Membrane Journal (멤브레인)

The Membrane Society of Korea (한국막학회)
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Separation of Hydrogen-Nitrogen Gases by PDMS-NaA zeolite Mixed Matrix Membranes

PDMS-NaA zeolite 혼합기지분리막에 의한 수소-질소 분리

  • Received : 2015.06.04
  • Accepted : 2015.06.26
  • Published : 2015.06.30
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Abstract

PDMS-NaA zeolite membranes were prepared by adding 0~40 wt% NaA zeolite. Based on SEM observation, NaA zeolite was dispersed in the PDMS-NaA zeolite membranes with $2{\sim}5{\mu}m$. The permeabilities of $H_2$ and $N_2$ gases through PDMS-NaA zeolite membranes increased as NaA zeolite contents increased and $H_2$ gas had better permeabilities than $N_2$. The selectivity ($H_2/N_2$) of PDMS-NaA zeolite membranes increased as NaA zeolite contents increased.

PDMS에 NaA zeolite를 0~40 wt% 가하여 PDMS-NaA zeolite 막을 제조하였다. SEM 관찰에 의하면 PDMS-NaA zeolite 막 내에 분산되어있는 NaA zeolite 입자의 크기는 $2{\sim}5{\mu}m$이었다. PDMS-NaA zeolite 막의 $N_2$와 $H_2$ 투과도는 막 내의 NaA zeolite 함량이 증가하면 증가하였고, $N_2$보다는 $H_2$의 투과도가 더 컸다. 그리고 PDMS-NaA zeolite 선택성($H_2/N_2$)은 NaA zeolite 함량이 증가하면 증가하였다.

Keywords

References

  1. D. P. Queiroz and M. N. de Pinho, "Structural characteristics and gas permeation properties of poly(dimethylsiloxane/propylene oxide) urethane/urea bi-soft segment membranes", Polymer, 46, 2346 (2005). https://doi.org/10.1016/j.polymer.2004.12.056
  2. A. Kumar and X. Jiang, "Performance of silicone- coated polymeric membrnae in separation of hydrocarbons and nitrogen mixtures", J. Membr. Sci., 254, 179 (2005). https://doi.org/10.1016/j.memsci.2004.12.041
  3. C. K. Yeom, "Modeling and evaluation of boundary layer resistance at feed in the permeation of VOC/$N_2$ mixtures through PDMS membrane", J. Membr. Sci., 204, 303 (2002). https://doi.org/10.1016/S0376-7388(02)00055-8
  4. P. C. Lebaron and T. J. Pinnavaia, "Clay nanolayer reinforcement of a silicone elastomer", Chem. Mater., 13, 3760 (2001). https://doi.org/10.1021/cm010982m
  5. P. Winberg, K. Desitter, C. Dotremont, S. Mullens, I. F. J. Vankelecom, and F. H. J. Maurer, "Free volume and interstitial mesopores in silica filled poly(1-trimethylsilyl-1-propyne) nanocomposites", Macromolecules, 38, 3776 (2005). https://doi.org/10.1021/ma047369j
  6. D. Gomes, S. P. Nunes, and K. Peinemann, "Membranes for gas separation based on poly(1-trimethylsilyl- 1-propyne)-silica nanocomposites", J. Membr. Sci., 246, 13 (2005). https://doi.org/10.1016/j.memsci.2004.05.015
  7. J. H. Kim and Y. M. Lee, "Gas permeation properties of poly(amide-6-ethylene oxide)-silica hybrid membranes", J. Membr. Sci., 193, 209 (2001). https://doi.org/10.1016/S0376-7388(01)00514-2
  8. H. B. Park, C. H. Jung, Y. K. Kim, S. Y. Nam, S. Y, Lee, and Y. M. Lee, "Pyrolytic carbon membranes containing silica derived from poly(imide siloxane): the effect of siloxane chain length on gas transport behavior and a study on the separation of mixed gases", J. Membr. Sci., 235, 87 (2004). https://doi.org/10.1016/j.memsci.2004.01.025
  9. S. Zhong, C. Li, Q. Li, and X. Xiao, "Supported mesoporous $SiO_{2}$ membrane synthesized by sol-gel template technology", Sep. Purif. Technol., 32, 17 (2003). https://doi.org/10.1016/S1383-5866(03)00034-0
  10. S. Zhong, C. Li, and X. Xiao, "Preparation and characterization of polyimide-silica hybrid membranes on kieselguhr-mullite supports", J. Membr. Sci., 199, 53 (2002). https://doi.org/10.1016/S0376-7388(01)00676-7
  11. S. Ulutan and T. Nakagawa, "Separability of ethanol and water mixtures through PTMSP-silica membranes in pervaporation", J. Membr. Sci., 143, 275 (1998). https://doi.org/10.1016/S0376-7388(98)00022-2
  12. H. Matsuyama, M. Teramoto, and K. Hirai, "Effect of plasma treatment on $CO_{2}$permeability and selectivity of poly(dimethylsiloxane) membrane", J. Membr. Sci., 99, 139 (1995). https://doi.org/10.1016/0376-7388(94)00217-M
  13. C. Dotremont, B. Brabants, K. Geeroms, J. Mewis, and C. Vandecasteele, "Sorption and diffusion of chlorinated hydrocarbons in silicate-filled PDMS membranes", J. Membr. Sci., 104, 109 (1995). https://doi.org/10.1016/0376-7388(95)00019-9
  14. Z. Gao, Y. Yue, and W. Li, "Application of zeolite- filled pervaporation membrane", Zeolite, 16, 70 (1996). https://doi.org/10.1016/0144-2449(95)00094-1
  15. Q. Hu, E. Marand, S. Dhingra, D. Fritsch, J. Wen, and G. Wilkes, "Poly(amide-imide)/$TiO_{2}$ nano-composite gas separation membranes : fabrication and characterization", J. Membr. Sci., 135, 65 (1997). https://doi.org/10.1016/S0376-7388(97)00120-8
  16. J. P. Boom, I. G. M. Punt, H. Zwijnenberg, R. de Boer, D. Bargeman, C. A. Smolders, and H. Strathmann, "Transport through zeolite filled polymeric membranes", J. Membr. Sci., 138, 237 (1987).
  17. H. J. C. te Hennepe, D Baremann, M. H. V. Mulder, and C. A. Smolders, "Zeolite-filled silicone rubber membranes: Part I. Membrane preparation and pervaporation results", J. Membr. Sci., 35, 39 (1987). https://doi.org/10.1016/S0376-7388(00)80921-7
  18. M. D. Jia, K. V. Peinemann, and R. D. Behling, "Preparation and characterization of thin-film zeolite- PDMS composite membranes", J. Membr. Sci., 7a, 119 (1992).
  19. M. D. Jia, K. V. Peinemann, and R. D. Behling, "Molecular sieving effect of the zeolite-filled silicone rubber membranes in gas permeation", J. Membr. Sci., 57, 289 (1991). https://doi.org/10.1016/S0376-7388(00)80684-5
  20. M. G. Suer, N. Bac, and L. Yilmaz, "Gas permeation characteristics of polymer-zeolite mixed matrix membranes", J. Membr. Sci., 91, 77 (1994). https://doi.org/10.1016/0376-7388(94)00018-2
  21. J. M. Duval, A. J. B. Kemperman, B. Folkers, M. H. V. Mulder, G. Desgrandchamps, and C. A. Smolders, "Preparation of zeolite filled glassy polymer membranes", J. Appl. Polym. Sci., 54, 409 (1994). https://doi.org/10.1002/app.1994.070540401
  22. O. S. Kim and S. R. Hong, "Separation of $H_{2}$ and $N_{2}$ gases by PTMSP-NaY zeolite composite membranes", Membr. J., 24, 285 (2014). https://doi.org/10.14579/MEMBRANE_JOURNAL.2014.24.4.285
  23. O. S. Kim and S. I. Yun, "Separation of $H_{2}$ and $N_{2}$ gases by PTMSP-NaA zeolite composite membranes", Membr. J., 25, 107 (2015). https://doi.org/10.14579/MEMBRANE_JOURNAL.2015.25.2.107
  24. S. R. Hong and H. Y. Lee, "Preparation and Permeation characteristics of PTMSP-PDMS-silica/PEI composite membranes", Membr. J., 18, 146 (2008).
  25. J. I. Ha and T. B. Kang, "Separation of $H_{2}$ and $N_{2}$ by PDMS-NaY zeolite composite membrnaes", Membr. J., 20, 47 (2010).
  26. S. B. Tantekin-Erslmaz, C. Atalay-Oral, M. Tatlier, A. Erdem-Snatalar, B. Schoeman, and J. Sterte, "Effect of zeolite particle size on the performance of polymer-zeolite mixed matrix membranes", J. Membr. Sci., 175, 285 (2000). https://doi.org/10.1016/S0376-7388(00)00423-3