• Macromolecular Research
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• 제9권2호
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• pp.122-128
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• 2001

Monodisperse composite latex particles with size of ca. 300 nm, which consist ofn-butyl acrylate as a soft phase and methyl methacrylate as a hard phase with different morphology, were synthesized by seeded multi-stage emulsion polymerization. Three types of composite latex particles including random-, core/shell-, and gradient-type particles were obtained by using different monomer feeding methods during semi-batch emulsion polymerization. Effect of poly(butyl acrylate)-poly(methyl methacrylate) rubber particle morphology on the mechanical and rheological properties of rubber toughened poly(methyl methacrylate) was investigated. Among three different rubber particles, the gradient-type rubber particle showed better toughening effect than others. No significant variation of rheological property of poly(methyl methacrylate)/rubber blends was observed for the different rubber particle morphology.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1996년도 가을 학술발표회 논문집
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• pp.51-57
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• 1996

The purpose of this study is to improve the properties by increasing of the adhesion strength of styrene-butadiene rubber(SBR) latex coated powdered rubber in cement mortar. SBR-modified mortar using powdered rubber is also tested as the same method. From the test results, the cement mortar using SBR latex coated powdered rubber have a good mechanical properties compared with that using uncoated powdered rubber. The mechanical properties of SBR-modified mortar using powdered rubber with polymer-cement ratios of 10% are also improved.

• 콘크리트학회지
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• 제8권6호
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• pp.163-172
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• 1996

최근 많은 양의 폐타이어가 발생됨에 따라 사회적 문제로 대두되고 있는 실정이며, 이에 대한 재활용은 각 분야에서 활발하게 연구되고 있다. 건설 분야에서는 폐타이어를 냉각 분쇄하여 만든 분말을 시멘트 콘크리트에 혼입하여 사용하는 연구가 많이 수행되고 있다. 시멘트 콘크리트에 폐타이어 분말을 혼입하여 사용할 때는 폐타이어 분말과 시멘트경화체 사이에서 접착성의 문제로 기초적 성질이 저감된다. 본 연구에서는 시멘트 모르터 내부에서 폐타이어 분말의 접착력을 증진시키기 위하여 시멘트 혼화용 폴리머 중의 하나인 스티렌 부타디엔 고무(SBR)라텍스를 사용하여 기초적 성질을 개선하고자 하였다. 실험결과 SBR 코팅 폐타이어 분말을 혼입한 시멘트 모르터는 코팅하지 않은 폐타이어 분말을 사용한 경우보다 기초적 성질이 개선되는 것으로 나타났으며, 또한 폴리머 시멘트비 10%를 사용한 SBR 라텍스 혼입 폴리머 시멘트 모르터의 경우에도 기초적 성질이 개선되었다.

• 반도체디스플레이기술학회지
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• 제16권1호
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• pp.52-58
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• 2017

Graphene oxide (GO)/carboxylated styrene-butadiene rubber (XSBR) nanocomposites with various contents of GO were prepared by a latex compounding method. It has been confirmed that the functional groups of GO and the hydrogen bonds between GO and XSBR are existed. It can be seen that the scorch time ($t_{s2}$), which is the measurement of incipient vulcanization of rubber, showed a delay after the addition of GO. Field emission scanning electron microscopy was employed to confirm the uniform dispersion of filler in the matrix. Indeed, with increasing fillers loading, the torque, tensile strength, thermal stability and crosslink density of obtained nanocomposites were improved. These results were correlated to the better dispersion of fillers through the rubber matrix.

• Elastomers and Composites
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• 제55권3호
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• pp.199-204
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• 2020

Considering the immense applicability of isoprene rubbers, such as natural rubber (NR) and synthetic polyisoprene rubber (IR), attempts are being made to introduce more functionality within the rubber structure, e.g. epoxidation, to widen their technological viability. Epoxidation introduces polar epoxy bonds into the rubber molecular chain, resulting in enhanced intermolecular interactions among the rubber chains, increasing the oil resistance and air impermeability. Although there have been many reports on the epoxidation of NR in its latex form, there has been no such report using its solid form (or gum), which limits the epoxidation in terms of portability. Furthermore, the gum form has longer lifetime, while the latex form has limited lifetime for its efficient use. In this study, the epoxidation of natural rubber and polyisoprene rubber (using meta-chloroperoxybenzoic acid (mCPBA) as the epoxidizing agent) by dissolving their gum in hexane (i.e., the solution method) have been studied and compared. The effects of the amount of mCPBA, reaction time, and reaction temperature were investigated. The present process is easy and facilitates the epoxidation of rubbers in their solid form; therefore, it can be used for industrial upscaling of epoxidized rubber production.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1991년도 가을 학술발표회 논문집
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• pp.99-106
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• 1991

Result of an experimental study on the manufacture, the mechanical properties and waterightness of pitch-based carbon fiber reinforced fly ash.cement composites are presented in this paper. The carbon fiber reinforced fly ash.cement composites using early strength cement, silica powder and a small amount of stylene butadiene rubber latex are prepared with carbon fiber, foaming agents and mixing conditions. As a result, the mechanical and plysical properties such as compresive, tensile and flectural strengths, watertightness and cement composites are improved by using a small amount of stylene butadiene rubber latex.

• Elastomers and Composites
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• 제39권4호
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• pp.301-308
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• 2004

라텍스 고무의 기계적 성질과 생체적합성 등의 표면특성을 개선하기 위하여 3가지 종류의 패럴린(PA-N, PA-C 및 PA-D)을 라텍스 고무 표면에 증착하였다. 패럴린 증착은 화학기상증착법(chemical vaper deposition)법을 이용하였으며, 증착필름의 표면특성을 조사하였다. 증착 후 열처리에 의한 증착 필름의 기계적 성질 변화를 조사하였다. 패럴린 증착 필름과 라텍스 고무와의 접착력은 PA-C와 PA-D 모두 우수하였다. 열처리 온도가 증가함에 따라 PA-N의 경우는 접촉각이 커져 보다 소수성 쪽으로 변화는 경향을 보였으며, PA-C와 PA-D는 친수성에 가까운 쪽으로 변화하였다. 열처리 온도가 증가할수록 인장강도는 증가하고 연신율은 감소하였다. CVD법으로 증착된 패럴린 박막은 우수한 생체적합성을 나타내었다.

• Elastomers and Composites
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• 제33권2호
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• pp.83-92
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• 1998

SBR latex, polyurethane latex and epoxy latex were mixed with polyvinyl acetate emulsion in 0~15% (wt.%). For the mixtures, the viscous properties were examined. The viscosity was influenced by the dispersed phase and the chain structures of polymer, and decreased with the rising of temperatures. The viscosity was increased with mixing of epoxy latex, but decreased with addition of SBR latex or polyurethane latex. Thixotropic index was influenced on the size of micelle and hydrogen bond. The thixotropic index was increased with mixing of epoxy latex or polyurethane latex within 5%, but keep up equality over that. The thixotropic index was decreased with mixing of SBR latex within 5%, but keep up equality over that. The relative viscosity were influenced on the activity of molecule and the interference of dispersed phases, was increased with the rising of temperatures. The relative viscosity was decreased with mixing of epoxy latex, but increased with mixing of SBR latex or polyurethane latex.

• Elastomers and Composites
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• 제32권4호
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• pp.276-283
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• 1997

• Elastomers and Composites
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• 제19권3호
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• pp.178-193
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• 1984