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Development of CCD(Corrosion Control Document) in Refinery Process (정유공정의 CCD(Corrosion Control Document) 개발)

  • Kim, Jung-Hwan;Kim, Ji-Yong;Lee, Young-Hee;Park, Sang-Rok;Suh, Sun-Kyu;Lee, Yoon-Hwa;Moon, Il
    • Journal of the Korean Society of Safety
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    • v.24 no.1
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    • pp.31-36
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    • 2009
  • This paper focuses on techniques of improving refinery reliability, availability, and profitability. Our team developed a corrosion control document(CCD) for processing of the crude distillation unit(CDU). Recent study shows the loss due to corrosion in US is around $276 billion. It's a big concern for both managers and engineers of refinery industry. The CCD consists of numerous parts namely damage mechanism(DM), design data, critical reliability variable(CRV), guidelines, etc. The first step in the development of CCD is to build material selection diagram(MSD). Damage mechanisms affecting equipments and process need to be chosen carefully based on API 571. The selected nine DM from API 571 are (1) creep/stress rupture, (2) fuel ash corrosion, (3) oxidation, (4) high temperature sulfidation, (5) naphthenic acid corrosion, (6) hydrochloric acid(HCL) corrosion, (7) ammonium chloride(salt) corrosion, (8) wet $H_2S$ corrosion, and (9) ammonia stress corrosion cracking. Each DM related to corrosion of CDU process was selected by design data, P&ID, PFD, corrosion loop, flow of process, equipment's history, and experience. Operating variables affecting severity of DM are selected in initial stage of CRV. We propose the guidelines for reliability of equipments based on CRV. The CCD has been developed on the basis of the corrosion control in refinery industry. It also improves the safety of refinery process and reduces the cost of corrosion greatly.

A Design of Economic CUSUM Control Chart Incorporating Quality Loss Function (품질손실을 고려한 경제적 CUSUM 관리도)

  • Kim, Jungdae
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.41 no.4
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    • pp.203-212
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    • 2018
  • Quality requirements of manufactured products or parts are given in the form of specification limits on the quality characteristics of individual units. If a product is to meet the customer's fitness for use criteria, it should be produced by a process which is stable or repeatable. In other words, it must be capable of operating with little variability around the target value or nominal value of the product's quality characteristic. In order to maintain and improve product quality, we need to apply statistical process control techniques such as histogram, check sheet, Pareto chart, cause and effect diagram, or control charts. Among those techniques, the most important one is control charting. The cumulative sum (CUSUM) control charts have been used in statistical process control (SPC) in industries for monitoring process shifts and supporting online measurement. The objective of this research is to apply Taguchi's quality loss function concept to cost based CUSUM control chart design. In this study, a modified quality loss function was developed to reflect quality loss situation where general quadratic loss curve is not appropriate. This research also provided a methodology for the design of CUSUM charts using Taguchi quality loss function concept based on the minimum cost per hour criterion. The new model differs from previous models in that the model assumes that quality loss is incurred even in the incontrol period. This model was compared with other cost based CUSUM models by Wu and Goel, According to numerical sensitivity analysis, the proposed model results in longer average run length in in-control period compared to the other two models.

Proposal of design plan to improve immersion in online video education -Focusing on Zoom and Webex- (온라인 화상 교육 몰입도 향상을 위한 디자인 방안 제안 -줌(Zoom)과 웹엑스(Webex)를 중심으로-)

  • Lee, Kaha;Kim, Seung-In
    • Journal of Digital Convergence
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    • v.19 no.7
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    • pp.341-348
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    • 2021
  • This study identified learners' immersion, focusing on online video education platforms, Zoom and Webex, used in colleges after the 'Covid-19', and suggested design improvement measures to improve immersion. Through prior research and literature research, the components of immersion and screen components of the online distance education platform were identified, and measures to improve immersion were suggested through questionnaire surveys and in-depth interviews. The research method was conducted for 5 days from April 7 to 12, 2021 for 50 college students and graduate students in their 20s and 30s who are receiving online education through Zoom and Webex, and 6 people were interviewed in-depth. As a result of the experiment, the communication between learners and lecturers was deduced as the biggest factor, so a design plan to facilitate communication between learners and lecturers was proposed based on Gutenberg's diagram. As online video education is predicted to continue even after the Covid-19, continuous online video education immersion research is needed, and we hope that it can contribute to the direction of the research.

Derivation of the Synthetic Unit Hydrograph at Ungaged Small Watershed (미계측 소하천수계의 합성단위도 유도)

  • 안상진;이억한
    • Water for future
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    • v.19 no.2
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    • pp.157-166
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    • 1986
  • The objective of this study was to determine the best representative synthetic unit hydrograph that is applicable to ungaged small watershed. A typical unit hydrograph was established with the actual data from a small watershed. Four currently well-known methods for analyzing ungaged small watershed, including Snyder's, Clark's S.C.S. and Nash methods, were evaluated with the data from the same small watershed. The following observations were noted from the analysis of four methods. The Snyder's method yielded the similar peak discharge value as the typical unit hydrograph. With co-ordinates of three discharge values, i.e. 25%, 50% and 75% of peak discharge, were not adequate for deriving a typical unit hydrograph in ungaged small watershed. With Clark's method there shall be some way of obtaining the exact base length of time area diagram and isochrone of each reach of the stream. With Nash method peak discharge and base flow time are affected by the storage constant and gamma function argument; therefore, for deriving a more reliable and workable unit hydrograph one needs to select for the better estimation of storage constant and gamma function argument. In S.C.S. method peak discharge is directly related to the watershed area and inversely related to the time of peak diacharge. Therefore area with faster peak discharge yielded the higer peak discharge value. Although the peak discharge value obtained frome the S.C.S. method higher than the value obtained from the unit hydrograph developed from the actual data, this method contains a number of advantageous factors. The peak discharge value and the time of peak discharge can be claculated easity from the morphological characteristics of the watershed, and in S.C.S method co-ordinates of the unit hydrograph can be calculated easily from that of the dimensionless unit hydrograph. When the four currently used methods were evaluated with a typical unit hydrograph obtained from the actual data, the S.C.S method was show to be the best method in deriving a synthetic unit hydrograph for ungaged small watershed.

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Breeding of Fragrant Yellow Phalaenopsis and Scent Pattern Analysis by GC/SAW Electronic Nose System (유향성 황색계 호접란 육성 및 전자코를 이용한 향기패턴 분석)

  • Been, Chul-Gu
    • Horticultural Science & Technology
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    • v.28 no.4
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    • pp.656-663
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    • 2010
  • In order to improve the consumer acceptance of fragrant yellow hybrids of $Phalaenopsis$ ($Phal.$), crosses between yellow hybrid varieties were made and the obtained hybrids were investigated for horticultural characteristics as well as difference in fragrance patterns. Cross combination of $Phal.$ Brother lawrence and $Phal.$ Brother saragold yielded good seedling population of 500 plants. Segregation was noticed in color density, spot and stripe patterns on yellow color base of petal and also in fragrance. Six lines with multi-branch on flower stalk and strong fragrance flower were finally selected. Volatile fragrance components were compared among $Phal.$ Brother lawrence, $Phal.$ Brother saragold and their hybrids by GC/SAW electronic nose. In the derivative pattern of chromatogram and polar derivative pattern of fragrance, similar dominant peaks appeared on retention time 7-9 s and some hybrid lines had two strong peaks on retention time 20-25 s, respectively. Also in polar frequency pattern of fragrance obtained by $VaporPrint^{TM}$ image analysis among parent flowers and hybrids, an identical strong peak near 8 s of retention time was shown. This single fragrance component is considered a key element of fragrance in $Phal.$ Brother lawrence, $Phal.$ Brother saragold and their hybrids. This peak could be used as a marker for the breeding of fragrance in $Phalaenopsis$.

Assessment of Acquisition Protocols for Post-Radioembolization Yttrium-90 PET/CT: Initial Study (90Y SIR-Spheres를 사용한 암의 간 전이치료에서 PET 영상획득에 관한 초기연구)

  • Bahn, Young Kag;Oh, Shin Hyun;Kim, Jung Yul;Lee, Seung Jae;Park, Joon Young;Shin, Heui Soon;Lim, Han Sang;Kim, Jae Sam
    • The Korean Journal of Nuclear Medicine Technology
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    • v.18 no.1
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    • pp.89-93
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    • 2014
  • Purpose: We investigated the quantitative evaluation of PET/CT images for evaluation after treatment in the treatment of liver metastasis of cancer with $^{90}YSIR$-Sphere. Materials and Methods: Confirmed the correlation between the measured counts was expressed by setting a region of interest from the image and a measure of the dose calibrator to see a correlation diagram of an image in a PET of $^{90}Y$. A portion uptake coefficients between PET images were acquired for 20 minutes LIST mode in 15 patients treated for liver metastasis of cancer using $^{90}Y$ SIR-Spheres high, intermediate portion, a lower portion, three measuring the coefficient of the region of interest is divided into parts, we studied the conditions for proper image acquisition. Results: Coefficient of sites that set the region of interest of the PET image and the measured counts of $^{90}Yappears$ that there is a correlation diagram statistically, ($R^2=0.956$), correlation diagram from the PET image of $^{90}Yis$, PET coefficient the coefficients of all regions of interest were increased in proportion to the image acquisition time, partial ROI coefficients of the PET image is higher about 10 minutes on average, about 14 minutes on average, the central portion is lower part 19 minute average in, confirmed the equilibrium of the standard deviation. Conclusion: Using the isotope $^{90}Y$, it is suitable to obtain a PET image, to obtain the time of proper image, the evaluation of PET/CT images, using the $^{90}Y$ SIR-Spheres and that in the treatment of liver metastases of cancer, it is useful for assessing treatment.

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A Study on Sea Water and Ocean Current in the Sea Adjacent to Korea Peninsula -III. Chemical Characteristics of Water Masses in the Polar Front Area of the Central Korean East Sea- (한반도 근해의 해류와 해수특성 -III. 한국 동해 중부 극전선역에 출현하는 수괴의 화학적 특성-)

  • YANG Han-Soeb;KIM Seong-Soo;KANG Chang-Geun;CHO Kyu-Dae
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.24 no.3
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    • pp.185-192
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    • 1991
  • The vertical distribution and chemical characteristics of water masses were measured along two south-north transects in the polar front region of the central Korean East Sea. In February, a thermocline was present at depth between 50m and loom at the southern sites of a landward A-transect, and its depth was gradually deepened northward. At an outside B-transect, a thermocline was observed at significantly deep depth of 300m to 400m at two northern stations(Stn. 10 and 11), though the depth of the southward stations was nearly identical to that at the northward stations on a A-transect. In September, there were vertically more various water masses, i.e. the Tsushima Warm surface water(TWSW) or more than $20^{\circ}C$, the Tsushima Middle water(TMW) with a range of $12{\~}17^{\circ}C$, the North Korea Cold Water(NKCW) with $1{\~}7^{\circ}C$ temperature, the Japan Sea Proper Water(JSPW) of less than $1^{\circ}C$, and the mixed water. The North Korea Cold Water could be distinguishable from the other waters, especially from the mixed water of the Tsushima Middle Water and the Japan Sea Proper Water by the pattern of $T-O_2$ diagram. For instance, the North Korea Cold Water had higher oxygen by $1{\~}2ml/l$ than those in the mixed water, although both the two water masses ranged $1{\~}7^{\circ}C$ in water temperature. AOU value was the highest in the JSPW and the lowest in the TWSW. Also, AOU indicated a nearly linear and negative correlation with water temperature. However, AOU data for two masses, the NKCW and the TMW, in September departed remarkably from a regression line. Moreover, the ratio of $$\Delta P/\Delta AOU)$ in September was about $0.45{\mu}g-at/ml$ and higher than the value observed in the open sea. This high value could be elucidated by two factors; intrusion of the NKCW with high oxygen and molecular diffusion of dissolved oxygen from the surface into the lower layer. AOU would be a useful tracer for water masses in the polar front area of the Korean East Sea.

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A Study on the Behavior of Deformation in Soft Soils Subjected to Lateral Flow (측방유동을 받는 연약지반의 변형거동에 관한 연구)

  • 안종필;홍원표
    • Geotechnical Engineering
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    • v.10 no.2
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    • pp.25-40
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    • 1994
  • In order to investigate behavior of lateral flow by plasticity of soils and construction control due to it, in the case of unsymmetrical surcharge load on the soft soils, we examine the existing theoretical background, and compared and analysed the experimental results by model test. After model test fabricated by model test apparatus, which made full remolding samples of soft soils, we observed the state of behavior for deformation with increasing load step to constant time interval. The critical surcharge and ultimate capacity showed tendency to approach to the proposed value of Jaky and Meyerhof, and the lateral flow pressure of which the maximum value was acted on the depth calculated by z/H=0.26+1.71cu and one third value of the maximum lateral flow pressure acted on the ground surface, approach the trapezoid distribution And maximum lateral flow pressure will be calculated by proposed equation of Hong or simple equation which($\alpha=0.4$) the flow pressure coefficient . of proposed equation by Tschebotarioff exchanged to($\alpha=K_0$) . Basides, the failure surcharge by [(q/$y_m$)-q] and [$S_y-(y_m/S_y)$] showed the smaller than ultimate bearing capacity, especially failure criteria line of control diagram of [$S_y(y_m/S_y)$] will be calculated by following equation. $S_y.=3.15exp[-0.58(y_m/S_y)$

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Geochemistry and Petrogenesis of the Granitic Rocks in the Vicinity of the Mt. Sorak (설악산 부근의 화강암류에 대한 지구화학 및 성인)

  • Kyoung-Won Min;Sung-Bum Kim
    • The Journal of the Petrological Society of Korea
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    • v.5 no.1
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    • pp.35-51
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    • 1996
  • The granitic rocks in the vicinity of the Mt. Sorak, the northeastern part of the NE-SW elongated Mesozoic granitic batholith in the Kyeonggi massif, consist of granodiorite, biotite granite, two-mica granite and alkali feldspar granite. Variations In major and most trace elemental abundances show a typical differentiation trend in a granitic magma. Granitic rocks all display a calc-alkaline trend in the AFM diagram. Also, In the ACF diagram discriminating between I- and S-type granitic rocks, granodiorite and most biotite granite in the southeastern area represent I-type and magnetite-series characteristics, while most biotire granite and two-mica granite in the northwestern area exhibit S-type and ilmenite-series ones.According to recent studies of the granitle rocks In the Inje-Hongcheon district. all ihe granitic rocks distributed in the northeastern part of the Kyeonggi massif have been classified as late Triassic to early Jurassic Daebo granite. With reference of the formerly published ages, an age oi $125.6{\pm}4.4$ Ma calculated by the slope in the plot of $^{87}Rb/^{86}Sr-^{87}Sr/^{86}Sr$ for the biotite granite samples from the southeastern area is inferred as an emplacement age for the granitic rocks in the vicinity of the Mt. Sorak. On the basis of elemental variations and Sr isotope compositions, an possible evolutional process for the granitic magmas in this area is suggested. The primary magma of I-type and magnetite-series generated about 125 Ma by partial melting of igneous originated crustal materials, might be emplaced and evolved through fractional crystallization, convection and assimilation of the surrounding Precambrian metasediments to become S-type and ilmenlte-serles in the outer area, and then solidified to granodiorite, biotite granite and two-mica granite.At the latest stage, the evolved hydrothermal solution altered the formerly solidified biotite granite to alkali feldspar granite and probably later local igneous activities affected the alkali feldspar granite again.

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Petrology and petrochemistry of the Jurassic Daebo granites in the Pocheon-Gisanri area (포천 - 기산리 일대에 분포하는 쥬라기 대보화강암류의 암석 및 암석화학)

  • 윤현수;홍세선;이윤수
    • The Journal of the Petrological Society of Korea
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    • v.11 no.1
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    • pp.1-16
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    • 2002
  • The study area is mostly composed of Precambrian Gyeonggi gneiss complex, Jurassic Daebo granites, Cretaceous tonalite and dykes, and so on. On the basis of field survey and mineral assemblage, the granites can be divided into three types; biotite granite (Gb), garnet biotite granite (Ggb) and two mica granite (Gtm). They predominantly belong to monzo-granites from the modes. Field relationship and K-Ar mica age data in the surrounding area suggest that intrusive sequences are older in order of Gtm, Ggb and Gb. Gb and Ggb, major study targets, occur as medium-coarse grained rocks, and show light grey and light grey-light pink colors, respectively. Mineral constituents are almost similar except for opaque in Gb and garmet in Ggb. Gb and Ggb have felsic, peraluminous, subalkaline and calc alkaline natures. In Harker diagram, both rocks show moderately negative trends of $TiO_2$, MgO, CaO, $Al_2O_3$, $Fe_2O_3$(t), $K_2O$ and $P_2O_5$ as $SiO_2$ contents increase. Among them, $TiO_2$, MgO and CaO show two linear trends. From the trends and the linear patterns in AFM, Sr-Ba and Rb-Ba-Sr relations, it is likely that they were originated from the same granitic magma and Ggb was differentiated later than Gb. REE concentrations normalized to chondrite value have trends of parallel LREE enrichment and HREE depletion. One data of Ggb showing a gradually enriched HREE trend may be caused by garnet accompaniment. Ggb have more negative Eu anomalies than Gb, suggesting that plagioclase fractionation in Ggb have occurred much stronger than that in Gb. In modal (Qz+Af) vs. Op, Gb and Ggb belong to magnetite-series and ilmenite-series, respectively. From the EPMA results, opaques of Gb are magnetite and ilmenite, and those of Ggb are magnetite-free ilmenite or not observed. Bimodal distribution of magnetic susceptibility reveals two different granites of Gb (332.6 ${mu}SI$) and Ggb (2.3 ${mu}SI$). Based on the paleomagnetic analysis as well as modal analysis, the main susceptibilities of Gb and Ggb reside in magnetite and mafic minerals, respectively. They belong to S-type granite of non-magnetic granite by susceptibility value. In addition, $SiO_2$ contents, $K_2O/Na_2O$, A/CNK molar ratio and ACF diagram support that they all belong to S-type granites.