• Macromolecular Research
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• 제14권1호
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• pp.1-33
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• 2006

Polyimides (PIs) exhibit excellent thermal stability, mechanical, dielectric, and chemical resistance properties due to their heterocyclic imide rings and aromatic rings on the backbone. Due to these advantageous properties, PIs have found diverse applications in industry. Most PIs are insoluble because of the nature of the high chemical resistance. Thus, they are generally used as a soluble precursor polymer, which forms complexes with solvent molecules, and then finally converts to the corresponding polyimides via imidization reaction. This complexation with solvent has caused severe difficulty in the characterization of the precursor polymers. However, significant progress has recently been made on the detailed characterization of PI precursors and their imidization reaction. On the other hand, much research effort has been exerted to reduce the dielectric constant of PIs, as demanded in the microelectronics industry, through chemical modifications, as well as to develop high performance, light-emitting PIs and liquid crystal (LC) alignment layer PIs with both rubbing and rubbing-free processibility, which are desired in the flat-panel display industry. This article reviews this recent research progresses in characterizing PIs and their precursors and in developing low dielectric constant, light-emitting, and LC alignment layer PIs.

• 한국정보전자통신기술학회논문지
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• 제16권1호
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• pp.8-17
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• 2023

기존 liquid crystal display(LCD) 공정에서 Indium Tin Oxide(ITO) 투명전극과 폴리이미드 배향막의 러빙 공정은 액정을 정렬하고 전계를 인가하기 위하여 필수적인 공정이다. 하지만 ITO의 증착은 높은 진공을 요구하며, 러빙 공정은 정전기에 의해 소자가 손상될 수 있는 단점이 존재한다. 본 논문에서는 기존 ITO 투명전극을 대체하기 위하여 PEDOT:PSS와 Multi-wall carbon nanotube(MWNT)를 혼합하여 PEDOT:PSS 나노복합체를 제조하고, 러빙 공정을 대체하기 위하여 나노 주름 구조 몰드를 통한 나노임프린팅을 통하여 박막을 형성함으로써 기존 액정 디스플레이의 투명전극과 배향막 두 가지 박막을 PEDOT:PSS/MWNT 나노복합체 박막 하나만으로 기능하게 하여 공정을 단순화 하였다. 전사된 나노 주름을 따라 액정이 잘 배향됨을 확인하였으며, 이를 기반으로 만들어진 액정 셀에서 박막 내 MWNT의 함량이 높아질수록 박막의 전기전도도가 증가하여 낮은 구동 전압과 빠른 응답 속도를 갖는다는 것을 확인하였다. 본 연구를 통해 공정 단순화와 용액공정에 의한 공정 단가 절감, 기존 러빙 공정의 단점을 해결하는데 기여 할 수 있을 것으로 기대된다.

• 동력기계공학회지
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• 제19권6호
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• pp.12-18
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• 2015

Austenitic stainless steels generally experience the occurrence of chromium-depleted zones at the boundaries, known as sensitization, caused by the carbide precipitation that takes place due to a welding process or heat treatment. Normally, the depleted zones become the focus of the intense corrosion. In this study, the Cr-free organic/inorganic hybrid solution was developed, and the artificially degraded STS316S and STS347H with the solution-coating investigated the corrosion resistance by salt spray test. Both the OIBD-1 and OIBD-2 solutions improved the corrosion resistance of STS310S and STS347H. The corrosion resistance with the OIBD-1 solution was better than that of OIBD-2 solution. Additionally, Both solutions have been proven excellence in adhesion ability, boiling water resistance and flexibility. However, a problem of rubbing after the boiling was found out to be overcome.

• 한국전기전자재료학회논문지
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• 제15권6호
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• pp.524-528
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• 2002

Conventional hybrid aligned nematic liquid crystal display (HAN-LCD) has several advantages on low operating voltage, fast response time and rubbing free on one substrate. We have fabricated a new hybrid aligned nematic display driven by fringe field. The new device exhibits much wider viewing: angle than that of the conventional HAN mode, owing to almost in-plane rotation of the LC director. Furthermore, we have developed the device that reveals more efficient electro-optic characteristics by placing common electrode on top and bottom substrates. In this paper, the electro-optic characteristics of the novel cell are investigated.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 하계학술대회 논문집 Vol.3 No.2
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• pp.945-948
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• 2002

We studied electro-optical (EO) performances of a vertical-alignment (VA)-in plane switching (IPS) cell on a photopolymer surfaces. The VA-IPS cell, dark in voltage-off state, reveals bright uniformity in all directions due to the dual domainlike dierector configuration in the voltage-on state. For voltage-transmittance (V-T) measurement, the transmittance characteristics of the VA-IPS cell on the photopolymer surface was better than that of the VA-IPS cell on a polyimide(PI) surface.

• 한국전기전자재료학회논문지
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• 제26권9호
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• pp.677-681
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• 2013

Apart from the deposition of alignment layer, alignment process needs to be involved for alignment of liquid crystal (LC) molecules. To simplify manufacturing process, several method were used such as rubbing, ion-beam irradiation, UV irradiation, and lithography. But, eventually it needs another treatment for LC alignment. Here, we suggested Si induced polyimide (PI) alignment layer at low temperature. Using this method, we are able to eliminate the alignment process and found that the alignment and electro-optic performance are much better than that of the rubbed PI LC cells. Compared to the rubbed PI cells, the response time was decreased by 70% and C-V characteristics have hysteresis-free.

• Journal of Mechanical Science and Technology
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• 제15권12호
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• pp.1630-1638
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• 2001

Partial rotor rub occurs when an obstacle on the stator of a rotating machinery disturbs the free whirling motion of the rotor, which is more common than full annular rub among the cases of rubbing in rotating machinery. The intermittent contacts and friction during partial rotor rub makes the phenomenon complex. The several nonlinear phenomena of superharmonics, subharmonics, and jump phenomenon are demonstrated for the partial rub using an experimental apparatus in this study. The orbit patterns are also measured experimentally. In order to explain the phenomena of partial rotor rub, the analytical model for the contact between the rotor and stator should be chosen carefully. In this respect, a piecewise-linear model and a rebound model using the coefficient of restitution are investigated on the basis of the experimental observations. Also, Numerical simulations for the two models of contact are done for the various system parameters of clearance, contact stiffness, and friction coefficient. The results show that the piecewise-linear model for partial rotor rub is more plausible to explain the experimental observgations.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2001년도 춘계학술대회논문집
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• pp.277-282
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• 2001

Partial rotor rub occurs when an obstacle on the stator of a rotating machinery disturbs the free whirling motion of a rotor, which is more common than full annular rub for the cases of rubbing in rotating machinery. The nonlinearity due to the intermittent contacts and friction during partial rotor rub makes the phenomenon complex. The several nonlinear phenomena of superharmonics, subharmonics, and jump phenomenon are demonstrated for the partial rub using an experimental apparatus in this study. A piecewise-linear model and a rebound model using the coefficient of restitution are investigated on the basis of experimental observations in order to adopt as an analytical model of the contact between the rotor and stator during whirling motion. The contact stiffness, coefficient of restitution, and friction coefficient for the contact during partial rub are calculated from the comparison between the numerical simulation and the experimental results. Also, the numerical simulations for the model of partial rub are done for the various system parameters of clearance, contact stiffness, and friction coefficient in order to find the nonlinear behavior of partial rotor rub.

• E2M - 전기 전자와 첨단 소재
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• 제10권10호
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• pp.1011-1015
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• 1997

In this paper we investigated the electro-optical characteristics of amorphous (a)- twisted nematic (TN)-liquid crystal display(LCD) on polymide (PI) surfaces with different molecular structure. It was found that the domaine size of a-TN-LCD on PI with high polarization is small compared to a-TN-LCD on PI with medium polarization. It is considered that the response time of a-TN-LCd contributes to surface effect between the substrate surfaces and the LC molecules. Finally we obtained that the viewing angle of a-TN-LCD on PI surfaces increases with decreasing the domain size.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1998년도 춘계학술대회 논문집
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• pp.109-112
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• 1998

In this paper, we studied on electro-optical (EO) characteristics of photo-aligned twisted nematic (TN)-LCD. We obtained that uniform LC alignment in TN-LCD with linearly polarized ultraviolet (LPUV) light irradiation on polyimide (PI) surface increases according to increasing irradiation time for 10 to 60 min. The voltage-transmittance and response time characteristics of photo-aligned TN-LCD with UV light irradiation time of 60 min were almost same in comparison with conventional TN-LCD were observed. From the results, we suggest that photo-aligned TN-LCD with LPUV light irradiation on PI surface is useful in applying LCD as for rubbing-free treatment method.