• Title/Summary/Keyword: s-PDMS

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Gas Permeation of CO2 and N2 through PDMS-HNT and PDMS-mHNT Composite Membranes (PDMS-HNT과 PDMS-mHNT 복합막을 통한 CO2와 N2의 기체투과)

  • Lee, Seul Ki;Hong, Se Ryeong
    • Applied Chemistry for Engineering
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    • v.29 no.1
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    • pp.67-76
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    • 2018
  • In this study, PDMS-HNT and PDMS-mHNT composite membranes were prepared by the addition of halloysite nanotube (HNT) and modified HNT (mHNT) to PDMS. To investigate the physico-chemical characteristics of composite membranes, analytical methods such as FT-IR, XRD, TGA, and SEM were utilized. The gas permeability and selectivity properties of $N_2$ and $CO_2$ were evaluated. In particular, the PDMS-HNT with 10 wt% HNT and PDMS-mHNT with 5 wt% mHNT showed the highest $CO_2/N_2$ selectivity and $CO_2$ permeability at $35^{\circ}C$, respectively. Overall, PDMS-HNT and PDMS-mHNT composite membranes improved the $CO_2/N_2$ selectivity compared to that of using PDMS membrane.

Separation of $H_2$ and $N_2$ Gases by PDMS-chitosan Composite Membranes (PDMS-chitosan 복합막에 의한 수소와 질소 기체 분리에 관한 연구)

  • Ha, Jung Im;Kang, Tae Beom
    • Membrane Journal
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    • v.23 no.6
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    • pp.418-424
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    • 2013
  • The PDMS-chitosan composite membranes were prepared by addition of 0.02~0.60 wt% chitosan to PDMS. In order to investigate the characteristics of these membranes, we used the analytical methods such as SEM and TGA. Gas permeation experiments was performed in $30^{\circ}C$, $4kg/cm^2$, the permeability and selectivity of $H_2$ and $N_2$ according to content change in composite membrane were investigated. The permeability of $H_2$ and $N_2$ for the PDMS-chitosan composite membranes increased when 0~0.20 wt% chitosan was added, and then decreased at higher wt% as chitosan content increased. The selectivity ($H_2/N_2$) of PDMS-chitosan composite membranes decreased when 0~0.20 wt% chitosan was added, and then increased as chitosan content increased. In the case of PDMS-chitosan in which chitosan was inserted to PDMS, thermal stability of PDMS was enhanced. Based on SEM observation, as the chitosan content within PDMS increased, the surface of the composite membranes became coarse and began to form holes.

Investigation on Transcription Accuracy of PDMS Stamps to Mold Patterns (PDMS stamp 제조시 패턴의 전사 정확도 연구)

  • Yi, Eun-Ji;Kim, Kyoung-Seob;Kim, Nam-Hoon;Roh, Yong-Han
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.99-100
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    • 2007
  • Transferring patterns from mold to PDMS stamp is very useful technology in micro-fabrication, complex and three-dimensional structures. First experimentation, mold's patterns wens transferred to PDMS stamp. Comparing with PDMS stamp and Mold, patterns were transferred about 97.9%. Second experimentation, PDMS stamps were made several times by only one mold, scale and distance of transferred patterns were uniform about 89.3%. We proved that transferring patterns from mold to PDMS stamp is accurate. The uniformity of stamps is the same after mold was used several times. Transferring patterns from mold to PDMS stamp has uniformity and accuracy, it will be useful technology.

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Synthesis and Properties of Amphiphilic Polymers Containing Silicone (실리콘을 함유한 양친성 중합체의 합성 및 성질)

  • Yoon, Koo Sik;Sung, Yong Kiel;Kim, Sung Wan
    • Journal of the Korean Chemical Society
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    • v.39 no.1
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    • pp.76-80
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    • 1995
  • Polydimethylsiloxane(PDMS)-co-poly(2-hydroxyethyl methacrylate)(PHEMA) was prepared and the degree of swelling of solvents into the polymers was examined. It was confirmed that the solubility parameter of PHEMA homopolymer is 26 (J/cm3)1/2. Ethanol was significantly absorbed into copolymers containing large amount of PHEMA, while tetrahydrofuran was effectively absorbed into copolymers containing large amount of PDMS. Absorption of polar solvents into the copolymers were increased with the increase of PDMS content. The model drug, crystal violet (CV), was more absorbable into PDMS-HPEMA copolymers than PHEMA homopolymer. Absorption of CV was decreased with the increase of PDMS content of the copolymers.

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Temperature Maintenance of an ITO Nanoparticle Film Heater (ITO 나노입자 면상발열체의 온도유지에 대한 연구)

  • Yang, Kyungwhan;Cho, Kyoungah;Im, Kiju;Kim, Sangsig
    • Journal of IKEEE
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    • v.20 no.2
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    • pp.171-173
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    • 2016
  • In this study, we fabricate a high efficiency heater consisting of the indium tin oxide (ITO) nanoparticle (NP)-paste and polydimethylsiloxane (PDMS) and investigate the effect of PDMS on temperature maintenance of the heater through the comparison with the PDMS-free ITO film heater. Compared to the ITO film heater, the temperature of the PDMS/ITO film heater lasts 1.5 times longer. And the power consumption of the PDMS/ITO film heater is reduced by 35%, owing to the low thermal conductivity of the PDMS layer.

Separation of Hydrogen-Nitrogen Gases by PDMS-NaA zeolite Mixed Matrix Membranes (PDMS-NaA zeolite 혼합기지분리막에 의한 수소-질소 분리)

  • Kang, Tae Beom;Hong, Se Ryeong
    • Membrane Journal
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    • v.25 no.3
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    • pp.295-300
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    • 2015
  • PDMS-NaA zeolite membranes were prepared by adding 0~40 wt% NaA zeolite. Based on SEM observation, NaA zeolite was dispersed in the PDMS-NaA zeolite membranes with $2{\sim}5{\mu}m$. The permeabilities of $H_2$ and $N_2$ gases through PDMS-NaA zeolite membranes increased as NaA zeolite contents increased and $H_2$ gas had better permeabilities than $N_2$. The selectivity ($H_2/N_2$) of PDMS-NaA zeolite membranes increased as NaA zeolite contents increased.

Volatile Components Analysis using SPME in Traditional Aromatic Plant Resources, Zanthoxylum schinifolium Siebold et Zucc. and Z. piperitum DC (SPME법을 이용한 전통 향료 유전자원 산초 및 초피의 정유성분 분석)

  • Cho, Min-Gu;Chae, Young-Am;Song, Ji-Sook
    • Korean Journal of Medicinal Crop Science
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    • v.9 no.3
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    • pp.192-197
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    • 2001
  • This study was carried out to select proper SPME fiber for volatile component analysis in Zanthoxylum schinifolium and Z. piperitum. PDMS, PDMS/DVB and CAR/PDMS were better for single standard absorption analysis. PDMS and PDMS/DVB showed similar results in comparison between direct injection and the mixture of 24 single standards as well as the mixture of 10 single standards. PDMS and PDMS/DVB were not different each other in absorption patterns between direct injection and headspace SPME regardless of split ratio of GC injection port. However PDMS/DVB rather than PDMS was effective in absorbing the sesquiterpenes within 30-40 minutes as using the SDE extracts from Z. schinifolium and Z. piperitum.

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Preparation, Surface Characteristics and Physical Properties of Polyurethane-based Gel-coat Containing Reactive Silicone Oligomers

  • Jang, Su-Hee;Baek, Seung-Suk;Hwang, Seok-Ho
    • Elastomers and Composites
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    • v.51 no.4
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    • pp.269-274
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    • 2016
  • Two different reactive silicone oligomers, hydroxylpropyl terminated PDMS (PDMS-L) and 1-(2,3-dihydroxy-propoxy)propyl terminated PDMS (PDMS-B), were synthesized through hydrosilylation reaction under Karstedt's catalyst. Using the reactive silicone oligomers, two different silicone-modified gel-coat series were prepared to investigate their thermal and mechanical properties as well as surface characteristics according to reactive silicone oligomer contents. In case of thermal stabilities and mechanical properties, the gel-coat series containing PDMS-B showed higher values than that of the gel-coat series containing the PDMS-L. The contact angle for the gel-coat containing both silicone oligomers/was increased with reactive silicone oligomer contents but there was similar surface tension between PDMS-L and PDMS-B.