• Title/Summary/Keyword: rock salt

Search Result 85, Processing Time 0.032 seconds

Growth and Optical Properties of PbSnSe Epilayers Grown on BaF2(111) (PbSnSe 단결정 박막의 성장과 광학적 특성)

  • Lee, Il-Hoon
    • Journal of Korean Ophthalmic Optics Society
    • /
    • v.9 no.1
    • /
    • pp.35-41
    • /
    • 2004
  • This study investigated the crystal growth, crystalline structure and the basic optical properties of $PbSnSe/BaF_2$ epilayers. The PbSnSe epilayer was grown on $BaF_2$(111) insulating substrates using a hot wall epitaxy (HWE) technique. It was found from the analysis of X-ray diffraction patterns that $PbSnSe/BaF_2$ epilayer was grown single crystal with a rock-salt structure oriented along [111] the growth direction. Using Rutherford back scattering, the atomic ratios of the PbSnSe was found to be proper stoichiometric. The best values for the full width at half maximum (FWHM) of the DCXRD was 162 arcsec for PbSnSe epilayer. The epilayer-thickness dependence of the FWHM of the DCXRD shows that the quality of the $PbSnSe/BaF_2$ is as expected. The dielectric function ${\varepsilon}(E)$ of a semiconductor is closely related to its electronic energy band structure and such relation can be drawn from features around the critical points(CPs) in the optical spectra. The real and imaginary parts(${\varepsilon}1$ and ${\varepsilon}2$) of the dielectric function ${\varepsilon}$ of PbSe were measured, and the observed spectra reveal distinct structures at energies of the E1, E2 and E3 CPs. These data are analyzed using a theoretical model known as the model dielectric function (MDF). The optical constants related to dielectric function such as the complex refractive index ($n^*=n+ik$), absorption coefficient (${\alpha}$) and normal-incidence reflectivity (R) are also presented for $PbSnSe/BaF_2$.

  • PDF

Energy Band Structure, Electronic and Optical properties of Transparent Conducting Nickel Oxide Thin Films on $SiO_2$/Si substrate

  • Denny, Yus Rama;Lee, Sang-Su;Lee, Kang-Il;Lee, Sun-Young;Kang, Hee-Jae;Heo, Sung;Chung, Jae-Gwan;Lee, Jae-Cheol
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2012.02a
    • /
    • pp.347-347
    • /
    • 2012
  • Nickel Oxide (NiO) is a transition metal oxide of the rock salt structure that has a wide band gap of 3.5 eV. It has a variety of specialized applications due to its excellent chemical stability, optical, electrical and magnetic properties. In this study, we concentrated on the application of NiO thin film for transparent conducting oxide. The energy band structure, electronic and optical properties of Nickel Oxide (NiO) thin films grown on Si by using electron beam evaporation were investigated by X-Ray Photoelectron Spectroscopy (XPS), Reflection Electron Energy Loss Spectroscopy (REELS), and UV-Spectrometer. The band gap of NiO thin films determined by REELS spectra was 3.53 eV for the primary energies of 1.5 keV. The valence-band offset (VBO) of NiO thin films investigated by XPS was 3.88 eV and the conduction-band offset (CBO) was 1.59 eV. The UV-spectra analysis showed that the optical transmittance of the NiO thin film was 84% in the visible light region within an error of ${\pm}1%$ and the optical band gap for indirect band gap was 3.53 eV which is well agreement with estimated by REELS. The dielectric function was determined using the REELS spectra in conjunction with the Quantitative Analysis of Electron Energy Loss Spectra (QUEELS)-${\varepsilon}({\kappa},{\omega})$-REELS software. The Energy Loss Function (ELF) appeared at 4.8, 8.2, 22.5, 38.6, and 67.0 eV. The results are in good agreement with the previous study [1]. The transmission coefficient of NiO thin films calculated by QUEELS-REELS was 85% in the visible region, we confirmed that the optical transmittance values obtained with UV-Spectrometer is the same as that of estimated from QUEELS-${\varepsilon}({\kappa},{\omega})$-REELS within uncertainty. The inelastic mean free path (IMFP) estimated from QUEELS-${\varepsilon}({\kappa},{\omega})$-REELS is consistent with the IMFP values determined by the Tanuma-Powell Penn (TPP2M) formula [2]. Our results showed that the IMFP of NiO thin films was increased with increasing primary energies. The quantitative analysis of REELS provides us with a straightforward way to determine the electronic and optical properties of transparent thin film materials.

  • PDF

Magnetic Properties of Cr Substituted SiTe Compounds (SiTe에 Cr을 치환한 화합물의 자기적 성질)

  • Landge, Kalpana;Bialek, Beata;Lee, Jae-Il
    • Journal of the Korean Magnetics Society
    • /
    • v.21 no.4
    • /
    • pp.127-131
    • /
    • 2011
  • In this paper, we study the electronic and magnetic properties of Cr substituted SiTe in the rock-salt structure compound using the full potential linearized augmented plane wave method within the generalized gradient approximation to the exchange correlation potential. Two stoichiometries are studied: $CrSi_3Te_4$ with 25 %, and $CrSiTe_2$ with 50 % Cr substitution. We found, from the total energy calculations, that the equilibrium lattice constant for cubic $CrSi_3Te_4$ is 11.64 a.u. and a = 7.89 a.u. and c = 11.13 a.u. for tetragonal $CrSiTe_2$. The integer value of the calculated magnetic moment per unit cell, $4{\mu}_B$ for $CrSiTe_2$ suggests that this compound is halfmetallic. The magnetic moment per unit cell for $CrSi_3Te_4$ is slightly larger than $4{\mu}_B$. The magnetic moment on Cr atoms are 3.61 and $3.62{\mu}_B$ in the $CrSi_3Te_4$ and $CrSiTe_2$, respectively. The presence of Cr atoms causes that the other atoms become slightly magnetized in both compounds. The electronic properties and the magnetism are discussed with the calculated spin-polarized density of states.

The Innovative Strategy on the Activation of Marine Tourism in Busan (부산의 해상관광활성화에 관한 혁신적 전략(1))

  • Kim, Jae-Gwan
    • Journal of the Korean association of regional geographers
    • /
    • v.13 no.2
    • /
    • pp.156-170
    • /
    • 2007
  • The commerce and industry of Busan was developed because of good geographical conditions with harbor. After passing its settling-down and diffusing time, Busan has grown in the trade city. Busan has lost the competitive power of the port city since 2000, because of the weakness of its economic power which is caused by the secession of manufacturing industry and the decrease of resident population and foreign tourist. In order to overcome these weaknesses, it is necessary for Busan to take the innovative strategy for the activation of marine tourism. This goal can be achieved by the strong quality of the port city, the coastal terrain, the traditional industry and the international traffic. The aim of this paper is to explore the Innovative Strategy for the activation of marine tourism in Busan and to suggest the following proposal. First, the government must decide the base of marine tourism under the geography viewpoint of the coast and sea, and develope tourism resources after analyzing the identity of marine tourism base. Second, the core part along the selected bases of marine tourism must be constructed the tourism terminal as the landmark of Busan in order to concentrate foreign tourist. Third, after each base of marine tourism must become the resort for tourists, they are able to experience the activity of marine tourism in this resort. Therefore, each base must be specialized. Fourth, each base must be connected with the route of marine tourism Fifth, in order to overcome the off-season of marine tourism, winter tourism goods such as skates, skis, artificial sea-bathing pool, artificial swimming beach, artificial sled, artificial rock wall of coast, hot spring resort of salt water are required to be developed in the center of marine tourism base.

  • PDF

Analysis on Material Characteristics of Restored Areas with Mortar and Basis of Surface Deterioration on the Stupa of State Preceptor Jigwang from Beopchensaji Temple Site in Wonju, Korea (원주 법천사지 지광국사탑 복원부 모르타르 재료학적 특징 및 표면손상 기초 해석)

  • Chae, Seung A;Cho, Ha Jin;Lee, Tae Jong
    • Journal of Conservation Science
    • /
    • v.37 no.5
    • /
    • pp.411-425
    • /
    • 2021
  • The Stupa of State Preceptor Jigwang from Beopcheonsa Temple Site in Wonju (National Treasure) is a representative stupa of the Goryeo Dynasty, with outstanding Buddhist carvings and splendid patterns, clearly indicating its honoree and year of construction. However, it was destroyed by bombing during the Korean War (1950-1953) and repaired and restored with cement and reinforcing bars in 1957. The surface condition of the original stone shows long-term deterioration due to the m ortar used in past restorations. In order to identify the exact causes of deterioration, the m ortar and surface contaminants on the original stone were analyzed. Portlandite, calcite, ettringite, and gypsum from the mortar were identified, and its ongoing deterioration was observed through pH measurements and the neutralization reaction test. Analysis of surface contaminants identified calcite and gypsum, both poorly water-soluble substances, and their growth in volume among rock-forming minerals was observed by microscopy. Based on those results, semi-quantitative analysis of Ca and S contents significantly influencing the formation of salt crystals was conducted using P-XRF to analyze the basis of surface deterioration, and cross-validation was performed by comparing the body stone affected by the mortar and the upper stylobate stone unaffected by the mortar. Results indicate that the elements are directly involved in the surface deterioration of the body stone.

A Study on the Semiotics and Poetic Meaning of Literature Content - at the Center of Moon Sam­seok's Children's Poetry - (문학콘텐츠의 기호학적 시적의미 연구 -문삼석의 동시(童詩)를 중심으로-)

  • Sung, Hyun-Ju
    • The Journal of the Korea Contents Association
    • /
    • v.19 no.6
    • /
    • pp.72-79
    • /
    • 2019
  • This study tries to study the poetic beauty of the space deconstructed by the medium appearing in Moon Sam-seok's children's poetry to help with simultaneous education and guiding methodology. The research method is based on the assumption that semiotics spatial image is read. In other words, we intend to derive the poetic beauty of the space in which the great pole space built by is deconstructed by the intervention of by the medium term . Among Moon Sam-seok's series of works, the research text is "The Wind and the Fire," "The Wind and the Empty Bottle," "The Wind and Salt," "The Wind and the Rock." According to the study, the wind deconstructed a space that was differentiated by the presence or absence of matter into a "coexistence space." These poetic spaces symbolize poetic beauty as ideal places of life that coexist in a distinction but not discrimination. Second, the wind has eliminated the gap between alienation, suffering and solitude. In other words, the wind deconstructed poetic space produced poetic beauty with the 'space of communication' based on homogeneity of the nature of existence. In conclusion, Moon's poetic speech can be seen that he intended to express the discreteness of the poetic space as 'communication' and 'common life' by deconstructing it with deviation and convergence by introducing a medium.

Concentric Structure and Radial Joint System within Basic Lava Flow at the seashore of Aewol, Jeju Island, South Korea (제주도 애월읍 해안의 염기성 용암류에 발달한 동심원 구조와 방사상 절리)

  • Ahn, Kun Sang
    • Journal of the Korean earth science society
    • /
    • v.42 no.2
    • /
    • pp.185-194
    • /
    • 2021
  • A lava dome and sheet lava flow can be observed at the seashore of Aewol, Jeju island. The cylindrical lobes are characterized by a concentric structure consisting of a massive core and radial joints. Columnar joints with different thickness between the upper and lower parts are developed in the sheet lava flow around the rock salt field in Goeomri. The upper part of the columnar joints is uneven in shape, and has a diameter of 120-150 cm. The lower part of the columnar joints is hexagonal and pentagonal in shape, and has a diameter of about 60 cm. The cylindrical lobes can be divided into two groups based on size and shape. One is a megalobe, with a semicircular outline and a maximum diameter of 30 m. The other is a circular lobe with a diameter of less than 10 m. The columns in the radial joints have hexagonal and pentagonal cross sections and gradually increasing diameter, outward from the core, to a size of 80-120 cm at the rim. The concentric structure observed in the cylindrical lavas is attributable to a combination of four factors. The first is a circular crack caused by the decrease of the temperature and density difference between the inside and outside of the cylindrical lava flow. The second is a concentric chisel mark of the radial joints, which formed at the same time as the radial joints. The third is a flow band, which is a trace left in a round passage when lava flows through. The fourth is a vesicular band formed in a cave by gas bubbles escaping from the lava flow.

Morphological Landscape of Patagonia and Atacama in the Andes based on Geotourism (지오투어리즘 관점에서 본 안데스 파타고니아와 아타카마의 지형경관)

  • PARK, Jongkwan
    • Journal of The Geomorphological Association of Korea
    • /
    • v.20 no.4
    • /
    • pp.15-28
    • /
    • 2013
  • This paper was made on the basis of geotourism to explain morphological characteristics of Patagonia and Atacama region in the Andes through 10-day fieldwork. The Patagonian landscape was focused on the Torres del Paine National Park, Chile and the Los Glacier National Park, Argentina; on the other hand, the Atacama morphological landscape was investigated around the San Pedro de Atacama. Many geomorphological features such as uplift, semiarid and glacier landscapes can be found in Patagonia, so it is strongly recommended to have an opportunity to enjoy these landforms by geotourism. Massive intrusive rock bodies of granite can be shown in those two National Parks declared a Biosphere Reserve by UNESCO. And, the Atacama Desert located on the forearc depression in the Andes, Chile has also many geomorphological destinations of arid and volcanic landforms; badland, pediplain, pediment, salt lake and geyser. Especially, huge pediplain is one of the greatest view points in the Atacama Desert. Patagonia and Atacama are the best geographical tourism sites to know diverse tectonic landforms made by the conflict between South American and Pacific plates.

Parametric Study for Seismic Design of Temporary Retaining Structure in a Deep Excavation by Dynamic Numerical Analysis (동적수치해석을 이용한 대심도 흙막이 가시설 내진설계 변수연구)

  • Yang, Eui-Kyu;Yu, Sang-Hwa;Kim, Dongchan;Kim, Jongkwan;Ha, Ik-Soo;Han, Jin-Tae
    • Journal of the Korean Geotechnical Society
    • /
    • v.38 no.12
    • /
    • pp.45-65
    • /
    • 2022
  • In this paper, a diaphragm wall that supports soils and rock was modeled using FLAC, a finite difference analysis program, to evaluate the seismic behavior of temporary retaining structures in a deep excavation. The appropriateness of the numerical model was verified by comparing its results with those of the centrifuge test performed in a similar condition. The bending moment distribution along the diaphragm wall shows a very similar tendency, and the maximum acceleration obtained at the backfill and top of the wall shows a difference within 5%. Based on the developed model, a parametric study was conducted in various input earthquake, ground, and excavation conditions. The maximum structural forces and bending moment under earthquake loading were compared with the maximum values during excavation, from which the critical condition that requires a seismic design was roughly sorted out. The maximum bending moment of a wall that retains soil layers increased 17%. Particularly, the axial force of struts located in loose soils increased 32% under 100 years return period of an earthquake event, which strongly is estimated to require seismic design for structural safety.

Draft List and Relative Importance of Principal Processes in the Geosphere to be Considered for the Radiological Safety Assessment of the Domestic Geological Disposal Facility through Analyzing FEPs for KBS-3 Type Disposal Repository of High-level Radioactive Waste(HLW) (KBS-3 방식 고준위방폐물 심층처분장 FEP 분석을 통한 국내 사용후핵연료 심층처분시설 방사선학적 안전성 평가용 지권영역 주요 프로세스 항목 및 상대적 중요도 도출)

  • Sukhoon Kim;Donghyun Lee;Dong-Keuk Park
    • Journal of Radiation Industry
    • /
    • v.17 no.1
    • /
    • pp.33-44
    • /
    • 2023
  • The deep geological repository of high-level radioactive waste shall be designed to meet the safety objective set in the form of radiation dose or corresponding risk to protect human and the environment from radiation exposure. Engineering feasibility and conformity with the safety objective of the facility conceptual design can be demonstrated by comparing the assessment result using the computational model for scenario(s) describing the radionuclide release and transport from repository to biosphere system. In this study, as the preliminary study for developing the high-level radioactive waste disposal facility in Korea, we reviewed and analyzed the entire list of FEPs and how to handle each FEP from a general point of view, which are selected for the geosphere region in the radiological safety assessment performed for the license application of the KBS-3 type deep geological repository in Finland and Sweden. In Finland, five FEPs (i.e., stress redistribution, creep, stress redistribution, erosion and sedimentation in fractures, methane hydrate formation, and salt exclusion) were excluded or ignored in the radionuclide release and transport assessment. And, in Sweden, six FEPs (i.e., creep, surface weathering and erosion, erosion/sedimentation in fractures, methane hydrate formation, radiation effects (rock and grout), and earth current) were not considered for all time frames and earthquake out of a total of 25 FEPs for the geosphere. Based on these results, an FEP list (draft) for the geosphere was derived, and the relative importance of each item was evaluated for conducting the radiological safety assessment of the domestic deep geological disposal facility. Since most of information on the disposal facility in Korea has not been determined as of now, it is judged that all FEP items presented in Table 3 should be considered for the radiological safety assessment, and the relative importance derived from this study can be used in determining whether to apply each item in the future.