의 분리 및 회수를 위한 PEI-PDMS 중공사 복합막의 내용매성 및 기체 투과 특성)

  • Kim, Se-Jong;Lee, Chung-Seop;Koh, Hyung-Chul;Ha, Seong-Yong;Nam, Sang-Yong;Rhim, Ji-Won;Choi, Whee-Moon
    • Membrane Journal
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    • v.22 no.1
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    • pp.54-61
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    • 2012
  • To separate and recover of VOCs, supporting membranes using PEI were prepared by phase separation method and it was coated with PDMS to prepare PEI-PDMS hollow composite membrane. To investigate characteristic of prepared membrane, pure gas permeability was measured using oxygen and nitrogen, the stage cut and permeance property with feed concentration were evaluated using xylene, ethyl benzene, toluene and cyclohexane. Also, to check solvent resistance on VOCs, stress-strain property of membrane with immersion time in solvent were measured by DMA. The permeance value of $O_2$ and $N_2$ showed 63 GPU and 30 GPU respectively. Permeated VOCs concentration was decreased with increasing stage cut. But, conversely, recovery efficiency that was increased with increasing stage cut. As a result of DMA test, the stress and strain were 11.93 MPa and 13.52%, respectively.

Surface Modification of Li Metal Electrode with PDMS/GO Composite Thin Film: Controlled Growth of Li Layer and Improved Performance of Lithium Metal Battery (LMB) (PDMS/GO 복합체 박막의 리튬 금속 표면 개질: 리튬전극의 성장 제어 및 리튬금속전지(LMB) 성능 향상)

  • Lee, Sanghyun;Seok, Dohyeong;Jeong, Yohan;Sohn, Hiesang
    • Membrane Journal
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    • v.30 no.1
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    • pp.38-45
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    • 2020
  • Although Lithium metal battery (LMB) has a very large theoretical capacity, it has a critical problem such as formation of dendrite which causes short circuit and short cycle life of the LMB. In this study, PDMS/GO composite with evenly dispersed graphene oxide (GO) nanosheets in poly (dimethylsiloxane) (PDMS) was synthesized and coated into a thin film, resulting in the effect that can physically suppress the formation of dendrite. However, PDMS has low ion conductivity, so that we attained improved ion conductivity of PDMS/GO thin film by etching technic using 5wt% hydrofluoric acid (HF), to facilitate the movement of lithium (Li) ions by forming the channel of Li ions. The morphology of the PDMS/GO thin film was observed to confirm using SEM. When the PDMS/GO thin film was utilized to lithium metal battery system, the columbic efficiency was maintained at 87.4% on average until the 100th cycles. In addition, voltage profiles indicated reduced overpotential in comparison to the electrode without thin film.

Control of Wettability Using Regularly Ordered Two-Dimensional Polymeric Wavy Substrates

  • Yi, Dong Kee
    • Nano
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    • v.13 no.10
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    • pp.1850120.1-1850120.9
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    • 2018
  • Two-dimensional poly(dimethylsiloxane) (PDMS) films with wavy patterns were studied in order to investigate reversible and irreversible wetting effects. Pre-strained, surface oxidized layers of PDMS were used to form relieved wavy geometries, on which hydrophobic functionalization was carried out in order to produce irreversible wetting effects. Wavy-patterned PDMS films showed time-dependent reversible wetting effects. The degree of surface wettability could be tuned by the choice of wavy groove geometries. And the groove geometries were controlled via $O_2$ plasma treatment and mechanical pre-straining. The pre-strained, buckled PDMS films were applied to the fabrication of hydrophobic polystyrene nano-patterns using colloidal self-assembly, where the colloids were arrayed in two-dimensional way. The wavy polystyrene films were found to be more hydrophobic relative to flat polystyrene films. The grooving methodology used in this study could be applied to enhancing the hydrophobicity of other types of polymeric thin films, eliminating the need for chemical treatment.

Optimization of Crack Based Sensor Sensitivity According to Thermal Curing Conditions of PDMS (Polydimethylsiloxane) (PDMS(Polydimethylsiloxane)의 열경화조건에 따른 크랙 이용 센서 감도 최적화)

  • Injoo Hwang;Sang-seok Yun;Yong Whan Choi
    • Journal of the Korean Society for Heat Treatment
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    • v.36 no.4
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    • pp.237-241
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    • 2023
  • Recently, research on flexible sensors for personal health management has been gaining attention. In this study, we fabricated a crack-based flexible sensor in thin film form to measure the pulse on the wrist. We evaluated the characteristics of the sensor based on the curing conditions of the PDMS (Polydimethylsiloxane) film to optimize the sensor's gauge factor. The modulus of PDMS varies depending on the curing conditions. In this case, the modulus of PDMS has a significant influence on crack formation, leading to changes in the sensitivity of the sensor. This study examined the changes in the gauge factor associated with these variations.

Hydrophobisity Recovery of PDMS Blended with Fluorinated Silicone Rubber Using Dynamic Contact Angle Measurement (동적 접촉각 측정을 이용한 실리콘고무 블렌드의 발수성회복 검토)

  • Lee, C.R.;Ryu, S.S.;Homma, H.;Izumi, K.
    • Proceedings of the KIEE Conference
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    • 2001.11a
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    • pp.6-8
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    • 2001
  • This report describes the effect of the blending of poly(trifluoropropylmethylvinylsiloxane) (PTFPMVS) with poly(dimethylsiloxane) (PDMS) on the surface properties such as water repellency using dynamic contact angle (DCA) measurement. We have investigated the surface molecular mobility of the PDMS/PTFPMVS blends via a DCA measurement and an adhesion tension relaxation. It could be shown that a flexible side-chain segment in PTFPMVS having higher surface energy, could be reoriented easily in water to decrease the interfacial tension of the polymer/water interface, which seems to play a major role at the decrease of the receding contact angle and the surface resistivity of PDMS/PTFPMVS blends.

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Effect of Contact Angles of PDMS and External Voltage on Flow Velocity in Microchannel (PDMS의 접촉각 및 외부전압 변화에 따른 마이크로채널에서 유체의 속도변화)

  • Lee, Hyo-Song;Kim, Jin-Yong;Kim, Jeong-Soo;Rhee, Young Woo
    • Korean Chemical Engineering Research
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    • v.43 no.1
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    • pp.92-97
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    • 2005
  • In this study, the effect of contact angles of PDMS and external voltage has been investigated. SU-8 (Microchem, USA) negative photoresist and PDMS are used to make the microchannel. The contact angle of the native PDMS is $105^{\circ}$. The native PDMS is treated with the oxygen plasma and the contact angle changes $19^{\circ}$, $46^{\circ}$ and $69^{\circ}$. As a result, the rate of increase in flow velocity is not directly proportional to the rate of increase of external voltage. This is because the electrical double layer is condensed and the zeta potential is increased with an increase of the external voltage. The flow velocity is highest for the contact angle of $19^{\circ}$ at the same external voltage. Hence we conclude that the thickness of electrical double layer and flow velocities vary with contact angle at the same external voltage.

Surface Immobilization of Amphiphilic Comb-like Polymer on Polydimethylsiloxane and in vitro Cytotoxicity Assay (양친성 빗 모양 고분자의 PDMS 표면 고정화 및 세포독성 평가)

  • Choi, Jaeyoo;Jung, Jaeyeon;Cheng, Jie;Lee, Jonghwan;Hyun, Jinho;Kim, Hyunjoong
    • Journal of Adhesion and Interface
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    • v.11 no.2
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    • pp.70-75
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    • 2010
  • It described the modification of polydimethylsiloxane (PDMS) with amphiphilic methyl methacrylate-based polyethylene glycol (PMMA-b-PEG) to enhance the hydrophilicity of a PDMS surface and cytotoxicity of it. PMMA-b-PEG solutions in water/ethanol mixture was spun-cast on the PDMS surface and the surface was characterized by long-term measurement of water contact angle. The morphology of PDMS surfaces coated with PMMA-b-PEG was characterized by field emission scanning electron microscopy and atomic force microscope. Cytotoxicity of the modified surfaces was investigated by MTT assay which would be necessary for the evaluation of tissue compatibility after implantation of the materials. Based on the MTT assay, PDMS coated with PMMA-b-PEG didn't show any significant cytotoxcity.

Synthesis and Swelling Characteristics of Poly(N-isopropylacrylamide) Containing Polydimethylsiloxane and Nano Clay (Nano Clay와 Polydimethylsiloxane을 포함하는 Poly(N-isopropylacrylamide) 공중합체의 합성과 팽윤거동)

  • Nho, Hui-Cheol;Lee, Chan-Woo;Park, Sang-Youn;Yoon, Koo-Sik
    • Polymer(Korea)
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    • v.34 no.2
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    • pp.166-171
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    • 2010
  • Poly(N-isopropylacrylamide)(PNIPAAm) containing polydimethylsiloxane(PDMS) block and nano clay was obtained by the polymerization of NIPAAm and [3-(methacryloylamino)propyl]trimethyl ammonium montmorillonite(MAPTAC-MMT) with PDMS-macroinitiator. The polymer was characterized with FT-IR, XRD and DSC. The addition of PDMS in the polymers did not affect the value of the lower critical solution temperature(LCST) and the glass transition temperature($T_g$) of the PNIPAAm. However, the swelling ratio decreased with increasing PDMS contents. In the case of PNIPAAm containing nano clay, the content of MAPTAC-MMT did not affect swellability, but the $T_g$ of the PNIPAAm decreased with increasing nano clay contents.