• 제목/요약/키워드: room-temperature curing

검색결과 139건 처리시간 0.023초

Viscoelastic Properties of MF/PVAc Hybrid Resins as Adhesive for Engineered Flooring by Dynamic Mechanical Thermal Analysis

  • Kim, Sumin;Kim, Hyun-Joong;Yang, Han-Seung
    • Journal of the Korean Wood Science and Technology
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    • 제34권2호
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    • pp.37-45
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    • 2006
  • The viscoelastic properties of blends of melamine-formaldehyde (MF) resin and poly(vinyl acetate) (PVAc) for engineered flooring used on the Korean traditional ONDOL house floor heating system were investigated by dynamic mechanical thermal analysis (DMTA). Because MF resin is a thermosetting adhesive, the effect of MF rein was shown across all thermal behaviors. The addition of PVAc reduced the curing temperature. The DMTA thermogram of MF resin showed that the storage modulus (E') increased as the temperature was further increased as a result of the cross-linking induced by the curing reaction of the resin. The storage modulus (E') of MF resin increased both as a function of increasing temperature and with increasing heating rate. From isothermal DMTA results, peak $T_{tan{\delta}}$ values, maximum value of loss modulus (E") and the rigidities (${\Delta}E$) of MF/PVAc blends at room temperature as a function of open time, peak $T_{tan{\delta}}$ and maximum loss modulus (E") values were found to increase with blend MF content. Moreover, the rigidities of the 70:30 and 50:50 MF/PVAc blends were higher than those of the other blends, especially of 100% PVAc or MF. We concluded that blends the MF/PVAc blend ratios correlate during the adhesion process.

비닐하우스를 이용한 양파의 상온 저장 중 품질 변화 (Changes in Onion (Allium cepa L.) Bulb Quality during Storage at Room Temperature and Greenhouse)

  • 고은영;홍세진;금영수;박세원
    • 한국자원식물학회지
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    • 제25권5호
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    • pp.591-595
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    • 2012
  • 온실을 이용한 상온 저장시설의 실용화 가능성을 예측해보고 '창녕대고'와 '터보' 양파의 저장성을 비교해 보고자 3개월간 저온과 상온조건에서 품질변화를 조사하였다. 중량 감소율은 저장기간 동안 지속적으로 증가하였으며 저온저장시 3개월 후 약 2% 정도 감소하였고 상온저장의 경우 약 4% 감소를 나타내었다. 저장 전후의 경도를 비교한 결과 저장 조건 및 품종 간에 따른 유의한 차이는 인정되지 않았으나 수확직후의 경도에 비해 3개월 저장 후 경도가 두 품종 모두 감소하는 경향을 나타내었다. 양파 외피의 착색정도를 나타내는 Hunter a 값은 두 품종 모두 상온저장한 양파가 저온저장 처리에 비해 높은 값을 나타내었으며 이는 상온저장한 양파의 외피가 건조되면서 착색된 것으로 사료된다. Hunter L 값은 저장조건에 관계없이 저장일수에 따라 감소하는 경향을 나타내었다. 부패율은 상온저장시 창녕대고에 비해 터보 품종이 7.8%로 현저히 낮았으며, 저온 저장시 두 품종 모두 2% 미만의 부패율을 나타났다. 따라서 온실을 이용하여 상온저장 할 경우 저장 가능기간으로는 3개월 이내가 적당할 것으로 예측되며 저장성이 강한 품종을 이용할 경우 저장기간을 더 연장할 수 있을 것으로 판단된다.

Effect of Electron Beam and ${\gamma}$-Ray Irradiation on the Curing of Epoxy Resin

  • Kang, Phil-Hyun;Park, Jong-Seok;Nho, Young-Chang
    • Macromolecular Research
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    • 제10권6호
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    • pp.332-338
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    • 2002
  • The effect of an electron beam and ${\gamma}$-ray irradiation on the curing of epoxy resins was investigated. Diglycidyl ether of bisphenol A (DGEBA) and diglycidyl ether of bisphenol F (DGEBF) as epoxy resin were used. The epoxy resins containing 1.0-3.() wt% of triarylsulphonium hexafluoroantimonate(TASHFA) and triarylsulphonium hexafluorophosphate(TASHFP) as initiator were irradiated under nitrogen at room temperature with different dosage of EB and ${\gamma}$-rays from a Co$^{60}$ u source. The chemical and mechanical characteristics of irradiated epoxy resins were compared after curing of EB and ${\gamma}$-ray irradiation. The thermal properties of cured epoxy were investigated using dynamic mechanical thermal analysis. The chemical structures of cured epoxy were characterized using near infrared spectroscopy. Mechanical properties such as flexural strength, modulus were measured. The gel fraction of DGEBA with ${\gamma}$-ray was higher than that of the epoxy with EB at the same dose. Young's modulus of the sample irradiated by ${\gamma}$-ray is higher than that of sample cured by EB. From the result of strain at yield, it was found that the epoxy cured by ${\gamma}$-ray had a higher stiff property compared with the irradiated by EB.

유리섬유 / 탄소섬유 강화 비대칭 하이브리드 복합재료의 스프링 백 (Spring-back in GFR / CFR Unsymmetric Hybrid Composite Materials)

  • 정우균;안성훈;원명식
    • Composites Research
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    • 제18권6호
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    • pp.1-8
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    • 2005
  • 섬유강화 복합재료는 우수한 기계적, 전자기적 물성 등으로 다양한 분야에서 응용되고 있다. 열경화성 복합재는 제작공정에서의 성형온도와 제품의 운용온도인 상온간의 온도차이로 형상의 변형(스프링 백)이 발생하게 된다. 이러한 스프링 백은 하이브리드 구조의 정밀한 형상 제작을 위해서 반드시 보정되어야할 부분이다. 본 연구에서는 유리섬유/에폭시 복합재와 카본섬유/에폭시 복합재로 구성된 비대칭 하이브리드 복합재를 경화사이클, 적층두께, 적층방법 등 다양한 조건을 적용하여 제작하고 3차원 좌표측정기를 이용하여 스프링 백을 측정하였다. 또한 고전 적층판 이론(CLT)과 유한요소해석(ANSYS)으로 스프링백을 예측하고 실험결과와 비교하였다. 고전 적층판 이론과 유한요소해석으로 예측된 스프링 백은 실험 결과와 잘 일치하였으며, 성형온도가 낮을수록 스프링 백이 감소되는 경향을 보임을 확인하였으나 근원적으로 스프링 백이 제거되지는 않았다.

알칼리 활성화 알루미노실리케이트계 경화체의 고온 열화 특성 (Degradation Propeties of Alkali-Activated Alumino-Silicate Composite Body Exposed to High Temperature)

  • 김원기;김홍주;이승헌
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2005년도 추계 학술발표회 제17권2호
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    • pp.627-630
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    • 2005
  • This paper examines degradation properties of alkali-activated alumino-silicate composite body by NAS solution exposed to high temperature. Activators include sodium hydroxides and sodium silicate solution. In the result of experiment, flexural and compressive strength of AAS base mortar exposed to high temperature ($400\~600^{\circ}C$) was higher than alumina cement base mortar. Particularly, In case of compressive strength, alumina cement base mortar was decreased by about $60\~70\%$. While, AAS base mortar exposed to high temperature ($400\~600^{\circ}C$) was higher than that curing by room temperature. The above results showed that AAS base inorganic binder has a good mechanical properties exposed to high temperature($400\~600$).

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VDPM을 이용한 PMBA/4,4-DDE polyimide의 제작과 전기적특성 (Fabrication and Electric characteristics of PMDA/4,4-DDE Polyimide by Vapor Deposition Polymerization(VDP) Method)

  • 김형권;우호환;김종석;한상옥;이덕출
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1995년도 추계학술대회 논문집
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    • pp.139-142
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    • 1995
  • Polyimide(PI) thin films are fabricated by vapor deposition polymerization(VDP) from PMDA and DDE. The IR spectrum show that PAA the films are changed into PI films by curing. The activation energy of PI films is estimated to be 0.32 [eV] at the electric field of 0.133 [Mv/cm]. The resistivity is about 4.5${\times}$10$\_$16/ [$\Omega$$.$cm] at room temperature.

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간이 큐어링 설비를 이용한 큐어링 처리가 장기간 저장 중 고구마의 품질 개선에 미치는 영향 (Application of Simplified Curing Unit for the Extension of Storage Life and Improvement of Physicochemical Quality of Sweet Potatoes during Long-term Storage)

  • 송정화;김성겸;전창후
    • 생물환경조절학회지
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    • 제20권4호
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    • pp.304-310
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    • 2011
  • 본 연구는 기존의 농가 보급형 고구마 저장고에 가열기(본체), 환기팬, 배풍구 팬, 습도 조절을 위한 관으로 구성된 간이 큐어링 설비를 부가시킨 후, 그 효과를 검증하기 위하여 수행되었다. 6일간의 큐어링 처리 기간 동안 저장고 내 기온 및 상대습도는 $32^{\circ}C$, 90%로 설정되었다. 고구마의 저장 기간(6 개월) 동안 1개월에 1회씩 표본을 수집하여 물리화학적 품질을 측정한 결과, 부패율과 부패 정도를 함께 보여주는 McKinney Index는 큐어링 처리구의 경우 0.83%였으며, 큐어링 처리를 하지 않은 대조구의 경우 5.08%였다. 큐어링 처리구의 경도 및 당도, 건물율은 모두 대조구보다 높았으며, 대조구의 표피색이 큐어링 처리구보다 빠르게 변하여 큐어링 처리가 저장기간 동안 고구마의 변색을 지연시켰음을 알 수 있었다. 본 연구를 통하여 간이 큐어링 설비를 이용한 큐어링 처리는 초기 비용이 많이 소모되는 일반 큐어링 설비를 대체하여 고구마의 물리화학적 품질을 증진시킬 수 있으며, 저장 기간을 늘릴 수 있음을 알 수 있었다.

Laboratory investigation for engineering properties of sodium alginate treated clay

  • Cheng, Zhanbo;Geng, Xueyu
    • Structural Engineering and Mechanics
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    • 제84권4호
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    • pp.465-477
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    • 2022
  • The formation of biopolymer-soil matrices mainly depends on biopolymer type and concentration, soil type, pore fluid and phase transfer to influence its strengthening efficiency. In this study, the physical and mechanical properties of sodium alginate (SA) treated kaolinite are investigated through compaction test, thread rolling teat, fall cone test and unconfined compression test with considering biopolymer concentration, curing time, initial water content, mixing method. The results show that the liquid limit slightly decreases from 69.9% to 68.3% at 0.2% SA and then gradually increases to 98.3% at 5% SA. At hydrated condition, the unconfined compressive strength (UCS) of SA treated clay at 0.5%, 1%, 2% and 3% concentrations is 2.57, 4.5, 7.1 and 5.48 times of untreated clay (15.7 kPa) at the same initial water content. In addition, the optimum biopolymer concentration, curing time, mixing method and initial water content can be regarded as 2%, 28 days, room temperature water-dry mixing (RD), 50%-55% to achieve the maximum unconfined compressive strength, which corresponds to the UCS increment of 593%, compared to the maximum UCS of untreated clay (780 kPa).

Ca(OH)2와 전구체의 화학 조성이 고속경화 지오폴리머의 물성에 미치는 영향 (Effects of Chemical Composition of Ca(OH)2 and Precursors on the Properties of Fast-Curing Geopolymers)

  • 고현석;노정영;임형미
    • 한국재료학회지
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    • 제29권11호
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    • pp.690-696
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    • 2019
  • Geopolymer is an alumina silicate-based ceramic material that has good heat-resistance and fire-resistance; it can be cured at room temperature, and thus its manufacturing process is simple. Geopolymer can be used as a reinforcement or floor finish for high-speed curing applications. In this manuscript, we investigate a high-speed curing geopolymer achieved by adding calcium to augment the curing rate. Metakaolin is used as the main raw material, and aqueous solutions of KOH and $K_2SiO_3$ are used as the activators. As a result of optimizing the high bending strength as a target factor for geopolymers with $SiO_2/Al_2O_3$ ratio of 4.1 ~ 4.8, the optimum ranges of the active agent are found to be $0.1{\leq}K_2O/SiO_2{\leq}0.4$ and $10{\leq}H_2O/K_2O{\leq}32.5$, and the optimum range of the curing accelerator is found to be $$0.82{\leq_-}Ca(OH)_2/Al_2O_3{\leq_-}2.87$$. The maximum flexural strength is found to be 1.35 MPa at $Ca(OH)_2/Al_2O_3=2.82$, $K_2O/SiO_2=0.3$, and $H_2O/K_2O=11.3$. The physical and thermal properties are analyzed to validate the applicability of these materials as industrial insulating parts or repairing finishing materials in construction.

Acetoacetoxy기 함유 아크릴수지와 HDI-Trimer에 의한 하이솔리드 도료의 도막물성 (Physical Properties of High-Solid Coatings with Acrylic Resins Containing Acetoacetoxy Group and HDI-Trimer)

  • 유혁재;정동진;함현식;박홍수;김성길
    • 한국응용과학기술학회지
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    • 제20권3호
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    • pp.237-242
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    • 2003
  • The high-solid coatings were prepared by blending the synthesized acrylic resin in the previous paper and hexamethylene diisocyanate-trimer and curing it at room temperature. The characterization of the films of the prepared coatings was performed. The impact resistance, $60^{\circ}C$ specular gloss, cross-hatch adhension, and heat resistance of the films proved to be good, and the pencil hardness and drying time proved to be slightly poor. Especially, there was a remarkable improvement in the heat resistance. This improvement may stem from the regular arrangement of ethyl groups introduced into the acrylic resin. From a viscoelastic measurement using a rigid-body pendulum, curing was accelerated with the $T_g$ value. With the increase in $T_g$, log damp value was lowered and dynamic viscoelasic $T_g$ of a cured film was increased.